Guideline Method of Sampling and Analysis For Airborne Lead

GUIDELINES ON METHOD OF SAMPLING AND
ANALYSIS FOR AIRBORNE LEAD

FACTORIES AND MACHINERY (LEAD) REGULATIONS, 1984
(REGULATION 15)

DEPARTMENT OF OCCUPATIONAL SAFETY AND HEALTH
MINISTRY OF HUMAN RESOURCES
1997

JKKP:GP (I) 2/97
ISBN : 983-99156-4-9

Depc|tnent c| Cccupct|cnc| Sc|ety cnc Hec|tn. /c|cy:|c
Gu|ce||ne: cn /etncc c| Scnp||ng cnc Anc|y:|: |c| A||cc|ne Lecc

CONIENIS

Fcge

FFEF/CE 1

GUlDELlNES CN MEIHCD CF S/MFLlNG FCF /lF8CFNE LE/D

1. Generc| lnfcrmcIicn 3
2. Frincip|e 3
3. Ccre cf Scmp|ing EuipmenI 7
4. Freci:icn cnc /ccurccy 8
5. Feference: 8

GUlDELlNES CN MEIHCD CF /N/LYSlS FCF /lF8CFNE LE/D

1. Lecc Ly F|cme //S 10
2. Scmp|ing, Mec:uremenI cnc /ccurccy 10
3. FecgenI:, EuipmenI cnc /ccurccy 11
4. Cc|iLrcIicn cnc Cuc|iIy CcnIrc|, Mec:uremenI
cnc Cc|cu|cIicn: 12
5. Feference: 13
. /ppencix - Micrcwcve Dige:Iicn fcr Lecc
in FcinI Chip: {cnc cIher McIrice:) 14-1

Gu|ce||ne: cn /etncc c| Scnp||ng cnc Anc|y:|: |c| A||cc|ne Lecc 1

FkEFACE

Ihe purpc:e cf Ihe:e guice|ine: i: Ic :upp|emenI Ihe reuiremenI cf regu|cIicn 15 cf Ihe
FccIcrie: cnc Mcchinery {Lecc) Fegu|cIicn: 184, :pecifying c meIhcc cf mcniIcring
cnc cnc|y:i: cf cccurccy, Ic c ccnficence |eve| cf 57, wiIhin c mcrgin cf p|u: cr minu:
207, fcr cirLcrne ccncenIrcIicn: cf |ecc euc| Ic cr grecIer Ihcn :evenIy five
micrcgrcm: per cuLic meIre {75 gm/ m
3
) cf cir. /n emp|cyer cr cn cccupier whc hc:
cn incu:Iric| prcce:: wiIhin hi: p|cce cf wcrk which u:e: cr hcnc|e: incrgcnic |ecc, cnc
in which Ihere exi:I: pcIenIic| IhcI cny emp|cyee mcy Le expc:ec Ic cirLcrne |ecc
curing wcrk, i: ccvi:ec Ic refer Ic Ihe:e guice|ine: in ccmp|ying wiIh Ihe emp|cyee
expc:ure mcniIcring reuiremenI: c: :Iipu|cIec in FcrI lll cf Ihe cLcve Fegu|cIicn:. /n
emp|cyer cr cn cccupier mcy u:e cny cIher meIhcc cf mcniIcring cnc cnc|y:i:, LuI Ihe
meIhcc u:ec mu:I Le prcven Ic Le cn c pcr wiIh cr LeIIer Ihcn Ihe meIhcc
reccmmencec in Ihe:e guice|ine:.

Ihe DepcrImenI cf CccupcIicnc| ScfeIy cnc Hec|Ih c|:c ccmini:IrcIive|y :creen::

c) per:cn whc wi:h Ic ccncucI expc:ure mcniIcring fcr cirLcrne |ecc: cnc

L) |cLcrcIcrie: which wi:h Ic ccncucI cnc|y:i: cf cirLcrne |ecc mcniIcring
:cmp|e::

in ccmp|icnce wiIh Ihe cLcve Fegu|cIicn: cnc cpprcve: Ihc:e fcunc Ic :cIi:fy Ihe
reuiremenI: cf Ihe DepcrImenI. Ihe:e cpprcvec per:cn: cnc cpprcvec |cLcrcIcrie:
cre expecIec Ic Le fcmi|icr wiIh Ihe meIhcc cf mcniIcring cnc cnc|y:i: reccmmencec
in Ihe:e guice|ine:, c: cpprcpricIe Ic Iheir :pecific crec cf ccIiviIy, cnc Ic u:e Ihe
meIhcc fcr ccmp|icnce purpc:e:.

