VidyamandirClasses

SolutionstoJEEMains/TestSeries8/IITJEE2013

[CHEMISTRY]

1.(D) 2.(B)

NaBrO3 + 5 NaBr + 3 H 2O Options (A, B, C) are true facts : 6 NaOH + 3 Br2

y = 92 4 = 88 x = 238 8 = 230

B = y z = 86

A = 230

Neutrons in L

230 86

144.

3.(B) 4.(D)
2H 2O2 2H 2O + O2
1 56 2 56

2 mole of H2O2 1 mole of O2

Given : 400 mL O2 at STP

2 56 1000 20 = 100 56

mole of O2

mols of H2O2

So, in 20 mL H2O2: Molarity of H2O2 = Also, 5.(D) 6.(D) 7.(A)

(Molar)
100 56 M H 2O 2 11.2 100 56 20 vol H 2O2

by definition; 1M H 2O2 11.2 vol. H 2O 2

In sheet type silicates, three oxygen per tetrahedron are shared (Refer to NCERT). As a result of lanthanoid contraction, the properties of 4d series become similar to those of 5d series. In depression of freezing point experiment, vapour pressure of solution is less than that of pure solvent because of presence of solute particles. Only solvent molecules freeze at the freezing point.
NH 4 HS(S) NH3(g) + H 2S(g) 0.5 0 0.5 + x x

8.(B)

t=0 t = t eq

Now 0.5 + 2x = 0.84 9.(B)

x = 0.17

k p = PNH3 PH2S = (0.67) (0.17) = 0.11

Greater the value of r, more will be the slope. He r = 5/3 = 1.66 O2 r = 7/5 = 1.4 Ar r = 5/3 = 1.66 N2 r = 7/5 = 1.4 O2 and He respectively.

10.(A) Greater the reduction potential, easier will be the deposition

Ag > Hg > Cu > Mg.

11.(D)

12.(A)

6HNO3 + P2O5 3N 2 O5 + 2H 3PO4

13.(B)

Cu 2+ 45o 3d 9

1 unpaired e ; Ti3+ 45o 3d1

1 unpaired e

14.(C) Nitrous acid test is for amines 16.(C) Glucose having a six member ring is called pyranose

15.(B)

Natural rubber in a polymer of cis-isoprene

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17.(C)
3 CH 3CH = CH 2 CH 3 C HCH 3 CH 3 C H CH 3 CH 3 C H CH 3 | | | Br CN COOH

HBr

alc. KCN

H O+

[Assume alkoxide does not abstract acidic hydrogen from COOH group].

CH 3 CH 3 | | P / Br2 E2 CH 3 C COOH CH 2 = C COOH | Br

18.(B)

Since P gives only one derivative, it will be p-isomers. 19.(C) Increasing pKb means decreasing basicity. Decreasing basicity . . . . . Et2NH > Me2NH > MeNH2 > Me3N 20.(B)
Ph C = CH CH 3 CHO
|

pKb :

IV < II < I < III

Since the reactivity of both aldehydes is almost same, so the formation of carbanion will decide the final product according to the more acidic hydrogen i.e. in Ph CH 2 CHO .
O O O || || || + H / H 2O Oxid R1 C O R 2 R1 C OH + R 2 OH H C OH

21.(A)

R1 = H

R 2 = CH 3

H CO O CH 3

Methyl formate

22.(D) Acetals cannot be reduced.

23.(C) Since benzene is in excess, the next attach will be on the other benzene molecule rather than an intra-molecular attack because after 1st step, the benzene ring is deactivated because of carbonyl group. 24.(C) Alkene must be (Et)2 C = CHCH 3 Hence the original ketone must be Et CO Et and Grignard reagent must be EtMgX. 25.(B) From Bohr model we have: mVrn =
nh 2

n 2 R nh mV = Z 2

9R 3h = For Bohrs radius of H-atom, n = 3, Z = 1 : mV 1 2

mV =

h 6R

From de-Broglies definition : = 26.(A)

S = nCy ln

h mV

= 6R

T2 V 5R T 10 ln + R ln = R ln 10 + nRln 2 = T1 V1 2 T 1 27.(C) The most stable alkene will have the lowest heat of hydrogenation.

