Universiti Tun Hussein Onn Malaysia Centre For Diploma Studies Science and Mathematics Department Semester 1, Session

2011/2012 Chemistry DAS 12102/12203/DSK 1912/1913 ___________________________________________________________________________ Test 2 Duration : 1 hour ___________________________________________________________________________ Answer all questions. Please write your answer in pen. Q1 (a) (i) (ii) (b) Explain, how nitrogen atom achieve an octet when joined with another nitrogen atom to form nitrogen gas, N . Describe the existence of multiple bonding in a molecule. (4 marks) Write the Lewis dot symbols of the reactants and products in the following reactions. (i) (ii) Mg + O ? Ca + Cl + Cl ? (Atomic number, Z : O = 8, Mg = 12, Cl = 17, Ca = 20) (5 marks) (c) By the Lewis structure of carbonate ion (CO32-). Show esonance structures (if any). (6 marks)
2

Q2

(a)

At 15 C, a natural gas storage tank has a volume of 3.25 103 L. What is the volume at 31 C? (4 marks) A 50.0 mL sample of gas is at 3.00 atm of pressure and a temperature of 298 K. What volume would the gas occupy at STP? (6 marks) Tennis balls are filled with nitrogen gas, N2 to increase their bounce. Find the pressure inside the tennis ball if it contains 0.33 g of N2 gas at 24 C and given the volume of the ball is 144 mL. (Relative atomic mass: N = 14, R = 0.0821 L.atm.mol-1.K-1) (5 marks)

(b)

(c)

Q3

(a)

A layer of copper welded to the bottom of a skillet weighs 125 g. How much heat is needed to raise the temperature of the copper layer from 25 C to 300 C? (sCu = 0.387 J/g.C) (5 marks) When 1 mol of KBr(s) decomposes to its elements, 90.29 kJ of heat is absorbed. (i) (ii) Write a balanced thermochemical equation for this reaction. How much heat is released when 13.5 kg of KBr forms from its elements (reversed reaction from (i)) (Relative atomic mass: K = 39, Br = 80) (6 marks)

(b)

(c)

Calculate H o of the following reaction: rxn SiO2(s) + 4HF(g) SiF4(g) + 2H2O(l) H o = ? rxn
(4 marks)

(H of (kJ/mol): SiO2(s) = -911, HF(g) = -271, SiF4(g) = -1615, H2O(l) = -285.8) For the reaction: NO(g) + O2(g) N2O3(g) (i) Balance the equation. (ii) Express the rate in terms of the change in concentration with time for each substance. (iii) How fast is [O2] decreasing when [NO] is decreasing at a rate of 1.60 10-4 mol/L.s ? (7 marks) For the reaction : CF4(g) + H2(g) CHF3(g) + HF(g), the following data were obtained at 1100 K. Experiment 1 2 3 4 (i) (ii) [CF4(g)] Mol/L 0.1 0.15 0.20 0.20 [H2(g)] Mol/L 0.1 0.1 0.20 0.30 Initial rate (mol/L.s) 45 67.5 180 270

Q4

(a)

(b)

Write the rate law of the reaction. Calculate the average value of the rate constant. (8 marks)

DSK1912 DSK1913

Universiti Tun Hussein Onn Malaysia Faculty of Science, Arts and Heritage Session 2009/10 Semester 1 Chemistry

Test 2 1 hour

Answer all questions. Please write your answer using ink, NOT PENCIL. Q1 (a) (i) (ii) The volume of oxygen gas at 700 K is 123 mL. Calculate the volume of the gas if the temperature is decreased to 350 K at constant pressure,. The volume of sulfur dioxide gas at 700 K and 2 atm is 123 mL. Calculate the volume of the gas if the pressure is increased to 8 atm at constant temperature. (4 marks)

(b)

Calculate the volume of a sample of carbon monoxide gas at 14 oC and 367 torr if it initially occupies 3.65 L at 25 oC and 745 torr. ( 4 marks) A sample of chlorine gas is filled in a 5.0 L container at 1.5 atm and 300 K. How many moles of gas are present in the sample? (R = 0.0821 atm.L/mol.K ) (2 marks)

