Code No.

34

Total No. of Questions : 39 ]

[ Total No. of Printed Pages : 16

March, 2009

CHEMISTRY
( Kannada and English Versions )
Time : 3 Hours 15 Minutes ]

[ Max. Marks : 90
( Kannada Version )

i)

XR XxY @ .

ii)

- A,
O.

iii)

- A XR x@ 10 , - B
XR x@ 2 20 , - C XR
x@ 5 40 - D Y D 1 10

D 2
Y XR x@ 5 10

B, C

Y XRR W

O.
iv)

WY XR O R .

- A
:

1.

i)

ii)

XR Y WY OR
. X XR O.
10 1 = 10

10

XRR O.

|| U QMY NY X ?

[ Turn over

Code No. 34
2.

X T R X yY @ WY.
yR .
O

Y NR O ?

3.

Cu+1

Cu2+

4.

O XY WZW K W J ?

5.

6.

"W@ # R WzW.

7.

Z zW 6. {W ?

8.

XR

273 K

NY {O. x ?

@y

Xx]

R .
9.

y| Y. x ?

10.

Y XR .

- B
:

i)

O XRR O.

ii)

X XR R O.
10 2 = 20

11.

W x] O R x] }R YW
x\R . Y
NY O y ?

1500C

Code No. 34

12.

| xX| X, | Xx] O ?

13.

||X y(II) T|Y xX }y

zW

14.

( EAN )

R y@ .

( LCAO )

O X \ R X.
15.

X X X

80

50

J _O.

X PR @ .
16.

X \R .

17.

N pH 454. Y

18.

x Y

CH3 CH2 Cl

A, B, C

[ H+ ]

R @ .

R :

CH3 CH2 OH

CH3 COOH

NaOH

NaOH+CaO
D .
heat
19.

|] X ? W R .

20.

x X R :
i)

yW] | @ J x

ii)

y Y T |xY

21. D
22.

J W XR .

|XJR | Xx] X y | }
? R x.
[ Turn over

Code No. 34

- C
I.

xY XR O :
23. a)

b)

2 5 = 10

SR .

||Xy R X. O _
R O ?

24. a)

] Q XK XR
XW ? .

b)

ydy WR . y B
y .

25. a)

b)

II.

"

QM#

XR .

yd QM , B .

xY XR O :
26. a)

b)

27. a)
b)

"y }# ?

{LY

3 5 = 15

CHO

y }R O ?

|X X XR .

x |
R XW ? .

J ? ||XJ Y J J ?

5
28. a)

WZ

Code No. 34

xY

WR O ?

Br C COOH

CH 3

CH 3

b)

XR ?
R .
2

c)

Yx y X R
XR x.
1

29. a)

III.

2
OH

H
Br C Br

xYW|Y x R @ .

b)

X y XR . X W
R .
2

c)

R x_O.
O?
1

xY XR O :
30. a)
b)

3 5 = 15

X X P R .

G O R .

31. a)

y Y O || XR Y
P X XR .
3

b)

X WOR X T| O XxYy Y
X XY u}X
64 .X X }_O. X K N O
OY ( S.T.P. ) J X R @ .
(X = 32)

2
[ Turn over

Code No. 34
32. a)
b)

K X xd R .
WX

J R .

Y R .
c)

{Y \O P

( Dispersed phase )

O x\

WR ( Dispersion medium ) .
33. a)

"|X# R WzW. X |XY

| } ?

b)

X ? |O ?

c)

" x#R WzW.

34. a)

2+

Mg | Mg(1m)

Eo Ag = 08 V

Ag(1m)

| Ag xY

Eo Mg =

237 V

QY x O

WY | }R @ .
b)

WZW QM
XR x.

- D
D 1
IV.

xY XR O :
35. a)
b)

1 10 = 10

{ _R XW y R .

X O _ . x ?
} .

Code No. 34

c)

XY X
QM
x\
zO O
\x@ O.
X X ? X } x.
2

d)

} KO W 298 K Y 166 kJ
O. X P P Kp R @ .

e)
36. a)
b)

mol1

W ?

xR{ X yWR x.