28.(C)

t A B

0 a 8a

10 4a

20 2a

30 a

40 a/2

50 a/2 a/4

Hence at t = 50, Nuclei of A = 2 Nuclei of B

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29.(D) 30.(A) [Co(NH3)5ONO]Cl2
3

The correct answer is: Pentaammine nitrito-O cobalt(III) chloride Hence K sp M 2 X = K sp Y2 > K sp PZ3

K sp M 2 X = 4s ; K sp Y2 = 4s3 ; K sp PZ3 = 27s 4

SolutionstoJEEMains/TestSeries8/IITJEE2013

[PHYSICS]

31.(B) 32.(C)

Net force on a current carrying loop in uniform magnetic field is zero = m B = 0 as m is paralled to B
u in yz plane and B is along x-axis uniform circular motion in yz plane, the path of circular motion cutting the positive z-axis and negative y-axis.

33.(C)

B=

0 i $ 3 0 i $ 3 0 i k+ k = 0 and c = 2a
2c 4 2b 4 2a
a=

34.(B)

5b 3 i 1 1 $ B = 0 1 + + ........... k 2 2 4 0 i 1 $ = 1.33 107 k $ k = 2 1 ( 1 / 2 )

1 1 + F = Bil and i = Bvl R R 2 1 $, l = 5 $ B = 3$ i + 4$ j + 5k j, v = 1$ i

35.(B) 36.(B)

1 1 + F = B2l2v2 = 4N R R 2 1

Induced emf = = v B l = 25V

(Scalar triple product)

37.(A) In steady state

UE 1 q 2 ( 200 ) = = J = 1mJ 2 C 2 20
2

1 1 2 U B = Li 2 = 5 ( 5 ) = 62.5 mJ 2 2

38.(A) Let q1 and q2 are charges on left and right capacitors when the current is maximum. di When the current is maximum =0 P.d. across inductor is zero dt q q KVL : 1 + 2 = 0 and by the conservation of charges q1 + q2 = CV0 + 6CV 0 C 3C 5CV0 15CV0 15CV0 q1 = and q2 = P.d. across each capacitor = 4 4 4 By conservation of energy :
3V 1 1 1 5V 2 2 CVv0 + 3C ( 2V0 ) = ( C + 3C ) 0 + Li 2 i = imax = 0 2 2 2 2 4
2 /

3C L

39.(C) 40.(C)

I rms =
cos =

( I1 cos t + I 2 sin t )2 dt
2 /
tan = 1 =

=
xL xC R

2 I I2 + I 2 2

1 2

100 ( 0.1)

1 = 10 100C

C or C = 500 F

41.(A) Air to glass :

1.5 1 1.5 1 = v1 = 30cm v1 10

glass to air : u = 30 5 = 25cm

1 1.5 1 1.5 = v2 = 25cm v2 25 5

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air to glass : u = 25 10 = 35cm glass to air : u = 35 / 3 5 = 50 / 3cm
42.(A) Shift = new fringe width
1 2 hc mv = 2 480 1 2 and m ( 2v ) = 2 hc 1.3 = 400 hc 0.9 = 4500
2

1.5 1 1.5 1 = 35 5 v3

v3 = 35 / 3 cm

( 2D ) Dt ( 1) = d d

1 1.5 1 1.5 = 10 v4 50 / 3

v4 = 25cm

t ( 1) 2

43.(D)

hc 600 hc hc 600

1 120 = 4 480 ( 600 )

600 = = 300nm

44.(C)

1.3 + 9 = 0.9 + 8

10.4 + 8 = 8.1 + 9 = 2.3 eV

45.(C) 18000eV = mc 46.(C)

18, 000 1.6 1019 = m 3 108

m = 3.2 1032 kg

2 1 27.2 9 n 4 1 1 21 n=6 10.2 + 17 = 13.6 z 2 and 4.25 + 5.95 = 13.6 z 2 = 10.2 4 n 2 9 4 n 9 n

( (

) )

z=3

47.(C) more energy is released when B is formed from its nucleons as compared to Energy released when two nucleus of A are formed from their nucleons . 48.(B) 49.(C)
1 1 3 2 C ( 2V ) CV 2 = W CV 2 = W 2 2 2 E5 2 r+5 ( r + 10 ) 2 = E10 2 ( r + 5) 3 3 and r + 10

then

1 1 2 2 C ( 4V ) C ( 2V ) = 6CV 2 = 4W 2 2

50.(B)

3r + 30 = 4r + 20 r = 10

51.(C)

KA ( 200 TB )
TB

KA (TB TC ) KA (TC 20 ) = 2 = 2l l l = 140C and TC = 80C

52.(B)

U a b = 84 32 = 52 kJ

Qadb = 52 + 10.5 = 62.5 kJ Q curve = 52 21 = 73kJ

ba

heat is released.