(c)

Q2

(a)

Given the following equation : 2Na(s) + 2H2O() H2(g) + 2NaOH(aq), Find H when 2 moles of H2 is produced. H = 368 kJ (2 marks)

(b)

Find Hrxn for the following reaction 2FeS2(s) +

11 O2(g) Fe2O3(s) + 4SO2(g) 2

Given : Hf (FeS2) = 177.5 kJ Hf(Fe2O3) = 824.2 kJ Hf(SO2) = 296.8 kJ (c)

(5 marks)

Calculate the standard enthalpy of formation, Hf for diamond, given that C(graphite) + O2(g) CO2(g), C(diamond) + O2(g) CO2(g), H = 393.5 kJ H = 395.4 kJ (3 marks)

Q3

(a)

The initial rate of a reaction H2(g) + Br2(g) 2HBr(g) was measured for several different starting concentrations of H2(g) and Br2(g), with the following results. 3

Experiment 1 2 3

[H2(g)] (M) 0.100 0.100 0.200

[Br2(g)] (M) 0.100 0.200 0.100

Initial Rate (M/s) 4.0 10 5 4.0 10 5 16.0 10 5

Using these data, determine: (i) The rate law for the reaction. (ii) The rate constant, k. (8 marks) (b) Conversion of ozone to oxygen is a first order reaction. Given its reaction rate constant, k = 1.15 10 3 s 1 . Calculate half-life of the reaction. (2 marks)

Universiti Tun Hussein Onn Malaysia Centre For Diploma Studies Science and Mathematics Department Semester 2, Session 2010/2011 Chemistry DAS 12102/12203/DSK 1912/DSK 1913 ___________________________________________________________________________ Test 2 Duration : 1 hour ___________________________________________________________________________ Answer all questions. Please write your answer in pen. Q1 (a) Predict the type of bonding (ionic or covalent) resulting from the following combination of elements: (i) K and I2 (ii) C and S (iii) P4 and Cl2 (iv) Sr and O2 (Atomic number, Z: K = 19, I = 53, C = 6, S = 16, P = 15, Cl = 17, Sr = 38, O = 8) (4 marks) (b) Draw Lewis dot symbols of (i) Br (ii) Br(iii) NaBr (Atomic number, Z: Br = 35, Na = 11) (4 marks) (c) Write correct Lewis structure for the following molecule and ion and assign a formal charge to each atom. (i) C2N2 (atoms bonded in the order of NCCN) (ii) NO2(Atomic number, Z: C = 6, O = 8, N = 7) (7 marks) A balloon has a volume of 75 L at 25 C. To what temperature does it need to be raised in order for the balloon to have a volume of 100 L at the same pressure? (4 marks) (b) Carbon dioxide, CO2 occupies 2.54 L at standard temperature and pressure (STP). What is the volume when the pressure is 150 kPa and 26 C? 5

Q2

(a)

(6 marks) (c) How many litres of hydrogen gas can be produced at 290 K and 2.5 atm if 40.0 g of sodium, Na reacts with excess water according to the following equation 2 Na(s) + 2 H2O() 2 NaOH() + H2(g)

(Relative atomic mass: Na = 23, R = 0.0821 L.atm.mol-1.K-1) (5 marks) (a) Given the following reaction : 2 Mg(s) + O2(g) 2 MgO(s), H = 1204 kJ (i) (ii) (iii) Is this reaction exothermic or endothermic? Why? Calculate the amount of heat transferred when 2.4 g of Mg reacts. How many moles of MgO are produced if H is 96 kJ? (Relative atomic mass: Mg = 24.3, O = 16) (6 marks) Find H o of NO from the following thermochemical equation f 2NO(g) + O2(g) 2 NO2(g), H = 113.1 kJ Given H o NO2 = 33.84 kJ/mol f (5 marks) (c) Calculate the enthalpy change for the reaction P4O6(s) + 2 O2(g) P4O10(s) Given the following enthalpies of reaction P4(s) + 3 O2(g) P4O6(s) H = 1640.1 kJ P4(s) + 5 O2(g) P4O10(s) H = 2940.1 kJ (4 marks) (a) Write the rate expression for the reaction 2 C6H14(g) + 19 O2(g) 12 CO2(g) + 14 H2O(g) (2 marks)

