Академический Документы
Профессиональный Документы
Культура Документы
Rope Dyeing is considered a superior dyeing technology where the dyeing uniformity achieved is better than other Indigo Dyeing technologies like Slasher Dyeing. However, Rope Dyeing is a also a more difficult dyeing technology. One needs to master its nitty gritties to get the best out of the system. I , recently came across a very well written article on Rope Dyeing and thought it appropriate to share here. The article mentions in great details the technical points to be kept in consideration while using Rope Dyeing.. Read on only if you are very technically oriented !
tend to be spun into the solid yarn body rather than remaining on the yarn surface, which is typical of ring spun yarns. Although embedded in the yarn core, these neps still represent a short mass defect and will therefore trigger the imperfection counter upon exceeding the preset value. However, compared to neps that are attached to the yarn surface, fully embedded neps are barely perceptible for the human eye. Thus, in order to balance the typical visual appearance of rotor spun yarn with the imperfection counts, +280 sensitivity setting is a common convention for rotor spun yarns. Comparison of Ring Yarn with OE yarn at Ne 7
1.
Which tenders the yarn. Now at acidic pH reaction is much faster. So we add only a small amount of softener (25 gpl) as against that in indigo which is 100gpl. 3rd Point Over all during sulphur dyeing and storing, the yarn strength is reduced by 15% as compared to Indigo. 4th point If ball formation takes place of sulphur dyed warp at loom shed, then we can taken in 4th dye bath little Na2S+Caustic to reduce the free sulphur.
2. The dyeing is done at room temperature as indigo belongs to Ik class of vat dyes, where dyeing is done at room temperature and oxidation is done by air only and not by chemicals. If oxidizing agents are used, they will cause stripping of colors. 3. Indigo is not soluble in water. So it is reduced with Sodium Hydrosulphide. Then caustic soda is added to make sodium salt of vat colors to make it soluble. To reduce 1 kg of Indigo, 700 gms of sodium hydrosulphide is required. However some extra SHS needs to be taken to avoid some decomposition of SHS. Practically it is prepared in the following sequence -Take indigo -Add caustic -Then reducing agent 4. When caustic is added to indigo, it is an exothermic reaction. It is allowed to cool down, then before sending it to feeder, sodium hydro-sulphide is added. Reducing agent is not added first as it will be decomposed first, so consumption of it will increase. It is also not advisable to take solubalised vat, as offered by some companies due to the following reasons: a. If it is used after 6 months, there will be a decomposition of sod. Hydrosulphide. It will become partially soluble. Then to make it soluble again, more SHS has to be added. b. Transportation is difficult c. Cost is more 5. Feeding System Rat of flow of yarn is given by ((No of ropes x no of ends x speed of machine)/ count x 1.693 x 1000) in kg of yarn / minute So we can determine the rate of feed of indigo. It is very important that replenishment of indigo is there as any variation will result in the change of shade and also if level is more, there is a problem of over-flow. 6. If total capacity of dye bath for example is 15000 litres, then circulation must be 3 times the volume. If it is less then there are 100% chances of getting a lighter shade. 7. Core and ring dyeing effect This effect is obtained by multidip-multinip facility 8. pH of the Dye bath should be kept in between 10.5-11.5. At this pH , sodium salt of Indigo is mono phenolic form. At this form, the strike rate of dye is very high. So after washing, there will be a better dye effect. At pH 11.5 to 11.7, at this affinity is less, so dye effect will be less prominent. pH is controlled by the addition of caustic soda. 9. Testing of Hydro TOTAL HYDRO We take 10 ml of indio with SHS in 30-35 ml of water. It is set for one minute and shaken. As air will decompose SHS. So vacuum created will fetch the water from above. If 3 ml of water is required, then concentration of hydro is 3 gpl. As a thumb rule, concentration of total hydro should be min. 1.5 gpl. REDUCED HYDRO It is the hydro that is used for the reduction of Indigo. It should be around 0.7 ( 1000 kg of Indigo needs 700 kg of hydro to reduce it). For testing we take 10 ml of dye solution and 30 ml of water and 5-6 drops of 40% formaldehyde and shake it for one minute. The water that goes gives the readings of the reduced hydro. Total Hydro- Reduced Hydro = free hydro If Total hydro is min. 1.5 gm/lit. then free hydro must be min. 0.5 gms/ litre which
