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ELEMENTS SOLUTIONS
r /
_ J
TECHNICAL
FINAL
REPORT
SUBMITTED
TO
NATIONAL MARSHALL
SUBMITTED
BY
SHAWKY July
Shawky Project
H. Tadros, Manager
N94-I3048 (NASA-CR-193481) TRACE ELEMENTS IN SULFATE SOLUTIONS Report (Alabama A DETERMINATION TRIGLYCINE Final Technical & M Univ.) OF
Uncl 14 p
as
G3/25
0177366
OF
TRACE
ELEMENTS SOLUTIONS
SULFATE NAG08-204
TECHNICAL
FINAL
REPORT
SUBMITTED
TO
NATIONAL MARSHALL
SUBMITTED
BY
TADROS 1993
Shawky Project
H. Tadros, Manager
Ph.D.
Jeanette VP,Reseach
CONTENTS
Acknowledgement
Abstract
Objectives
Introduction
Research
Plan 4
measurements
Periodic
measurements
second group
Elements
behaviour
in a mixture
Electrochemical
series
Extension
of
the project I0
References
,}
oo
Acknowledgement
is
extended
to
Dr.
Donald
Chemistry
Department,
suggestion Hanley
fruitful as a
discussion. dependable
Sean
served
competant,
assistant.
ABSTRACT Ten elements first group were divided iron, into nickel, 2 groups. The elements manganese, included in the copper,
included
Chromium,
zinc,
medium.The glycine
was performed
5100
Atomic
Spectrophotometer. was the observation of chromium of glycine. the concentration These of that there which
of these in the
experiments concentration
and gold,
these
elements
Further other
research
elements will
(TGS) solutions.
elements calcium,
magnesium,
strontium,
most likely
elements
to be found
the sulfuric
the violet
compounds,
1-naphthyl
such as gold,
Title: Determination Objectives: I. To spike a triglycine the elements sulfate Fe, Ni, (TGS) solution Cr, with 5 ppm of Trace Elements in Triglycine sulfate solutions.
of each of
Cd, 2. To and remove Au.
from above
the
TGS
by
determining 3. To recognize
elements that
elements
the
derivative
1-naphthyl
isocyanate
glycine.
Introduction: Triglycine has received of sulfate (TGS) is an infrared as a A in detector good space the material candidate lab 3 that for experiment
fluid
growth
cell. that
extensive metals initial the the result TGS the lined of and
sulfuric as a result
itself, of the
foil.
crystal
solution largely o%
hardware metals
the
accuracy
trace
solutions.
plan: of Fe, second metals nickel, group Cd, each sulfate polyethylene solution in I the it first and were Ni, studied. chromium, of Au. of each group The flask like of before each group in was spiked was up in a I% in the a mark. The Cr, zinc, first copper, Zn, group Cu, composed and Co, gold, lead,
composed gold,
cobalt,
cadmium, ppm of
element (TGS)
solution.
put to
without removed
TGS. by
bottle
reacting
with
1-naphthyl
isocyanate
ether 0
fi
medium.
/_-N:C:O
H2N-CH2COOH
_'_/'_'HN-C-HN-CH2COOH
l-naphthy]
isocyanate
+ glycine
l-naphthyl
isocyanate
glycine
The
derivative
1-naphthy1 and
glycine was
was
by
gravity
filtration,
analyzed
elements. of the control atomic for analysis solution absorption purpose. The were also determined.
Table
Element
CH
two. week
three week
four week
I14 week_F24week s
5.0
5.1
5.0
5.1
Cr
3.1
3.1
3.0
3.0
Ni
w/out
TGS with TGS 5
3.1
5.1
5.1
Mn
w/out
TGS with TGS
5.0
5.1
5.1
5.1
Au
w/out
TGS with TGS 5 .1
3.1
3.1
.1
.I
.1
.I
.I
Fe
w/out
TGS with TGS
5.1
5.1
5.0
5.1
Table
2:
elements
Element
at once
on wee_
two, week
three week
_een w_ r
24 week week
W/out TGS
5
with TGS
5.1
Cd w/out
TGS
5 5 5.1
with TGS
Pb w/out
TGS
5 5 5.0
with TGS
5
5 5 5 5
5.1
Au
w/out
TGS with TGS
Elements
Behaviour
in
Mixture:
Chromium a strong
atom, reducing in
Cr,
in agent
the
is
considered
equillibrium
eq.
will _Cr3++ 3+ Cr
shifted 3e-
right
-0.744 spiked
(Tabl_ by 2 the
absorption by I)
ppm
were (I-NICG)
chelated (Table 3) It is is
glycine
3+
ion seeking
Au
(Table species.
considered considered
a a in
acid" oxidizing is
the side: 3+ +
chemical
equillibrium
shifted
(2) gold by
detected
chelated Au week
decrease the
structural can be
formula
compounds
represented can be
by used
formula confirm
indicated this
figure
spectroscopy
structural
._-IR
.M, Oo
Proposed
Formula
(.0 Z
Li _ K _ Ca _ Na _ Mg _ Be = AI _ Mn _ ZnCam) _ Cr = Ga _ Fe _: Cd _z Co ,z Ni = Sn (weiID = Pb = D2 H2 = = = = = _z = =
+ O + O + 2 G + O + 20 + 20 + 30 + 20 +2o + 30 + 30 + 2O + 2 0 + 20 + 20 + 2O + 2 O + 2 O + 2 O + + + + + + 2 O O 20 20 20 30
_ 3.04561 -- 2.925 -- 2.866 -- 2.714 -- 2.363 -- 1.847 -- 1.662 -- 1.180 -- 0.7627 -- 0.744 --0.529 -- 0.4002 --0.4029 -- 0.277 -- 0.250 --0.136 -- 0.126 -- 0.0034 0.0000 + + + + ~+ + 0.337 0.7991 0.854 0.987 1.2 1.498
u,1 t-z uJ
m z
r,4
t,--4
W e_
Cu Ag Hg Pd Pt Au
x 0
to
the
research in
elements will
solutions.
include
magnesium,
the
sulfuric
our
research colored
of the
derivative elements,
1-naphthyl such as
glycine
different
References
I.
Mitchell, Ed.
c.
A. s F.
Organic Inc. E.
Vol.
VIII p.
5th 234
Balckiston A. 80-90
2.
"Lerhbuch Berlin,
Auflage,
Gryter:
New
1976,
i0