54 X Wy OR 612 X
Y X z X z
@ XR . X UY 0708 X
O X UY 0035 X XWY J |.
Wy O R @ .
( = 74 xJ).

c)

Al3+

NH4 OH

R Xx@ NH4 Cl
R Al ( OH )3 X OO. y

Zn2+

x. 2
d)

i)

CH3 CH CH2 COOH IUPAC

|
Cl

R .
ii)

CH3 CH CH2 COOH

|
Cl

O
CH3 CH2 CH COOH
|
Cl
Y E pKa WR
e)

CsCl

xY { ( Lattice points ) J ?

[ Turn over

Code No. 34

8
D 2

V.

xY XR O :
37. a)

XY

|X

2 5 = 10

|-|XR

? R .
b)

38.

W x\R :
i)

ii)

yX|

|| Y X hx@
Q XR .

39.

T| XR | |
( KMnO4 )

XR XY,

i)

X R .

ii)

| | R x.

iii)

iv)

yO Y | N } ?

v)

xJ XY | |
XWR

( mass / dm3

XR .

XW @
5

Code No. 34

( English Version )

Instructions :

i)

The question paper has four Parts.

ii)

Parts A, B, C and D are common to all the candidates.

iii) Part A carries 10 marks. Each question carries one mark.

Part B carries 20 marks. Each question carries two marks.
Part C carries 40 marks. Each question carries five marks.
In Part D D 1

carries 10 marks and D 2

carries

10marks. Each question of D2 carries five marks.

iv) Write balanced chemical equations and draw diagrams
wherever necessary.

PART A
Note :

i)

Answer all the 10 questions.

ii)

Questions have to be answered in one word or in one

sentence each. Each question carries one mark.
10 1 = 10

1.

What is the role of limestone in the extraction of iron from haematite ?

2.

Hydrogen sulphide gas cannot be dried using conc. H2

SO4 . Give

reason.
3.

Which one among Cu+1 and Cu2+

4.

What is the limiting value of degree of dissociation of an electrolyte at

salts is coloured ?

infinite dilution ?
5.

Sea-water freezes below 273 K. Why ?

[ Turn over

Code No. 34

10

6.

Define electrophoresis.

7.

The coordination number of a crystal is 6. What is the geometry of the

crystal?

8.

Name the gas liberated when bromoethane is heated with alcoholic potash.

9.

Phenol does not react with sodium bicarbonate. Why ?

10. Name the protein present in hair.

PART B
Note :

i)

Answer any ten questions.

ii)

Each question carries two marks.

10 2 = 20

11. Draw Ellingham diagram for the formation of oxides of aluminium and
magnesium. Which one of these metals acts as better reducing agent
above 1500C?
12. How

does

potassium

dichromate

solution

react

with

potassium

hydroxide?
13. Calculate the EAN value of the central metal ion in tetramine copper(II)
sulphate.
14. Sketch the shapes of bonding and antibonding molecular orbitals formed
when two S orbitals undergo LCAO.
15. A first order reaction is 50% completed in 80 min. Calculate the rate
constant of the reaction.

11

Code No. 34

16. Mention any two characteristics of an ideal solution.

17. pH value of a sample of mango juice is 454. Calculate the [ H+ ].
18. Identify A, B, C and D in the following equation :
CH3 CH2 Cl

CH3 CH2 OH

CH3 COOH

NaOH

NaOH+CaO
D .
heat
19. What is Wurtz-Fittig reaction ? Write the general equation.
20. Write the equations for the following reactions :
i)

Dry distillation of calcium acetate

ii)

Reaction of phosphorous pentachloride with acetic acid.

21. Write the Haworth structure of D maltose.

22. What happens when tristearin is heated with potassium hydroxide
solution? Give the equation.
PART C
I.

Answer any two of the following questions :

23. a)
b)

2 5 = 10

Describe the manufacture of ammonia by Habers process.

Sketch the shapes of nickel tetracarbonyl. Which type of

hybridisation is involved in the formation of this compound ?

24. a)

How is a mixture of noble gases separated by Dewars charcoal

method?

b)

Write the electronic configuration of lithium molecule. Comment

on its magnetic property with reason.

2
[ Turn over

Code No. 34
25. a)

12
State any three postulates of Werners theory of co-ordination
compounds.

b)

On the basis of electron gas theory, explain bright lustre of

metals.

II.

Answer any three of the following questions :

26. a)

b)

27. a)

b)

What is mesomeric effect ? What type of mesomeric effect is

shown by CHO group in benzaldehyde ?

