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Equipment: Accumulator

Equipment Code: AC-01


Type: Vessel
Function: Serve as a mixing tank for fresh 98% ethanol feed, recycled ethanol solution from the
fractionators and recycle water stream from extraction column. Exit stream from this equipment
is composed of 10% ethanol solution in water.
Calculation Considerations:
1. Accumulation in the equipment is 0.05%







Calculation:
A + P + K= C + Accumulation
A + P + K = C + 0.005(A + P + K)
Material balance Sheet:
Feed Stream:
Components A P K
Ethanol 5472.061329 474.0244539 0
Water 111.674721 4266.220085 49110.11986
Total 5583.73605 4740.244539 49110.11986

Outgoing Stream:
Components C Accumulation
Ethanol 5943.11274 2.973042892
Water 53461.27066 26.74400733
Total 59404.3834 29.71705022
Fresh Ethanol (A)
5583.73605 kg
To EH-01 (C)
59404.3834 kg
Recycled Water (K)
49110.11986 kg
Recycled Ethanol (P)
4740.244539 kg
Equipment: Electric Heater -01
Equipment Code: EH-01
Type: Screw Plug Immersion Heater
Function: Allows ethanol- water solution to be heated directly without using heat transfer fluid.
EH-01 increases the temperature of the feed from 303.15 K to the temperature requirement for
the reactor which is 453K.
Calculation Considerations:
1. Accumulation in the equipment is 0.05%





Calculation:
C= E + Accumulation
C= E + 0.005C
Material balance Sheet:
Components C E Accumulation
Ethanol 5,943.11274 5,940.141184 2.97155637
Water 53,461.27066 53,434.54002 26.73063533
Total 59,404.3834 59,374.68121 29.7021917



Energy Balance:

Components Molecular Weight
(kg/kmol)
Heat Capacity, C
p

(J/mol-K)
Ethanol 46 112.4
Water 18 75.327

From Accumulator (C)
59404.3834
To Reactor (E)
59374.68121
Q
Feed
Q


Q
Feed
Q
EtOH
Q
Water

Q
EtOH
nCp(T2-T1)
Q
EtOH

Kg
46 kg/kmol

1000 mol
1 kmol
112.4
J
mol-K
(453-303.15) K
Q
EtOH
2,176,101.74 kJ
Q
H2O
nCp(T2-T1)
Q
H2O

53461.2706 Kg
18 kg/kmol

1000 mol
1 kmol
75.327
J
mol-K
(453-303.15) K
Q
H2O
33,525,417.15 kJ
Q
Feed
Q

35,701,518.88 kJ




















Equipment: Electric Heater -02
Equipment Code: EH-02
Type: Screw Plug Immersion Heater
Function: Allows air feed to be heated directly without using heat transfer fluid. EH-01
increases the temperature of the feed from 303.15 K to the temperature requirement for the
reactor which is 453K.
Calculation Considerations:
1. Accumulation in the equipment is 0% since feed is in gas phase.





Calculation:
B= F + Accumulation
B= F + 0.005B
Material balance Sheet:
Component B F Accumulation
Nitrogen 16,322.47491 16,322.47491 0
Oxygen 4,958.726554 4,958.726554 0
Total 21,281.20146 21,281.20146 0




Energy Balance:

Components Molecular Weight
(kg/kmol)
Heat Capacity,
C
p

(J/mol-K)
Nitrogen 28 29.124
Oxygen 32 29.378
From Air Storage (B)
21281.20146
To Reactor (F)
21281.20146
Q
Feed
Q


Q
N2
nCp(T2-T1)
Q
N2

16322.475 Kg
28 kg/kmol

1000 mol
1 kmol
29.124
J
mol-K
(453-303.15) K
Q
N2
2,544,109.20 kJ
Q
O2
nCp(T2-T1)
Q
O2

4958.7266 Kg
32 kg/kmol

1000 mol
1 kmol
29.378
J
mol-K
(453-303.15) K
Q

682,180.27 kJ
Q
Feed
Q

3,226,289.47 kJ






















Equipment: Oxidation Reactor -01
Equipment Code: OR-01
Type: Fixed Bed Reactor
Function: Using 1% by wt. VO
x
/TiO
2
/clay catalyst the reactor is enable to convert 92% of
ethanol to Acetic Acid and Carbon dioxide to a selectivity of 97% and 3% respectively.
Calculation Considerations:
1. Ethanol to reactor is 10% solution in water
2. Accumulation is 0.05%
3. Reaction conversion is 92%
4. Acetic Acid selectivity is 97%
5. Carbon Dioxide selectivity is 3%
6. Per cent excess air is 20%
7. No incomplete combustion






