1. (15 pts) Analysis of a rock sample shows that it contains 0.42 mg of 40Ar for every 1.00 mg of 40K.

Assuming that all the Ar resulted from decay of the K and that neither element has left or entered the rock since its formation, estimate the age of the rock in years, given that 40K has a half-life of 1.28 x 109 yr and that of the 40K that decomposes, only 10.7% of it decomposes to 40Ar.

Answer:_________________ 2. (8 pts) If Micha Simons takes a photocell constructed from cesium down to Bermuda, what is the longest -19 wavelength of light in meters that will eject an electron from cesium if its work function is 3.43 x 10 J?

Answer:_______________ 3. (3 pts) Write the de Broglie equation_____________________________. 4. (3 pts) Write the Heisenburg Uncertainty equation_____________________________. 5. (3 pts) Write the Schrdinger equation_________________________________.

6. (15 pts) The following questions pertain to the figure at the right, which represents K+ and F coming together. Given the following terms: IE(K) IE(F) EA(K) EA(F) Ed E Ecoul Electronegativity (K) Electronegativity (F)

a b

(a) Which term applies to arrow a? ______________ (b) Which term applies to arrow b? ______________ (c) Which term applies to arrow c?_______________ g (d)&(e) Draw two arrows on the figure which show how to get arrow c and label each arrow with the appropriate term from above. (f) Short answer---Why does the curve go up from right to left in the region indicated by arrow f?

(g) Short answer---What has happened at the point in the curve indicated by arrow g?

(h) Short answer---Why does the curve go down from right to left in the region indicated by arrow h?

(i) What is the label for the y-axis of this figure?__________________________ (j) What is the label for the x-axis of this figure?___________________________ (k) Draw on the figure a curve that would correspond to K atom and F atom combining to form KF molecule. Please label your curve. 7. (8 pts) Using your best guess, write fully complete nuclear chemistry equations for what has been started for you below, making sure to include those ill-defined, very small mass particles that may be produced: (a)
238

(b)

57

Co +

(c)

22

Na

(not by EC)

(d) 3H

8. (4 pts) Use the "aufbau" and other key information you have been given to provide the actual array of electrons for the following species: A. Give SHORT-FORM ELECTRON CONFIG.
82Pb2+

B. Give ELECTRON DOT PICTURE

______________________________________

47Ag+

______________________________________

9. (8 pts) Write formulas for the following compounds: ammonium perchlorate ____________ magnesium fluoride____________ calcium hydrogenphosphate______________ sodium carbonate______________

10. (4 pts) Write formulas for the following individual ions: iron(III)___________ sulfate____________ nitrate_____________ sulfite______________

11. (6 pts) Circle the formulas below that represent molecular compounds: H2O H3PO4 CsI NH4Br SrS2O3 12. (8 pts) Please fill out the table below according to the method illustrated in class. NH3

central e pairs to be arranged O N O around N,____

e- pair shape? (sketch & name)

molec. shape? (sketch and name) formal charges?

how many -bonds likely? resonance? drawing correction?

O O S O

2around S,____

13. (15 pts) Clearly circle the letter of all of the TRUE statements below: (a) The process of measuring a system must perturb the system. (b) A baseball does not have a humanly observable wavelength because it is not massive enough. (c) The pattern observed by the detector after thousands of electrons have passed through the slits in a double slit experiment is explained by postulating that the electron has both wave and particle character. (d) In the photoelectric effect the velocity of an ejected electron will decrease if the frequency of the photon is increased. (e) In the photoelectric effect the velocity of an ejected electron will decrease if the wavelength of the photon is increased. (f) In PET, positrons are what are measured by the detector placed near the patient. (g) For a radiotherapeutic agent, you want a radioisotope that emits high energy gamma rays. (h) Radioactive chlorine is administered to patients with hyperthyroidism because it accumulates preferentially in the thyroid. (i) Radioactive strontium is administered to patients with bone tumors because it preferentially accumulates in bone. (j) An ideal radiotherapeutic isotope would have a half-life of either a few seconds or several years. (k) The wave function, , is not directly observable by experiment. (l) A hydrogen bomb contains plutonium. (m) A hydrogen bomb generates vast energy due to the fissioning of tritium. (n) A neutron leaving a nucleus after a nuclear event has a very low probability of striking the nucleus of a neighboring atom. (o) In the detonation of a plutonium-based atom bomb, the explosion of a conventional explosive around the plutonium is necessary to create an exponentially increasing fission chain reaction in the plutonium. (p) If we add a slit to the two slit experiment to make it a three slit experiment, the new wave function for the electron is e = (1/3)(1 + 2 + 3). (q) For a three slit experiment with an electron, the probability density distribution is e2 = 12 + 22 + 32.

PLEDGED:_____________________________________________________