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Designation: D4650 08

Standard Specification for

Normal Butane Thermophysical Property Tables1


This standard is issued under the fixed designation D4650; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon () indicates an editorial change since the last revision or reapproval.

3.1.2 Thermophysical Properties of Normal Butane Along


Isobars, in SI units. See Table 2.
3.2 The tabulated thermophysical properties are:
r, molar density (moll-1)
H, molar enthalpy (Jmol-1)
S, molar entropy (JK-1mol-1)
Cv, constant volume molar heat capacity (JK-1mol-1)
Cp, constant pressure molar heat capacity (JK-1mol-1)
c, speed of sound (ms-1)
h, viscosity (Pas)
l, thermal conductivity (mWm-1K-1)
3.3 These tables were produced by equations from a computer package, NIST Standard Reference Database 23; Reference Fluid Thermodynamic and Transport Properties Database (REFPROP): Version =8.0 A wide selection of units (SI
units, engineering units, chemical units) is available with this
program.2

1. Scope
1.1 The thermophysical property tables for normal butane
are for use in the calculation of the pressure-volumetemperature (PVT), thermodynamic, and transport properties
of normal butane for process design and operations. Tables are
provided for gaseous and liquid normal butane at temperatures
between 136 and 560 K at pressures to 20 MPa. One table
provides properties at the conditions of liquid-vapor equilibrium (saturation properties). The other table provides properties at selected T, p points for the equilibrium phase at those
conditions. The tables were developed by the National Institute
of Standards and Technology from a Standard Reference
Database product REFPROP, version 8.0.
1.2 The values stated in SI units are to be regarded as
standard. No other units of measurement are included in this
standard.
2. Applicability
2.1 These tables apply directly only to pure gaseous normal
butane. However, it is expected that they may find substantial
use in mathematical models and tables for the thermophysical
properties of mixtures containing normal butane.

4. Additional Information
4.1 Reference state properties are required to calculate
certain of the thermodynamic properties (enthalpy, entropy,
etc.) from an equation of state formulation. The reference state
properties used to generate the tables in this specification are:
enthalpy, H, and entropy, S, at 298.15 K and 0.101325 MPa
(H = 19275.7 J/mol and S = 309.909 J/(mol K). The molar
mass of normal butane is 58.122 g/mol.

3. Tables
3.1 These thermophysical property tables are:
3.1.1 Thermophysical Properties of Coexisting Gaseous and
Liquid Normal Butane, in SI units. See Table 1.

5. Keywords
5.1 natural gas; normal butane gas tables; thermodynamic
properties of normal butane; transport properties of normal
butane

1
This specification is under the jurisdiction of ASTM Committee D03 on
Gaseous Fuels and is the direct responsibility of Subcommittee D03.08 on
Thermophysical Properties.
Current edition approved Dec. 1, 2008. Published January 2009. Originally
approved in 1987. Last previous edition approved in 2003 as D4650 93 (2003).
DOI: 10.1520/D4650-08.

2
Available from Standard Reference Data, National Institute of Standards and
Technology (NIST), 100 Bureau Drive, Stop 3460, Gaithersburg, MD 20899.

Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.

D4650 08
TABLE 1 Thermophysical Properties of Coexisting Gaseous and Liquid Normal Butane
T
K