Calculation:
E + F = G + Accumulation
E + F = G + 0.005(E + F)
Material balance Sheet:
Components E F G Accumulation
Ethanol
5940.141184 - 474.9736891 0.237605647
Water
53434.54002 - 55673.44725 27.85064895
Nitrogen
- 16322.47491 16322.47491 -
Oxygen
- 4958.726554 928.9347744 -
Carbon Dioxide
- - 313.6394545 -
Acetic Acid
- - 6910.867176 3.457162169
Total
53434.54002 21281.20146 80624.33725 31.54541677
From EH-01 (E)
59374.68121
To HE-01 (G)
80624.33725
From EH-02 (F)
21281.20146
Reaction:
C
2
H
5
OH + O
2
CH
3
COOH + H
2
O
C
2
H
5
OH + 3O
2
2CO
2
+ 3H
2
O

Acetic Acid
5940.141184 (0.92)kg EtOH
46
kg
kmol
EtOH

.97 mole HAc


1 mole EtOH

60 kg HAc
Kmol HAc

Acetic Acid 6914.324338 kg (w/o accumulation)
Carbon dioxide
5940.141184 (0.92)kg EtOH
46
kg
kmol
EtOH

.03(2) mole CO2


1 mole EtOH

44 kg CO2
Kmol CO2

Carbon dioxide 313.6394545 kg (w/o accumulation)
Water produced
6910.867176 kg HAc
60
kg
kmol
HAc

1 mole water
1 mole HAc

313.6394545 kg
44 kg/mol

3 mole water
2 mole CO2

Water produced 2266.757876 kg
Total water2266.757876 kg 53434.54002 kg
Total water 55701.2979 kg (w/o accumulation)

Oxygen Supplied
5940.141184 kg EtOH
46
kg
kmol
EtOH

1.2 mole O2
1 mole EtOH

32 kg O2
Kmol O2

Oxygen Supplied 4958.726554 kg
Nitrogen Supplied 4958.726554 kg
79 mole N2
21 mole O2
16322.47491 kg
Oxygen Consumed
6910.867176 kg HAc
60
kg
kmol
HAc

1 mol O2
1 mol HAc

313.6394545 kg
44 kg/mol

3 mol O2
2 mol CO2

Oxygen Consumed 4029.791779kg
Oxygen Remained 4958.726554 kg - 4029.791779kg
Oxygen Remained 928.9347744 kg
Energy Balance:
Components Molecular Weight
(kg/kmol)
Heat of Formation, H
f

(KJ/mol)
Acetic Acid 60 -542.33
Carbon Dioxide 44 -2010.52

Q
rxn
Q


Q
rxn
Q
HAc
Q
CO2

Q
HAc

6914.324338 Kg
48Kg/Kmol

1000 mol
1 kmol
-
542.33KJ
mol

1000J
1KJ

Q
HAc
-78,121,781.63 kJ
Q
CO2

313.6395 Kg
44Kg/Kmol

1000 mol
1 kmol
-
2010.52KJ
mol

1000J
1KJ

Q
CO2
-14,331,329.26 kJ
Q
rxn
-92,453,110.89 kJ
Q
HTF
nCp(T2-T1) -92,453,110.89 kJ
Cp
HTF
75.327
J
mol-K

Q
HTF
n 75.327
J
mol-K
(338.15-303.15) K
n 35,067,339 moles
m
HTF
631,212.1042 kg




Equipment: Heat Exchanger -01
Equipment Code: HE-01
Type: Countercurrent, Shell and Tube Heat Exchanger
Function: Allows feed to be cooled by using cooling water at 303.15 K. HE-01 reduces the
temperature of the feed from 453 K to the temperature requirement for the reactor which is
313.15 K.
Calculation Considerations:
1. Accumulation is 0.05% for liquid stream
2. No accumulation for gas stream