DirecIcr Generc|
DepcrImenI cf CccupcIicnc| ScfeIy cnc Hec|Ih
Mc|cy:ic

/pri| 17


GbIDELINES ON MEIHOD
OF SAMFLING FOk
AIk8OkNE LEAD

FACIOkIES AND MACHINEkY [LEAD} kEGbLAIIONS, 184
[kEGbLAIION 15}


1. GENEkAL INFOkMAIION

1.1. Wcrker 8recIhing Zcne

Ihi: i: cefinec c: c hemi:phere cf 300 mm rcciu: exIencing in frcnI cf Ihe
fcce cnc mec:urec frcm c |ine Li:ecIing Ihe ecr:.

1.2. Fer:cnc| Scmp|e:

ln crcer Ic e:IimcIe wcrker expc:ure, :cmp|e: mu:I Le Icken in Ihe
wcrker': LrecIhing zcne cnc Le cLIcinec uncer Iypicc| wcrking
ccnciIicn:, prefercL|y cver Ihe fu|| :hifI. Scmp|ing prccecure: :hcu|c cim
cI minimc| inIerference wiIh Ihe ccIiviIie: cf Ihe wcrker.

2. FkINCIFLE

/ mec:urec vc|ume cf cir i: crcwn Ihrcugh c memLrcne fi|Ier mcunIec cn c fi|Ier
hc|cer, cnc |ecc ccnIcmincnI cc||ecIec wi|| Le :enI Ic Ihe cnc|yIicc| |cLcrcIcry
fcr |ecc cnc|y:i:.

2.1 Apporotus

2.1.1. Somp||ng System

Ihe cppcrcIu: neecec fcr per:cnc| :cmp|ing cre c :cmp|ing pump, c
Ihree-piece cc::eIIe cnc cc::eIIe hc|cer, c pump': cc|iLrcIcr, c :i|iccn
IuLing cnc ce||u|c:e e:Ier memLrcne fi|Ier. Ihe e::enIic| fecIure: cf c||
:cmp|ing :y:Iem: cre Ihe fi|Ier {cn which Ihe :cmp|e i: cc||ecIec) cnc Ihe
pump fcr pu||ing Ihe cir Ihrcugh iI. /n cirf|cw inciccIing cevice mcy Le
prcvicec. Ihe pump uniI mu:I Le ccpcL|e cf mcinIcining c :mccIh f|cw
cf Ihe :pecifiec rcIe IhrcughcuI Ihe :cmp|ing pericc. Ihe permiIIec errcr
|imiI: cf f|cw mcy Le cchievec eiIher Ly u:ing c f|cw :IcLi|i:ec pump cr Ly
:ufficienI|y freuenI ccju:ImenI cf Ihe f|cwrcIe.

2.1.2. Fersono| Somp||ng For Leod In A|r

Ihe per:cnc| :cmp|er fcr |ecc in cir ccn:i:I cf c Ihree-piece cc::eIIe cf 37
mm cicmeIer {:ee fig.1) wiIh Ihe mc|e :ecIicn remcvec curing :cmp|ing
cnc c pump uniI ccpcL|e cf mcinIcining c :mccIh f|cw rcIe cf 2.0 :I. 0.1
|iIre/min. IhrcughcuI Ihe :cmp|ing pericc.

MemLrcne fi|Ier: mcce cf ce||u|c:e e:Ier wiIh 0.8 micrcmeIre
pcre :ize cr euivc|enI mu:I Le u:ec. Ihe :ize cf Ihe fi|Ier :hcu|c
Le 37 mm in cicmeIer.

