Concept Recap Test Mains 4 Sol

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ANSWERS, HINTS & SOLUTIONS

CRT(SetIV)

ANSWERS KEY
PHYSICS CHEMISTRY MATHEMATICS
Q. No. ANSWER ANSWER ANSWER
1. C B D
2. C D C
3. A A B
4. C D A
5. D B D
6. A D B
7. A C D
8. D B B
9. C D C
10. A D C
11. A C C
12. C B B
13. A C A
14. A C A
15. D A A
16. B B B
17. A C A
18. B B A
19. C B D
20. D C A
21. B D C
22. B A B
23. B A D
24. B C A
25. D D D
26. D D B
27. B D B
28. B C D
29. B B D
30. A A D
A
L
L

I
N
D
I
A

T
E
S
T

S
E
R
I
E
S

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AITS-CRT(Set-IV)-PCM(S)-JEE(Main)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
2
P Ph hy ys si ic cs s PART I

SECTION A

1. Since V
L
= V
C
,
so it is resonance.
and
V
i
R
=

2. Energy lost in the collisions
rel
2 2
r
1
m U (1 e )
4
= .

3. The equivalent circuit is

eq
V 2V
I
R R
= and current through ammeter is halved

ammeter
I V
I
2 R
= =
V
A
R
R

4.
0
q
V
4 d
=
;
2
0
q
E
4 d
=

5. initially the current in the circuit is zero, and there is no potential drop across the internal
resistance.

1 2
1 2
di di
L L ,
dt dt
= = at t = 0.
At any time t,

1 2
1 2
di di
L L ir
dt dt
= =

6.
3 2 3 4
(1.2 10 10 10 10 ) (10 10 ) F

= Buoyant force = weight
F = 20 N in down ward direction

7. % error in V 6%
% error in i 1%
maximum percentage error in value of R is 6%.
R = (20 1.2).

8. Kinetic energy is maximum at centre and potential energy is minimum.

10.
32
5 9
C F
= .

11.
dt
dv
a =

dt
dv
kv
2
= ,

=
v
v
2
t
0
0
v
dv
kdt
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3

v
1
v
1
kt
0
= +

t kv 1
v
v
0
0
+
=

12. When an incident ray I
is reflected by a mirror whose normal is N
, the reflected ray is given by

the following :

( I.N)N
R 2 I
(N.N)
= +

Using this expression twice, we get the result,

2j 2k i
R
3
+
=

13. =60
Let A = acceleration of (5M) (horizontal rightward)
FBD of (5M) along X-axis
T 2T
Nsin Tcos
A

T Tcos Nsin 5MA + =

N 2Mgcos 2Mgcos 60 Mg = = =

1 3
T T Mg 5MA
2 2
+ =

3T 3Mg 10MA =
(i)
y
x
(horizontal)

FBD of (M) along X-axis
Let a = acceleration of M
T + MA = Mg (ii)
FBD of 2M along incline
2 Mg sin - 2 MA cos - T = 2 Ma
T
a
MA

3 1
2Mg 2MA T 2Ma
2 2
=
3Mg MA T 2Ma = (iii)
(i), (ii) and (iii) A = 0

14.
1 2
B
2
B
res
x
y
B
1

15.
min
for n = 2 1.

17. The relative speed between the two image is
zero

I
2
u
u I
1
u

4
18.
2
1 1
.
2
mgx
dU Adx
LA y
| |
=
|
\ .

2 2
2
2 2
0
1
2
l
m g A
U x dx
L A Y
=

2 2
6
m g l
U
AY
= .

19. The torque due to the normal reaction (N) and friction (f) about the C.M. topple the body in the
forward direction.

21. A node is a point where there is no vibration. There is vibration at other points where nodes are
not formed.

22. W F.dr =

b dr
.dr
| dr | R
=

b 2 Rb
| dr |
R R
= =
= 2 bJ.

23.
L
C
L
C
2L 2L
i i

25. This balanced wheat stone bridge

4 8 2 4
8 4 2 4
4

+ +
=
x
;
8 32
6 4 12.
=
x

x = 8
T
3
0

P
G
4
8
x
4
8
2
4

27. Use Kirchoffs current law.

28. Using A
1
v
1
= A
2
v
2
(i)
and Bernoullis principle we get

2 2
1 1 2 2
1 1
P v P v
2 2
+ = + ..(ii)
From (i) and (ii)

1 2
1 2 2 2
1 2
2(P P )
v A
(A A )
=

Rate of flow = A
1
v
1
1 2
1 2 2 2
1 2
2(P P )
A A
(A A )
=

But P
1
P
2
= P
5
rate of flow of glycerine
1 2 2 2
1 2
2 P
A A
(A A )
=

29. Surface integral E d S .

=

Eds cos EdS = =

0
2
Gm
dS m G
r
0
4 = =
dS
m
0

30. In adiabatic compression, the temperature always increases and since PV = nRT, the quantity PV
also increases.

6
C Ch he em mi is st tr ry y PART II

SECTION A
1.
M C O
+

3.
cell cell
P
E
G nFE ;n 2; and H nF E T
T
( | |
= = = +
( |
\ .

