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microzaTM UNA-620A
OPERATING INSTRUCTION
Caution: Read and carefully follow this manual prior to use of the module. Keep this manual in a place easy to find and easy to consult with.
PREFACE
The MF module and the module system may be subject to the Export Control Regulation of Japan. If it is the case, the Export license is required as the formal application for the export. Asahi Kasei Chemicals Corporation inspects every Microza MF module, and ships only the modules that meet Asahi Kasei's specifications. However, even the modules are used within the standard operating conditions in this manual, there will remain a possibility of membrane failure, causing leakage of feed into the permeate side. It is therefore necessary for the user of the Microza module to monitor in order to immediately detect any leakage, and to have adequate countermeasures for the equipment and quality control procedures, to prevent any damage which may be caused by membrane failure. Asahi Kasei Chemicals Corporation will not be responsible for any damages, injuries, or losses without following those notices.
APPLICATIONS OF UNA-620A
Applications of UNA-620A are as follows: Water purification in drinking water makeup process Clad removal in condensate of boiler water Secondary treatment of sewage Pre-treatment for RO desalination Iron and manganese removal *in combination with pre-oxidation by oxidant, such as sodium hypochlorite Clarification of water as an alternative to coagulation sedimentation and/or coagulation filtration Consult Asahi Kasei Chemicals Corporation: - should your application not be specifically noted in the sample applications of this instruction - should there be a change in the application or system use after modules or system have been deployed.
APPLICABILITY OF UNA-620A
This instruction introduces the typical applications and operating conditions. As applicability of module varies depending on the feed solution and operating conditions, please check the applicability precisely prior to use. 2
Store the Module Short-Term Suspension of Operation and Module Storage Long-Term Suspension and Module Storage Protect from freezing Keep away from UV light and high temperature Do not expose to physical impact 3
Transportation of MF System
Do not install modules in the system during transportation
3. PARTS LIST 4. HOW TO INSTALL THE MODULE 5. HOW TO DISCONNECT THE MODULE 6. TYPICAL OPERATING CONDITIONS
Inside-out Filtration Outside-in FiltrationMode Mode Filtration Pressure Recirculation Flow Rate Reverse Filtration pH Range
16 18 20 21
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8. STANDARD SPECIFICATION
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1. SAFETY INSTRUCTIONS
Follow the notices in this instruction when using microfiltration module (MF module hereafter) for the safety and correct operation. Asahi Kasei will not be in a position to be responsible for any damages, injuries, or losses of users or any third parties without following the notices.
Definition of Signals Safety instructions in this guide and the warning label attached on the module, are classified to two categories as follows:
Warning: Warning flags notify you of the potential for serious bodily harm or fatal injures.
Caution: Caution flags notify you of the potential for bodily harm or, hardware or product damage.
Safety Guidance
Warning: Wear protective clothing when fragments can cause injuries. cutting modules. Scattering
Wear protective clothing including safety glasses and gloves when handling the chemicals such as sodium hypochlorite and caustic soda, etc. If the chemicals touch the skin or the eyes, wash the area with much amount of water then see a doctor. It can cause of eyesight loss or chemical skin burn Do not mix acid and sodium hypochlorite when both are used for chemical cleaning. Chlorine gas emerges by the mixture and it is very hazardous.
Caution: MF membrane is wetted by the preservative that contains 30% of calcium chloride. Wear protective clothing to avoid skin contact and eye contact when draining the preservative. The heavy loaded module ought to be carefully carried out by at least two workers. Fasten cap nut of TP-joint when installing or disconnecting modules. If the TP-joint comes off, it can cause injuries or damages to the TP-joint itself. Fix the module with a U-band or chain to the module rack when installing modules. If the module falls down, it can cause injuries or damages to the module housing. (However, do not fasten the module too tight.)
Fasten firmly the pressure hose not to come off by pressurizing during module inspections such as leakage check in particular.
Clean MF System
Install MF Modules
Operation
Chemical Cleaning
Repeat
Preservative:
Membrane in the module is wetted with aqueous preservative solution that contains calcium chloride by 30% when it is shipped. The purpose of the solution is to keep membrane wet and to prevent proliferation of microorganisms. Rinse off the solution thoroughly with clean water before use. (Important) Calcium chloride is highly corrosive resistant to metals so that needs to be carefully used if there are peripheral piping or member of framework, which are made from metals. Definition of clean water is one that contains less turbidity component, less organic substance so as it may not give any bad effect on flux of the module, for example drinking water and membrane filtered water.