p
MPa

r
moll-1

H
Jmol-1

S
Jmol-1K-1

Cv
Jmol-1K-1

Cp
Jmol-1K-1

c
ms-1

h
Pas

l
mWm-1K-1

136
136

8.201E-07
8.201E-07

12.627
7.252E-07

-22292
6477.2

134.96
346.50

83.79
56.23

114.72
64.54

1819.4
149.44

2201
3.349

176.2
4.905

140
140

1.692E-06
1.692E-06

12.563
1.454E-06

-21832
6737.0

138.29
342.36

83.80
57.05

114.92
65.36

1793.1
151.48

1887
3.452

174.8
5.091

144
144

3.338E-06
3.338E-06

12.499
2.788E-06

-21372
7000.1

141.53
338.56

83.81
57.85

115.12
66.16

1767.4
153.49

1645
3.555

173.4
5.283

148
148

6.32E-06
6.32E-06

12.435
5.136E-06

-20911
7266.2

144.69
335.08

83.82
58.62

115.33
66.94

1742.2
155.48

1452
3.658

172.0
5.479

152
152

1.152E-05
1.152E-05

12.371
9.118E-06

-20450
7535.4

147.76
331.88

83.84
59.38

115.55
67.70

1717.5
157.44

1295
3.760

170.4
5.681

156
156

2.029E-05
2.029E-05

12.307
1.565E-05

-19987
7807.5

150.77
328.94

83.87
60.13

115.79
68.44

1693.2
159.37

1165
3.863

168.8
5.888

160
160

3.461E-05
3.461E-05

12.243
2.602E-05

-19523
8082.6

153.70
326.24

83.92
60.86

116.05
69.18

1669.2
161.28

1055
3.965

167.2
6.099

164
164

5.732E-05
5.732E-05

12.178
4.205E-05

-19059
8360.5

156.57
323.76

83.98
61.59

116.32
69.91

1645.4
163.17

961.7
4.067

165.6
6.316

168
168

9.238E-05
9.238E-05

12.114
6.615E-05

-18593
8641.1

159.38
321.49

84.07
62.31

116.62
70.63

1621.8
165.02

881.0
4.170

163.9
6.538

172
172

0.0001452
0.0001452

12.050
0.0001016

-18126
8924.5

162.13
319.40

84.17
63.03

116.93
71.36

1598.4
166.85

810.7
4.271

162.1
6.766

176
176

0.0002229
0.0002229

11.986
0.0001524

-17657
9210.6

164.82
317.48

84.30
63.75

117.27
72.09

1575.2
168.66

749.1
4.373

160.4
6.998

180
180

0.0003348
0.0003348

11.921
0.0002238

-17187
9499.3

167.46
315.72

84.46
64.48

117.64
72.82

1552.1
170.43

694.6
4.475

158.6
7.235

184
184

0.0004928
0.0004928

11.856
0.0003223

-16716
9790.6

170.05
314.11

84.64
65.21

118.03
73.56

1529.2
172.18

646.1
4.576

156.8
7.478

188
188

0.0007118
0.0007118

11.792
0.0004558

-16243
10084

172.59
312.63

84.85
65.95

118.44
74.31

1506.3
173.90

602.7
4.677

154.9
7.725

192
192

0.0010102
0.0010102

11.727
0.0006337

-15768
10381

175.09
311.28

85.08
66.70

118.89
75.07

1483.5
175.59

563.7
4.778

153.1
7.977

196
196

0.0014104
0.0014104

11.661
0.000867

-15292
10680

177.55
310.05

85.34
67.46

119.36
75.85

1460.8
177.25

528.5
4.879

151.2
8.235

200
200

0.001939
0.001939

11.596
0.0011686

-14814
10981

179.96
308.93

85.63
68.23

119.86
76.64

1438.2
178.87

496.5
4.979

149.4
8.497

204
204

0.0026276
0.0026276

11.531
0.0015535

-14333
11284

182.34
307.92

85.94
69.01

120.38
77.45

1415.7
180.46

467.4
5.079

147.5
8.765

208
208

0.003513
0.003513

11.465
0.0020385

-13850
11590

184.68
306.99

86.29
69.81

120.94
78.28

1393.2
182.01

440.8
5.179

145.6
9.037

212
212

0.0046377
0.0046377

11.399
0.0026425

-13365
11898

186.99
306.16

86.65
70.63

121.53
79.13

1370.8
183.53

416.5
5.279

143.7
9.315

216
216

0.00605
0.00605

11.332
0.0033866

-12878
12208

189.27
305.41

87.05
71.46

122.15
80.01

1348.5
185.00

394.1
5.378

141.8
9.597

220
220

0.0078045
0.0078045

11.265
0.0042942

-12388
12520

191.52
304.74

87.47
72.32

122.80
80.91

1326.2
186.44

373.4
5.477

139.9
9.884

224
224

0.0099624
0.0099624

11.198
0.0053905

-11895
12835

193.73
304.14

87.92
73.18

123.48
81.83

1304.0
187.82

354.4
5.575

138.0
10.176

228
228

0.012592
0.012592

11.131
0.0067034

-11400
13151

195.93
303.60

88.40
74.07

124.19
82.78

1281.8
189.16

336.7
5.674

136.1
10.47

D4650 08
TABLE 1

Continued

T
K

p
MPa

r
moll-1

H
Jmol-1

S
Jmol-1K-1

Cv
Jmol-1K-1

Cp
Jmol-1K-1

c
ms-1

h
Pas

l
mWm-1K-1

232
232

0.015766
0.015766

11.063
0.0082627

-10901
13469

198.09
303.13

88.89
74.98

124.93
83.75

1259.7
190.45

320.3
5.772

134.2
10.78

236
236

0.019568
0.019568

10.995
0.0101

-10400
13788

200.23
302.73

89.42
75.90

125.70
84.76

1237.6
191.69

305.1
5.869

132.3
11.08

240
240

0.024086
0.024086

10.926
0.012251

-9895.3
14109

202.35
302.37

89.96
76.84

126.50
85.79