4.
| |
| || | | || || | | || |
3
1 3 2 2 3 3
d O
K M O K O O M K O O
dt
= +
On applying ssa for intermediate o

| || | | || || | | || |
1 3 2 2 3 3
K M O K O O M K O O = +
| |
| || |
| || | | |
1 3
2 2 3 3
K M O
O
K M O K O
=
+

Then we get
| | | || |
| || | | |
2
3 1 3 3
2 2 3 3
d O 2K K M O
dt K M O K O
=
+

And if K
3
[O
3
] >> K
2
[O
2
][M]
Then
| | | || |
| |
| || |
2
3 1 3 3
1 3
3 3
d O 2K K M O
2K M O
dt K O
= =
Hence K
1
= K (for overall process)
So in the given condition.

1
a a
E E = (for overall process)
5.
S
+
O
( )
3 2
CH CO O
NaOAc
S
+
O
C
CH
3
O C
O
CH
3
O
AcO
S
+
O
H
COCH
3
AcO
AcOH
S
+
O COCH
3
S
O COCH
3
( )
AcO
RDS
S
+
S
AcO
S OAc

6. (A) Bulky groups are stabilized at anti position.

(B)
N H
60
o
hence lone pair resides in almost sp
2
hybrid orbital, i.e. in an orbital
with 33% in S-character. While in

N H

lone pair of N-occupy sp
3
hybrid orbital so its donation is more easy.
(C) At high pH : COOH COO H
+
+
, so two anionic groups stabilised at anti position.

7.
B
H
H
H
B
H
H
B
H
7

8.
O
O
O H
H
O
O
O

10. More stabilised group or ion is better leaving group.

11.
O
S
S
O
O
S
O
O
O
O
O
O

12. Probability density
2
1s 3
0
1
a
=
(at nucleous r = 0)

13. According to Werners theory, only those ions are precipitated which are attached to the metal
atoms with ionic bonds and are present outside the co-ordination sphere.

14. It is cyanide process of extraction of Ag and Au.

15. [Co(en)
2
Cl
2
]
+
shows geometrical as well as optical isomerism.

16.
N
H
3
Si SiH
3
SiH
3

Trigonal planar. Lone pair is no longer available to donate to any lewis acid.

N
CH
3
C H
3
CH
3

Pyramidal, l.p. is localized on N.

18.
3
A
4
b 4 N r
3
= put the values of b, N
A
and and get r = 0.2944 nm.

20. This is because acidity increases with increase in the size of borane. In larger borane, the charge
formed upon deprotonation can be better delocalized over a large anion with many boron atoms
than over a small one.

21. ( )
2
V V
1
T 3
S nC n ;C Ar R
T 2
= =

8
22.
Me
O H
Me
H
+
1,2 methyl shift

( )
o
2
Me
O H
Me
Me
O H
Me
H
( )
o
3
Me
O H
Me
( ) more stable
( ) less stable

23. Diels-Alder reaction is given by conjugated (S)-cis and (S)-trans conformations.

24.
H
o
490 C
CH
3
CH
2

25. In (I) lone pair is delocalized to activate the ring while in (III) lone pair is not delocalized. Among I
and II, N is more basic than sulphur because the lone pair of N resides in a orbital of high p-
character.

26. For E Z priority order is:

OH
OH
O
5
4
3
2
1

Priority for R S configuration OH > = bond > R-grp. > H

C OH
OH
O
H
4
3
2
1
R

But least prior group is attached to solid line so result is S.

28.
H
CH
3
( )
2
2
Hg OAc
H O,ether
Hg(OAc)
CH
3
OH
H
4
2
NaBH
H O,EtOH
H
CH
3
OH
H
1
2
3
5
6
1 methylcyclohexanol

29. -ketoacid decarboxylate at a faster rate.