Concentration Less than 5,000ppm (Concentration of chlorine needed to be effective) Less than 4%
Less than 10% HNO3, HCl Less than 2% Oxalic acid Less than 10% Citric acid Less than 0.4% EDTA Sanitization Sodium hypochlorite 10 to 100ppm Hydrogen peroxide Less than 1% *Standard chemical cleaning: (2,000 5,000ppm NaClO +1% NaOH) x 7 to 8 hrs 2-5% acid x 2hrs water rinsing (2) Cleaning procedure The sequence of chemical cleaning and water flux measurement consists of the following steps. *Remove SS on membrane surface by air scrubbing as much as possible prior to chemical cleaning. Preliminary water rinsing (Air scrubbing) Flux measurement Chemical cleaning Water rinsing Flux measurement
(3) Operating condition for cleaning Preliminary water rinsing (Air scrubbing) Module Air Flow Rate Time Procedure
Fill the module up with water during air scrubbing. Drain water of feed inlet in the module after finishing air scrubbing. 6 m3/hr x 30 sec. 45 liter/ module
UNA-620A 90 liter/ module (30 liter of hold up volume inside the module + rough standard of chemicals inside the piping) 0.5 0.75 m3/ hr NaClO, NaOH: 3-7 hrs Acid: 1-2 hrs Less than 40 degrees Celsius Add cleaning solution in the recirculation tank. Circulate the cleaning solution while the filtrate is returned to the recirculation tank.
UNA-620A About 0.5 1 m3/ hr About 0.5 m3/ hr Rinse by feeding clean water in feed tank Drain retentate and permeate to the wastewater tank. Determined by concentration of the residual NaClO, pH, etc.
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Warning Wear protective clothing including safety glasses and gloves when handling the chemicals such as sodium hypochlorite and caustic soda, etc. If the chemical touch the skin or the eyes, wash the area with much amount of water and see a doctor. It can cause of eyesight loss or chemical skin burn.
Warning Do not mix acid and sodium hypochlorite when both are used for chemical cleaning. Chlorine gas emerges by the mixture and it is very hazardous.
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[Temperature Compensation coefficient] 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 30 0.0 1.463 1.422 1.383 1.346 1.310 1.276 1.243 1.212 1.181 1.152 1.124 1.098 1.072 1.047 1.023 1.000 0.978 0.956 0.935 0.915 0.896 0 0.896 0.1 1.459 1.418 1.379 1.342 1.307 1.273 1.240 1.209 1.178 1.149 1.121 1.095 1.070 1.045 1.021 0.998 0.976 0.954 0.933 0.913 0.894 1 0.877 0.2 1.455 1.414 1.375 1.339 1.304 1.269 1.237 1.206 1.175 1.146 1.119 1.093 1.067 1.042 1.018 0.996 0.974 0.952 0.931 0.911 0.892 2 0.859 0.3 1.451 1.410 1.372 1.335 1.300 1.266 1.234 1.203 1.172 1.144 1.116 1.090 1.065 1.040 1.016 0.993 0.971 0.950 0.929 0.909 0.890 3 0.842 0.4 1.447 1.406 1.368 1.331 1.297 1.263 1.231 1.200 1.169 1.141 1.114 1.088 1.062 1.037 1.014 0.991 0.969 0.948 0.927 0.907 0.888 4 0.825 0.5 1.443 1.403 1.364 1.328 1.293 1.260 1.228 1.197 1.167 1.138 1.111 1.085 1.060 1.035 1.011 0.989 0.967 0.945 0.925 0.906 0.887 5 0.808 0.6 1.438 1.399 1.361 1.324 1.290 1.256 1.224 1.193 1.164 1.135 1.108 1.082 1.057 1.033 1.009 0.987 0.965 0.943 0.923 0.904 0.885 6 0.793 0.7 1.434 1.395 1.357 1.320 1.287 1.253 1.221 1.190 1.161 1.132 1.106 1.080 1.055 1.030 1.007 0.985 0.963 0.941 0.921 0.902 0.883 7 0.777 0.8 1.430 1.391 1.354 1.317 1.283 1.250 1.218 1.187 1.158 1.130 1.103 1.077 1.052 1.028 1.005 0.982 0.960 0.939 0.919 0.900 0.881 8 0.782 0.9 1.426 1.387 1.350 1.313 1.280 1.246 1.215 1.184 1.155 1.127 1.101 1.075 1.050 1.025 1.002 0.980 0.958 0.937 0.917 0.898 0.879 9 0.748
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Do not expose modules to direct sunlight or UV lamp for long time. Module housing and/or parts made from resin may degrade by UV light and high temperature, if they are exposed to them for a long time.
Modules should be prohibited from any physical impact such as falling and shocking. Membrane may be damaged even if it seems to be no damages on the module housing from appearance.