Q3

(b)

Q4

(b)

The rate law for the oxidation of SO2 to SO3 2 SO2(g) + O2(g) 2 SO3(g) Is rate = k[SO2][O2] 2 (i) What is the order with respect to SO2 and SO3? (ii) What is the overall order for the reaction?
1

(2 marks) (c) For the following reaction : M + N P + Q

From the data collected, determine the : (i) (ii) Rate law Rate constant, k. Experiment 1 2 3 [M] M 0.010 0.020 0.020 [N] M 0.010 0.010 0.030 Reaction rate (M/s) 2.5 10-3 5.0 10-3 4.5 10-2 (11 marks)

Universiti Tun Hussein Onn Malaysia Centre For Diploma Studies Science and Mathematics Department Semester 1, Session 2010/2011 Chemistry DAS 12203/DSK 1913 ___________________________________________________________________________ Test 2 Duration : 1 hour ___________________________________________________________________________ Answer all questions. Please write your answer in pen. Q1 (a) A balloon filled with helium has a volume of 5.00 L at 0.00 C. What would be the balloons volume at 25.00 C if the pressure surrounding the balloon remained constant? (4 marks) (i) What is the partial pressure of each gas in a mixture of 0.65 mole of hydrogen and 1.15 mole of helium gas in a 0.5000 L container at 200.0 0 C? (R = 0.0821 atm.L / K.mol) What is the total pressure of the mixture in (i)? (8 marks)

(b)

(ii) (c)

Calculate how much faster CH4 gas will diffuse than He gas at 300 K. (Molar mass of He = 4, C = 12, H = 1) (3 marks)

Q2

(a)

The initial temperature of 150 g of ethanol is 22 C. What will be the final temperature of the ethanol if 3240 J is needed to raise the temperature of the ethanol? (The specific heat of ethanol is 2.44 J/g C) (3 marks) Calculate H for the reaction: CH4(g) + Cl2 (g) CH3Cl(g) + HCl(g)

(b)

Given the following information: Compound CH4 CH3Cl HCl Hf (kJ/mol) - 74.8 - 82.0 - 92.3 (5 marks)

(c)

The reaction between sodium oxide and water to produce sodium hydroxide occurs as follows: Na2O(s) + H2O() 2 NaOH(aq)

Calculate the heat of reaction for the above reaction using the following standard enthalpy of formation: H2(g) + O2(g) 2 Na(s) + O2(g) H2O() Na2O(s) NaOH Hf = - 286 kJ/mol Hf = - 414 kJ/mol Hf = - 425 kJ/mol (7 marks)

Na(s) + O2(g) + H2(g)

Q3

(a)

Ammonia reacts with oxygen to produce nitric acid and water 4 NH3(g) + 5 O2(g) 4 NO(g) (i) (ii) + 6 H2O(g)

is

write the rate expression for the reaction, if ammonia, NH3 is reacting at 4.23 10-4 Ms-1, find the rate at which NO produced. (4 marks)

(b)

The rate for a hypothetical reaction : A+B+C D + E is rate = k[A][B]2 Give the order with respect to each reactant and the overall order. (2 marks)

(c)

One reaction that destroys ozone molecules in the stratosphere is NO + O3 NO2 + O2 The above reaction is first order with respect to both NO and O3. (i) (ii) write the rate law calculate the rate constant given that the rate is 4.56 10-6 Ms-1 and [NO] = 1.2 10-5 M and [O3] = 2.0 10-5 M. (5 marks)

(d)

The reaction H2O2(aq) H2O() + O2(g) is first order with a rate constant, k = 7.0 10-4 s-1. Find the half-life, t in hours. (4 marks)