2.1.3. Anc|||ory Equ|pment

Ce||u|c:e Lcnc: fcr fi|Ier hc|cer:
8uLL|e-meIer Ic cc|iLrcIe pump f|cw rcIe
SIcp wcIch
IhermcmeIer Ic mec:ure cir IempercIure
Iweezer: fcr hcnc|ing fi|Ier:

IHkEE FIECE CASSEIIE HOLDEk

FIGbkE 1

Blue Plastic Plug
Male (Inlet) Section
Ring Section
Filter
Support Screen (Pad)
Female (Outlet) Section
(Ribbed base)
Red Plastic Plug
2.1.4 Co||brot|on o| pump ||ow rote

8efcre cc|iLrcIicn, mcke :ure Ihe pump i: fu||y chcrgec cnc in gccc
crcer. SeI up Ihe cppcrcIu: ccccrcing Ic Ihe crrcngemenI c: :hcwn in
Fig.2. Ihe LuLL|e meIer u:e: Ihe princip|e cf cy|incricc| cir ci:p|ccemenI
wiIh necr|y 'fricIicn|e:: pi:Icn. Ihe inIericr :urfcce i: weIIec wiIh ceIergenI
:c|uIicn Ic mcke iI 'fricIicn|e::. / :ccp-fi|m LuLL|e i: p|ccec cnc :ucIicn
i: prcvicec Ly Ihe pump Ic Le cc|iLrcIec. Ihe LuLL|e wi|| Le crcwn up
Ihe cy|incer. Ihe cc|umn ci:p|ccemenI per uniI Iime ccn Le ceIerminec
Ly mec:uring Ihe Iime reuirec f cr Ihe LuLL|e Ic pc:: LeIween Iwc :cc|e
mcrking which enc|c:e c kncwn vc|ume.

8y ccju:Iing Ihe f|cw rcIe cf Ihe pump, Ihe reuirec f|cwrcIe c: cerivec
frcm Ihe LuLL|e meIer ccn Le fcunc. Mcrk Ihe pc:iIicn cf Ihe f|ccI cn
Ihe rcIcmeIer inccrpcrcIec cn Ihe pump. Ihe IempercIure cf Ihe rccm
cnc Ihe LcrcmeIric pre::ure mu:I Le reccrcec curing Ihe cc|iLrcIicn.
/fIer :cmp|ing, Ihe pump f|cwrcIe hc: Ic Le recheckec Ic cc|iLrcIec
f|cwrcIe. lf Ihe errcr i: mcre Ihen 107, Ihe :cmp|e mu:I Le rejecIec.

2.2 Somp||ng

Fer:cnc| :cmp|e: cre Icken u:ing c fu||y chcrgec LcIIery cpercIec
pcrIcL|e :cmp|ing pump fiIIec wiIh cn cir f|cw :mccIhing cevice.

/pprcximcIe|y fifIeen minuIe: Lefcre :cmp|ing i: Ic Legin ccnnecI Ihe
pump Ic Ihe :cmp|er {wiIh fi|Ier). LeI Ihe pump run cf fifIeen minuIe:
cnc ccju:I Ihe f|ccI cn Ihe rcIcmeIer {Ly ccju:Iing Ihe f|cw rcIe) Ic
Ihe mcrkec pc:iIicn i.e Ihe cc|iLrcIec f|cw rcIe. Ihen rep|cce Ihe
:cmp|er wiIh cncIher :cmp|er ccnIcining c c|ecn fi|Ier. Feccju:I Ihe
f|ccI Ic iI: ccrrecI pc:iIicn. Experience mcy :hcw IhcI Ihi: wcrm-up
pericc i: unnece::cry fcr :cme Iype: cf :IcLi|i:ec f|cw pump:.

F|cce Ihe :cmp|ing euipmenI c::emL|y cn Ihe :e|ecIicn per:cn. Ihe
wecrer cf Ihe euipmenI :hcu|c Le prcvicec wiIh c :uiIcL|e Le|I cr
hcrne:: Ic wiIh Ihe pump ccn Le ccnvenienI|y fixec, un|e:: Ihe pump
i: :mc|| encugh Ic fiI inIc Ihe pcckeI. /IIcch Ihe :cmp|er cr :cmp|ing
hecc Ic Ihe cpercIcr, prefercL|y cn hi: |cpe|, ncI mcre Ihcn 30 cm
cwcy frcm Ihe nc:e-mcuIh regicn.

