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in

Indian National Chemistry Olympiad

Theory 2012

Name of Student
Problem 1 Heterocyclic compounds
1.1 B, C

Roll No.
18 marks

1.2

F>G>E

1.3

B. 1.4 a)

00
or

m .1
N

+
H

+
H

+ N
H

ar w
O3 S N H N H NO2

b)

HO3 S

HBCSE, 28th January 2012

ks
H

NO2

.in
+ N
H
1

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Indian National Chemistry Olympiad

1.5
or

Theory 2012

or

1.6

N H2

O H5 C2
CHO

1 mole
C. 1.7

2 moles

00
1.9
H N H

m
..

1.8

Yes

.1
H OH N H

ar

ks

N H2

.in
N

N H

S (gives an oxime)

T (C H NO) 9 11

U (C H N) 9 9

V(C9 H7 N)

HBCSE, 28th January 2012

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Indian National Chemistry Olympiad Problem 2 Analysis of alloys

A. 2.1 2Cu2+ (aq) + 4I (aq) Cu2I2 + I2(aq) 2S2O32 (aq) + I2(aq) S4O62 (aq) + 2I(aq) 2.2 0.484 g of copper 70% 2.3 Cr2O72 (aq) + 14H+ (aq) + 6I (aq) 2Cr3+ (aq) + 7H2O + 3I2 Molarity of thiosulphate = 0.0485 M

Theory 2012 12 marks

2.4

B. 2.6

NO3(aq) + 10H+ (aq) + 8e NH4+(aq) + 3H2O Pb2+ (aq) + 2H2O PbO2 + 4H+ (aq) + 4e

2.8

mmol of PbO2 = 0.0132

2.9

Fraction of the total current = 36.1%.

C. 2.10 Amount of zinc = 0.184 g Percentage = 26.8 % of zinc

HBCSE, 28th January 2012

2.7

.1

00

Relative percentage deviation = 3.1%

ar

2.5

0.469 g of copper

ks

.in
3

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Indian National Chemistry Olympiad Problem 3 Halogens

3.1 (c ) X

Theory 2012 18 Marks

3.2

(a) (c)

X X

3.3

No

X KI7 /I7
X

Solvent Carbon tetrachloride Diethyl ether

Solubility

ar
19

(c)

ks
Solvent n-Hexane Toluene Solubility 13 182

(b) (iii)

00

Carbon tetrachloride Diethyl ether 3.6

3.5

Solvent

.1

337

max 520 - 540 nm 460 - 480 nm

F2 + Br2 2BrF (A) 3BrF Br2(g) + BrF3 (B) 5BrF 2Br2(g) + BrF5 (B) 3.7 BrF3 + SbF5 or BrF5 + SbF5 [BrF2]+[SbF6] [BrF4]+[SbF6] or

HBCSE, 28th January 2012

.in
Color Bright violet Deep brown 4

3.4

(a)

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Indian National Chemistry Olympiad

3.8 Reactants Products Lewis Acid SbF5 BrF2+ / BrF4+

Theory 2012
Lewis Base F SbF6

3.9

a)

b)

... . . .
F

N S

. . ..

..
F

c)

12 Tetrahedral

d)

3.10
F F F F F F Sb F

F Sb F

HBCSE, 28th January 2012

3.11

XeO64

.1

00
F

ar

ks

.in
5

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Indian National Chemistry Olympiad Problem 4 Chemistry of carbocations

4.1 sp2 IV > III > I > II i) Yes ii) No iii) Yes 4.4 X X X

Theory 2012 23 marks

4.2

4.3

4.5

4.8

4.9

F [C15 H15 N2 O]+

HBCSE, 28th January 2012

4.7

(ii)

4.6

(iii)

Br

.1
G [C15H15O]

00

m
H
6

ar

ks

.in

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Indian National Chemistry Olympiad

4.10 .
HO HO HO

Theory 2012

J (C17H24 O)

4.11
or

N (C13 H21O) (carbocation)

4.12
O

4.14

(i)

or

(ii)

.1
X (As per the given structure of P in 4.12)

4.13

(i)

4.15

O O O H

00
and
H

m
CH3

HBCSE, 28th January 2012

ar

ks

.in
7

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Indian National Chemistry Olympiad Problem 5 The light side of chemistry

5.1 Propagation steps: (ii) & (iii) Termination step: (iv)
d[H ] = 0 k 1 [Cl ][H 2 ] k 2 [H ][Cl 2 ]. dt d[Cl ] = 0 2I abs + k 2 [H ][Cl 2 ] k 1 [Cl ] [H 2 ] 2k 3 [Cl ] 2 dt k [H ] = 1 k2

Theory 2012 18 marks

5.2

I abs k 3

[H 2 ] [Cl 2 ]

or 2K 1

.[H 2 ]

5.4

The correct statement/s is/are i) ii) X X

B. 5.6

a) . UAOH = NAh AOH UAO = NAhAO b)

U* = UAO + U UAOH H - H* = NAh (AOH AO ) pka= NAh (AO AOH) /2.303RT

c)

5.7

a)

b)

pka = 3.5

HBCSE, 28th January 2012

.1

5.5

Quantum Yield = 1.05

00

ar

ks

5.3

1 d[HCl] = k ' [I abs ] 2 [H 2 ] dt

abs1/2 k 31/2

.in
8

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Indian National Chemistry Olympiad Problem 6 Acids, bases and buffers A.

6.1 [Pr NH 2 ]
+ [Pr NH 3 ]

Theory 2012 11 marks

= 0 .1

6.2

pH = 10.08

appropriate indicator is Methyl red. (4.2-6.2)

B. 6.4
H3 N C H2 H3N C H2

COOH C H2

m
C H2

H2 C

ar 00
H2 N H2 C C H2 COO

C H2

6.6

[H 2 N R COO ] [H 3 N + R COOH]
(iii)

6.5

around point B

.1

H2 C

COO

ks
around point D X

= 0.03

6.7

HBCSE, 28th January 2012

.in
9

6.3

pH 6