11

th
PQRS (Date: 07-08-2011) Review Test-3
PAPER-1
Code-A
ANSWER KEY
PHYSICS
SECTION-1
PART-A
Q.1 B
Q.2 B
Q.3 B
Q.4 C
Q.5 D
Q.6 A
Q.7 D
Q.8 D
Q.9 B
Q.10 D
Q.11 C
Q.12 D
Q.13 A
Q.14 B
Q.15 D
Q.16 B,C
Q.17 B,D
Q.18 A,D
Q.19 A,C,D
Q.20 A,C
Q.21 B
CHEMISTRY
SECTION-2
PART-A
Q.1 C
Q.2 C
Q.3 A
Q.4 A
Q.5 D
Q.6 B
Q.7 C
Q.8 D
Q.9 A
Q.10 D
Q.11 B
Q.12 C
Q.13 B
Q.14 B
Q.15 A
Q.16 A,C,D
Q.17 A,D
Q.18 A,B,C,D or ABC
Q.19 A,B,C
Q.20 B,C
Q.21 A,C,D
MATHS
SECTION-3
PART-A
Q.1 A
Q.2 D
Q.3 B
Q.4 D
Q.5 C
Q.6 C
Q.7 D
Q.8 D
Q.9 C
Q.10 C
Q.11 B
Q.12 D
Q.13 A
Q.14 B
Q.15 A
Q.16 A,B,C,D
Q.17 A,B
Q.18 B,C,D
Q.19 A,C
Q.20 A,B
Q.21 A,B,D
PHYSICS
Code-A Page # 1
PART-A
Q.1
[Sol.
v
AW
v
AG
v
WG
A
B
]
Q.2
[Sol. Radius of curvature at point B is minimum. ]
Q.3
[Sol.
B
A
510=50
510=50
]
B A AB
v v v

= =
) j

( 50 ) j

( 50
=
j

100
]
Q.4
[Sol. H
max
=
2
gT
8
1
v
v
]
Q.5
[Sol. 2 second later
40 m/s
30 m/s
Relative acceleration = g g = 0
velocity of separation = 40 30 = 10
so reparation keeps on increasing before hitting ground. ]
Q.6
[Sol. K.E
max
=
2
1
me
2
A
2
=
2
1
m (2tf)
2
A
2
= 2t
2
mf
2
A
2
or check dimensionally ]
PHYSICS
Code-A Page # 2
Q.7
[Sol.
F=T
T
T
T
3T
T
T
3T = ma = 3F,
m
F 3
a =
]
Q.8
[Sol.
v
A
g
h
g
v
B
V
B
2
= V
A
2
+ 2gh, acceleration for both g downward. ]
Q.9
[Sol. l
0
+
1
k
N 4
=
l
0
+
2
k
N 6
=
l
0
= 3l
1
2l
2
]
Q.10
[Sol.
2
2a
F
sp
5 F
sp
a
36N
F
sp
= 2 2a
36N F
sp
= 5a F
sp
= 16N o =
100
16
m = 16 cm ]
Q.11
[Sol.
N
mg
N mg = ma N = m(g + a) = 50 (10 + 6) = 800 N ]
Q.12
[Sol.

= +
= +
105 ) 1 9 2 ( a
2
1
u
65 ) 1 5 2 ( a
2
1
u
u = 20, a = 10 } 20 +
2
1
10(2 30 1) = 315 ]
PHYSICS
Code-A Page # 3
Q.13
[Sol.
v=gt
0
v=0
relative acceleration = g g = 0
relative velocity of separation = gt
0
so separation keep on increasing ]
Q.14
[Sol.
g
]
Q.15
[Sol.
u u
e
T T
2T sin u = W
u
=
sin 2
W
T
as u 0, T so not possible ]
Q.16
[Sol.
e t = rad/s
x
y
(1,0), t=0
3
1
t =
, u = et = t
3
1
=
3
t
,
(