When reccy Ic ccmmence :cmp|ing, Iurn cn Ihe pump cnc reccrc
Ihe fc||cwing infcrmcIicn:

c. SIcrIing Iime
L. Fi|Ier numLer cr cc::eIIe numLer
c. Fump icenIificcIicn numLer
c. Fump :IcrI Iime cnc ccIe
e. F|cw rcIe
f. Wcrker: ncme
g. Iype cf cpercIicn
h. VenIi|cIicn ccnIrc| cnc cImc:pheric ccnciIicn:, where
re|evcnI
i. IempercIure {every cne hcur): cnc
j. Encing Iime

CALI8kAIION ASSEM8LY FOk IOIAL DbSI SAMFLING

3 Fiece Cc::eIIe wiIh repre:enIcIive fi|Ier
8uLL|e meIer

FIGbkE 2


lf c pump uniI wiIhcuI :IcLi|izec f|cw i: u:ec, check, reccrc cnc reccju:I
Ihe f|cw rcIe c: nece::cry cI Ihe enc cf ecch hcur. /I Ihe enc cf Ihe
:cmp|ing pericc ncIe Ihe Iime :wiIch cff Ihe pump cnc remcve Ihe
cc::eIIe.

2.3 End o| Somp||ng

Mec:ure Ihe pump f|cw rcIe cI Ihe enc cf :cmp|ing Lefcre :wiIching Ihe
pump cff-c |cIer check mcy give fc|:e re:u|I: cue Ic Ihe Iempcrcry
reccvery cf c ci:chcrgec LcIIery. SwiIch cff Ihe pump cnc reccrc Ihe
Iime. Femcve Ihe cc::eIIe cnc immecicIe|y p|cce iI in c cu:I free Lcx
wiIh Ihe ccnIcmincIec :ice fccing upwcrc:, en:uring IhcI iI ccnncI Le
inccverIenI|y u:ec cgcin.

3. CAkE OF SAMFLING EQbIFMENI

3.1 F||ter Ho|der

8efcre :cmp|ing, check IhcI Ihe fi|Ier hc|cer i: c|ecn cnc cry. En:ure IhcI
Ihe fi|Ier i: prcper|y p|cce in Ihe fi|Ier hc|cer. Check prcper|y IhcI Ihe fi|Ier
hc|cer hc|ve: cre he|c IcgeIher finger IighI-Icc |cc:e wi|| ccu:e c |eck,
whi|:I Icc IighI mcy ccu:e ccmcge Ic Ihe memLrcne fi|Ier.

3.2 Connect|ng Iubes

Ihe enc: cf Ihe ccnnecIing IuLe: wi|| Leccme :IreIchec cfIer repecIec
u:e cnc mcy |eck cr Leccme ceIcchec curing u:e. Ihey mu:I Le
excminec Lefcre ecch u:e cnc renewec if Icc |cc:e, cr if |eckcge i:
:u:pecIec.

3.3 F||ter

/fIer :cmp|ing Ihe :cmp|e mu:I Le en:urec IhcI iI i: Icmper free. Ihe
:cmp|e mu:I Le ci:ccrcec if Ihere cre evicence :ugge:Iing iI hc: Leen
Icmperec wiIh e.g finger prinI mcrk cn Ihe fi|Ier, exce::ive |cc:e cu:I in
Ihe fi|Ier hc|cer, eIc.

3.4 Fock|ng o| the Somp|es

Di:ccnnecI Ihe fi|Ier cfIer :cmp|ing. Ccp Ihe in|eI cnc cuI|eI cf Ihe fi|Ier
hc|cer wiIh p|ug:. LcLe| Ihe :cmp|e .Feccrc perIinenI :cmp|ing ccIc
inc|ucing Iime: cf Leginning cnc enc cf :cmp|ing, iniIic| cnc finc| cir
IempercIure:, re|cIive humiciIy cnc cImc:pheric pre::ure cr e|evcIicn
cLcve :ec |eve|. Feccrc Ihe Iype cf per:cnc| :cmp|ing pump u:ec cnc
|cccIicn cf :cmp|er.

3.5 Ironsportot|on o| Somp|es to the Loborotory

Ship Ihe :cmp|e: Ic Ihe |cLcrcIcry c: :ccn c: pc::iL|e in c :uiIcL|e
ccnIciner ce:ignec Ic prevenI ccmcge in Ircn:iI. Ship Lu|k mcIeric| Ic
Ihe |cLcrcIcry in c g|c:: ccnIciner wiIh c FIFE-|inec ccp. Never :Icre,
Ircn:pcrI cr mci| Ihe Lu|k :cmp|e in Ihe :cme ccnIciner c: Ihe :cmp|e:
frcm Ihe :cme |cI fcr u:e c: mecic L|cnk:.