Explain the mechanism of nitration of benzene.

How is phenol isolated from coal tar ?

What is a dipeptide ? How many peptide linkages are present in

a tetrapeptide ?

28. a)

What is optical activity ? Which one of the following compounds

shows optical isomerism ?

Br C Br

Br C COOH

CH 3

CH 3

How is ethyl bromide converted into ethyl isocyanide ? Write the

equation.

c)

2
OH

b)

3 5 = 15

Give a chemical reaction to show that a molecule of glucose

contains a carbonyl group.

13
29. a)
b)

Code No. 34

Calculate angle strain in cyclobutane.

Explain carbylamine reaction for a primary amine. Write general

equation.

c)

One mole of a given amine consumes two moles of methyl iodide

for exhaustive methylation. What type of amine is this ?

III. Answer any three of the following questions :

30. a)

3 5 = 15

Derive an expression for rate constant of a first order reaction.

4

b)
31. a)

State Schultz-Hardy rule.

Explain buffer action in acidic buffer containing mixture of

acetic acid and sodium acetate.

b)

When the same amount of electricity passed through solutions

of copper sulphate and hydrochloric acid, 64 mg of copper is
deposited on the cathode in the first case. Calculate the volume
of hydrogen obtained in the second case at S.T.P.

32. a)
b)

( Equivalent weight of Cu = 32 ).

Mention two limitations of standard hydrogen electrode.

Write Nernst equation for single electrode potential. Explain any

two terms in the equation.

c)

Mention the dispersed phase and dispersion medium in a gel.

1
[ Turn over

Code No. 34
33. a)

14
Define entropy. What happens to entropy when

a liquid

vaporises?

b)

What is Brownian movement ? How is it caused ?

c)

Define unit cell.

34. a)

Calculate the change in free energy for the cell

2+

Mg | Mg(1m)

Ag(1m)

Ag

if Eo Ag = 08 V and Eo Mg = 237 V.
b)

State any three postulates of Arrhenius theory of electrolytic

dissociation.

PART D
D 1
IV. Answer any one of the following :
35. a)

Describe

Parkes

process

1 10 = 10
for

the

desilverisation

Argentiferrous lead.
b)

Why

are transition elements and

catalysts? Explain.
c)

of
3

their

compounds

good
2

For a reaction, the graph of rate of the reaction against molar

concentration of the reactant is a straight line parallel to the
concentration axis. What is the order of this reaction ? Give an
example for such a reaction.

15
d)

Code No. 34

The value of standard free energy of formation of ammonia at

298 K is 166 kJ mol1 . Calculate the equilibrium constant

e)
36. a)
b)

Kp for the reaction.

What is iodine value ?

Give the mechanism of Cannizzaros reaction.

A current of dry air was passed through a solution containing

54g of an aromatic compound in 612 g of diethyl ether and
then through the solvent. The loss in mass of solution bulb was
0708g and that in the solvent bulb was 0035 g. Calculate the
molecular weight of the aromatic compound.
( Given molecular weight of diethyl ether = 74 )

c)

When NH4 Cl and NH4 OH are added to a solution containing

Al3+

and Zn2+

ions, only Al ( OH )3

precipitates. Give

reason.
2
d)

i)

Write the IUPAC name of

CH3 CH CH2 COOH
Cl

ii)

Out of CH3 CH CH2 COOH

Cl
and
CH3 CH2 CH COOH
Cl
which one has higher pKa value ?

e)

How many Lattice points are present in a unit cell of CsCl ?

[ Turn over

Code No. 34

16
D 2

V.

Answer any two of the following :

37. a)

How

is m-nitrobenzene prepared

2 5 = 10
in

the

laboratory

nitrobenzene ? Write the equation.

b)

from
3

Mention a general test for

i)

Protein

ii)

Carbohydrate.

38. Describe an experiment to show that acid hydrolysis of methyl

acetate follows first order kinetics.

39. For the estimation of potassium permanganate ( KMnO4

) using

standard ferrous ammonium sulphate

i)

Write the chemical equation for the reaction involved.

ii)

Give the equivalent weight of potassium permanganate.

iii)

Name the indicator used.

iv)

What is the colour change at the end point ?

v)

Write the equation for calculating mass / dm3

of potassium

permanganate in a given solution from its normality.