Вы находитесь на странице: 1из 16

Types of Heat-Treatment (Steel)

_ Annealing / Normalizing, _ Case hardening, _ Precipitation hardening, _ Tempering, and Quenching

Time-Temperature- Transformation (TTT)Curve


TTT diagram is a plot of temperature versus the logarithm of time for a steel alloy of definite composition. It is used to determine when transformations begin and end for an isothermal heat treatment of a previously austenitized alloy. _ TTT diagram indicates when a specific transformation starts and ends and it also shows what percentage of transformation of austenite at a particular temperature is achieved.

Decarburization during Heat Treatment _ Decrease in content of carbon in metals is called Decarburization _ It is based on the oxidation at the surface of carbon that is dissolved in the
metal lattice _ In heat treatment processes iron and carbon usually oxidize simultaneously

_
During the oxidation of carbon, gaseous products (CO and CO2) develop _ In the case of a scale layer, substantial decarburization is possible only when the Gaseous products can escape

Decarburization Effects _ The strength of a steel depends on the presence of carbides in its structure
_ In such a case the wear resistance is obviously decreased _ In many circumstances, there can be a serious drop in fatigue resistance To avoid the real risk of failure of engineering components, it is essential to Minimize decarburization at all stages in the processing of steel

Annealing _ It is a heat treatment wherein a material is altered, causing changes in its


properties such as strength and hardness _ It the process of heating solid metal to high temperatures and cooling it slowly so that its particles arrange into a defined lattice

Types of Annealing
1. Stress-Relief Annealing (or Stress-relieving) 2. Normalizing3. Isothermal Annealing 4. Spheroidizing Annealing (or Spheroidizing )

Causes of Residual Stresses


1. Thermal factors (e.g., thermal stresses caused by temperature gradients within the work piece during heating or cooling) 2. Mechanical factors (e.g., cold-working) 3. Metallurgical factors (e.g., transformation of the microstructure)

How to Remove Residual Stresses? _ R.S. can be reduced only by a plastic deformation in the microstructure.
_ This requires that the yield strength of the material be lowered below the value of the residual stresses. _ The more the yield strength is lowered, the greater the plastic deformation and correspondingly the greater the possibility or reducing the residual stresses. _ The yield strength and the ultimate tensile strength of the steel both decrease with increasing temperature

Stress-Relief Annealing Process: _ For plain carbon and low-alloy steels the temperature to which the specimen is
heated is usually between 450 and 650C, whereas for hot-working tool steels and high-speed steels it is between 600 and 750C _ This treatment will not cause any phase changes, but recrystallization may take place. _Machining allowance sufficient to compensate for any warping resulting from stress relieving should be provided

Stress-Relief Annealing R.S.


_ In the heat treatment of metals, quenching or rapid cooling is the cause of the greatest residual stresses. _ To activate plastic deformations, the local residual stresses must be above the yield strength of the material. _ Because of this fact, steels that have a high yield strength at elevated temperatures can withstand higher levels of residual stress than those that have a low yield strength at elevated temperatures. _ Soaking time also has an influence on the effect of stress-relief annealing

Stress Relief Annealing -Cooling


_ The residual stress level after stress-relief annealing will be maintained only if the cool down from the annealing temperature is controlled and slow enough that no new internal stresses arise. _ New stresses that may be induced during cooling depend on the (1) cooling rate, (2) on the crosssectional size of the workpiece, and (3)on the composition of steel

_ A heat treatment process consisting of austenitizing at temperatures of 3080C above the AC3 transformation temperature followed by slow cooling (usually in air) _ The aim of which is to obtain a fine grained, uniformly distributed, ferrite pearlite structure _ Normalizing is applied mainly to unalloyed and low-alloy hypoeutectoid steels _ For hypereutectoid steels the austenitizing temperature is 3080C above the AC1 or ACm transformation temperature

Need for Normalizing: _ Grain refinement or homogenization of the structure by normalizing is usually
performed either to improve the mechanical properties of the workpiece or (previous to hardening) to obtain better and more uniform results after hardening _ Normalizing is also applied for better machinability of low-carbon steels

Normalizing after Forging:


_ After forging at high temperatures, especially with work pieces that vary widely in cross-sectional size, because of the different rates of cooling from the forging temperature, a heterogeneous structure is obtained that can be made uniform by normalizing Normalizing - Cooling _ Care should be taken to ensure that the cooling rate within the workpiece is in a range corresponding to the transformation behavior of the steel-in-question that results in a pure ferritepearlite structure _ If, for round bars of different diameters cooled in air, the cooling curves in the core have been experimentally measured and recorded, then by using the appropriate CCT diagram for the steel grade in question, it is possible to predict the Structure and hardness after normalizing 3. Isothermal Annealing _ Hypoeutectoid low-carbon steels as well as medium-carbon structural steels are often isothermally annealed, for best machinability _ An isothermally annealed structure should have the following characteristics: 1. High proportion of ferrite 2. Uniformly distributed pearlite grains 3. Fine lamellar pearlite grains

Process Isothermal Annealing _ Austenitizing followed by a fast cooling to the temperature range of pearlite
formation (usually about 650C.) _ Holding at this temperature until the complete transformation of pearlite _ and cooling to room temperature at an arbitrary cooling rate

4. Spheroidizing Annealing
_ It is also called as Soft AnnealingAny process of heating and cooling steel that produces a rounded or globular form of carbide _ It is an annealing process at temperatures close below or close above the AC1
9

temperature, with subsequent slow cooling

Spheroidizing - Uses _ such a soft structure is required for good machinability of steels having more
than 0.6%C and for all cold-working processes that include plastic deformation. _ Spheroidite steel is the softest and most ductile form of steel.