1215.6
192.87

290.9
5.966

130.4
11.40

244
244

0.029415
0.029415

10.857
0.01475

-9387.3
14432

204.45
302.07

90.53
77.80

127.33
86.85

1193.7
194.00

277.6
6.064

128.6
11.71

248
248

0.035656
0.035656

10.787
0.017637

-8875.9
14756

206.53
301.82

91.13
78.78

128.20
87.94

1171.8
195.06

265.2
6.160

126.7
12.03

252
252

0.042919
0.042919

10.717
0.020952

-8360.9
15082

208.58
301.61

91.74
79.78

129.10
89.06

1149.9
196.06

253.5
6.257

124.8
12.36

256
256

0.051319
0.051319

10.646
0.024739

-7842.3
15408

210.62
301.44

92.37
80.80

130.02
90.22

1128.1
197.00

242.6
6.354

123.0
12.70

260
260

0.060978
0.060978

10.575
0.029042

-7319.7
15736

212.64
301.32

93.03
81.84

130.98
91.40

1106.4
197.86

232.3
6.450

121.19
13.03

264
264

0.072022
0.072022

10.503
0.033908

-6793.2
16065

214.65
301.23

93.70
82.89

131.98
92.62

1084.7
198.66

222.6
6.547

119.4
13.38

268
268

0.084586
0.084586

10.430
0.039388

-6262.7
16394

216.64
301.18

94.39
83.96

133.00
93.88

1063.0
199.38

213.5
6.644

117.6
13.73

272
272

0.098809
0.098809

10.357
0.045533

-5727.8
16725

218.62
301.16

95.10
85.05

134.06
95.16

1041.4
200.03

204.9
6.740

115.8
14.08

276
276

0.11484
0.11484

10.283
0.052397

-5188.6
17055

220.58
301.17

95.83
86.15

135.15
96.49

1019.8
200.59

196.7
6.838

114.1
14.45

280
280

0.13282
0.13282

10.208
0.060039

-4644.9
17387

222.53
301.21

96.57
87.27

136.28
97.85

998.26
201.08

189.0
6.935

112.3
14.82

284
284

0.15291
0.15291

10.132
0.068517

-4096.6
17719

224.46
301.28

97.33
88.41

137.44
99.25

976.74
201.47

181.6
7.034

110.6
15.20

288
288

0.17526
0.17526

10.055
0.077896

-3543.4
18051

226.39
301.37

98.10
89.56

138.64
100.69

955.24
201.78

174.6
7.133

108.9
15.58

292
292

0.20005
0.20005

9.9773
0.088241

-2985.3
18383

228.31
301.48

98.89
90.72

139.88
102.17

933.77
202.00

168.0
7.233

107.2
15.97

296
296

0.22744
0.22744

9.8985
0.099622

-2422.1
18714

230.21
301.62

99.70
91.90

141.15
103.70

912.32
202.13

161.7
7.334

105.6
16.37

300
300

0.2576
0.2576

9.8186
0.11212

-1853.7
19046

232.11
301.78

100.51
93.10

142.47
105.27

890.88
202.15

155.6
7.436

103.9
16.78

304
304

0.2907
0.2907

9.7376
0.12580

-1279.9
19377

234.00
301.95

101.34
94.31

143.83
106.89

869.44
202.08

149.9
7.540

102.3
17.20

308
308

0.32694
0.32694

9.6553
0.14075

-700.5
19707

235.88
302.14

102.18
95.53

145.24
108.56

848.01
201.89

144.3
7.646

100.7
17.64

312
312

0.36648
0.36648

9.5717
0.15707

-115.4
20037

237.75
302.35

103.03
96.76

146.69
110.29

826.57
201.61

139.0
7.754

99.16
18.08

316
316

0.40952
0.40952

9.4867
0.17485

475.7
20365

239.62
302.56

103.90
98.01

148.20
112.08

805.11
201.2

134.0
7.865

97.62
18.53

320
320

0.45624
0.45624

9.4002
0.19420

1072.8
20693

241.48
302.80

104.78
99.27

149.76
113.94

783.62
200.69

129.1
7.978

96.10
18.90

324
324

0.50684
0.50684

9.3122
0.21521

1676.3
21018

243.34
303.04

105.66
100.55

151.38
115.87

762.10
200.05

124.4
8.095

94.61
19.48

328

0.56152

9.2224

2286.3

245.20

106.56

153.07

740.53

119.9

93.14

D4650 08
TABLE 1

Continued

T
K

p
MPa

r
moll-1

H
Jmol-1

S
Jmol-1K-1

Cv
Jmol-1K-1

Cp
Jmol-1K-1

c
ms-1

h
Pas

l
mWm-1K-1

328

0.56152

0.23803

21342

303.29

101.84

117.87

199.28

8.215

19.98

332
332

0.62047
0.62047

9.1307
0.26278

2903.0
21663

247.04
303.55

107.47
103.13

154.83
119.97

718.90
198.38

115.5
8.339

91.69
20.49

336
336

0.6839
0.6839

9.0371
0.28961

3526.8
21982

248.89
303.82

108.40
104.45

156.67
122.17

697.19
197.35

111.3
8.467

90.27
21.02

340
340

0.75201
0.75201

8.9414
0.31868

4157.8
22298

250.74
304.09

109.33
105.77

158.60
124.47

675.39
196.17

107.2
8.601

88.88
21.58

344
344

0.82501
0.82501

8.8434
0.35017

4796.3
22611

252.58
304.36

110.28
107.10

160.62
126.90

653.49
194.83

103.3
8.740

87.51
22.15

348
348

0.90313
0.90313

8.7429
0.38429

5442.7
22919

254.42
304.64

111.24
108.43

162.77
129.46

631.45
193.35

99.44
8.886

86.16
22.75

352
352

0.98658
0.98658

8.6397
0.42128

6097.4
23223

256.26
304.92

112.22
