JNTU SYLLABUS (CM05044) APPLIED CHEMISTRY

UNIT I: Water Technology-I:

Introduction, Effect of Water on Rocks and Minerals, Types of impurities in Water, Hardness of Water – Temporary
and Permanent hardness. Units and inter conversions of Units. Estimation of hardness by EDTA Methods. Problems
on Temporary and Permanent hardnesses. Analysis of Water - Alkalinity; Chlorides and Dissolved Oxygen.
Disadvantages of Hard Water. Methods of Treatment of Water for Domestic Purposes - Sedimentation, Coagulation,
Filtration, Disinfection - Sterilization, Chlorination,Break point chlorination, Ozonization.
UNIT II: Water Technology-II:
Water for Industrial purpose - Water for Steam Making-Boiler Troubles – Carry Over - Priming and Foaming, Boiler
Corrosion, Scales and Sludges, Caustic Embrittlement. Water Treatment: - Internal Treatment – Colloidal, Phosphate,
Calgon, Carbonate, Sodium aluminate Conditioning of Water. External Treatment - Lime-Soda Process, Zeolite
Process, Ion- Exchange Process; - Numerical Problems.
UNIT III: Science of Corrosion:
Definition, Examples, Types of Corrosion: Theories of Corrosion and Mechanism – Dry Corrosion, (Direct Chemical
attack), Wet Corrosion, (Electro Chemical Theory) Principles of Corrosion, Galvanic Series, Galvanic Corrosion,
Concentration Cell Corrosion, Mechanism of Wet Corrosion – Hydrogen evolution type, Oxygen absorption type.
Factors Influencing Corrosion. Control of Corrosion – Proper Design, Use of pure metal and metal alloys, Passivity,
Cathodic Protection – Sacrificial anode and Impressed Current. Modifying the Environment, use of Inhibitors.
UNIT IV: Protective Coatings and their applications:
Surface Preparation: (1) Solvent Cleaning (2) Alkali Cleaning (3) Pickling and Etching (4) Sand Blasting (5)
Mechanical Cleaning.
Types of Protective Coatings: Metallic Coatings – Anodic Coatings, Galvanization, Cathodic Coatings – Tinning,
Metal Cladding, Electroplating Ex: Chromium Plating, Metal Spraying, Cementation–Sheradizing, Colourizing,
Chromizing.
Chemical Conversion Coatings: (1) Phosphate (2) Chromate (3) Anodized Coatings.
UNIT V: Polymer Science and Technology:
Polymerization Reactions – Basic concepts. Types of Polymerization – Addition and Condensation Polymerizations.
Plastics –Thermosetting and Thermoplastics – Differences. Compounding and Moulding of Plastics – Compression,
Injection, Transfer, and Extrusion molding methods. Preparation, Properties and Engineering Uses of the Following:
Polyethylene, PVC, Teflon, Bakelite, Nylon, Polyester, Polyurethane and Silicone Resins. Rubber – Processing of
Natural Rubber, Vulcanization and Compounding. Elastomers – Buna S, Buna N, Thiokol. Polyurethane Rubber.
UNIT VI: Refractories and Insulators:
Refractories – Definition, Classification With Examples; Criteria of a Good Refractory Material; Causes for the failure
of a Refractory Material; Insulators – Definition and Classification with Examples; Characteristics of Insulating
Materials; Thermal Insulators, Electrical Insulators - Their Characteristics and Engineering Applications.
UNIT VII: Lubricants:
Principles and function of lubricants - Types of Lubrication and Mechanism – Thick Film or Hydrodynamic Lubrication,
Thin Film or Boundary Lubrication, Extreme Pressure Lubrication. Classification and properties of lubricants-
Viscosity, flash and fire point, cloud and pour point, aniline point, Neutralization Number and mechanical strength.

UNIT VIII: Inorganic Cementing Materials:

Cement: Important Parameters for Manufacturing Cement Clinkers. Chemical Constituents and Composition of
Cement. Methods of Manufacture of Cement – Wet and Dry Processes. Additives for Cement. Properties of Cement -
Setting and Hardening. Types of Portland Cement.