Transportation of MF System
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Disposal of the module Follow the local safety codes for the handling of the industrial waste when you dispose the modules. Consult Asahi Kasei Chemicals Corporation for further information on detailed exploitation. Abridgment of Material Safety Data Sheet is described below. Caution: 1) Dispose of modules as industrial waste in accordance with local governmental regulation. 2) In case there is a possibility that hazardous and harmful substances remain in modules, take the necessary countermeasures for it. When modules are to incinerate, use the system which is capable of treating exhaust gas (over 800 degrees Celsius). And then, dispose by industry-waste-treatment plant which can neutralize hydrogen fluoride gas or dispose at designated landfill.
Warning
Wear protective clothing when cutting modules. Scattering fragments can cause injury.
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3. PARTS LIST
Concentrate outlet
4
Permeate outlet
3
Label Module housing
Feed inlet
No 1 2 3 4 5
Description CAP NUT BLIND PLATE GASKET END CAP PROTECTION CAP
Qty 1 1 1 2 1
16
8 7 6 5
12
5 9 7 10 11 2.5S Ferrule
No 1 2 3 4 5 6 7 8 9 10 11 12
Description CAP NUT BLIND PLATE GASKET UNION SOCKET O-RING CAP B NUT TP JPINT CAP A GASKET THREE PIECE CLAMP PROTECTION CAP
Qty 1 1 1 1 2 1 2 1 1 2 1 1
1. Open a carton box. Take out the module from the polyethylene bag. 2. Remove top and bottom end caps and a blind plate at the top concentrate outlet of the module. 3. Set MF module at up right position to drain out excess preservative. * *approx 100 500ml
Caution Wear appropriate safety clothing including safety glass and gloves, etc. 30% of calcium chloride is contained in the preservative solution and it can irritate your skin and eyes.
4. If the preservative come in contact with hands or outside the module, wipe out after washing by water. 5. Set an O-ring on the cap B and adjust the cap B with the permeate nozzle. 6. Screw up the cap B with the nut. (Screwing torque: 120N-m) 7. Set an O-ring in the package on the cap A and adjust the cap A with the feed inlet. 8. Screw up the cap A with the nut. (Screwing torque: 120N-m) 9. Mount gasket in the package on the ferrule. 10. Mount the module on the ferrule. Face the retentate side nozzle to the concentrate pipe. 11. Fix the module to the module rack so as the module may not fall down.
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Caution The heavy loading module ought to be carefully carried out by at least two workers.
12. Mount a gasket on the retentate side nozzle of the module. Adjust the nozzle with the retentate pipe and fasten the cap nut. (Keep the gasket on the right position) 13. Loosen the nut of the TP-joint then slide down the joint. Insert the top of the cap B into it and fasten the nut lightly. 14. Align the cap A on the feed side with the ferrule and tighten them lightly with a clamp. 15. Fasten the nut of the TP-joint and the clamp. 16. Test-run of the system with water and check for leakage from all piping and connection parts.
Caution Use TP-joint specified by Asahi Kasei. Using other types may cause leakage or damages on the module.
Caution Fix the module with a U-band or chain to the module rack when installing modules. If the module falls down, it can cause injuries or damages to the module housing.
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Caution The heavy loading module ought to be carefully carried out by at least two workers.
Caution Fasten the nut of the TP-joint tightly. Falling of the joint may injure workers and/or damage the joint itself.
(Important) Wipe off ferrule of the system. Dust and stain on the ferrule can cause the contamination or leak from the sealing.
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Outside-in filtration mode Inside-out Filtration Mode to the outside of hollow fiber membrane. The module is specifically Feed water should be supplied Filtration is carried out by "inside-out filtration mode" that supplies feed solution to the designed to be operated in the outside-in filtration mode. Therefore, dead-end filtration with solution inside of hollow fiber membrane and filtrate is taken out from the outside. containing high amount of suspended solid causes clogging in the space between hollow fiber If the feed solution is supplied by "Outside-in mode", fouling substances can result in membranes and prevent the smooth supply of feednot water. It decrease module performance and it reduced performance and the cleaning may become effective. becomes the cause of poor flux recover by cleaning, etc..
Filtration pressure
Followings are maximum service pressure available. Feed side pressure: 300kPa Trans-membrane pressure difference: 300kPa
Maximum reverse-filtration pressure: 300kPa (Important) Do not give pressure shock in the case of reverse-filtration. Operation with repeated pressure shocks may cause degradation of hollow fiber membrane and damage end caps of the module.
Reverse-filtration flow rate (Reverse filtration only: Drain from feed inlet and retentate side of module)
Module Reverse-filtration flow rate UNA-620A 12 m3/hr/module
Drain out reverse-filtration effluent evenly (1:1 ration) from the feed side and the retentate side of the modules.