30. The H is abstracted from the axial position due to stereo electronic factors.

9
M Ma at th he em ma at ti ic cs s PART III

SECTION A
1. R R = {(x, y); 3 x 3, 0 y 5}
dom R R = [3, 3]
Range R R = [0, 5] [0, 4]
(0, 0) R R
and (0, 5) RR
0 is related to 0 as well as 5.
Hence RR does not define a
function.
(0, 5)
(3, 4)
(3, 4)
2. |z
1
+ z
2
| |z
1
| + |z
2
|
3. For real
f(x) = x
2
+ 2bx + 2c
2

(x + b)
2
+ 2c
2
b
2
(2c
2
b
2
)
f(x)
min
= 2c
2
b
2

g(x) x
2
2cx + b
2

(x + c)
2
+ c
2
+ b
2

(b
2
+ c
2
) (x + c)
2
(b
2
+ c
2
)
g(x)
max
= b
2
+ c
2

By the given condition 2c
2
b
2
> b
2
+ c
2

| c | 2| b | >
4. Since cos (n! x) will be a proper fraction between 1 and +1 (excluding 0 and 1) and
(It is) 0 as m .

5. x
2
y
2
= 8

dy
2x 2y 0
dx
=

1 y
dy x
dx

=
| |
|
\ .

At point
5 3
,
2 2
| |
|
\ .

1
1 3
m
dy 5
dx
= =
| |
|
\ .

Also 9x
2
+ 25y
2
= 225
18x + 50y
dy
0
dx
=

dx 25y
dy 9x
=
At point
5 3
,
2 2
| |
|
\ .

2
dx 5
m
dy 3
= =

1 2
m m 1 =
so = 90 =
2

10
6.
2
2
2
1
x 1 dx
x
1 1
x x x
x x
| |
|
\ .
(
| | | |
+ + + + (
| |
\ . \ .
(

Put
1
x z
x
+ =

2
1
1 dx dz
x
| |
=
|
\ .

dz
(z )(z ) + +

2
dz
z ( )z + + +

2 2
dz
z
2 2
+ | | | |
+
| |
\ . \ .

2 2
( )
log z z c
2 2 2
+ + | | | |
+ + +
| |
\ . \ .

( )
log z (z )(z ) c
2
+
+ + + +

7. Since S. D. Range = (b a)
Variance (b a)
2

Var.(X) (b a)
2
or (b a)
2
Var.(X)
8. sin
1
x + sin
1
y + sin
1
z =
sin
1
x + sin
1
y = sin
1
z

1 2 2 1
sin x 1 y y 1 x sin z
(
+ =
(

2 2
x 1 y y 1 x z + =
9. |z| = |z 2|
|z|
2
= |z 2|
2

zz (z 2)(z 2) =
z z 2 + = ..(i)
also |z| = |z + 2|
|z|
2
= |z + 2|
2

zz (z 2)(z 2) = + +
z z 2 + = .(ii)
By (i) and (ii) | z z | 2 + =
10. The system of linear equation will have a non zero solution if
3 3 3
a (a 1) (a 2)
a (a 1) (a 2) 0
1 1 1
+ +
+ + =
Now operate c
2
c
1
and c
3
c
2
, then expand.
11. B = CAC
1

B
2
= (CAC
1
) (CAC
1
) = CA
2
C
1

B
3
= B
2
B = (CA
2
C
1
)(CAC
1
)
= CA
2
(C
1
C)AC
1

= CA
2
.AC
1

= CA
3
C
1

11
12. The number of students answering at least r questions incorrectly = 2
n r

The number of students answering exactly r questions (where 1 r (n 1))
Incorrectly = 2
n r
2
n (r + 1)

The number of students answering all questions wrongly
2 = 1
Thus the total number of wrong answer is
1.(2
n 1
2
n 2
) + 2(2
n 2
2
n 3
)
2
n
1 = 4095
2
n
= 4096
n = 12

13. 2b = a + c ..(i)

2pr
q
p r
=
+
..(ii)
and b
2
q
2
= (ap) (cr) ..(iii)
put b from (i) and
q from (ii) in equation (iii)
then on simplification we get required result.

14.
x 1 x 1
lim f(x) lim(p[x 1] q[x 1])

= + = p(1) q(1) = p + q

x 1 x 1
lim f(x) lim p[x 1] q[x 1]
+ +

= + = 2p q(0) = 2p
f(x) is constant at x = 1
p + q = 2p p = q p q = 0

15. Since f(x) = g(x).(x a)
2

f(x) > 0 if g(a) > 0 and < 0 if g(a) < 0
f is increasing in the nbd of a if g(a) > 0 and f is decreasing in the nbd of a if g(a) < 0

16. f(x) = x
3
+ bx
2
+ cx
f(1) = 1 + b + c
f(2) = 8 + 4b + 2c
By Roles Theorem
f(1) = f(2)
3b + c + 7 = 0 ..(i)
f(x) = 3x
2
+ 2bx + c

4
f ' 0
3
| |
=
|
\ .

By Rolles theorem
8b + 3c + 16 = 0 ..(ii)
By (i) and (ii)

b c 1
5 8 1
= =

b = 5
c = 8.