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GURU NANAK Engineering College I B.Tech Hand Book Page - 1
Subject APPLIED CHEMISTRY

Faculty B.SRINIVAS
Book1 Text Book of Engineering Chemistry By Jain &Jain Publishers:Dhanpat Rai

Text Book of Engineering Chemistry By C..P.Murthy , C.V.Agrawal,and AndhraNaidu & B.S

Book2
publication.
Text Books for references
Book 3 Text book of Engineering Chemistry By S.S.Dara Publishers:Chand
Book 4 Text book of Engineering Chemistry By Shashi Chawla Publishers Dhanpat Rai & Co
Book 5 Engineering Chemistry By R.gopalan, D.Venkappaya and S.Nagarajan, Vikas publishers

Chapters No of Classes
Unit Topic
B-1 B-2 B-3 B-4 B-5
Water
I 1 2 1 6 18 7+1*
Technology-I
Water
II 1 2 1 6 18 9+1*
Technology-II
Science of
III Corrosion 7 8 4 17 6 9+1*
Protective
IV Coatings and 8 8,9 4 - 7 8+1*
their applications
Polymer Science
V 3 9 9 1 16 12+1*
and Technology

Refractories &
VI 11 10,1 16 8,14 11 7+1*
Insulators

VII Lubricants 10 7 5 7 13 7+1*

Inorganic
VIII Cementing 11 11 6 9 10 11+1*
Materials
Classes forCombustion
above curriculum topics 03
Descriptive tests 06
On – line tests 03
Revisions 03
Total no of classes 93

* Indicates Tutorial Class

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 Assignments

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 UNIT-I Water Technology - I
1. a) What is meant by “hardness” of water. And what are the disadvantages of hard
Week -1 water? b) Distinguish between temporary and permanent hardness of water. C) What
are its units? D) How do you express the hardness of water?
2. (a) What is the principle of EDTA method? Explain the estimation of hardness of
water by complex metric method.
(b) Mention the dis-advantages of using hard water for industrial purpose.
3. (a) Explain the terms temporary and permanent hardness of water. (b) How do you
estimate the temporary hardness of water by EDTA method? (c) 50 ml of a sample of
hard-water was titrated against 0.01 M EDTA, required 48 ml of EDTA for titration.
50 ml of the same hard-water after boiling and filtering etc. required 35ml of the
EDTA for titration. Calculate the total and temporary hardness of water in degree
Clark.
1. (a) Estimation of free chlorine in water samples.
(b) Discuss the impurities in water and their effects.
c. Explain the sedimentation process for the treatment of municipal water
Week-2 2. Write a short note on the following: (a) Break - point chlorination (b) Dissolved
oxygen (c) Hardness of water (d) Sedimentation and coagulation.
3. Distinguish the following: [4+4+4+4] (a) Hard water and soft water (b) carbonate
and non-carbonate hardness (c) mg/litre and ppm (d) Sedimentation and filtration.
1. What is meant by disinfection? What is its significance? Explain the different
methods used for disinfection of surface water.
2. (a) Why is sterilization of water necessary? Discuss any two methods of
sterilisation. (b) 0.5 g of CaCO3 was dissolved in dil.HCl and diluted to 1000 mL. 50
mL of this solution required 48 mL of EDTA solution for titration. 50 mL of hard
Week-3
water sample required 15 mL of EDTA solution for titration. 50 mL of same water
sample on boiling, filtering etc, required 10 mL of EDTA solution. Calculate
the different kinds of hardness in ppm.
3. Write short notes on the following: [4+4+4+4] (a) Units of hardness of water
(b) Break point chlorination (c) Filtration of water (d) Impurities in water
UNIT-II Water Technology – II
1. Write short notes on the following:
a) Carry over b) Phosphate conditioning (c) Caustic embrittlement
2. a) Write short notes on Internal treatment methods
b) State the disadvantages of scale formation in boilers.
Week-4 3. Distinguish between the following: (a) Scales and Sludge’s (b) Soft water and
dematerialized water. (c) Lime soda process and demineralization of water.
4. What are boiler scales? How their compositions effect the boiler? What are their ill
effects? Discuss the measures for their prevention. (b) Compare the lime soda process
with zeolite process of water softening. [8+8]
Week-5 1. (a) Describe the demineralisation of water by ion - exchange method.
(b) Mention the disadvantages of using hard water for any two industries
2. Explain the Ion-exchange method for the removal of dissolved impurities and its