acts as buffer 10. Also hydro reduction capacity is measured by mV meter which measures the Redox Potential. It should be around 760-800 Through the day, the redox potential should be +- 20 mV of the norm. If it is more then the process control is a failure. Caustic> It is around 0.4 to 0.5 times the hydro used. Washing Rubbing fastness of indigo is very important. On a scale of (1-4), it is 2. Washing is done to improve the rubbing fastness. Wash at 60 deg.> Wash at 60 deg.> Wash at room temperature> wash with softener Why Softener: 1. The rope is going to be opened at Long Chain Beamer. It the softener is not used, opening will be hampered. 2. It is generally 1.2% of the weight of the yarn. It is a cationic softener. It is always having pH in the range of 4 to 55. Softening is done at room temperature. If high temperature is used there is always some chance of tendering of yarn. 3. Concept of Buffer pH is given by Virkler USA, they say by addition of this, there is 40% less consumption of Indigo for same shade depth. 4. Metering Consumption If solution is of 900 litres 10% Indigo>90 litres Hydro> 90*.7 = 63 kg Caustic> 63*0.445= 28 kg. It belongs to a VAT class of dyes. It has a dark blue color wit a bronze lustre. It belongs to KI class of dyes. In this class, dyeing is done at cold and air oxidation is done to reoxidise the dye. It can be applied on both cellulosic and protein fibres. For protein fibres, a weaker alkaline solution is used. It can be reduced by NaOH and Na2SO4 in water to give monophenolate and biphenolate ions as complete solution. Reduced form of Indigo is called leuco indigo. Leuco has got low affinity for cellulosic fibres. Dye take up can be improved by: 1. Either mercerisation of cellulosic fibres before by dyeing 2. or by adopting multidip, squeeze and airing process, so that dye is coated on the fibre layer by layer Indigo can be further developed into Halogenated derivatives and sulphonated derivatives. Halogenated derivatives give better fastness properties and brighter shades, whereas sulphonated derivatives gives a soluble blue dye, good dye and is applicable on protein fibres. reaction : Image 1 Although indigo is a vat dye, it can be regarded as a trash dye, the dyeing and fastness properties are in no way comparable to other class of vat dyes. It is due to these properties, that make it an excellent dye for denim. The on tone fading and the bleach down properties of indigo blue has generated a lot of denim jeans fashions like stone, ice faded looks, etc. These special effects cannot be simulated by the other classes of dyes. During Preparatiuon of stock vat, the following points must be remembered: 1. Vatting temperture should be as close to room temperature as possible.
2. Stirring should be minumum, unnecessary stirring affects the stability of reduced vat. 3. Volume of the reduced vat should be kept constant for every stock vat batch, as the constant volume will ensure a constant replenishing amount. For rope dyeing system, with chemical replenishment with Stock replenishment Indigo: NaOH: Na2SO4 :: 1:0.8:0.8 Without stock replenishment indigo: NaOH: Na2SO4:: 1:1:1.2 Chemical Feeding NaOH: Na2SO4: : 1: 1.2-1.6 ie. for approximately 60 gpl of NaOH> 120 gpl of hydro is required Indigo Dyeing process control 1. Concentration of Hydrosulphite It is measured by vatometer. It should be from 1.5 gpl to 2.5gpl , or by redox potential of dye bath which should be from -730 mV to -860 mV. 2. Caustic Soda or pH value Should be from 11.5-12.5 3. Dye concentration in Dye bath it is measured by spectrophotometer. It should be in g/l Guidelines High Indigo Concentration > Shade is greener and lighter Low Indigo Concentration > Shade is dull and Red. High pH or Caustic Concentration > Redder and lighter Low pH or caustic concentration > greener and darker Dipping Time Longer the dipping time, better will be the penetration and lesser will be the ring dyeing effect. It varies from 15-22 seconds. Squeeze Pressure High pressure will lead to lower wet pick up and result in lesser color and better penetration. At rope dyeing, squeeze pressure is 5-10 tonnes, ie. wet pick up is as low as 60%. Hardness of squeeze roller is about 70-75 deg. shores. It sqeeze rolls are too hard then there are chances of slippage and uneven yarn tension.. If squeeze rollers are too soft then shading will occur. Surface of the squeeze rolls should be ground twice a year. Airing Time It should be 60-75 seconds. Longer airing time results in high tension on the yarn and subsequent processes will become difficult. Drying Insufficient or unevenly dried yarns will result in poor rebeaming Calculation of Replenishing Dye feed/min Conc. of stock vat is g/l= 90 range speed in yards/min=25 count = 7s totoal ends = 4100 Wt of yarn dyed /min= (4100*25*1000)/(7*840*202)= 7924 gms shade desired = 2% Amount of dye to be replenished/min= 158.5 gms
