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Class: 13

th
(VXY) Date: 22/01/2012 Time: 3 Hours. Max. Marks: 243
VERY IMPORTANT
A. The question paper consists of 3 section (Section-1 contains Mathematics , Section-2 contains Physics
and Section-3 contains Chemistry). Please fill the OMR answer Sheet accordingly and carefully.
B. Each Section contains (13 questions in Part-A and 8 questions in Part-C) and total number of pages
are 40.
C. Please ensure that the Question Paper you have received contains ALL THE QUESTIONS in
each Section and PAGES. If you found some mistake like missing questions or pages then
contact immediately to the Invigilator.
INSTRUCTIONS
PART-A
1. Q.1 to Q.6are single correct type questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
For Q.1 to Q.6, you will be awarded 4 marks, if you have darkened only the bubble corresponding to
the correct answer and zero mark if no bubble are darkened. In all other cases, minus one (1) mark
will be awarded.
2. Q.7 to Q.9 are Paragraph type. Based upon the paragraph 3 single correct type questions have to be
answered. Each of these questions has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
For each question, you will be awarded 3 marks if you have darkened only the bubble corresponding to the correct
answer and zero mark if no bubble are darkened. In all other cases, minus one (1) mark will be awarded.
3. Q.10 to Q.13 are multiple correct type questions.Each question has four choices (A), (B), (C) and
(D) out of which ONE OR MORE may be correct.
For each question, you will be awarded 4 marks if you have darkened only the bubble corresponding to the
correct answer and zero mark if no bubble are darkened. No negative marks will be awarded in this section.
PART-C
4. Q.1 to Q.8 are Integer Type questions. The answer to each question is upto 4 digit ranging from
0 to 9999. The correct digit below the question number in the OMR is to be bubbled.
For each question, you will be awarded 4 marks if you darken the bubble corresponding to the correct
answer and zero mark if no bubble is darkened.
For example, if for a given question, your answer is 25, then for the particular question, against question
number you must fill as 0025 in the OMR. No negative marks will be awarded in this section.
5. Indicate the correct answer for each question by filling appropriate bubble in your answer sheet.
6. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
7. The answers of the questions must be marked by shading the circle against the question by dark Black Ball
point Pen only.
USEFUL DATA
Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.5, Ti = 48,
Ba = 137, U = 238, Co= 59, B =11, F = 19, He = 4, Ne = 20, Ar = 40 , Mo = 96
[Take : ln 2 = 0.69, ln 3 = 1.09, e = 1.6 10
19
, m
e
= 9.1 10
31
kg ]
Take g = 10 m/s
2
unless otherwise stated
CODE
A
REVIEW TEST-6
PAPER- I
MATHEMATICS
XIII (VXY) RT-6 [Paper-I] Code-A Page # 2
PART-A
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.6 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Q.1 If the system of equations x y = 2 and cx + y = 3 have a solution (x, y) where x > 0 and y > 0,
then the true set of values of c is
(A) c > 1 (B) c <
2
3
(C) 0 < c <
2
3
(D) 1 < c <
2
3
Q.2 If sin u, 2 (sin u + 1), 6 (1 + sin u), .............. is a geometric progression, then the
fifth term of the progression, is
(A) 81 (B) 2 3 (C) 2 82 (D) 162
Q.3 Let f (x) =

e
e + +
Q x , x cos 4
Q x , 30 a 10 a x sin 3
2
.
Which one of the following statement is correct ?
(A) f (x) is continuous for all x when a = 5.
(B) f (x) is discontinuous for all x.
(C) f (x) is continuous for all x = 2nt tan
1
|
.
|

