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Chapter 4

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36
Heat

Gas Laws (III)


Pressure Law
For a fixed mass of gas, the pressure of the gas is directly proportional to the absolute
temperature of the gas at constant volume.
Closed metal
container As the gas is heated, the average velocity of its
molecules increases. The rate of collisions of
Gas molecules
the gas molecules with the wall of the container
increases and hence the pressure increases.

Bourdon
Pressure Law Experiment gauge
Glass Thermometer
Air pressure Air pressure
p (Pa) p (Pa)
tube

Ice
Air
Water Stirrer
bath

−273 0 Temperature θ (ºC)


Celsius temperature scale
0 273 Temperature T (K)
(Absolute temperature) Absolute temperature scale

As the temperature of the gas increases, its pressure also increases. The pressure of the
gas is measured by using a Bourdon gauge. When the graph is extrapolated to −273 ºC
or (0 K), we have p
p ∝ T or T = constant
p1 p
= 2
T1 T2

Ideal Gas Laws Ideal Gas Law


Formula
pV ∝ T Boyleʼs Charlesʼs
Law Law
Equation of state:
pV
= constant
T p1 p2 p2
p1V1 pV V1 Vʹ V2
= 2 2
T1 T2 T1 T1 T2

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