109.77

165.04
132.19

609.25
191.69

95.71
9.038

84.84
23.37

356
356

1.0756
1.0756

8.5335
0.46139

6760.7
23523

258.11
305.19

113.21
111.11

167.46
135.10

586.88
189.86

92.08
9.199

83.54
24.03

360
360

1.1704
1.1704

8.4241
0.50492

7433.0
23816

259.96
305.46

114.22
112.46

170.06
138.25

564.31
187.85

88.54
9.369

82.27
24.72

364
364

1.2712
1.2712

8.3111
0.55224

8115.0
24102

261.81
305.73

115.26
113.82

172.86
141.68

541.49
185.65

85.07
9.550

81.02
25.44

368
368

1.3783
1.3783

8.1941
0.60376

8807.2
24380

263.66
305.98

116.31
115.21

175.92
145.48

518.41
183.24

81.68
9.742

79.79
26.20

372
372

1.492
1.492

8.0727
0.65996

9510.3
24650

265.52
306.22

117.39
116.63

179.27
149.72

495.02
180.62

78.36
9.947

78.58
27.02

376
376

1.6124
1.6124

7.9462
0.72142

10225
24909

267.40
306.45

118.51
118.10

183.00
154.54

471.27
177.76

75.09
10.17

77.39
27.88

380
380

1.7399
1.7399

7.8141
0.78888

10953
25155

269.28
306.65

119.66
119.62

187.19
160.09

447.13
174.66

71.86
10.41

76.22
28.81

384
384

1.8749
1.8749

7.6755
0.86320

11694
25388

271.17
306.83

120.86
121.21

191.99
166.57

422.54
171.29

68.67
10.67

75.07
29.82

388
388

2.0175
2.0175

7.5292
0.94551

12451
25604

273.09
306.98

122.10
122.88

197.59
174.29

397.44
167.64

65.49
10.95

73.93
30.92

392
392

2.1682
2.1682

7.3739
1.0372

13226
25801

275.02
307.10

123.41
124.63

204.28
183.68

371.76
163.69

62.33
11.27

72.81
32.13

396
396

2.3274
2.3274

7.2077
1.1403

14021
25973

276.98
307.16

124.80
126.47

212.51
195.40

345.43
159.41

59.16
11.62

71.70
33.48

400
400

2.4954
2.4954

7.0280
1.2573

14841
26116

278.98
307.17

126.28
128.42

223.05
210.57

318.35
154.77

55.96
12.03

70.60
35.03

404
404

2.6729
2.6729

6.8308
1.3920

15690
26220

281.03
307.10

127.89
130.51

237.22
231.11

290.40
149.74

52.70
12.50

69.53
36.85

408
408

2.8602
2.8602

6.6104
1.5502

16577
26275

283.15
306.92

129.65
132.78

257.67
260.79

261.43
144.27

49.34
13.05

68.48
39.07

412
412

3.0582
3.0582

6.3565
1.7415

17518
26259

285.37
306.58

131.63
135.31

290.35
308.00

231.23
138.31

45.79
13.74

67.51
41.93

416
416

3.2676
3.2676

6.0492
1.9840

18541
26134

287.76
306.01

133.97
138.28

352.04
396.04

199.49
131.77

41.93
14.64

66.79
46.01

420
420

3.4897
3.4897

5.6393
2.3227

19721
25806

290.49
304.98

136.99
142.07

514.51
623.01

165.59
124.46

37.39
15.96

67.19
53.10

424
424

3.7262
3.7262

4.8868
2.9801

21424
24823

294.42
302.43

142.65
148.13

2001.10
2609.40

127.24
115.73

30.58
18.84

79.51
77.92

D4650 08
TABLE 2 Thermophysical Properties of Normal Butane Along Isobars
T
K

r
moll-1

H
Jmol-1

S
Jmol-1K-1

140
150
160
170
180
190
200
210
220
230
240
250
260
270
272.31
272.31
280
290
300
320
340
360
380
400
420
440
460
480
500
520
540
560

12.564
12.404
12.243
12.083
11.922
11.760
11.597
11.433
11.267
11.098
10.927
10.753
10.576
10.394
10.351
0.046045
0.044602
0.042873
0.041289
0.038480
0.036056
0.033938
0.032067
0.030400
0.028904
0.027552
0.026324
0.025203
0.024176
0.023230
0.022357
0.021548

-21826
-20674
-19517
-18353
-17181
-16000
-14807
-13602
-12382
-11146
-9891.0
-8615.5
-7317.7
-5995.4
-5685.7
16750
17488
18466
19466
21532
23694
25954
28313
30773
33331
35986
38737
41581
44516
47539
50648
53840

138.28
146.22
153.69
160.75
167.45
173.83
179.95
185.83
191.50
197.00
202.34
207.55
212.64
217.63
218.77
301.16
303.83
307.26
310.65
317.32
323.87
330.33
336.70
343.01
349.25
355.43
361.54
367.59
373.58
379.51
385.37
391.18

140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
320
340
352.62
352.62
360
380
400
420
440
460
480
500
520
540
560

12.570
12.411
12.251
12.091
11.931
11.770
11.608
11.444
11.279
11.112
10.942
10.770
10.594
10.413
10.229
10.038
9.8412
9.4218
8.9549
8.6234
0.42728
0.40955
0.37116
0.34181
0.31812
0.29835
0.28143
0.26670
0.25369
0.24209
0.23164
0.22217

-21767
-20616
-19459
-18295
-17124
-15943
-14752
-13547
-12329
-11093
-9839.7
-8565.9
-7270.0
-5950.0
-4603.9
-3229.6
-1824.8
1087.1
4159.1
6199.6
23270
24245
26878
29536
32248
35025
37875
40802
43807
46890
50051
53289