Calculation:
G= H + Accumulation
G= H + 0.005(G + H)
Material balance Sheet:
Components G H Accumulation
Ethanol
474.9736891 474.7362022 0.237605647
Water
55673.44725 55645.61052 27.85064895
Nitrogen
16322.47491 16322.47491 0
Oxygen
928.9347744 928.9347744 0
Carbon Dioxide
313.6394545 313.6394545 0
Acetic Acid
6910.867176 6907.411743 3.457162169
Total
80624.33725 80592.8076 31.54541677

Energy Balance:
Components Molecular Weight
(kg/kmol)
Heat Capacity, C
p

(J/mol-K)
Ethanol 46 112.4
From Reactor (G)
80,624.3373 kg
To Flash Drum (H)
80,592.8076 kg
Water 18 75.327
Nitrogen 28 29.124
Oxygen 32 29.378
Carbon Dioxide 44 38.01
Acetic Acid 60 123.1

Q
Ieed
Q
HTF

Q
Ieed
Q
EtOH
Q
H20
Q
N2
Q
O2
Q
CO2
Q
CH3COOH

Q
EtOH
nCp(T2-T1)
Q
EtOH

474.97369 Kg
46 kg/kmol

1000 mol
1 kmol
112.4
J
mol-K
(313.15-453) K
Q
EtOH
-162,308.32 kJ
Q
H2O
nCp(T2-T1)
Q
H2O

55,673.447 Kg
18 kg/kmol

1000 mol
1 kmol
75.327
J
mol-K
(313.15-453) K
Q
H20
-32,582,826.08 kJ
Q
N2
nCp(T2-T1)
Q
N2

16,322.475 Kg
28 kg/kmol

1000 mol
1 kmol
29.124
J
mol-K
(313.15-453) K
Q
N2
-2,374,332.14 kJ
Q
O2
nCp(T2-T1)
Q
O2

928.93477 Kg
32 kg/kmol

1000 mol
1 kmol
29.378
J
mol-K
(313.15-453) K
Q
O2
-119,266.90 kJ


Q
CO2
nCp(T2-T1)
Q
CO2

313.63945 Kg
44 kg/kmol

1000 mol
1 kmol
38.01
J
mol-K
(313.15-453) K
Q
CO2
-37,891.20 kJ
Q
CH3COOH
nCp(T2-T1)
Q
CH3COOH

6910.8672 Kg
60 kg/kmol

1000 mol
1 kmol
123.1
J
mol-K
(313.15-453) K
Q
CH3COOH
-1,982,904.60 kJ
Q
Ieed
-37,259,529.13 kJ
Q
HTF
nCp(T2-T1) -37,259,529.13 kJ
Cp
HTF
75.327
J
mol-K

Q
HTF
n 75.327
J
mol-K
(338.15-303.15) K
n 14,132,488.69 moles
m
HTF
254,384.7964 kg









Equipment: Flash Drum -02
Equipment Code: FD-02
Type: Gas- Liquid Separator w/ mist eliminator and vortex breaker
Function: Separates gas components (oxygen, nitrogen and carbon dioxide) from liquid
components (acetic acid, ethanol and water). The equipment has mist eliminator and vortex
breaker, which enables 99.9999% phase separation. Mist eliminator prevents acetic acid, ethanol
and water vapor from escaping as a gas and the vortex breaker releases dissolved oxygen,
nitrogen and carbon dioxide from liquid components.
Calculation Considerations:
1. 99.9999% separation for gas and liquid phase
2. Accumulation is 0.05% for liquid streams






Calculation:
H= AG +I+ Accumulation
H= AG+I+ 0.005H
Material balance Sheet:
Components H AG I Accumulation
Ethanol
474.7362022 - 474.4988341 0.237605647
Water
55645.61052 - 55617.78772 27.85064895
Nitrogen
16322.47491 16322.45858 - -
Oxygen
928.9347744 928.9338455 - -
Carbon Dioxide
313.6394545 313.6391409 - -
Acetic Acid
6907.411743 - 6903.958037 3.457162169
From HE-01 (H)
80,952.8076 kg
To Reactor (AG)
17,565.0316 kg
From Air Storage (I)
62,996.2446 kg
Total
80592.8076 17565.03157 62996.24459 31.54541677