If Ua = 0, Ud = 42 then Ub = 52, As db is isochoric Wad = Wadb = 10.5 kJ Q ad = 42 + 10.5 = 52.5 kJ Qdb = U db = 52 42 = 10kJ
53.(B)

Let total elongation in the spring is x

loss in GPE = gain in EPF

x= mg + k m2 g 2 k
2

mg ( h + x ) =

1 2 kx 2

kx 2 2mgx 2mgh = 0

2mgh k

amplitude of oscillation = x x0 = A mg k

where x0 : elongation in the spring in equilibrium =

54.(C)
340 + 20 cos 60 0 f = 1000 1094 Hz 340 + 20 cos 60 30

A=

m2 g 2 k
2

2mgh mg 2kh = 1+ k k mg

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55.(C) Let position of projectile if it was not exploded at t = 2sec is (x, y)

x = 30 cos 37 2 = 48 m

and

y = 30 sin 37 2

10 ( 2 )2 = 16m 2

Position of centre of mass of the pieces = (48, 16) at t = 2 sec Let the position of 2nd piece is (x2, y2) 4 (105 ) + 6 ( x2 ) 4 ( 43) + 6 ( y2 ) x2 = 10 48 = 16 = and y2 = 2 10 10
3a a = mg 2 2 mg 3

56.(A) About C : F

F =

57.(D) About A : mg

l mg =T l T = 2 2

58.(B)

required force = P0(bottom area) + weight of liquid about the curved surface 2 2 H2 P H 2 H 3 g H gH P H P0 + H H g = 0 + = H2 0 + 4 2 3 2 4 6 6 4
h = gh 2 Applying Bernaulli theorem at two points just in and just out side the lower hole P0 + gh + 2 gh / 2 P v2 = 0 + 2 v2 = 2 gh v1 : v2 = 1 : 2 g g 2g v1 =

59.(B)

2g

60.(D) Let no of droplates = n 4 4 b3 loss in surface energy = gain in KE b3 = n . a 3 n = 3 3 3 a 3 1 4 b 2 ( b a ) b3 2 6 ( b a ) b 3 4 a 2 4 b 2 = b3 v 2 = v v= 6 a ab 2 3 a

SolutionstoJEEMains/TestSeries8/IITJEE2013

[MATHEMATICS]

61.(A)

x 0

lim log cos x 2 + [|a 1 |]

( (
(

)) = 0

log cos ([|a 1| ]) = 0

cos [ |a 1 |] = 1 0 |a 1| < 1 a ( 0, 2 )

As cos ( 0 ) =1 , [ |a 1 | ] = 0
62.(A) 63.(A)

= 2 4, = 3
n

lim sin 2 ( x )

is discontinuous when sin 2 ( x ) = 1

1 3 and x + is also discontinuous at x = 2 2 2 3+ Q f 2 3 3 = 2 , f = 3, f = 1 2 2

x = ( 2n + 1)

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64.(D) Max. ([x], | x |)

Hence discontinuity at no point

65.(A) Let P ( x, y ) is any point on the ellipse.

Then AN = a x, AN = a + x Since Now

x2 a2 + y2 b2 = 1 a2 x2 = a2 y2 b2

PN 2 y2 PN 2 b2 = 2 = AN .A N a x 2 AN .A N a 2

66.(B)

If P ( , ) lies on the line

x y . . . .(i) + = 1 , then + = 1 a b a b a b The mid-point of AB is h = , k = . Then from (i), 2 2

= 2 . So the locus of (h, k) is

=2

x y = 2 2 4

Which is a rectangular hyperbola with centre , 2 2 4a cos 67.(A) r1 = sin 2

Replacing by 90 for perpendicular chord, r2 =

83

4a sin cos 2

r1r2 =
2

( 4a ) 16a 2 43 ( r1r2 ) = sin cos ( sin cos )4 3

23

Also,

16a

( 4a )

cos 2 3 sin 2 3 ( 4 a ) .1 = 43 + 43 43 sin cos ( sin cos )

83

68.(A) Given, pair of lines xy = 0 , x 4 = 0 x = 4 and y + 5 = 0 . The figure is a rectangle.