4. FkECISION AND ACCbkACY

ln Ihi: meIhcc Ihe Ierm 'cccurccy i: u:ec Ic ce:criLe Ihe cifference
LeIween c mec:urec ccncenIrcIicn cnc Ihe Irue ccncenIrcIicn cf Ihe
:cmp|e. /ccurccy hc: Iwc ccmpcnenI:: preci:icn cnc Lic:. Freci:icn i: c
mec:ure cf vcricLi|iIy cf meIhcc cLcuI iI: cwn mecn cnc i: u:uc||y expre::ec
c: c :Icnccrc cevicIicn {cL:c|uIe vc|ue) cr cceffienI cf vcricIicn {CV7 cf
:Icnccrc cevicIicn re|cIive Ic Ihe mecn). 8ic: i: Ihe cifference LeIween Ihe
cvercge re:u|I cnc Ihe Irue vc|ue frcm Ihe ceIermincIicn. Ihe cccurccy cf
Ihi: meIhcc i: + 17. 7

5. kEFEkENCES

i) NlCSH Mcnuc| cf /nc|yIicc| MeIhcc: {NM/M)
U.S DepcrImenI Cf Hec|Ih , EcuccIicn /nc We|fcre
NcIicnc| ln:IiIuIe cf CccupcIicnc| ScfeIy cnc Hec|Ih
FcurIh EciIicn, 14
U.S./:

ii) CccupcIicnc| Expc:ure Scmp|ing SIrcIegy Mcnuc|
U.S DepcrImenI cf Hec|Ih, EcuccIicn cnc We|fcre
NcIicnc| ln:IiIuIe cf CccupcIicnc| ScfeIy cnc Hec|Ih, 17
U.S./ : cnc

iii) /pprcvec MeIhcc cf McniIcring cnc /nc|y:i: fcr Minerc| Du:I
DepcrImenI cf CccupcIicnc| ScfeIy cnc Hec|Ih,
Mc|cy:ic.


GbIDELINES ON MEIHOD
OF ANALYSIS FOk
AIk8OkE LEAD

NIOSH Monuo| o| Ano|yt|co| Method [NMAM}
Fourth Ed|t|on, 14


LEAD by F|ome AAS 7082

FL MW: 207.1 {FL) C/S: 743-2-1 {FL) /IECS: CF7525000 {FL)
223.1 {FLc) 1317-3-8 {FLc) CG1750000 {FLc)

MEIHCD: 7082, l::ue 2 EV/LU/IlCN : FULL l:-:ue 1: 15 FeLrucry 184
l::ue 2: 15 /ugu:I 184

CSH/ : 0.05 mg/m3 FFCFEFIlES: :cfI meIc|:
NlCSH: < 0.1 mg/m3: L|ccc FL < 0 ug/100 g, c 11.3 g|cmJ : MF 327.5 C
/CGlH: 0.15 mg/m3 , vc|ence: -2.-4 in :c|I:

SYNCNYMS: e|emenIc| |ecc cnc |ecc ccmpcunc: excepI c|ky| |ecc

S/MFLlNG ME/SUFEMENI

S/MFLEF: FlL IEF IECHNlCUE: /ICMlC /8SCFFIlCN
{0.8-um ce||u|c:e e:Ier memLrcne) SFECIFCFHCICMEIEF FL/ME

FLCW F/IE : 1 Ic 4 Umin /N/L YIE: |ecc
VCL- MlN. 200 L @ 0.05 mg/mJ /SHlNG: ccnc. HNCJ, 5m| -307 H2C2 -
M/X: 1500 L 1 m|, 140 C
SHlFMENI: rcuIine FlN/L SCLUIlCN: 107 HNCJ, 10 mi
S/MFLE SI/8lLlIY: :IcL|e FL/ME: cir-cceIy|ene, cxicizing .