Equipment: Surge Vessel -01
Equipment Code: SV-01
Type: Vessel
Function: Surge vessel-01 are necessary to reduce fluctuations in flow rate and composition of
the entering stream in the fractionators.
Calculation Considerations:
1. Accumulation is 0.05% for liquid streams






Calculation:
I= J + Accumulation
I= J + 0.005I
Material balance Sheet:
Component I J Accumulation
Ethanol 474.4988341 474.2615847 -
Water 55617.78772 55589.97883 -
Acetic acid 6903.958037 6900.506058 -
Total 62996.24459 62964.74647 -


From Flash Drum (I)
62,996.2446 kg
To Fractionators (J)
62694.7465 kg



Equipment: Fractionators -01
Equipment Code: FR-01
Type: Multi-component Rectifier
Function: Uses the difference in volatility to separate ethanol, water and acetic acid. Ethanol
being more volatile is rich in vapor phase while acetic acid remains in liquid phase.
Calculation Considerations:
1. Base on the initial condition, feed is subcooled.
2. Accumulation is 0.05% for liquid stream
3. No accumulation for gas stream









Calculation:
J + N + R = L + Q + Accumulation
J + N + R = L + Q +0.005J
Material balance Sheet:
Feed Stream:
Components J N R
To CD-01 (L)
5287.742784 kg
To RB-01 (Q)
63480.21498 kg
From RB-01 (R)
5287.742784 kg
From RD-01 (N)
547.2244952 kg
From FR-01 (J)
62694.7465 kg
Ethanol 474.2615847 0 474.0244539
Water 55589.97883 426.4086975 4692.842094
Acetic acid 6900.506058 120.8157976 120.8762358
Total 62694.74647 547.2244952 5287.742784
Outgoing Stream:
Components Q L Accumulation
Ethanol 474.0244539 414.0244539 0.237130792
Water 55988.37933 4692.842094 28.00819376
Acetic acid 7017.811194 120.8762358 3.510660928
Total 63480.21498 5287.742784 31.75598548





















Equipment: Condenser -01
Equipment Code: CD-01
Type: Partial Condenser
Function: Condense acetic acid and excess water contained in the vapor from the fractionators.
The amount of ethanol in water in the vapor phase must be 10% by wt.
Calculation Considerations:
1. Total condenser
2. No accumulation for gas streams





Calculation:
L= M + Accumulation
L= M + 0.005L
Material balance Sheet:
Component L M Accumulation
Ethanol 414.0244539 414.0244539 -
Water 4692.842094 4692.842094 -
Acetic acid 120.8762358 120.8762358 -
Total 5287.742784 5287.742784 -

Energy balance:
Components Molecular Weight
(kg/kmol)
Heat of Vaporization, H
V

(KJ/mol)
Ethanol 48
38.560
From FR-01 (L)
5287.742784 kg
To RD-01 (M)
5287.742784 kg
Water 18
40.680
Acetic Acid 60
23.700
Q
Ieed
Q
water

Q
Ieed
Q
HAc
Q
Water
Q
EtOH

Q
HAc

120.8762358 kg
60Kg/Kmol

1000 mol
1 kmol

23.700 KJ
mol

Q
HAc
47,746.1131 kJ
Q
Water

4692.842094 kg
18Kg/Kmol

1000 mol
1 kmol

40.680KJ
mol

Q
Water
10,605,823.13 kJ
Q
EtOH

474.0244539 kg
48Kg/Kmol

1000 mol
1 kmol

38.560KJ
mol

Q
EtOH
380,799.6446 kJ
Q
Ieed
11,034,368.89 kJ
Q
HTF
nCp(T2-T1) 11,034,368.89 kJ
Cp
HTF
75.327
J
mol-K

Q
HTF
n 75.327
J
mol-K
(338.15-303.15) K
n 4,185,321.10 moles
m
HTF
75,335.7798 kg





Equipment: Reflux Drum -01
Equipment Code: RD-01
Type: Gas-liquid Separator
Function: Contains the stream from the CD-01 and promotes separation of ethanol-water vapor
to acetic acid water solution. It acts as a distribution point for reflux and distillate. Acetic
acid water solution is recycled back to FR-01 while ethanol-water vapor proceeds to CD-02.
Calculation Considerations:
1. Accumulation is 0.05% for liquid stream
2. No accumulation for gas stream