138.19
146.13
153.60
160.65
167.35
173.73
179.84
185.72
191.39
196.88
202.21
207.41
212.49
217.48
222.37
227.19
231.95
241.35
250.66
256.55
304.96
307.70
314.81
321.63
328.25
334.70
341.04
347.27
353.40
359.45
365.41
371.30

Cv
Jmol-1K-1

Cp
Jmol-1K-1

c
ms-1

h
Pas

l
mWm-1K-1

114.91
115.44
116.04
116.77
117.63
118.65
119.85
121.22
122.79
124.54
126.49
128.63
130.97
133.52
134.15
95.27
96.77
98.84
101.03
105.67
110.52
115.48
120.48
125.45
130.36
135.18
139.90
144.49
148.97
153.32
157.54
161.64

1793.4
1730.2
1669.6
1610.6
1552.6
1495.4
1438.8
1382.6
1326.8
1271.4
1216.2
1161.4
1106.7
1052.3
1039.7
200.07
203.31
207.36
211.28
218.74
225.80
232.55
239.03
245.29
251.36
257.25
262.99
268.59
274.06
279.42
284.66
289.80

1889
1371
1056
845.4
695.1
583.2
496.9
428.7
373.8
328.6
291.1
259.4
232.4
209.2
204.2
6.748
6.945
7.200
7.452
7.952
8.446
8.934
9.419
9.899
10.38
10.85
11.32
11.78
12.25
12.71
13.17
13.62

174.9
171.2
167.3
163.0
158.6
154.1
149.4
144.7
139.9
135.2
130.5
125.8
121.2
116.7
115.7
14.11
14.82
15.77
16.75
18.80
20.98
23.28
25.72
28.27
30.96
33.78
36.72
39.79
42.98
46.31
49.76
53.34

114.88
115.40
116.00
116.72
117.57
118.58
119.77
121.13
122.68
124.41
126.34
128.45
130.76
133.27
135.98
138.92
142.09
149.32
158.25
165.40
132.62
131.74
131.97
134.10
137.13
140.64
144.41
148.29
152.21
156.11
159.98
163.79

1796.8
1733.9
1673.5
1614.8
1557.2
1500.3
1443.9
1388.1
1332.7
1277.6
1222.9
1168.5
1114.4
1060.6
1006.9
953.24
899.57
791.34
679.85
605.80
191.42
197.12
210.36
221.49
231.27
240.10
248.23
255.80
262.94
269.71
276.17
282.37

1905
1381
1064
851.3
700.1
587.4
500.6
432.0
376.7
331.4
293.6
261.8
234.7
211.3
191.0
173.1
157.3
130.3
107.8
95.14
9.064
9.229
9.690
10.16
10.62
11.09
11.55
12.02
12.48
12.93
13.38
13.84

175.1
171.5
167. 4
163.4
159.0
154.4
149.8
145.1
140.4
135.6
131.0
126.3
121.8
117.3
112.9
108.7
104.5
96.58
89.13
84.64
23.47
24.30
26.68
29.23
31.93
34.77
37.74
40.84
44.07
47.42
50.91
54.52

114.85
115.36
115.95

1800.5
1737.9
1677.9

1923
1393
1072

175.4
171.8
167.9

Pressure = 0.1 MPa


83.81
83.84
83.92
84.12
84.46
84.96
85.63
86.47
87.48
88.65
89.97
91.43
93.03
94.74
95.16
85.13
86.83
89.13
91.50
96.40
101.45
106.54
111.64
116.69
121.67
126.54
131.30
135.93
140.43
144.80
149.05
153.16
Pressure = 1 MPa
83.86
83.89
83.97
84.17
84.51
85.01
85.68
86.52
87.52
88.69
90.01
91.48
93.07
94.79
96.61
98.54
100.54
104.79
109.33
112.37
109.97
111.18
115.04
119.28
123.67
128.13
132.59
136.99
141.32
145.55
149.68
153.71
Pressure = 2 MPa
140
150
160

12.578
12.419
12.260

-21702
-20551
-19394

138.09
146.03
153.49

83.92
83.94
84.03

D4650 08
TABLE 2

Continued

T
K

r
moll-1

H
Jmol-1

S
Jmol-1K-1

Cv
Jmol-1K-1

Cp
Jmol-1K-1

c
ms-1

h
Pas

l
mWm-1K-1

170
180
190
200
210
220
230
240
250
260
270
280
290
300
320
340
360
380
387.52
387.52
400
420
440
460
480
500
520
540
560

12.100
11.941
11.780
11.619
11.457
11.293
11.126
10.958
10.787
10.613
10.435
10.252
10.065
9.8708
9.4601
9.0072
8.4882
7.8483
7.5472
0.93517
0.83711
0.73671
0.66788
0.61565
0.57375
0.53891
0.50919
0.48337
0.46062

-18231
-17060
-15880
-14690
-13486
-12269
-11035
-9782.4
-8510.4
-7216.6
-5899.1
-4556.0
-3185.2
-1784.7
1115.7
4167.9
7410.6
10925
12360
25579
27639
30732
33754
36778
39838
42947
46116
49348
52647

160.54
167.23
173.61
179.72
185.59
191.26
196.74
202.07
207.26
212.34
217.31
222.19
227.00
231.75
241.11
250.35
259.62
269.12
272.86
306.97
312.2
319.75
326.78
333.50
340.01
346.36
352.57
358.67
364.67