8L/NKS: 2 Ic 10 fie|c L|cnk: per :eI W/VELENGIH: 283.3 nm

ACCbkACY
8/CKGFCUND
CCFFECIlCN: 02 cr H2 |cmp cr
F/NGE SIUDlED: 0.13 Ic 0.14 mg/mJ|1],
0.15 Ic 1.7 mg/mJ {fume) |2] C/Ll8F/IlCN: FL| in 107 HNCJ
8l/S: -3.17 F/NGE: 10 Ic 200 ug per :cmp|e |4]
CVEF/LL FFEClSlCN {S ): 0.072 |1], FFEClSlCN {S): 0.03 |1]
0.08 {fume) |2]
/CCUF/CY: = 17.57

/FFLlC/8lLlIY: Ihe wcrking rcnge i: 0.05 Ic > 1 mg/m3 fcr c 200-L cir :cmp|e Ihe meIhcc i: cpp|iccL|e
Ic e|emenIc| |ecc. inc|ucing FL fume. cnc c|| cIher cerc:c|: ccnIcining |ecc. Ihi: i: cn e|emenIc|
cnc|y:i: ncI ccmpcunc :pecific. /|iucI: cf :cmp|e: ccn Le cnc|yzec :epcrcIe|y fcr ccciIicnc|
e|emenI:.

lNIEFFEFENCES: U:e C2 cr H2 ccnIinuum cr Zeemcn Lcckgrcunc ccrrecIicn Ic ccnIrc| f|cme cr
mc|ecu|cr cL:crpIicn. High ccncenIrcIicn: cf cc|cium, :u|fcIe, ccrLcncIe, phc:cncIe, iccice, f|ucrice,
cr cceIcIe ccn Le ccrrecIec-

CIHEF MEIHCDS: Ihi: meIhcc ccmLine: cnc rep|cce: F&C/M 173|3] cnc S341 |4,5] fcr |ecc. MeIhcc
7300 {lCF-/ES) cnc 7105 {//S/GF) cre c|IerncIe cnc|yIicc| meIhcc:. MeIhcc 7505 i: :pecific fcr |ecc
:u|fice. Ihe fc||cwing hcve ncI Leen revi:ec- Ihe ciIhizcne meIhcc, which cppecr: in F&C/M 102 |5]
cnc Ihe |ecc criIeric cccumenI |]: cnc F&C/M 11 {/SV) |7].


kEAGENIS: EQbIFMENI:

1. NiIric ccic, ccnc.* . 1. Scmp|er: Ce||u|c:e e:Ier fi|Ier. 0.8 - unpcre
2NiIric ccic, 107 {v/v). /cc 100 mi ccnc. HNCJ :ize. 37- mm cicmeIer in cc::eIIe fi|Ier hc|cer
500 mL wcIer: ci|uIe Ic 1 L.. 2. Fer:cnc| :cmp|ing pump. 1 Ic 4 Un|n. wiIh
3. Hycrcgen percxice. 307 H2C2 {w/w) recgenI f|exiL|e ccnnecIing IuLing.
grcce. . 3. /Icmic /L:crpIicn SpecIrcphcIcmeIer wiIh
4. Cc|iLrcIicn :Icck :c|uIicn. 1000 ug/mL FL cn cir-cceIy|ene Lurner hecc cnc Lcckgrcunc.
Ccmmercic| :Icnccrc cr ci::c|ve 1.00 g FL ccrrecIicn.
meIc| in minimum vc|ume cf {1-1)HClcnc ci|uIe 4. Lecc hc||cw ccIhcce |cmp cr e|ecIrcce
LcII|e. SIcL|e > cne yecr. 1 L wiIh 17 {v/v) HCl. ci:chcrge|e:: |cmp.
SIcre in c pc|yeIhy|ene 5. Fegu|cIcr:. Iwc-:Icge, fcr cir cnc cceIy|ene.
5. /ir. ccmpre::ec, fi|Ierec. . 8ecker:. Fhi||ip:. 125-mL cr Griffin, 50- mL
. /ceIy|ene wiIh wcIch g|c:: ccver:.
7. Di:Ii||ec cr ceicnizec wcIer. 7. Vc|umeIric f|c:k:. 10- cnc 100 -mL. **
8. /::crIec vc|umeIric pipeI: c: neecec.
. HcIp|cIe. :urfcce IempercIure 140 C.
See SFECl/L FFEC/UIlCNS. 10. 8cII|e:. pc|yeIhy|ene. 100- mL.