In which length is 5 unit and breadth is 4 unit. So, area = 4 5 = 20 sq. unit

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69.(B)

Since, two chords bisect each other, it means both the chords pass through the centre of circle. Length of chords are equal. i.e.

a 2 1 = 3 ( a + 1)

a 2 3a 4 = 0
a=4

( a 4 )( a + 1) = 0
Radius of circle =

(Q a = 1 is not possible)

a 2 1 16 1 15 = = 2 2 2 f ( x ) = 3x 2 24ax + 36a 2

70.(A) Given, f ( x ) = x 3 12ax 2 + 36a 2 x 4

On differentiating w.r.t. x, we get : Put

f ( x) = 0

3 x 2 8ax + 12a 2 = 0

x = 2a, 6a ( x 6a )( x 2a ) = 0 Now, f ( x ) = 6 x 24a At x = 2a, f ( x ) = 12a 24a = 12a < 0 , maxima i.e. p = 2a At x = 6a, f ( x ) = 36a 24a = 12a > 0 , minima i.e., q = 6a

Also, given 3 p = q2

71.(B)

3 2a = ( 6a )

a=

1 6

2e , if x 1 Given, g ( x ) = log ( x 1) , if x > 1

For the point (3, log 2), we take y = g ( x ) = log ( x 1)

dy 1 = dx ( x 1) 1 1 dy = = dx ( 3, log 2 ) 3 1 2

Equation of normal is y log 2 = 2 ( x 3)

y + 2 x = 6 + log 2

72.(C) Let I = e sin log ( sin ) cos d + e sin cosec 2 cos d

Put

sin = t

cos d = dt

I = e log t dt + e t dt
t

t 2

= log t et

1 3

e et .t 1 et .t 1 1 dt + dt = et log t + c = e sin ( log sin cosec ) + c t 1 1 t

t

73.(A) Let

I=

cos
1 3

dx

sin

x sin 4 x

I = cot 1 3 x cos ec 2 x 1 + cot 2 x + dx = 3 3 = cot 2 3 x + cot 8 3 x + c 2 8

)(

( cot

1 3

x + cot 5 3 cos ec 2 x dx

)(

74.(D) Given,

0 f ( x ) dx = 5
I = 100
9 10 0 x f ( x ) dx 1

Let

Put

x10 = t
1

10 x9 dx = dt
1

I = 100

f (t ) 10

dt = 10 5 = 50

9 10 0 f ( x ) dx + 1000 x f ( x ) dx = 5 + 50 = 55

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75.(B)

Required area =
=

2a

x3 2 2a x

dx

(Put x = 2a sin 2 )

3 a 2 sq. unit 2

76.(B)

dy x + x3 = dx 1 + y + x 2 y dy 1 + y + x2 y = dx x + x3 dy y 1 + = dx x x 1 + x2

2 1 dy y 1 + x + = dx x 1 + x 2 x 1 + x2

( (

) )

IF = e

1 dx x

= elog x = x

77.(A) Given, differential equation can be rewritten as

dy y + = e 2 dx x
1 dx =e2 x x x

Here,

P=

1
x

,Q =e

2 x

IF = e

Solution is ye2

= e2

x 2 x

dx = 1dx ye2

= x+c

78.(C) Since, and are the roots of x 2 ax + a + b = 0 , then 2 a = ( a + b ) and 2 a = ( a + b )

2 1 1 2 = + + =0 a + b ( a + b) ( a + b) ( a + b)

79.(C)

f ( c2 ) f ( c1 ) < 0

and

f ( c1 ) f ( c2 ) > 0

f ( c1 ) > 0 and f ( c2 ) < 0

c2 is locus maximum and c1 is local minimum for f (x)

f ( x ) = 0 at least four times in c1 1, c2 + 1 .

80.(A)

ax 2 + bx + 6 = 0 roots are not real

D < 0 b 2 24a < 0 a >

Also,

f ( 1) > 0 a b + 6 > 0

b2 i.e., a is +ve 24

. . . .(i) . . . .(ii)

a >b6

b2 a > max , b 6 ; using equations (i) and (ii). 24

100

Hence, (A) is the correct answer.