17. Put a = 2, b = 3, c = 0

2 2
0
dx
2(2 3)(3 0)(0 2) 60
(x 4)(x 9)

= =
+ + +
+ +

12
18. Area of OABCO

1 1
2 2
2 2
0 0
2 c 1 x dx (1 1 x )dx
(
(
(

(
(

1 1
2 2
2
0 0
2 (c 1) 1 x dx 1dx
(
(
(
+
(
(

O
X
A
B
C
(0, 1)
2
1
2
2
0
1
2 1 x dx
2
(
(
(

(
(

2 2
4 2
..(i)
Area inside the circle and outside the ellipse

2 2
4 2
| |

|
|
\ .

1
(4 2)
4
2
+

19. Put
y
z
x
=

dy dz
x z
dx dx
= +

dz 1
x z z
dx z
| |
+ = +
|
\ .

dz 1
x
dx z
| |
=
|
\ .

dz dx
log | c |
1 x
z
= +
| |
|
\ .

Since
x 1
log | cx |
y z
= =

1 dz
1 z
z
=
| |
|
\ .

2
1 1
1
z
z
=
| |
|
\ .

2
2
2
1 y
z
z
x
| |
= =
|
\ .

2
2
x y
y
x
| |
=
|
\ .

13
20. In right angled PAC

2 2
1
CA g f c
tan
2 PA S
+
= =
Now
2
2
1 tan
2
cos
1 tan
2
+

/2
/2
A
B
C
(g, f)
P
(x , y )
1 1

21. Equation of the tangent at the vertex is
x y + 1 = 0 ..(i)
Equation of the axis of the parabola is
x + y + k = 0 ..(ii)
Since it passes through (0, 0)
0 + 0 + k = 0
k = 0
Equation of axis is x + y = 0 ..(iii)
Z A S
Vertex Focus

Where z is a point on directrix
Solving (i) and (iii) we get
1 1
A ,
2 2
| |
|
\ .

z is (1, 1)
Now directrix is
x y + c = 0 ..(iv)
But equation (iv) is passes through z
1 1 + c = 0
c = 2
So directrix is x y + 2 = 0 ..(v)
Using PS = PM
PS
2
= PM
2

22. Equation of a tangent to the ellipse
2 2
2 2
x y
1
a b
+ = is

xcos ysin
1
a b

+ =

a b
A ,0 B 0,
cos sin
| | | |

| |

\ . \ .

Y
X
O
A
B
P

Let P is the mid point of AB, P (h, k)

a
h
2cos
=
..(i)

b
k
2sin
=
.(ii)
Eliminate by (i) and (ii)
23. PQ = 2b tan

2 2 2 2
OQ OP a sec b tan = = +
since OQ = OP = PQ

2
2
1
sin
3(e 1)
=

sin
2
< 1

2
1
1
3(e 1)
<

O
(0, 0)
P(asec , btan )
Q(asec , btan )

14

2
e
3
>

24. Since a is perpendicular to b
Let V xa yb z(a b) = + + .. (A)
Given a.b 0, V.a 0, V.b 1, [Vab] 1 = = = =
By equation (i)

2 2
V.a x a x a 0 x 0 = = = = .. (i)
Again
2
2
2
1
V.b y b 1 yb y
b
= = = .. (ii)
Again
2
V.(a b) z a b =

2
2
1
1 z a b z
| a b |
= =
.. (iii)
Put (i)/(ii)/(iii) in equation (A).
25. Probability that problem is not solved by 1
st
=
1 1
1
2 2
=
Probability that problem is not solved by 2
nd
=
1 2
1
3 3
=
Probability that problem is not solved by 3
rd
=
1 3
1
4 4
=
Probability that problem is not solved by any one of the three =
1 2 3 1
. .
2 3 4 4
=
Hence the required Probability
1 3
1
4 4
=

26. Mean = np = 4
Variance = npq = 3
n = 16,
3 1
q , p
4 4
= =
So P(X 1) = 1 P(X = 0) =
16
3
1
4
| |
|
\ .

27. sin ( + ) = sin cos + cos .sin
12 3 5 4
13 5 13 5
| | | |
= +
| |
\ . \ .

56
65
=

28. cos 2 = sin
cos2 cos
2
| |
=
|
\ .

2 2n
2
| |
=
|
\ .

29. h
1
= x tan 60
h
2
= x tan 30.
30 60
h
1 h
2
A
B C
x x

30. Put b = ar, c = ar
2
, d = ar
3
, e = ar
4
, f = ar
5
.

Concept Recap Test Mains 4 Sol

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Concept Recap Test Mains 4 Sol

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is reflected by a mirror whose normal is N

, the reflected ray is given by

, so two anionic groups stabilised at anti position.

1,2 methyl shift

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