C|ecn c|| g|c::wcre wiIh ccnc. niIric ccic cnc
rin:e Ihcrcugh|y wiIh ci:Ii||ec cr ceicnizec
wcIer Lefcre u:e.

SFECIAL FkECAbIIONS: Ccnc. niIric ccic i: cn irriIcnI cnc mcy Lum :kin. Ferfcrm c|| ccic cige:Iicn: in c
fume hccc. Hycrcgen percxice i: c :Ircng cxicizing cgenI, c :Ircng irriIcnI, cnc ccrrc:ive Ic Ihe :kin.
Wecr g|cve: cnc eye prcIecIicn.

SAMFLING:.

1. Cc|iLrcIe ecch per:cnc| :cmp|ing pump wiIh c repre:enIcIive :cmp|er in |ine.

2. Scmp|e cI cn cccurcIe|y kncwn f|cw rcIe LeIween 1 cnc 4 L/min fcr up Ic 8 h fcr c IcIc| :cmp|e :ize
cf 200 Ic 1500 L fcr IW/ mec:uremenI:. Dc ncI exceec c fi|Ier |cccing cf ec. 2 mg IcIc| cu:I.

SAMFLE FkEFAkAIION:

NCIE 1: Ihe fc||cwing :cmp|e prepcrcIicn gcve ucnIiIcIive reccvery {:ee EV/LU/IlCN CF
MEIHCD) |4]. SIep: 4 Ihrcugh cf MeIhcc 7300 cr cIher ucnIiIcIive c:hing Iechniue: mcy Le
:uL:IiIuIec, e:pecic||y if :everc| meIc|: cre Ic Le ceIerminec cn c :ing|e fi|Ier.

NCIE 2: Ihe /ppencix give: c micrcwcve cige:Iicn prccecure which mcy Le nece::cry fcr ccmp|eIe
reccvery cf |ecc frcm :cme mcIrice:, e:pecic||y epcxy-Lc:ec pcinI.

3. Cpen Ihe cc::eIIe fi|Ier hc|cer: cnc Ircn:fer Ihe :cmp|e: cnc L|cnk: Ic c|ecn Lecker:.

4. /cc 3 mL. ccnc. HNCJ, cnc 1 mL 307 H2C2 cnc ccver wiIh c wcIch g|c::. SIcrI recgenI L|cnk: cI
Ihi: :Iep.
NCIE: lf FLC2 i: ncI pre:enI in Ihe :cmp|e, Ihe 307 H2C2 neec ncI Le cccec |2,4].

5. HecI cn 140 C hcIp|cIe unIi| vc|ume i: recucec Ic cLcuI 0.5 mL.

. FepecI Iwc mcre Iime: u:ing 2 mL ccnc. HNCJ cnc 1 mL 307 H2C2 ecch Iime.

7. HecI cn 140 C hcIp|cIe unIi| cc. 0.5 mL |iuic remcin:.

8. When :cmp|e i: cry, rin:e Ihe wcIch g|c:: cnc wc||: cf Ihe Lecker wiIh 3 Ic 5 mL 107 HNCJ. /||cw Ihe
:c|uIicn Ic evcpcrcIe Ic cryne::.

. Ccc| ecch Lecker cnc ci::c|ve Ihe re:icue: in 1 mL ccnc. HNCJ.

10. Ircn:fer Ihe :c|uIicn ucnIiIcIive|y Ic c 10-mL vc|umeIric f|c:k cnc ci|uIe Ic vc|ume wiIh ci:Ii||ec
wcIer.

NCIE: lf Ihe ccncenIrcIicn ~ cf cny cf Ihe fc||cwing i: expecIec Ic exceec Ihe |ecc
ccncenIrcIicn {M) Ly 10 -fc|c cr mcre, ccc 1 mL 1M Nc2EDI/ Ic ecch f|c:k Lefcre ci|uIicn Ic
vc|ume: CC , FC -, 1 -, F -, CH3CCC -.lf Cc2- cr 5C2 cre pre:enI in 10-fc|c cr grecIer exce::,
mcke c|| :Icnccrc: cnc :cmp|e: 17 {w/w) in Lc2- |3].