t
+
t
t = j

3
sin 1 i

3
cos 1 k

= ( ) j

2
i

2
3 t
+
t
r a
2

e = =
(

t
+
t
t j

3
sin 1 i

3
cos 1
2
=
(
(

+ t j

2
3
2
i

2
]
Q.17
[Sol. R = 20m, u =
2 10
,
g
2 sin 2 u u
= R sin 2u = 1, u = 45, u
x
= 4 cos u = 2 10 sin 45 = 10
|u
x
| relative to observer should become half as vertical motion is same as observed by ground and time
of flight same. Velocity of observer =
2
10
10
= 5 or 15 ]
PHYSICS
Code-A Page # 4
Q.18
[Sol.
u
=
sin v
d
t
V sin u
V
u
V sin u
V
u
t
min
u = 90 ]
Q.19
[Sol. y
1
= y
2
max height
t
1
= 2t
2
, t
2
= 2t
1
x
1
= u cos u
2
T
, x
2
= u cos u T
2
1
x
x
=
2
1
,
2
1
t
t
=
2
1
]
Q.20
[Sol.
g sin u
g
x y
g cos u
V
3
2
= V
1
2
2g sin u x so V
3
< V
1
V
4
2
= V
2
2
2g cos u (Ay) = V
2
2
2g cos u (0) = V
2
2
V
4
= V
2
]
Q.21
[Sol. x = (t 1) (t 2) x(0) = 2 = 0
3 t 2
dt
dx
=
3
dt
dx
0 t
=
=
(-ve)
2
dt
x d
2
2
=
speed =
dt
dx
speed decreasing from t = 0 to t = 3/2 then increasing. ]
Code-A Page # 1
CHEMISTRY
PART-A
Q.1
[Sol. Z
eff
= Z o
1s
2
2s
2
2p
6
3s
2
Z
eff
= 12 (2 + 8 0.85 + 0.35)
= 2.85 unit Ans.]
Q.2
[Sol. Molecular mass of Na
2
SO
4
.xH
2
O = (142 + 18x)
After heating, Na
2
SO
4
will form and it's molecular mass = 142
(142 + 18x)g Na
2
SO
4
xH
2
O gives loss of 18x g due to evaporation of water
100 g Na
2
SO
4
xH
2
O gives loss of
g
) x 18 142 (
100 x 18
+

= 47 gm
x = 6.9958
~
7 (nearest integer) ]
Q.3
[Sol. Specific heat capacity = 1.68 J/g-k
=
2 . 4
68 . 1
cal/g-k = 0.4 cal/g-k
Specific heat capacity atomic weight
~
6.4
Atomic weight =
4 . 0
4 . 6
= 16 ]
Q.4
[Sol. Let x gm KCl is added in 60g H
2
O
Total weight of solution = (60 + x)
Percent weight of KCl =
x 60
100 x
+

= 20
x = 0.2 (60 + x)
x =
8
120
= 15g ]
Q.5
[Sol. IE
2
and IE
3
are very high compared to IE
1
, so it will prefer to show valency of 1 and form AF, A
2
O and
A
3
N ]
Q.6
[Sol. Let the volume of each be 1 lit. (arbitravily chosen) so each solution contains 0.2 mole H
+
, 0.2 mole Cl

and 0.4 mol K

+
, 0.4 mole OH

before mixing a
After mixing :
HCl + KOH KCl + H
2
O
0.2 0.4
mole of H
+

~
0
mole of OH

= 0.4 0.2 = 0.2

mole of K
+
= 0.4
mole of Cl

= 0.2
Volume of solution = 2 lit
Code-A Page # 2
CHEMISTRY
So molarity of [K
+
] =
2
4 . 0
= 0.2 M
|
|
.
|

\
|
=
solution of volume Total
solute of mole
M
molarity of [Cl

] =
2
2 . 0
= 0.1 M
molarity of [OH

] =
2
2 . 0
= 0.1 M ]
Q.7
[Sol. Lets weight of SO
3
in 0.5 gm sample = x
Weight of H
2
SO
4
in 0.5 gm sample = 0.5 x
H
2
SO
4
+ 2NaOH Na
2
SO
4
+ 2H
2
O
98
x 5 . 0
SO
3
+ 2NaOH Na
2
SO
4
+ H
2
O
80
x
1000
7 . 26 4 . 0
98
x 5 . 0
80
x
2

= |
.
|

\
|
+
x = 0.103
% SO
3
=
100
5 . 0
103 . 0

= 20.6 ]
Q.8
[Sol. m mole of Na
2
S
2
O
3
consumed = 20 0.3 = 6
Corresponding m mole of I
2
=
2
6
= 3 m mole
Corresponding m mole of H
2
O
2
=
60
100
3
= 5 m mole
25 ml H
2
O
2
solution contains 5 m mole = 5 10
3
mole
Molarity =
025 . 0
10 5
3

=
5
1
Volume strength =
5
1
11.2 = 2.24 ]
Q.9
[Sol. (NH
4
)
2
SO
4
+ NaOH Na
2
SO
4
+ 2NH
3
+ 2H
2
O
NH
3
+ HCl NH
4
Cl
HCl + NaOH NaCl + H
2
O
Actual m moles of HCl used for reacting NH
3
= 100 0.4 40 0.3
= 28 m mole
m mole of N-atom = 28 m mole
Code-A Page # 3
CHEMISTRY
mass of Nitrogen atom = 28 10
3
14 g = 0.392 g
Percent N is fertilizer =
100
92 . 3
392 . 0