10

Spheroidizing Mechanism _ The physical mechanism of soft annealing is based on the coagulation of
cementite particles within the ferrite matrix, for which the diffusion of carbon is decisive. _ Globular cementite within the ferritic matrix is the structure having the lowest energy content of all structures in the ironcarbon system. _ The carbon diffusion depends on temperature and time. The solubility of carbon in ferrite, which is very low at room temperature(0.02% C), increases considerably up to the Ac1 temperature _ At temperatures close to Ac1, the diffusion of carbon, iron, and alloying atoms is so great that it is possible to change the structure in the direction of minimizing its energy content

Spheroidizing - Process
_ Prolonged heating at a temperature just below the lower critical temperature, usually followed by relatively slow cooling _ In the case of small objects of high C steels ,the spheroidizing result is achieved more rapidly by prolonged heating to temperatures alternately within and slightly below the critical temperature range. _ Tool steel is generally spheroidized by heating to a temperature of 749-804C and higher for many alloy tool steels, holding at heat from 1 to 4 hours, and cooling slowly in the furnace.

CASE HARDENING: _ Case hardening or surface hardening is the process of hardening the surface of
a metal, often a low carbon steel, by infusing elements into the material's surface, forming a thin layer of a harder alloy.Case hardening is usually done after the part in question has been formed into its final shape
11

Case-Hardening Processes:

1. Flame/Induction Hardening 2_ Carburizing 3.Nitriding


4.Cyaniding 5.Carbonitriding

Flame and induction hardening: _ Flame or induction hardening are processes in which the surface of the steel is
heated to high temperatures (by direct application of a flame,or by induction heating) then cooled rapidly,generally using water _ This creates a case of martensite on the surface. _ A carbon content of 0.40.6 wt% C is needed for this type of hardening _ Application Example-Gears

Carburizing:
_ Carburizing is a process used to case harden steel with a carbon content between 0.1 and 0.3 wt% C. _ Steel is introduced to a carbon rich environment and elevated temperatures for a certain amount of time, and then quenched so that the carbon is locked in the structure. _ Example -> Heat a part with an acetylene torch set with a fuel-rich flame and quench it in a carbon-rich fluid such as oil. _ Carburization is a diffusion-controlled process, so the longer the steel is held in the carbon-rich environment the greater the carbon penetration will be and the higher the carbon content.the carburized section will have a carbon content high enough that it can be hardened again through flame or induction hardening _the carbon can come from a solid, liquid or gaseous source

12

_ Solid source :pack carburizing. Packing low carbon steel parts with a carbonaceous material and heating for some time diffuses carbon in to the outer layers. _ A heating period of a few hours might form a high-carbon layer about one millimeter thick. _ Liquid Source -> involves placing parts in a bath of a molten carbon-containing material, often a metal cyanide _ Gaseous Source -> involves placing the parts in a furnace maintained with a methane-rich interior. Nitriding _ Nitriding heats the steel part to 482621C in an atmosphere of NH3 gas and broken NH3. _ The time the part spends in this environment dictates the depth of the case. _ The hardness is achieved by the formation of nitrides. _ Nitride forming elements must be present in the Work piece for this method to work. _ Advantage -> it causes little distortion, so the part can be case hardened after being quenched, tempered and machined. Cyaniding: _ Cyaniding is mainly used on low carbon steels. _ The part is heated to 870-950C in a bath of sodium cyanide (NaCN)and then is quenched and rinsed, in water or oil, to remove any residual cyanide. _ The process produces a thin, hard shell (0.5-0.75mm) that is harder than the one produced by carburizing, and can be completed in 20 to 30 minutes compared to several hours. _ It is typically used on small parts. _ The major drawback of cyaniding is that cyanide salts are
13

poisonous

Carbonitriding _ Carbonitriding is similar to cyaniding except a gaseous atmosphere of ammonia and hydrocarbons (e.g. CH4)is used instead of sodium cyanide. _ If the part is to be quenched then the part is heated to 775885C; if not then the part is heated to 649788C

_ Cooling speeds, from fastest to slowest, go from polymer, brine, fresh water, oil, and forced air _ However, quenching certain steel too fast can result in cracking, which is why high-tensile steels such as AISI 4140 should be quenched in oil, tool steels such as H13 should be quenched in forced air, and low alloy such as AISI 1040 should be quenched in brine Metals such as austenitic stainless steel (304,316), and copper, produce an opposite effect when these are quenched: they anneal.

14

Tempering: _ Untempered martensite, while very hard, is too brittle to be useful for most
applications. _ In tempering, it is required that quenched parts be tempered (heat treated at a low temperature, often 150C) to impart some toughness. _ Higher tempering temperatures (may be up to 700C, depending on alloy and application) are sometimes used to impart further ductility, although some yield strength is lost. _ Tempering is done to toughen the metal by transforming brittle martensite or bainite into a combination of ferrite and cementite or sometimes Tempered martensite
15

_ Tempered martensite is much finer-grained than just-quenched martensite. _ The brittle martensite becomes tough and ductile after it is tempered. _ Carbon atoms were trapped in the austenite when it was rapidly cooled, typically by oil or water quenching, forming the martensite. _ The martensite becomes tough after being tempered because when reheated, the microstructure can rearrange and the carbon atoms can diffuse out of the distorted body-centred-tetragonal (BCT) structure. _ After the carbon diffuses out, the result is nearly pure ferrite with body-centred structure.

16