\
|
4
3
, n e I when a = 5.
(D) f (x) is continuous for all x = 2nt tan
1
|
.
|

\
|
3
4
, n e I when a = 5.
Q.4 If the circle x
2
+ y
2
2x 4y + k = 0 and director circle of ellipse
4
x
2
+ y
2
= 1 intersects
orthogonally then k equals
(A) 0 (B) 5 (C) 5 (D) 2
Q.5 The maximum value of f (x) =
}
t +
1
0
dt ) t x sin( t , is
(A)
4
1
2
+ t
t
(B)
4
1
2
2
+ t
t
(C)
4
2
+ t
(D)
4
2
1
2
2
+ t
t
Q.6 In triangle ABC, if cos
b
c
c
b
2
1
2
A
+ = , then
[Note : All symbols used have usual meaning in triangle ABC.]
(A) bc = a
2
(B) 2ac = b
2
(C) 2bc = a
2
(D) ab = c
2
MATHEMATICS
XIII (VXY) RT-6 [Paper-I] Code-A Page # 3
[PARAGRAPH TYPE]
Q.7 to Q.9 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Paragraph for question nos. 7 to 9
Consider two straight lines L
1
: 2x + 4 = 2y 4 = z 4 and L
2
: 2x = y + 1 = z + 3.
Let the points P and Q be on L
1
and L
2
respectively and point M divides PQ in the ratio 2 : 3
(internally). Also R and S be points on lines L
1
and L
2
respectively which are nearest to each other.
Given the line L
2
intersects xy, yz, zx planes at A, B, C respectively.
Q.7 The distance between the points R and S is equal to
(A) 5 (B)
5
(C)
5
1
(D)
5
1
Q.8 The locus of M is
(A) 2x + z = 6 (B) y + 2z = 8 (C) x + y = 2 (D) 3x + y + z = 8
Q.9 Volume of tetrahedron OABC (where O is origin), is
(A) 0 (B) 1 (C) 2 (D) 3
[MULTIPLE CORRECT CHOICE TYPE]
Q.10 to Q.13 has four choices (A), (B), (C), (D) out of which ONE OR MORE may be correct.
Q.10 Locus of the middle point of chords of parabola y
2
= 4x, tangents drawn at the ends of which intersect
at right angle is a parabola whose
(A) vertex is (1, 0) (B) length of shortest focal chord is 2
(C) equation of directrix is x =
2
1
(D) tangents at ends of latus-rectum intersect at
|
.
|

\
|
0 ,
2
1
Q.11 If a, b and c are all different from zero such that 0
c
1
b
1
a
1
= + + ,
then the matrix A =
(
(

+
+
+
c 1 1 1
1 b 1 1
1 1 a 1
is
(A) symmetric (B) non-singular (C) skew-symmetric (D) singular
Q.12 Let f : R { 1, 0, 1} be defined as f(x) = sgn {sin x}. Which of the following statement(s) is(are)
correct ?
[Note : sgn k and {k} denotes signum of k and fractional part of k respectively.]
(A) f(x) is periodic function (B) 1 ) x ( f Lim
2
x
=
t

(C) f(x) is an even function (D)


}
t
t
= 0 dx ) x ( f
MATHEMATICS
XIII (VXY) RT-6 [Paper-I] Code-A Page # 4
Q.13 Consider two fixed points A(1, 0, 0) and P(1, 0, 1). If OA (where 'O' is origin) is rotated through 'O'
in xy-plane by a variable angle u, to reach a new position OB, then which of the following statement(s)
is(are) correct ?
(A) Maximum volume of tetrahedron OAPB is
6
1
.
(B) Maximum volume of tetrahedron OAPB is unity.
(C) The distance of plane OPB from point A is
) sin 1 (
sin
2
u +
u
.
(D) Equation of the plane OPB is (z x) sinu + y cos u = 0.
PART-C
[INTEGER TYPE]
Q.1 to Q.8 are "Integer Type" questions. (The answer to each of the questions are upto 4 digits)
Q.1 A circle touches the parabola y
2
= 4x at P. It also passes through the focus S of the parabola and
intersects its axis at Q. If angle SPQ is 90, then find the radius of the circle.
Q.2 Three circles each of radius r touches each other and inscribed in a circle of radius R.
If
c
b
a
1
R
r
+
=
, where a, b, c e N then find the minimum value of (a + b + c).
Q.3 Let
c , b , a

be three vectors of magnitude 1, 2 ,


2
1
respectively, satisfying | | c b a

= 1.
If
( ) ( ) ( ) ( ) b c a c a c b a 2

+ + +
=
k
13
, then find the value of k.
Q.4 If the number of ways in which the letters of the word 'TEACHER' can be placed in the squares
of the given figure so that no row remains empty is (k)7!, then find the value of k.
Q.5 Find the number of integral values of 'c' for which the equation cos 2x + c sin x = 2c 7 has solution.
Q.6 Find the number of all possible symmetric matrices of order 3 3 with entries 1, 0, 1 and
whose trace equal to 1.
Q.7 Let I =
( )
}

2
1
2
1
dx 1 x cot
. Find the value of
t
+ t 2 n 8 I 8
2
l
.
Q.8 If the curves
( )
4
a x
y
2