= 10% ]
Q.10
[Sol. Fe +
2
1
O
2
FeO
(1x)
|
.
|

\
|
2
x 1
(1 x)
Fe +
4
3
O
2

2
1
Fe
2
O
3
x
4
3
x
2
x
2
x 1
+
x
4
3
= 0.65
x =
5
3
FeO : Fe
2
O
3
= (1 x) :
2
x
=
5
2
:
10
3
= 4 : 3 ]
Q.12
[Sol. Let x mole HCOOH & y mole H
2
C
2
O
4
is taken.
Mole of CO formed = (x + y)
mole of CO
2
formed = y
Potash absorb CO
2
so only CO will remain = (x + y)
Volume contraction = (x + 2y) (x + y) =
6
1
( x + 2y)
1
4
y
x
=
]
Q.13
[Sol. X
A
moles of solute present in 1 mole of solution
X
B
= X
A
, X
A
= 1 X
A
m =
17
1000
) X 1 (
X
A
A

m =
A
A
X 1
) X ( 82 . 58

]
Code-A Page # 4
CHEMISTRY
Q.14
[Sol. 3 x = 0.208
2 / 1
) 100 81 ( 115
=
10 9 115 208 . 0
=
25 208 . 0
= 0.208 5 = 1.04
x = 3 1.04 = 1.96 Ans. ]
Q.15
[Sol.
) AHCO ( n
2
1
n
3 B O H
2
=
) AHCO ( n
2
1
n
3 B CO
2
=
2 2
CO O H
m m +
= 6.2 g
Let M is the molar mass of AHCO
3

2 . 6 44
M
8 . 16
2
1
18
M
8 . 16
2
1
= +
g
M =
84
2 . 6
8 . 16 31
2 . 6
) 22 9 ( 8 . 16
=
+
=
+
]
Q.17
[Sol. (C) M =
100
42 15 . 0 25 12 . 0 07 . 0 10 + +
=
1 . 0
100
10
=
M
(D) M =
100
15 . 0 25 12 . 0 20 07 . 0 55 + +
M =
100
75 . 3 24 85 . 3 + +
= 0.1 M ]
Q.19
[Sol. Ionic mobility o
size Hydrated
1
]
Q.20
[Sol. Mass fraction =
260
10
= 0.0385
Mole fraction =
18
250
5 . 58
10
5 . 58 / 10
+
=
89 . 13 17 . 0
17 . 0
+
=
06 . 14
17 . 0
= 0.012
Molality =
1000
260
5 . 58 / 10

=
68 . 0 1000
250
17 . 0
=
Molarity =
6538 . 0 1000
260
5 . 58 / 10
=
]
MATHEMATICS
Code-A Page # 1
PART-A
Q.1
[Sol. Let the roots be 2k and 3k.
Now, sum of roots = 5k = 2 a ......(1)
and product of roots = 6k
2
= a + 2 ......(2)
Now proceed.
Q.2
[Sol. E = (sec 3A + cosec 3A)
2
=
( ) ( ) | |
2
2 6 2 6 + +
Hence, E = ( )
2
6 2 = 24. Ans.]
Q.5
[Sol. Given, cos A + cos B + cos C = a .......(1)
and sin A + sin B + sin C = b .......(2)
Square and add, we get the result.]
Q.7
[Sol. ( )

+
10
1 r
1 r
3 r 8 2 =

= = =

+
10
1 r
10
1 r
10
1 r
1 r
1 3 r 8 2 =
2
) 1 10 ( ) 10 ( 8
1 2
1 2
10
+
+

3 (10)
= 1024 1 + 440 30 = 1433. Ans.]
Q.8
[Sol. f (1) < 0
and f (2) < 0
2 1
f(x)
x-axis
]
Q.10
[Sol. Using A.M. > G.M. in
x
z
,
z
y
,
y
x
]
Q.14
[Sol. Let a
1
be the 1
st
term and d is the common difference.
a
7
= 9 = a
1
+ 6d (given) a
1
= 9 6d
a
1
a
2
a
7
= a
1
(a
1
+ d) (a
1
+ 6d) = 9(9 6d) (9 5d) = 27

upward opening parabola
2
) 27 d 33 d 10 ( +
Now proceed. ]
Q.15
[Sol. a
1
+ a
3
+ a
5
+ ....... + a
19
+ a
21
=
2
n
[2a
1
+ (n
1
1) 2d] =
2
11
[2a
1
+ 10 2d]
= 11 [a
1
+ 10d] = 11 33 = 363 Ans.]
MATHEMATICS
Code-A Page # 2
Q.16
[Sol. Given 0 < o , |, <
2
t
.......(1)
Also, 2cot | = cot o + cot .......(2)
Now proceed.
Q.17
[Sol. Given, o + | = a, o| = b
and o
2
+ |
2
= A, o
2
|
2
= B
Now, o
2
+ |
2
= (o + |)
2
2o| a
2
2b = A
So,
2
a b 2 A =
Also, o
2
|
2
= B (b)
2
= B
2
b B =
. Ans.]
Q.18
[Sol. Let first term and common difference of A.P. be a and d respectively.
Given, a
3
+ a
9
= 8 (a + 2d) + (a + 8d) = 8 a + 5d = 4 .........(1)
Also, S
7
= 14

2
7
(2a + 6d) = 14 a + 3d = 2 ..........(2)
From (1) and (2), we get
d = 1 and a = 1. Now verify alternatives. Ans.]
Q.21
[Sol. Put x = 1, (a + 2b 3c) + b + 2c 3a + 2a 3b = 0
so x= 1, is its one root.
Also, other root = Product of roots =
c 3 b 2 a
b 3 a 2 c
+
+
.
Now proceed. ]