81.(C) The given expansion

( x 3) + 2

m=0
100

100 Cm ( x 3)100 m . 2m can be rewritten as

= ( x 1)
100

= (1 x )

100

tr +1 = ( 1) . n Cr . x r
r

Coefficient of x 53 = 100C53
1 f ( x) = x 1 x

82.(C) Given,

( x 1)( x 2 ) ( x 1)( x 2 )( x 3) x ( x 1) x ( x 1)( x 2 )

1 1 3 x3 = 0 x

2 ( x 1)

3 ( x 1)( x 2 )

= ( x 1)( x 1)( x 2 ) x 1 x 2 x 3 x x x

Applying C1 C1 C2 , C2 C2 C3
= ( x 1)
2

( x 2)

1 0

1 0

(Q first and second columns are identical)

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f ( x ) = 0 f ( 49 ) = 0

83.(C) The sum of all the four digit numbers using the digits 3, 5, 7 and 9
104 1 24 6 9999 104 1 = 24 6 = = ( 3 + 5 + 7 + 9 ) ( 4 1) ! 10 1 10 1 9 x

Required average =
1 1 y+ 3 = 3 = z 1 1 1 1 6 3 2

24 6 9999 = 6666 9 24 1 1 p , , 1 3 3

84.(C)

;
1$ 1 $ 1 $ i+ j+ k 6 3 2

Vector collinear to line

u r $ 85.(D) Point p = $ i 2$ j + 3k r $ =5 i$ j +k Plane r . $

r 1 1 $ + $ $ and Eq. of line r = $ i $ j+k i + 2$ j + 3k 3 3 u r P p

r r r r = a + rb

$ vector parallel to line = 2$ i + 3$ j 5k Eq. of P D r u r r r = p + b u r u r u r r Point of intersection D d d = p + b u r r r p + b .n = k u r r k p . n 5 6 +1 = = r r = 6 6 b .n u r $ + 1 2$ $ d = $ i 2$ j + 3k i + 3$ j 5k 6 uuu r 1 4 $ 3 $ 13 $ 1 5$ i j+ k PD = $ i+ $ j k 3 2 6 3 2 6

( )

r r r .n = k

1 1 5 PD = + + = 3 2 6

38 6

86.(D)

r uu r uu r $ ; n = 2$ $ ; n =$ $ a =$ i 2$ j+k i 2$ j +k i $ j + 2k 1 2

$ i $ j uu r uu r n1 n2 = 2 2 1 1

$ k 1 = 3$ i 3$ j 2

r Eq. of Plane r . $ i+$ j = 1 1+ 2 +1 2 = 2 2

Distance from (1, 2, 2) =

87.(D)

(r b) a = 0

; r r Point of intersection = a + b

r r r r = b + a L1 r r r r = a + b L2 r r b (1 ) = (1 ) a

; ;

(r a) b = 0
=1, =1

r r r r b + a = a + b

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88.(B)
r r r r r r | a b c| = | a b | | c | sin 30

$ $ i $ j k $ a b = 2 1 2 = 2$ i 2$ j+k 1 1 0 r r r | a b| = 3 | a | = 3 r r |c a |2 = 8

r r r r | c |2 + | a |2 2a . c = 8 r r r Using a .c =|c| ; r r 9 + | c |2 2 | c | = 8 r r r | c |2 2| c | + 1 = 0 | c | = 1 r r r 1 3 | ab c|=3 1 = 2 2

89.(D)

p = 1 P(books go to same students) 10 ! 1 3 C1 2! 2 ( 4 !) ( 2 !) 2 ! 3 4! 3 8 = 1 = = 1 = 1 12 ! 1 2 ! 11 12 11 11 3! ( 4 !)3 3 !

90.(A)

P=

9 3 4

C3
10

C3 + C3 + ............. +

= C3

9 4 4

C3
10

C4 + C3 + ........... +

= C3

C3 C4

11

9 ! 7 ! 4 ! 74 14 = = 6 ! 3 ! 11 ! 11 10 55

CHEMISTRY 1 D 11 D 21 A PHYSICS 31 B 41 A 51 C 61 A 71 B 81 C 62 A 72 C 82 C MATHEMATICS 63 A 73 A 83 C 64 B 74 D 84 C 65 A 75 B 85 D 66 B 76 B 86 D 67 A 77 A 87 D 68 A 78 C 88 A 69 B 79 C 89 D 70 A 80 A 90 A 32 C 42 A 52 B 33 C 43 D 53 B 34 B 44 C 54 C 35 B 45 C 55 C 36 B 46 C 56 A 37 A 47 C 57 D 38 A 48 B 58 B 39 C 49 C 59 B 40 C 50 B 60 D 2 B 12 A 22 D 3 B 13 B 23 C 4 D 14 C 24 C 5 D 15 B 25 B 6 D 16 C 26 A 7 A 17 C 27 C 8 B 18 C 28 C 9 B 19 C 29 D 10 A 20 B 30 A

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