= and y = e
x
touches each other then find the sum of the squares of all possible
values of a.
PHYSICS
XIII (VXY) RT-6 [Paper-I] Code-A Page # 5
PART-A
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.6 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Q.1 Detector at the point P captures the image of the object S, with the help of 2 mirrors, which are at 90 to
each other (Fig.). Distances SM = 2.5 m, MK = 1 m, KP = 3 m. The distance from the object image to
the detector located at point P:
M
K
S
P
(A) 2 meters (B) 5.5 meters (C) 6.5 meters (D) 3.5 meters
Q.2 From the homogeneous square plate we cut a triangle (Figure). Side of
the square is a and, the apex of the triangle is at the center of the square.
Distance from the center of the square to the center of gravity of the
remainder of the plate is:
(A) a / 5 (B) a / 3 (C) a/6 (D) a/9
Q.3 An infinite current carrying sheet carrying uniform current density is placed
in an external magnetic field so that the net magnetic field on one side of
the sheet is
1
B

and on the other side of it is


2
B

. The external magnetic


field is :
Y
Z
B
2

B
1

(A)
2
) B B (
2 1

(B)
2
) B B (
2 1

(C) ) B B (
2 1

(D) ) B B (
2 1

Q.4 Fig. illustrates a cycle conducted with n moles of an ideal gas. In the states a and b the gas temperature
are T
a
and T
b
respectively. Temperature of the gas in the state C is:
P
0
V
a
c
b
(A) (T
a
T
b
)
1/2
(B) T
a
+ T
b
(C) T
a
T
b
(D) (T
a
+ T
b
) / 2
Q.5 Components of magnetic induction in Cartesian coordinates B are (0, 0, b), b> 0. From the origin an
electron flies out with velocity components as (u
x
, u
y
, 0), where u
x
> 0, u
y
> 0. Center of the circle, on
which the electron moves, is in the region:
(A) x > 0, y > 0 (B) x < 0, y > 0 (C) x < 0, y < 0 (D) x > 0, y < 0
PHYSICS
XIII (VXY) RT-6 [Paper-I] Code-A Page # 6
Q.6 The diagram in Fig. shows Resistance of resistors R
1
= 8 ohms, R
2
= 12 ohms, R
3
= 10 ohms, the
potential difference between points a and b is 60 V. The potential difference between points m and n is:
R
2
R
1
m
a
b
n
R
3
(A) 16 V (B) 60 V (C) 36 (D) 24 V
[PARAGRAPH TYPE]
Q.7 to Q.9 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Paragraph for question nos. 7 to 9
Figure shows the point electric charges of equal size and equally distant from the origin. Assume that the
potential of the electric field generated by a point charge at infinity is zero.
(A)
+
+
+
+
(B)