84.22
84.56
85.06
85.73
86.57
87.57
88.74
90.06
91.53
93.12
94.84
96.66
98.58
100.59
104.83
109.34
114.16
119.56
121.95
122.68
123.85
126.72
130.34
134.27
138.32
142.39
146.43
150.42
154.34

116.66
117.51
118.51
119.68
121.03
122.56
124.27
126.17
128.26
130.54
133.00
135.66
138.52
141.61
148.56
156.96
167.92
185.44
196.87
173.29
159.11
151.92
150.78
151.92
154.13
156.91
160.00
163.26
166.60

1619.5
1562.2
1505.6
1449.6
1394.2
1339.1
1284.5
1230.3
1176.4
1122.8
1069.6
1016.6
963.76
911.00
805.11
697.16
583.69
456.34
400.48
168.10
184.18
202.90
217.41
229.57
240.18
249.70
258.40
266.46
274.00

858.0
705.6
592.0
504.7
435.6
380.0
334.4
296.4
264.4
237.2
213.7
193.3
175.4
159.5
132.5
110.1
90.65
72.69
65.88
10.92
10.98
11.24
11.59
11.98
12.38
12.80
13.23
13.66
14.09

163.7
159.3
154.8
150.2
145.6
140.9
136.2
131.5
126.9
122.4
118.0
113.6
109.4
105.3
97.44
90.12
83.25
76.62
74.07
30.78
31.66
33.83
36.40
39.22
42.23
45.40
48.72
52.19
55.79

140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
320
340
360
380
400
410.85
410.85
420
440
460
480
500
520
540
560

12.585
12.426
12.268
12.109
11.951
11.791
11.631
11.469
11.306
11.141
10.974
10.804
10.632
10.456
10.275
10.090
9.8996
9.4970
9.0566
8.5593
7.9662
7.1622
6.4340
1.6821
1.4245
1.1738
1.0348
0.93874
0.86587
0.80748
0.75899
0.71770

-21636
-20486
-19330
-18167
-16997
-15818
-14628
-13425
-12208
-10976
-9725.0
-8454.7
-7162.8
-5847.7
-4507.4
-3140.0
-1743.6
1145.1
4179.5
7391.1
10839
14691
17240
26273
28427
32114
35469
38738
41998
45280
48601
51973

137.99
145.92
153.39
160.43
167.12
173.50
179.60
185.47
191.13
196.61
201.93
207.11
212.18
217.14
222.02
226.82
231.55
240.87
250.07
259.24
268.56
278.43
284.72
306.70
311.89
320.47
327.93
334.89
341.54
347.97
354.24
360.37

114.82
115.32
115.91
116.61
117.45
118.44
119.60
120.93
122.44
124.14
126.02
128.08
130.32
132.74
135.35
138.15
141.16
147.88
155.82
165.79
180.13
210.58
279.05
291.72
205.30
172.40
164.69
162.84
163.34
164.99
167.28
169.92

1804.1
1741.9
1682.2
1624.1
1567.1
1510.9
1455.3
1400.2
1345.5
1291.3
1237.5
1184.1
1131.1
1078.5
1026.1
974.03
922.12
818.38
713.55
605.20
488.16
348.01
240.08
140.09
161.75
189.36
208.23
223.17
235.76
246.79
256.68
265.71

1941
1405
1081
864.7
711.0
596.7
508.7
439.3
383.3
337.4
299.2
267.1
239.7
216.1
195.6
177.6
161.7
134.6
112.3
93.08
75.67
58.34
46.84
13.52
12.86
12.57
12.68
12.93
13.24
13.59
13.97
14.36

175.6
172.1
168.2
164.0
159.7
155.2
150.7
146.0
141.4
136.7
132.1
127.5
123.0
118.6
114.3
110.1
106.0
98.29
91.08
84.37
78.04
71.67
67.78
41.02
38.57
39.23
41.35
43.99
46.94
50.12
53.49
57.02

140
150
160
170
180
190
200
210

12.599
12.442
12.285
12.127
11.970
11.812
11.653
11.493

-21505
-20355
-19200
-18039
-16870
-15692
-14503
-13302

137.79
145.72
153.18
160.22
166.90
173.27
179.36
185.22

114.76
115.25
115.82
116.51
117.33
118.30
119.43
120.74

1811.4
1749.9
1690.8
1633.3
1576.9
1521.3
1466.4
1412.0

1977
1428
1098
878.1
722.1
606.1
516.9
446.6

176.1
172.6
168.8
164.7
160.5
156.0
151.5
146.9

Pressure = 3 MPa
83.98
84.00
84.08
84.27
84.61
85.11
85.78
86.61
87.62
88.79
90.11
91.58
93.17
94.89
96.71
98.63
100.63
104.86
109.35
114.10
119.28
125.62
131.03
134.55
132.14
133.32
136.31
139.83
143.56
147.37
151.19
154.98
Pressure = 5 MPa
84.10
84.11
84.18
84.37
84.71
85.21
85.87
86.71