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 advantages over lime soda process
3. (a) Explain the cold lime soda process and hot lime soda process. What are the
advantages of lime soda process? (b) 100 ml of a water sample contains hardness
equivalent to 25 ml of 0.08 N MgSO4. [8+8]
i. What is the hardness of water sample in ppm? ii. What is the amount of lime and
soda required for the treatment of the water sample?
3. Explain the Ion-exchange method for the removal of dissolved impurities and its
Advantages over lime soda process. [16]
1) a) What is the chemical composition of Zeolite? How are they classified? Explain
the mechanism of the treatment of hard water by Zeolites.
b) A Zeolite softener was exhausted and regenerated by passing 100 liters of NaCl
solution containing 585 gms per liter. Calculate the total hardness of the water sample
in ppm, if the Zeolite softener can soften 1000 liters of water before regeneration.
2) Write a comparative statement on lime soda & Zeolite process.
Week-6 3) Calculate the lime and soda needed for softening 50,000 litres of water containing
the following salts: CaSO4 = 136 mg/lit; MgCl2 = 95 mg/lit; Mg(HCO3)2 = 73 mg/lit;
Ca(HCO3)2= 162 mg/lit. Given that the molar mass of Ca(HCO3)2 is 162 and that of
MgCl2 is 95
4) Determine the amount of soda and lime required in Kg’s to soften 5000 lit of water
containing the following salts MgCl2 = 15.5 ppm, Ca(Hco3)2 = 32.5 ppm, Ca(No3)2 =
22.4 ppm, NaCl = 50 ppm, KCl = 22.5 ppm.
UNIT-III Science of Corrosion
1) Explain the process of wet corrosion by evolution of hydrogen and absorption of
oxygen (or) Describe the electrochemical theory of corrosion.
2) Differentiate the following with suitable examples. a) Galvanic series and
Week-7 electrochemical series. b) Pitting corrosion ad stress corrosion.
3)(a) What is meant by differential aeration corrosion? Illustrate with suitable
examples. (b) How is rate of corrosion influenced by i. Nature of corrosion product ii.
Relative anodic to cathodic areas iii. Temperature and moisture.
4) (a) What is oxidation corrosion and how does it take place? Describe the
mechanism of oxidation corrosion. (b) Describe the various factors influencing the
rate of chemical corrosion.
5) Write down the equation for the hydrogen evolution in an electro chemical
Week-8
corrosion reaction?
6. (a) What is oxidation corrosion and how does it take place? Describe the
mechanism of oxidation corrosion. (b) Describe the various factors influencing the
rate of chemical corrosion.
1. What are the factors effecting corrosion?
2. a) Explain the following factors influencing the rate of corrosion. i. Nature of
corrosion product ii. Position in electrochemical series iii. pH. (b) Differentiate
Week-9
between dry corrosion and wet corrosion
3. Define corrosion? Explain any 4 factors that affect the rate of corrosion & explain
any 4 corrosion control methods.

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 1. Explain how corrosion control can be brought about by the following methods.
Week-10 a) Modifying the environment b) Cathodic protection.
2. Write a short note on Inhibitors & Cathode protection.
UNIT-IV Protective Coatings and their Applications
Explain the protective coatings you would choose for steel; cast iron and concrete
pipe. Give reasons for your answer.
Week-11
2. (a) Write short notes on chromizing (b) How pH of an electrolyte affects
electrodeposit? (c) Explain the method of coating for protection of furnace parts
1.(a) Describe the mechanism of drying of conjugated oils. (b) Name any four
important drying oils. (c) Define the following:i. Acid value of an oil ii.
Saponification Value iii. Iodine Value.
2. Write notes on Surface preparation.
Week-12
3. (a) Discuss how the surface of a metal is prepared prior to the application of a
protective coating.
(b) Write the important applications of protective coating.
(c) Why is moderate current density employed during electroplating?
What is metallic coating? Name the metallic coating methods.
2. (a) Describe the process of sheradizing? Mention its applications?(b) Distinguish
between anodizing and electroplating. (c) Define Anodizing
Week-13
3. (a) List the differences between anodic coating and cathodic coating. (b) How zinc
coated on iron prevents corrosion? (c) Explain sand blasting method of surface
preparation?
1. Explain in detail the various methods of Chemical conversion coatings
2. (a) Explain the following: i. Alkali Cleaning ii. Mechanical cleaning. (b)
Week-14
Describe the principles involved in electro plating. (c) Anodized coating is
preferred for Aluminium - Give Reasons.
UNIT-V Polymer Science & Technology
1. Write the differences between a) compression-Injection moulding b) additional
polymerization-condensation polymerization c) thermoset-thermoplasts.
Week-15
2. Explain any one of the mechanism of additional polymerization, using suitable
example. .
1. Write a note on thermo setting plastics? Write a note on properties and uses of
Teflon.
2.Describe the manufacture , properties ,uses of a)polyethylene
Week-16
b) Teflon c) Thiokol d) PVC
3.(a) How is HDPE is prepared? Give its properties and uses? (b) Explain the
injection moulding process with a neat diagram? Mention its advantages.
Week-17 1.What is moulding of plastics? Explain compression moulding technique in detail.
2.How is Bakelite manufactured? Discuss its important uses and properties.
3. Identify the thermosets & thermoplasts among the following: PVC, polyethylene,
silicon, polyester fiber, bakelite. What is Bakelite? How is it manufactured and
mention its uses.
4. (a) Differentiate between LDPE & HDPE. (b) What are the drawbacks of raw