+
(C)
+

+
(D)
+

+
+
Q.7 The electric field and electric potential at the origin equal to zero in the case:
(A) A (B) B (C) C (D) D
Q.8 In which case the total electrostatic potential energy of interaction of system is zero.
(A) A (B) B (C) C (D) D
Q.9 If all the charges are moving in +ve x-direction with velocity v, in which case magnetic field at origin is
non-zero.
(A) A (B) B (C) C (D) D
[MULTIPLE CORRECT CHOICE TYPE]
Q.10 to Q.13 has four choices (A), (B), (C), (D) out of which ONE OR MORE may be correct.
Q.10 In the center of an isolated metal spherical shell we placed a charge +Q. Then the sphere is grounded.
Select the correct statement.
(A) The electric field outside the sphere coincides with the field of a uniformly charged sphere of total
charge +Q.
(B) The field strength inside the cavity is zero.
(C) On the inner surface of the shell charge Q is induced.
(D) The outside surface of the sphere has no charge.
Q.11 Dry and humi d ai r at the same temperature and pressure and vol ume of 1 m
3
each. Select the correct
statement
(A) The number of molecules of dry air is higher than the number of molecules of humid air.
(B) The number of molecules of humid air is more than the number of molecules of dry air.
(C) The density of humid air is less than the density of dry air.
(D) The density of humid air is greater than the density of dry air.
PHYSICS
XIII (VXY) RT-6 [Paper-I] Code-A Page # 7
Q.12 The potential at a is higher than the potential at b. Which of the following statements about the ideal
inductor current I could be true ?
a b
v > v
a b
(A) I is from a to b and increasing (B) I is from a to b and decreasing
(C) I is from b to a and increasing. (D) I is from b to a and decreasing.
Q.13 An image of a bright square is obtained on a screen with the aid of a convergent lens. The distance
between the square and the lens is 40 cm. The area of the image is nine times larger than that of the
square. Select the correct statement(s)
(A) Image is formed at a distance of 120 cm from the lens
(B) Image is formed at a distance of 360 cm from the lens
(C) Focal length of the lens is 30 cm
(D) Focal length of the lens is 36 cm
PART-C
[INTEGER TYPE]
Q.1 to Q.8 are "Integer Type" questions. (The answer to each of the questions are upto 4 digits)
Q.1 A bullet of mass m and velocity v passes through a pendulum bob of mass M and emerges with velocity
v/2 (figure). The pendulum bob is at the end of a string of length l. What is the minimum value of
v (in m/s) such that the pendulum bob will swing through a complete circle ?
(Take : l = 2m, M = 1kg, m = 10 gm.)
v
v/2
O
l
Q.2 A copper wire bent in the shape of a semicircle of radius r translates in its plane with a constant velocity
v. A uniform magnetic field B exists in the direction perpendicular to the plane of the wire. Find the emf
(in volts) induced between the ends of the wire if the velocity is perpendicular to the diameter joining free
ends. (Take : B = 0.1 T, v = 5 m/s, r = 2m)
Q.3 4 F and a 9 F capacitor are connected in series across a 26 V battery. What is voltage of the battery
required to charge a parallel combination of the two capacitors to the same total energy ?
Q.4 The drawing shows the top view of two doors. The doors are
uniform and identical. Door A rotates about an axis through its
left edge, while door B rotates about an axis through the center.
The same force F is applied perpendicular to each door at its
right edge, and the force remains perpendicular as the door
turns. Starting from rest, door A rotates through a certain angle
in 3 s. How long does it take door B to rotate through the same
angle ? Round off to nearest integer.
F
F
Door A
Door B
Axis
Axis
PHYSICS
XIII (VXY) RT-6 [Paper-I] Code-A Page # 8
Q.5 An electric drill starts from rest and rotates with constant angular acceleration. After it has rotated
through an angle , the magnitude of centripetal acceleration of a point on the drill is twice the magnitude
of tangential acceleration. What is the angle (in rad.)
Q.6 A thermos contains 140 gm coffee at 80C. To cool it, we drop two 10 gm ice cubes at 0C into
thermos. Ice cubes are at 0C initially. What is the final temperature of the coffee (in C), if its specific
heat capacity is same as that of water.
Q.7 A satellite of earth is in near earth circular orbit. What is its speed (in km/s). Round off to nearest integer.
Q.8 A proton moving at 4 10
6
m/s through a magnetic field of 0.2 Tesla experience a magnetic force of
magnitude 8 10
13
N. What is the radius of the helical path (in cm) followed by the proton ?
[Take mass of the proton as 1.6 10
27
kg ]
CHEMISTRY
XIII (VXY) RT-6 [Paper-I] Code-A Page # 9
PART-A
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.6 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Q.1 A reaction takes place in 3 steps, the rate constant are K
1
, K
2
and K
3
and energies of activation are 40,
30 and 20 kJ respectively. If overall rate constant K =
2
3 1
K
K K
, then overall energy of activation is :
(A) 10 (B) 15 (C) 30 (D) 60
Q.2 Ammonia gas does not evolve from the complex FeCl
3
4NH
3
but it gives white precipitate with aqueous
solution of AgNO
3
.Coordination number of central metal ion in the above complex is six. Give IUPAC
name of the complex:
(A) Ammonium trichloridotetraammineiron (III) (B) Dichloridotetraammineferrate (III) chloride
(C) Tetramminedichloridoiron (III) chloride (D) Tetramminedichloridoferrate (III) chloride
[Only V-Group Batch]
Q.3 H C
3
ONa

Et
D

I C H
3
P,,
P is
(A)
H C
3
OCH
3
Et
D
(B)
H C
3
OCH
3
Et
D
(C) H CO
3
CH
3
Et
D
(D)
CH
3
OCH
3
Et
D
[Only XY Batch]
Q.3
O