Calculation:
M= O + N +Accumulation
M= O + N + 0.005M
Material balance Sheet:
Components M O N Accumulation
Ethanol 414.0244539
474.0244539 - -
Water 4692.842094
4266.220085 426.4086975 0.213311004
Acetic acid 120.8762358
- 120.8157976 0.060438118
Total 5287.742784
4740.244539 547.2244952 0.273749122



From CD-01 (M)
5287.7428 kg
To FR-01 (N)
547.2245 kg

To CD-02 (O)
4740.2445 kg


Equipment: Reboiler -01
Equipment Code: RB-01
Type: Kettle-type reboiler
Function: Vaporizes ethanol, parts of water and acetic acid at 374.15 K and 1.02 atm by using
heat coming from superheated steam available at 448.15 K and 1.46 atm.
Calculation Considerations:
Calculation Considerations:
1. Accumulation is 0.05% for liquid stream
2. No accumulation for gas stream




Calculation:
Q= R + S +Accumulation
Q= R + S + 0.005Q
Material balance Sheet:
Components Q R S Accumulation
Ethanol
474.0244539 474.0244539 - -
Water
55988.37933 4692.842094 51269.88947 25.64776862
Acetic acid
7017.811194 120.8762358 6893.486491 3.448467479
Total
63480.21498 5287.742784 58163.37596 29.0962361


Energy balance:
Components
Molecular Weight
(kg/kmol)
Heat of Vaporization, H
f

(KJ/mol)
HV
(KJ/mol)
Ethanol 48 38.560 38560
From FR-01 (Q)
63480.21498 kg
To SV-02 (S)
58163.37596 kg
To FR-01 (R)
5287.742784 kg
Water 18 40.680 40680
Acetic Acid 60 23.700 23700

Q
Ieed
Q
R
Q
water

Q
Ieed
Q
HAc
Q
Water
Q
EtOH

Q
HAc

7017811194 kg
60Kg/Kmol

1000 mol
1 kmol

23.700 KJ
mol

Q
HAc
2,772,035.42 kJ

Q
Water

55988.37933 kg
18Kg/Kmol

1000 mol
1 kmol

40.680KJ
mol

Q
Water
126,533,737.30 kJ

Q
EtOH

4740244539 kg
48Kg/Kmol

1000 mol
1 kmol

38.560KJ
mol

Q
EtOH
380,799.6446 kJ

Q
Ieed
129,686,572.40 kJ

Q
R
Q
HAc
Q
Water
Q
EtOH

Q
HAc

1208762358 kg
60Kg/Kmol

1000 mol
1 kmol

23.700 KJ
mol

Q
HAc
47,476.1131 kJ

Q
Water

4692.842094 kg
18Kg/Kmol

1000 mol
1 kmol

40.680KJ
mol

Q
Water
10,605,823.13 kJ

Q
EtOH

4740244539 kg
48Kg/Kmol

1000 mol
1 kmol

38.560KJ
mol

Q
EtOH
380,799.6446 kJ

Q
R
11,034,098.89 kJ

Q
HTF
nCp(T2-T1) 11,034,098.89 kJ
Cp
HTF
75.327
J
mol-K

Q
HTF
n 75.327
J
mol-K
(448.15-384.15) K
n 2,288,791 moles
m
HTF
41,198.24647 kg





















Equipment: Surge Vessel -02
Equipment Code: SV-02
Type: Vessel
Function: Surge vessel-02 is necessary to reduce fluctuations in flow rate and composition of
the entering stream in the extraction column.
Calculation Considerations:
1. Accumulation is 0.05% for liquid stream
2. No accumulation for gas stream






Calculation:
S= T + Accumulation
S= T + 0.005S
Material balance Sheet:
Component S T Accumulation
Water 51269.88947 51244.25452 25.63494473
Acetic acid 6983.486491 6890.039748 3.446743246
Total 58163.37596 58134.29427 29.08168798




From RB-01 (S)
58,163.37596 kg
To HE-02 (T)
58,134.29427 kg


Equipment: Heat Exchanger -02
Equipment Code: HE-02
Type: Countercurrent, Shell and Tube Heat Exchanger
Function: Allows feed to be cooled by using cooling water at 303.15 K. HE-02 reduces the
temperature of the feed from 374.15 K to the temperature requirement for the extraction column
which is 373.15 K.
Calculation Considerations:
1. Accumulation is 0.05% for liquid stream