Effect of pH At pH of 10.5 to 11.5, there will be formation of more monophenolate ions, which lead to higher color yield, as strike rate of the dye to the yarn bundle is very high, and wash down activities will be very good. At pH higher than this, dye penetration will be less and wash down characteristics are also poor. Testing 1. Alkalanity in Dye Bath Liquor Pipet 10.0 ml of vat liquor into 100ml of distilled water in a 150 ml beaker. place under continuous agitation and insert the electrodes of a pH meter caliberated at pH 7.0 with standard buffer solution. Titrate with tenth normal HCl ( 0.1 HCl) to pH 7.0 (ml = A) calculate g/l of NaOH = A *0.40 2. Hydro in Dye bath Liquor Add 2 ml of 37% HCHO to 150 ml beaker. Add 2 ml of dye range liquor . Add 6 ml of 25% glacial acetic acid solution prepared by diluting 1 part acid with 3 parts water. Add 2 ml of starch/KI indicator. Add ml of water. Titrate with 0.046 N ( prepared by diluting 460 ml of 0.1 N Iodine to one liter ) solution until the color changes from emarald green to bluish purple. G/l of hydro= mo fo 0.046N of Iodine Importance of High Concentration of Free Hydrosulphite The clearest shades with minimum reddish streaks are observed at by relatively high conc. of hydrosulphite. On the other side, with lack of hydrosulphite, the leuco indigo is less dissolved and thereby adheres to a greater extent to the fibres. With lack of hydrosulphite furthermore, the amount of unreduced dyestuff by oxidation at the upper level of the liquor and through activiation of unfixed dyestuff, gets separated from the fibrous material would constantly rise as the reducing agent for creating leucoform would be missing. Under these circumstances a reddish bronze like shade results due to dispersion of not reduced dyestuff in the yarn. The min. proportion of hydrosulphite should be around 1.3 to 1.5 gpl in case of rope dyeing and 3-4 gpl in case of sheet dyeing. Also to avoid the lack of hydrosulphite or Indigo at certain places in the immersion, vat, the whole quantity of the liquor should be circulated 2-3 times every hour. Reaction Time At very short reaction time, an adequate liquor exchange ( i.e. the amount of chemicals consumed and replaced by fresh addition of reduced indigo) is not assured. This has a negative influence on dyeing and depth of dye penetration. In addition to this the time available for diffusion of dyestuff until oxidation commences is too short. To ensure an even and good depth of dye penetration by dyeing in several passages, the reaction time should be 20-30 sec. for each vat (eg. at a speed of 20m/min for a reaciton time of 10 seconds, the immersion path should be maximum 3.3 meters). A reaction time exceeding 60 seconds should be avoided as the amount of dyestuff again get reduced and released may again supersede that of additionally take up dye stuff, resulting in higher shades. Softening Agent: 8 g/lit Drying: Rest humidity should be 30% and then sized. Addition of chemicals
1. Red Tinge: reduce addition of NaOH, increase slightly Na2S2O3 2. Darkish Red: increase Hydro 3. Light Greenish: decrease Hydro 4. Dark Green: Increase Caustic Indigo dyeing calculations For 12 ropes, at 24 m/min, of 344 ends of 14000 m length of 7s count. wt of yarn = (12*344*14000*100*453.6)/(7*840*36*2.54*1000) kg= 5000 kg at 24 m/min, a lot of 14000 m will be completed in 14000/24 = 583.3 min at 1.8% shade 100 kg of yarn needs> 1.8 kg of Indigo 5000 kg of yarn needs > 90 kg of dye at 100 gpl 100 gms of dye = 1 lit of solution 90 kg of dye = 900 litres 900 litres should be completed in 583.3 min 1 litre would be completed in = 583.3/900= 38.8 seconds so flow rate will be 38.8 seconds / litre Similarly flow rate of caustic and hydro can be determined Hydro is taken around 100 gpl caustic is taken around 90 to 100 gpl Indigo preparation sequence In a tank of 1000 liters: a. take 400 litres of water (soft) b. add setamol ws> 4 g/l (stirring) ( dispersing solution) c. Add 100 kg of Indigo ( at 1.8 % shade -see the indigo calculations- stirring) d. add caustic soda > stirring ( for solubilising and pH) e. allow to cool it for 2/3 hours f. Add hydrosulphide ( As reducing agent) g. Make the solution to 1000 l by adding water. If pH is fluctuating, if it is > 11.7 then hydro is added (2-3 kg), if (<11.2) then caustic is added. For 100 kg of Indigo, Caustic Required= 90 kg Hydro Required= 80 kg
About the author : M Bilal Tariq has worked as a Deputy General Manager in a reputed Denim Mill in Pakistan . He is a textile Engineering Graduate and also maintains a Denim Blog Want to Get our Denim Articles Free? Enter Your Email Address . You can unsubscribe any time :)