D4650 08
TABLE 2

Continued

T
K

r
moll-1

H
Jmol-1

S
Jmol-1K-1

Cv
Jmol-1K-1

Cp
Jmol-1K-1

c
ms-1

h
Pas

l
mWm-1K-1

220
230
240
250
260
270
280
290
300
320
340
360
380
400
420
440
460
480
500
520
540
560

11.332
11.170
11.005
10.838
10.669
10.496
10.320
10.140
9.9548
9.5670
9.1483
8.6862
8.1588
7.5216
6.6460
4.6563
2.5025
1.9754
1.7051
1.5278
1.3979
1.2963

-12088
-10857
-9609.3
-8342.2
-7054.2
-5743.4
-4408.4
-3047.2
-1658.3
1210.4
4214.3
7375.2
10728
14340
18405
24326
31574
35948
39764
43400
46973
50535

190.87
196.34
201.65
206.83
211.88
216.82
221.68
226.45
231.16
240.42
249.52
258.55
267.61
276.87
286.78
300.52
316.67
325.99
333.78
340.91
347.65
354.13

87.72
88.89
90.21
91.67
93.27
94.99
96.81
98.72
100.72
104.94
109.39
114.06
118.98
124.35
130.86
141.61
141.80
143.37
146.11
149.32
152.73
156.24

122.22
123.88
125.72
127.73
129.91
132.26
134.78
137.48
140.34
146.66
153.90
162.47
173.30
189.21
223.30
450.47
250.79
199.26
184.83
179.63
178.08
178.32

1358.1
1304.7
1251.7
1199.3
1147.3
1095.7
1044.6
993.90
943.54
843.60
744.04
643.65
540.35
430.26
304.64
155.71
162.44
188.80
208.77
224.97
238.73
250.78

389.9
343.4
304.8
272.3
244.6
220.8
200.1
182.0
166.0
138.8
116.6
97.64
80.92
65.43
49.76
28.47
16.76
15.20
14.78
14.72
14.83
15.04

142.3
137.7
133.2
128.6
124.2
119.9
115.6
111.5
107.5
99.92
92.91
86.47
80.56
75.04
69.55
63.93
51.25
49.80
51.14
53.45
56.29
59.46

140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
320
340
360
380
400
420
440
460
480
500
520
540
560

12.617
12.461
12.305
12.149
11.994
11.837
11.681
11.523
11.364
11.204
11.043
10.879
10.713
10.545
10.374
10.199
10.020
9.6482
9.2520
8.8235
8.3508
7.8150
7.1824
6.3836
5.2865
4.0503
3.2073
2.7037
2.3765
2.1438

-21342
-20192
-19038
-17878
-16710
-15534
-14347
-13148
-11936
-10708
-9463.5
-8200.1
-6916.4
-5610.7
-4281.5
-2927.3
-1546.5
1300.8
4273.2
7386.1
10659
14122
17829
21895
26569
31735
36502
40777
44777
48642

137.54
145.47
152.92
159.95
166.63
172.99
179.07
184.92
190.56
196.02
201.32
206.47
211.51
216.43
221.27
226.02
230.70
239.89
248.90
257.79
266.63
275.51
284.55
294.01
304.39
315.38
325.12
333.50
341.05
348.08

114.69
115.16
115.72
116.38
117.18
118.13
119.24
120.52
121.97
123.59
125.38
127.33
129.45
131.72
134.15
136.72
139.45
145.38
151.99
159.45
168.08
178.64
192.92
215.85
252.63
253.10
224.13
205.30
195.82
191.36

1820.5
1759.7
1701.4
1644.6
1589.0
1534.2
1480.0
1426.5
1373.4
1321.0
1269.0
1217.6
1166.8
1116.5
1066.8
1017.6
968.94
873.03
778.73
685.58
592.97
500.14
406.27
311.63
228.45
195.26
199.23
212.67
227.03
240.47

2023
1458
1120
895.0
735.9
617.8
527.1
455.6
398.0
350.9
311.7
278.8
250.7
226.6
205.7
187.4
171.2
143.9
121.6
102.9
86.66
72.13
58.71
45.82
33.22
23.78
19.42
17.58
16.76
16.42

176.8
173.3
169.6
165.6
161.4
157.0
152.6
148.1
143.5
139.0
134.5
130.0
125.7
121.4
117.2
113.2
109.3
101.9
95.06
88.88
83.31
78.31
73.80
69.61
65.53
61.51
59.19
59.12
60.49
62.73

140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300

12.635
12.480
12.325
12.171
12.017
11.862
11.707
11.552
11.396
11.238
11.079
10.919
10.756
10.592
10.425
10.255
10.082

-21178
-20029
-18876
-17717
-16550
-15375
-14190
-12993
-11783
-10558
-9316.5
-8056.5
-6776.6
-5475.5
-4151.6
-2803.5
-1429.9

137.30
145.22
152.66
159.69
166.36
172.71
178.79
184.63
190.26
195.70
200.99
206.13
211.15
216.06
220.87
225.60
230.26

114.62
115.08
115.62
116.27
117.05
117.98
119.06
120.31
121.73
123.31
125.06
126.97
129.02
131.23
133.58
136.06
138.68

1829.4
1769.4
1711.8
1655.8
1600.9
1546.8
1493.4
1440.6
1388.4
1336.8
1285.8
1235.4
1185.7
1136.5
1088.1
1040.2
993.02