DCl
) Hg ( Zn

P,,
P is
(A)
D
OH
(B)
D D
(C) (D)
D
OD
Q.4 2.6 g of an element X is reacted with an aqueous solution of NaOH and NaNO
3
to yield Na
2
XO
2
and
NH
3
. The liberated NH
3
is absorbed in 100 ml of 0.11 M H
2
SO
4
. The excess acid is back titrated with
48 ml of 0.25 M NaOH. Find the atomic weight of (X).
(A) 65 (B) 63.5 (C) 64.5 (D) 63
CHEMISTRY
XIII (VXY) RT-6 [Paper-I] Code-A Page # 10
[Only V-Group Batch]
Q.5 H C
3
CH
3
C CH C
2
O O

2 2
I / ) OH ( Ca
Yellow ppt. + Salt
A
P..
P is
(A) H C
3
CH
3
C CCH
2
H
2
O
(B) H C
3
CH
3
C
O
(C) H C
3
CH
O
(D) None of these
[Only XY Batch]
Q.5
O
H C
3
COH
+ H O Me
18

+
H
AA
A is
(A) H C
3
O
C OMe
18
(B)
H C
3
O
C OMe
18
(C) H C
3
O
C OMe
18
18
(D) H C
3
O
C OMe
Q.6 Consider the following reactions at 1000C
(a) Zn(s) +
2
1
O
2
(g)

ZnO(s) ; AG = 360 kJ/mol
(b) C(graphite) +
2
1
O
2
(g)

CO(g) ; AG = 460 kJ/mol
Choose the correct statement at 1000C.
(A) Zinc can be oxidised by CO (B) Zinc oxide can be reduced by graphite
(C) Both (A) and (B) (D) Carbon monoxide can be reduced by zinc.
CHEMISTRY
XIII (VXY) RT-6 [Paper-I] Code-A Page # 11
[PARAGRAPH TYPE]
Q.7 to Q.9 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Paragraph for question nos. 7 to 9
Acid rain occurs due to combination of acidic oxides with water. During rain, SO
2
(g) present in atmosphere
is dissolved in water to form H
2
SO
3
(aq)
Given at 300 K,
3 2 1
SO H a
K = 0.5,
3 2 2
SO H a
K = 10
7
, R = 0.0821 Latm K
1
mol
1
Q.7 The solubility of SO
2
(g) at 1 atm and 300 K is 24.63 L in 1 litre of water. Calculate [HSO
3

] in the
saturated solution of SO
2
(aq).
(A) 0.5 M (B) 1M (C) 10
3
M (D) 0.1 M
Q.8 Degree of dissociation of water in the above solution is :
(A) 10
7
(B) 1.8 10
9
(C) 3.6 10
16
(D) 3.6 10
14
Q.9 100 ml 1M H
2
SO
3
is titrated with 1 M NaOH solution. Calculate pH when 150 ml NaOH is added.
(A) 7 (B) 7.6 (C) 6.4 (D) 7.8
MULTIPLE CORRECT CHOICE TYPE]
Q.10 to Q.13 has four choices (A), (B), (C), (D) out of which ONE OR MORE may be correct.
Q.10 One mole of an ideal diatomic gas (
v
C = 5 CalK
1
mol
1
) changes its state from state 1 (27C, 1L) to
state 2 (127C, 10L). For this process , which of the statements is(are) correct?
(Given : R = 2 CalK
1
mol
1
).
(A) AH = 700 cal
(B) AU = 500 cal
(C) AS = 5ln(4/3) + 2ln10 calK
1
(D) AG of the process can't be calculated using given information.
[Only V-Group Batch]
Q.11
Na C O + H SO
2 2 4 2 4
(A) + Na SO
2 4
A
H O +
2
(X) (Y) +
Burns with
blue flame
Turns lime water
milky
Which of the following reactions will give both gases (X) and (Y)?
(A) H
2
C
2
O
4
A
(B) FeC
2
O
4


A
(C) HCOONa
C 350
A

(D) HCOOAg

A
CHEMISTRY
XIII (VXY) RT-6 [Paper-I] Code-A Page # 12
[Only XY Batch]
Q.11 Mg
2
C
3
and Be
2
C on hydrolysis gives hydrocarbons A and B respecteively. Find the sum of o-bonds in
A and B.
(A) 10 (B) 6 (C) 12 (D) 4
[Only V-Group Batch]
Q.12 Alcohols which can give white turbidity immediately on reaction with Lucas reagent are
(A)
OH
(B) Ph
3
COH (C) H
3
COH (D)
H
|
OH C C H
|
CH
3
3