Calculation:
T= U + Accumulation
T= U + 0.005T

Material balance Sheet:
Component T U Accumulation
Water 51244.25452 51218.6324 25.62212726
Acetic Acid 6890.039748 6886.594728 3.445019874
Total 58134.29427 58105.22712 29.06714714

Energy Balance:
Components
Molecular Weight
(kg/kmol)
Heat Capacity, C
p

(J/mol-K)
Water 18 75.327
Acetic Acid 60 123.1

To EC-01 (U)
58105.22712 kg
From SV-02 (T)
58134.29427 kg


Q
Ieed
Q
HTF

Q
Ieed
Q
H2O
Q
CH3COOH

Q
H2O
nCp(T2-T1)
Q
H2O

5124425452 kg
18 kg/kmol

1000 mol
1 kmol
75.327
J
mol-K
(373.15-374.15) K
Q
H2O
-214,448.66 kJ
Q
CH3COOH
nCp(T2-T1)
Q
CH3COOH

6890.0397 Kg
60 kg/kmol

1000 mol
1 kmol
123.1
J
mol-K
(373.15-374.15) K
Q
CH3COOH
-14,136.06 kJ
Q
Ieed
-228,584.73 kJ
Q
HTF
nCp(T2-T1) -228,584.73 kJ
Cp
HTF
75.327
J
mol-K

Q
HTF
n 75.327
J
mol-K
(338.15-303.15) K
n 86,701.8770 moles
m
HTF
1,560.6338 kg







Equipment: Extraction Column -02
Equipment Code: EC-02
Type: Distillation column
Function: Separates acetic acid with water by introduction of tributylamine solvent.
Tributylamine solvent forms non-volatile salt with acetic acid that is immiscible to water. Pure
water is form as a distillate, whereas, unreacted tributylamine and salt formed is feed to the third
surge vessel.
Calculation Considerations:
1. Accumulation is 0.05% for liquid stream
2. No accumulation for gas stream









Material balance Sheet:
Feed Stream:
Components U W
Water 51218.6324 -
Acetic Acid 6886.594728 -
Tributylamine - 87201.44141
Total 58105.22712 87201.44141
From HE-02 (U)
58105.22712 kg
To SV-03 (Y)
94040.99212
From HE-03 (W)
87201.44141
To CD-03 (V)
51218.6324




Outgoing Stream:
Components Y V Accumulation
Water - 51218.6324 -
Acetic Acid - - -
Tributylamine 65934.79044 - 32.98388716
Acetic-amine Salt 28106.20168 - 14.0601309
Total 94040.99212 51218.6324 47.04401807





















Equipment: Condenser -03
Equipment Code: CD-03
Type: Total Condenser
Function: Condense water vapor from the extraction column.
Calculation Considerations:
1. Partial condenser
2. No accumulation for gas streams




Calculation:
V= X + Accumulation
V= X + 0.005B
Material balance Sheet:
Component V X Accumulation
Water 51218.6324 51218.6324 -

Energy Balance:
Components
Molecular Weight
(kg/kmol)
Heat of Vaporization,
H
f
(KJ/mol)
Water 18 40.680

Q
Ieed
Q
water

From EC-02 (V)
51218.6324 kg
To ST-04 (X)
51218.6324 kg
Q
Ieed
Q
Water

Q
Water

g
18Kg/Kmol

1000 mol
1 kmol

40.680KJ
mol

Q
Water
115,754,109.20 kJ
Q
Ieed
115,754,109.20 kJ
Q
HTF
nCp(T2-T1) 115,754,109.20 kJ
Cp
HTF
75.327
J
mol-K

Q
HTF
n 75.327
J
mol-K
(338.15-303.15) K
n 43,905,376.07 moles

m
HTF
790.296.7693 kg




























Equipment: Surge Vessel -03
Equipment Code: SV-03
Type: Vessel
Function: Surge vessel-03 is necessary to reduce fluctuations in flow rate and composition of
the entering stream in the solvent recovery column.
Calculation Considerations:
1. Accumulation is 0.05% for liquid stream
2. No accumulation for gas stream






Calculation:
Y= Z + Accumulation
Y= Z + 0.005Z
Material balance Sheet:
Component Y Z Accumulation
Tributyl amine 65394.79044 65901.82304 32.96739522
Salt 28106.20168 28092.14857 14.05310084
Total 94040.99212 93993.97162 47.02049606