Once/ 30 min (A/S +Reverse Filtration) x more than 30 sec *2 Flushing 30 sec. 5Nm3/Hr Flux1.0~1.5 times (Less than 8Nm3/Hr) 6m3/Hr Below 40 deg C 1 - 10 1) Periodical cleaning 2) When feed press. Reaches by100 - 200kPa. *4
Air volume Volume of Reverse filtration Flushing *3 Temperature pH range Chemical cleaning
3.5 - 5Nm3/Hr
5Nm3/Hr
*1: Based on 20 deg C. *2: Adjusted by recovery rate. *3: If flushing rate need to be changed, adjust the time to equate its emission (e.g. 6m3/ hr x 30 sec = 50 liter 3m3/ hr x 60 sec) *4: Feed pressure during the start-up is about 20-50kPa. (Note) Above figures are standard conditions and differ by the quality of raw water.
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You should check the integrity of a module in the following cases: * When you use a new module. * When leak is suspected. Refer to page 24 - 25 for further information. (Important) When the hollow fiber membrane is exposed to compressed air, the membrane can dry out and loose the filtration performance. Also, dirty compressed air can contaminate the membrane. Follow these cautions when checking the integrity of the module: * Finish each integrity check within 5 (five) minutes. Maximum pressure should be limited up to 200 kPa. * Fill up the inspected module with water as soon as the test is finished. If the membranes dry out, it would lose the performance of MF membrane. * Compressed air should be cleaned by filter to remove dust or oil prior to use.
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Checking Integrity (Inline) When the inspection is carried out while a module is still on the module rack. V-2
TP-joint
P2 V-3
P1 V-1 V-4
Compressed air (for air scrubbing)
Inspection Procedure
1. 2. 3. 4. Stop filtration. Close all the valves. Open V-2. Open V-4 slowly to send compressed air into the module and then raise the pressure up to 200kPa maximum. 5. Observe inside the transparent TP-joint to confirm if there are no continuous air bubbles. Generation of continuous bubbles: Abnormal No continuous bubbling: Normal (Note): Discontinuous bubbling just after the pressurization should not be judged as abnormal.
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V-1
P1
V-2
V-3
Fig.4 Pipe connection for the OFF-THE-SYSTEM INSPECTION Inspection Procedure 1. Disconnect the module from the system. 2. Cap the retentate nozzle with a blind plate. 3. Stand the module vertically as shown in the fig. 6 and connect all necessary pipes. In the case that the pressure-resist hose is used, fix it tightly not to come off by adding the pressure. Special connection parts must be prepared prior to the test if flexible hose is used to supply air.
4. 5. 6. 7. 8. 9.
Caution When using pressure resistant tubing, connect it tightly with a module to prevent the tubing from coming off the module by pressurizing. Fix the module facing its permeate end upward. Fill clean water from the retentate nozzle to fill up the feed side of the module. Again, cap the retentate side with a blind plate. Open V-1 and set the air pressure to 100kPa by the regulator. Open V-3 slowly and feed air to the module. Water overflows from the permeate side at first. Keep the condition till the overflow from the permeate outlet ceases. Observe occurrence of continuous bubbles in the permeate side. Raise the pressure up to 200kPa if there is no continuous bubbling. Continuous bubbling: Module is abnormal. No Continuous bubbling: Module is normal. (Note): Discontinuous bubbling will not last long. Repeat from step 5 if discontinuous bubbling lasts for a long time. There may be a possibility of dried membrane. Consult Asahi Kasei for the right judgment. 25
Items Membrane Material Effective surface area Performance Nominal pore size (um) Operating conditions Max feed pressure (kPa) Max TMP Difference (kPa) Max temperature (deg C) pH range Module housing Adhesive Gasket, O-ring
UNA-620A Polyvinylidene fluoride (PVDF) 50 m2 0.1 300 300 40 1 10 ABS Polyurethane NBR 2338L x 165
Material
60 30
Refer to page 21, "Typical Operating Conditions of UNA-620A" for more detail. Consult Asahi Kasei, if initial flux rate in the standard specification could not be confirmed. Poor water quality or the system design (ex. excess back pressure because of thin tubing etc.) may be the cause.
* Low initial water flux rate * Difficulty in judgment of integrity test * The application not listed in this instruction * Change of application from the original one * Storage of modules over one (1) year * More detailed information on design of MF system * Any other claim or questions on product or how to use
ASAHI KASEI CHEMICALS CORPORATION SALES & MARKETING DEPARTMENT MICROZA DIVISION Hibiya Mitsui Building 1-1-2 Yurakucho, Chiyodaku, Tokyo 100-8440 Tel: +81-3-3507-2682 Fax: +81-3-3508-1474
Asahi Kasei reserves the right to change these data, specifications or appearance of product without prior notice. Microza is a registered trademark of Asahi Kasei Edited in April 2004
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