[Only XY Batch]
Q.12 Which of the following compound(s) will give isocyanide test with CHCl
3
/ KOH ?
(A)
NH
2
(B)
N
H
(C)
NH
2
(D)
O
NH
2
[Only V-Group Batch]
Q.13 Which of the following option is / are correct?
(A) Inorganic Benzene is isoelectronic with ZnC
2
.
(B) CH
2
= C = CH
2
is non-planar as well as Non polar compound.
(C) B
2
H
6
. 2NH
3
having

e 2 c 3
bonds
(D) PCl
5
on partial hydrolysis gives POCl
3
and HCl.
[Only XY Batch]
Q.13 How many of the following options is/are correct for Bayer's process?
(A) In Bayer's process CO
2
reduces the pH of solution.
(B) To precipitate the Al(OH)
3
by using CO
2
(C) Excess of NaOH is neutralized by CO
2
.
(D) In Bayer's process NaOH is used as leaching agent due to amphoteric nature of Al
2
O
3
.
PART-C
[INTEGER TYPE]
Q.1 to Q.8 are "Integer Type" questions. (The answer to each of the questions are upto 4 digits)
Q.1 From the standard potentials in acidic medium as shown in the following diagram. Calculate (E

1
+ E

2
)
in volts.
MnO
4

MnO
4
2 0.55V
MnO
2
2.26V
Mn
3+ 0.96V
Mn
2+ 1.66V
E
1
E
2
CHEMISTRY
XIII (VXY) RT-6 [Paper-I] Code-A Page # 13
Q.2 How many of the following show(s) disproportionation reaction?
(i) XeF
4
+ H
2
O
(ii) XeF
2
+ H
2
O
(iii) Na
2
S
2
O
3
. 5H
2
O
A
(iv) P
4
+ NaOH + H
2
O
(v) F
2
+ NaOH
(vi) Cl
2
+ cold/ dilute NaOH
(vii) HOCl
A
(viii) NO
2
+ NaOH
(ix) Zn + NaOH
If your answer is 2, write the answer as 0002.
Q.3 Number of moles of Grignard reagent required for complete reaction with following in order.
(a)
O
(b)
OCH
3
O
(c)
OCH
3
H
3
CO
O
(d)
O
O
Cl
are
Write answer of part (a),(b), (c) and (d) in the same order and present the four digit number as
answer in OMR sheet. For example : If ans of (a) is 2 , (b) is 0, (c) is 5 and (d) is 7 then fill 2057
in OMR sheet.
Q.4 Calculate sum of the solution codes of all those statements which are correct.
Statement Solution codes
(1) Reaction C(graphite) C(diamond) is an example of phase transition 1001
(2) All adiabatic processes will be isoentropic for system 1002
(3) Half life of a first order radioactive reaction depends only on 1003
number of particles present and is independent of temperature
(4) pH at half the equivalence point in any weak basestrong acid 2001
titration = pK of the base
(5) Reduction potential of hydrogen electrode 3001
Pt(s) | H (aq, 0.5 M) | H (g, 4 bar) is negative
(6) For a reaction A B if rate of forward is greater than rate of 4002
backward reaction for same concentration of A and B then K will
be less than 1.

b
2
eq
+
CHEMISTRY
XIII (VXY) RT-6 [Paper-I] Code-A Page # 14
Q.5 How many of the following metals is extracted by self reduction process?
Pb, Au, Mg, Sn, Fe, Al, Ag, Hg, Na, Zn, Cu, Ca
If your answer is 2, write the answer as 0002.
Q.6 Number of monochloroderivative (Structure only) formed by photochlorination of methylcyclobutane
are X.
For example : If ans is 2 then fill 0002 in OMR sheet.
Q.7 Find the value of (Z) ; Z =
10
C B A +
A = Total number of linkage isomers of [Cu(CN)
2
(SCN)
2
]
2
B = Total number of structural isomers of [Cu(NH
3
)
4
][Pt(CN)
4
]
C = Total number of geometrical isomers of [Co(H
2
O)
2
(NH
3
)
2
Cl
2
]
+
If your answer is 2, write the answer as 0002.
Q.8 Total number of stereoisomers for
(i) (ii)
(iii) (iv)
COOH
Write answer of part (i),(ii), (iii) and (iv) in the same order and present the four digit number
as answer in OMR sheet. For example: If ans of (i) is 2 , (ii) is 0, (iii) is 5 and (iv) is 7 then fill
2057 in OMR sheet.

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