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 rubber?(c) Write the repeating unit for the following: i. Nylon 6,6 ii. PVC
1.Describe the preparation, properties and engineering uses of Polythylene.
2. (a) Explain the preparation, properties and uses of Bakelite.
(b) Describe with a neat sketch, the process of compression moulding
Week-18
3. (a) How will you synthesis nylon 6,6 from 1,3 butadiene?
(b) Describe the method of preparation of polyester and mention its properties
and uses. (c) What is the repeating unit of [6+6+4] i. natural rubber ii. Teflon.
1. (a) What are elastomers? Give the preparation, properties and uses of Buna S. (b)
Describe a method for moulding of thermoplastic resin
2. (a) Differentiate between elastomer and plastic. (b) Which rubbers are used in the
preparation of automobile parts? Discuss their manufacture and vulcanization.
Week-19
3 Write preparation, properties and uses of nylon, polyester, and polyurethanes. (a)
Why are Silicones called inorganic polymers? Discuss the synthesis of linear chain
Silicones. (b) Why Bakelite can’t be remoulded and write its repeating unit? (c)
Describe condensation polymerization with an example
UNIT-VI Refractories & Insulators
1. Discuss any FOUR essential properties of a good refractory in detail.
2. What are electrical insulators? Discuss their characteristics & engineering
Week-20 applications.
3. What are thermal insulators? Discuss their engineering applications and
characteristics
1. (a) What are refractories? How important are the properties – refractoriness under
load and thermal conductivity for industrial applications? (b) Compare acidic and
Week-21 basic refractories with examples
2.What do you understand by ‘refractoriness’. Explain its measurement.Write a note
on ‘refractoriness-under-load (RUL)’.
1. (a) Define Refractories and what are the criteria of a good refractory? (b) Give the
classification of refractories with suitable examples
Week-22 2. (a) What is pyrometric cone equivalent? How it is determined for a refractory?
What is its significance?(b) Write a short note on: i. porosity ii. Thermal Conductivity
iii. Dimensional Stability. Iv. Strength
UNIT-VII Lubricants
1. Write a short note on principle and function of Lubricants
2. (a) Give the functions of lubricants. (b) Describe the mechanism of extreme
Week-23 pressure lubrication. C) How a viscous lubricant is converted into grease?
3. Write a note on lubricants with special reference to their classification, mode of
action, examples and uses.
1. Explain the various mechanisms of lubrication in detail.
2.Explain the following two theories for the mechanism of the lubricants.
Week-24 a) Boundary lubrication b) Extreme pressure lubrication
3. (a) Give the functions of lubricants. (b) Describe the mechanism of extreme
pressure lubrication. C) How a viscous lubricant is converted into grease?
Week-25 1. Define lubricant. Discuss the Classification and important properties of the

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 lubricats.
UNIT-VIII Inorganic Cementing Materials
1. What are the chemical constituents of Cement? Discuss the function of each
Week-26
constituent.
1. (a) Why cements are called hydraulic cements? [6] (b) By writing the various
Week-27
chemical reactions involved explain the setting and hardening of cement.
1. (a) Discuss the chemical and physical changes that occur during the setting of
Week-28 cement with relevant chemical equations. (b) Write a note on types of Portland
cements.
1. What is Portland cement? Give its composition. What are the raw materials
required for its manufacture? b) Discuss the chemistry of setting and hardening of
Week-29 cement.
2. a. Write a short note on Additives for cement.
b. Write a note on type of Portland cement.
1. With the help of flow diagram explain the manufacture of Portland cement by dry
Week-30
and wet process.

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