From EC-01 (Y)
94040.99212 kg
To HE-03 (Z)
93993.97162 kg






Equipment: Heat Exchanger -03
Equipment Code: HE-03
Type: Countercurrent, Shell and Tube Heat Exchanger
Function: Allows feed to be heated by using superheated steam at 448.15 K and 1.46 atm. HE-
03 increases the temperature of the feed from 373.15 K to the temperature requirement for the
solvent regenerator which is 391.25 K.
Calculation Considerations:
1. Accumulation is 0.05% for liquid stream




Calculation:
Z= AA + Accumulation
Z= AA + 0.005Z
Material balance Sheet:
Component Z AA Accumulation
Tributyl amine 65901.82304 65868.87213 32.95091152
Salt 28092.14857 28078.1025 14.04067429
Total 93993.97162 93946.97463 46.99698581

Energy Balance:
Components Molecular Weight
(kg/kmol)
Heat Capacity, C
p

(J/mol-K)
From HE-03 (Z)
93993.97162 kg

To SR-01 (AA)
93993.97162 kg

Tributylamine 185 188
Acetic-amine salt 245 203

Q
Ieed
Q
HTF

Q
Ieed
Q
C12H27N
Q
Aceticamine salt

Q
C12H27N
nCp(T2-T1)
Q
C12H27N

g
185 kg/kmol

1000 mol
1 kmol
188
J
mol-K
(391.25-373.15) K
Q
C12H27N
1,728,879 kJ
Q
Acetic-amine salt
nCp(T2-T1)
Q
Acetic-amine salt

g
245 kg/kmol

1000 mol
1 kmol
203
J
mol-K
(391.25-373.15) K
Q
Acetic-amine salt
421,301.9653 kJ
Q
Ieed
2,150,181.352 kJ
Q
HTF
nCp(T2-T1) 2,150,181.352 kJ
Cp
HTF
75.327
J
mol-K

Q
HTF
n 75.327
J
mol-K
(410.3-383.15) K
n 1,051,367.592 moles
m
HTF
18,924.6167 kg











Equipment: Solvent Regenerator -02
Equipment Code: EC-02
Type: Distillation column
Function: Separates acetic acid with its salt.
Calculation Considerations:
1. Accumulation is 0.05% for liquid stream
2. No accumulation for gas stream








Calculation:
AA= AD + AB + Accumulation
AA= AD + AB + 0.005AA
Material balance Sheet:
Component AA AD AB Accumulation
Tributylamine 65868.87213 - 87027.16928 43.53535232
Salt 28078.1025 - - -
Acetic Acid - 6876.27 - -
From HE-03 (AA)
93946.97463 kg
To HE-04 (AB)
87027.16928 kg
To CD-04 (AD)
6876.27 kg
Total 93946.97463 6876.27 87027.16928 43.53535232




Equipment: Heat Exchanger -04
Equipment Code: HE-04
Type: Countercurrent, Shell and Tube Heat Exchanger
Function: Allows feed to be cooled by using water at 303.15 K. HE-04 reduces the temperature
of the feed from 391.25 K to 303.15 K.
Calculation Considerations:
1. Accumulation is 0.05% for liquid stream




Calculation:
AB= AC + Accumulation
AB= AC + 0.005B
Material balance Sheet:
Component AB AC Accumulation
Tributylamine 87027.16928 86983.6557 43.51358464

Energy Balance:
Components Molecular Weight
(kg/kmol)
Heat Capacity, C
p

(J/mol-K)
Tributylamine 185 188

From EC-02 (AB)
87027.16928 kg

To ST-03 (AC)
86983.6557 kg
Q
Feed
Q
HTF

Q
Feed
Q
C12H27N

Q
C12H27N
nCp(T2-T1)
Q
C12H27N

g
185 kg/kmol

1000 mol
1 kmol
188
J
mol-K
(303.15-391.25) K
Q
C12H27N
-7,791,424.861 J
Q
Ieed
-7,791,424.861 J
Q
HTF
nCp(T2-T1) -7,791,424.861 J
Cp
HTF
75.327
J
mol-K