2070.6
1488.3
1141.4
912.0
749.8
629.5
537.3
464.6
406.2
358.4
318.6
285.2
256.8
232.4
211.2
192.7
176.3

177.4
174.0
170.4
166.4
162.3
158.0
153.6
149.2
144.7
140.2
135.8
131.4
127.1
122.9
118.8
114.8
111.0

Pressure = 7.5 MPa


84.25
84.24
84.31
84.50
84.83
85.33
85.99
86.83
87.84
89.01
90.33
91.80
93.39
95.11
96.93
98.84
100.84
105.04
109.47
114.06
118.82
123.79
129.06
134.82
140.91
145.41
148.38
151.26
154.33
157.57
Pressure = 10 MPa
84.39
84.37
84.43
84.62
84.95
85.45
86.11
86.95
87.96
89.13
90.45
91.92
93.51
95.23
97.05
98.96
100.96

D4650 08
TABLE 2

Continued

T
K

r
moll-1

H
Jmol-1

S
Jmol-1K-1

Cv
Jmol-1K-1

Cp
Jmol-1K-1

c
ms-1

h
Pas

l
mWm-1K-1

320
340
360
380
400
420
440
460
480
500
520
540
560

9.7235
9.3461
8.9438
8.5098
8.0346
7.5052
6.9034
6.2060
5.4101
4.6089
3.9401
3.4352
3.0595

1399.1
4345.8
7421.2
10638
14011
17563
21326
25347
29654
34125
38529
42770
46870

239.39
248.32
257.11
265.8
274.45
283.11
291.86
300.8
309.96
319.09
327.72
335.73
343.18

105.15
109.56
114.11
118.79
123.57
128.48
133.51
138.61
143.52
147.84
151.55
154.96
158.28

144.30
150.46
157.19
164.61
172.93
182.54
194.14
208.29
221.41
223.43
216.25
208.15
202.21

900.52
810.46
722.73
637.27
554.16
473.76
397.04
326.99
272.28
243.50
236.05
239.33
247.22

148.8
126.5
107.8
91.84
77.78
65.18
53.70
43.21
34.02
27.08
22.71
20.20
18.78

103.7
97.10
91.10
85.77
81.08
77.00
73.48
70.44
67.87
65.91
64.94
65.13
66.32

140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
320
340
360
380
400
420
440
460
480
500
520
540
560

12.703
12.553
12.404
12.255
12.106
11.958
11.810
11.662
11.513
11.365
11.215
11.065
10.914
10.763
10.610
10.455
10.299
9.9823
9.6571
9.3222
8.9765
8.6189
8.2491
7.8672
7.4747
7.0739
6.6690
6.2660
5.8726
5.4975

-20522
-19376
-18226
-17070
-15908
-14738
-13559
-12369
-11166
-9949.7
-8717.7
-7468.8
-6201.6
-4914.9
-3607.5
-2278.2
-926.2
1849.8
4726.5
7708.6
10799
14001
17314
20739
24273
27913
31652
35480
39384
43347

136.34
144.25
151.67
158.68
165.32
171.64
177.69
183.50
189.09
194.5
199.74
204.84
209.81
214.67
219.42
224.09
228.67
237.63
246.34
254.87
263.22
271.43
279.51
287.48
295.33
303.07
310.71
318.21
325.58
332.78

114.37
114.78
115.27
115.86
116.58
117.44
118.45
119.61
120.93
122.40
124.02
125.78
127.67
129.69
131.82
134.05
136.38
141.27
146.44
151.80
157.30
162.88
168.46
173.99
179.38
184.53
189.28
193.44
196.81
199.34

1864.1
1807.0
1752.1
1698.7
1646.4
1595.0
1544.3
1494.3
1445.0
1396.5
1348.7
1301.6
1255.4
1210.0
1165.5
1121.8
1079.1
996.50
917.76
843.08
772.69
706.89
646.04
590.48
540.54
496.45
458.47
426.95
402.13
383.87

2271
1614
1231
981.1
805.9
676.8
578.2
500.7
438.6
387.8
345.7
310.4
280.4
254.7
232.4
213.0
195.9
167.4
144.4
125.5
109.6
95.94
84.11
73.73
64.57
56.49
49.41
43.28
38.08
33.76

179.8
176.7
173.3
169.6
165.8
161.7
157.6
153.4
149.2
144.9
140.8
136.6
132.5
128.6
124.7
121.0
117.3
110.6
104.4
98.88
94.05
89.92
86.45
83.64
81.44
79.80
78.67
78.03
77.84
78.08

Pressure = 20 MPa
84.93
84.88
84.91
85.08
85.41
85.90
86.57
87.41
88.42
89.59
90.91
92.38
93.98
95.70
97.52
99.43
101.42
105.60
109.98
114.48
119.04
123.62
128.20
132.73
137.20
141.58
145.85
149.99
154.00
157.88

D4650 08
The symbols are:
T, temperature (K)
r, molar density (moll-1)
H, molar enthalpy (Jmol-1)
S, molar entropy (JK-1mol-1)
Cv, constant volume molar heat capacity (JK-1mol-1)
Cp, constant pressure molar heat capacity (JK-1mol-1)
c, speed of sound (ms-1)
h, viscosity (Pas)
l, thermal conductivity (mWm-1K-1)

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