Q
HTF
n 75.327
J
mol-K
(338.15-303.15) K
n 2,955,276.845 moles
m
HTF
53,194.9832 kg

















Equipment: Heat Exchanger -05
Equipment Code: HE-05
Type: Countercurrent, Shell and Tube Heat Exchanger
Function: Allows feed to be heated by using superheated steam at 448.15 K and 1.46 atm. HE-
05 increases the temperature of the feed from 303 K to 373.15 K.
Calculation Considerations:
1. Accumulation is 0.05% for liquid stream




Calculation:
AI= W + Accumulation
AI= W + 0.005AI
Material balance Sheet:
Component AI W Accumulation
Tributylamine 87245.06394 87201.44141 43.62253197

Energy Balance:
Components Molecular Weight
(kg/kmol)
Heat Capacity, C
p

(J/mol-K)
Tributylamine 185 188
From ST-03 (AI)
87245.06394 kg
To EC-01 (W)
87201.44141 kg

Q
Feed
Q
HTF

Q
Feed
Q
C12H27N

Q
C12H27N
nCp(T2-T1)
Q
C12H27N

g
185 kg/kmol

1000 mol
1 kmol
188
J
mol-K
(303.15-391.25) K
Q
C12H27N
-7,810,932.676 kJ
Q
Ieed
7,810,932.676 kJ
Q
HTF
nCp(T2-T1) 7,810,932.676 kJ
Cp
HTF
75.327
J
mol-K

Q
HTF
n 75.327
J
mol-K
(338.15-303.15) K
n 2,962,676.132 moles
m
HTF
53,328.1704 kg

















Equipment: Condenser -04
Equipment Code: CD-04
Type: Total Condenser
Function: Condense acetic acid vapor from the solvent regenerator.
Calculation Considerations:
1. Total condenser
2. No accumulation for gas streams





Calculation:
AD= AF + Accumulation
AD= AF + 0.005AD
Material balance Sheet:
Component AD AF Accumulation
Acetic acid
6876.27 kg
6876.27 kg 0
Total
6876.27 kg
6876.27 kg 0

Energy Balance:
From SR-01 (AD)
6876.27 kg
To ST-05 (AF)
6876.27 kg

Components Molecular Weight
(kg/kmol)
Heat of Vaporization, H
f

(KJ/mol)
Acetic Acid 60 23.700

Q
Ieed
Q
HAc

Q
HAc

kg
60Kg/Kmol

1000 mol
1 kmol

23.700 KJ
mol

1000J
1KJ

Q
HAc
2,716,126.65 kJ
Q
Ieed
2,716,126.65 kJ
Q
HTF
nCp(T2-T1) 2,716,126.65 kJ
Cp
HTF
75.327
J
mol-K

Q
HTF
n 75.327
J
mol-K
(338.15-303.15) K
n 1,030,223.141 moles
m
HTF
18,544.01655 kg


















Equipment: Condenser -02
Equipment Code: CD-02
Type: Total Condenser
Function: Condense ethanol-water vapor from the reflux drum.
Calculation Considerations:
1. Total condenser
2. No accumulation for gas streams





Calculation:
O= P + Accumulation
O= P + 0.005O
Material balance Sheet:
Component O P Accumulation
Ethanol 474.0244539 474.0244539 -
Water 4266.220085 4266.220085 -
Total 4740.244539 4740.244539 -

From RD-01 (O)
4740.244539 kg
To AC-01 (P)
4740.244539 kg

Energy Balance:
Components Molecular Weight
(kg/kmol)
Heat of Vaporization, H
f

(KJ/mol)
Ethanol 48 38.560
Water 18 40.680

Q
Ieed
Q
water

Q
Ieed
Q
Water
Q
EtOH

Q
Water

g
18Kg/Kmol

1000 mol
1 kmol

40.680KJ
mol

Q
Water
9,641,657.392 kJ
Q
EtOH

g
48Kg/Kmol

1000 mol
1 kmol

38.560KJ
mol

1000J
1KJ

Q
EtOH
380,799.6446 kJ
Q
Ieed
10,022,457.04 kJ
Q
HTF
nCp(T2-T1) 10,022,457.04 kJ
Cp
HTF
75.327
J
mol-K

Q
HTF
n 75.327
J
mol-K
(338.15-303.15) K
n 3,801,504.312 moles
m
HTF
68,427.0776 kg

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