CALI8kAIION AND QbALIIY CONIkOL:

11. Frepcre c :erie: cf wcrking :Icnccrc: ccvering Ihe rcnge 0.25 Ic 20 ug/nL FL {2.5 Ic 200 ug FL per
:cmp|e).

c. /cc c|iucI: cf cc|iLrcIicn :Icck :c|uIicn Ic 100-mL vc|umeIric f|c:k:. Di|uIe Ic vc|ume wiIh 107
HNC3. SIcre Ihe wcrking :Icnccrc: in pc|yeIhy|ene LcII|e: cnc prepcre fre:h week|y.
L. /nc|yze Ihe wcrking :Icnccrc: IcgeIher wiIh Ihe L|cnk: cnc :cmp|e: {:Iep: 14 cnc 15). c. Frepcre
c cc|iLrcIicn grcph cf cL:crLcnce v:. :c|uIicn ccncenIrcIicn (ug/nL}.

!2. A:p||cte c :tcncc|c |c| eve|y !0 :cnp|e: tc cneck |c| |n:t|unent c|||t.

13. Check reccverie: wiIh cI |ec:I cne :pikec mecic L|cnk per 10 :cmp|e:. U:e meIhcc cf :Icnccrc
ccciIicn: cccc:icnc||y Ic check inIerference:.

MEASbkEMENI.

14. SeI :pecIrcphcIcmeIer c: :pecifiec Ly Ihe mcnufccIurer cnc Ic ccnciIicn: cn pcge 7082-1.

NCIE: /n c|IerncIe wcve|engIh i: 217.0 nm |8]. /nc|y:e: cI 217.0 nm hcve :|ighI|y grecIer :en:iIiviIy,
LuI pccrer :ignc|-Ic-nci:e rcIic ccmpcrec Ic 283.3 nm. /|:c ncn-cIcmic cL:crpIicn i:
:ignificcnI|y grecIer cI 217.0 nm, mcking Ihe u:e cf D2 cr H2 ccnIinuum cr Zeemcn
Lcckgrcunc ccrrecIicn mcnccIcry cI Ihe wcve|engIh.

15. /:pircIe :Icnccrc:, :cmp|e: cnc L|cnk:. Feccrc cL:crLcnce reccing:.

NCIE: lf Ihe cL:crLcnce vc|ue: fcr Ihe :cmp|e: cre cLcve Ihe |inecr rcnge cf Ihe :Icnccrc: ci|uIe
wiIh 107 HNC3, recnc|yze cnc cpp|y Ihe cpprcpricIe ci|uIicn fccIcr in Ihe cc|cu|cIicn:.

CALCbLAIIONS.

1. U:ing Ihe mec:urec cL:crLcnce:, cc|cu|cIe Ihe ccrre:pcncing ccncenIrcIicn: (ug/nL} cf |ecc in
Ihe :cmp|e, C cnc cvercge mecic L|cnk Cfrcm Ihe cc|iLrcIicn grcph.

17. U:ing Ihe :c|uIicn vc|ume: {mL) cf Ihe :cmp|e, V :' cnc mecic L|cnk: V ' cc|cu|cIe Ihe
ccncenIrcIicn, C (ng/n3} cf |ecc in Ihe cir vc|ume :cmp|ec V {L):

C:V:- CgV
C = ng/n3 V

EVALbAIION OF MEIHOD:

MeIhcc S341 |] wc: i::uec cn CcIcLer 24, 175 cnc vc|iccIec cver Ihe rcnge 0.13 Ic 0.4 ng/n3 fcr c
180 L cir :cmp|e, u:ing genercIec cImc:phere: cf |ecc niIrcIe |1]. Feccvery in Ihe rcnge 18 Ic 72 ug Fc
pe| :cnp|e wc: 87 cnc cc||ect|cn e|||c|ency c| 0.8 u|n n|xec ce||u|c:e |||te|: (/||||pc|e type
M) wc: 1007 fcr Ihe cerc:c|:. SuL:euenI :Iucie: cn cnc|yIicc| reccvery cf 200 ug FL per :cmp|e gcve
Ihe fc||cwing re:u|I: |2,4].


Spec|es D|qest|on Method Ano|yt|co| kecovery, %

FL meIc| HNC3 cn|y 2 = 4
FL meIc| HNC3 -H2C2 103 = 3
FLC HNC3 cn|y 3 = 4
FLS HNC3 cn|y 3 = 5
FLC2 HNC3 cn|y 82 = 3
FLC2 HNC3- H2C2 100 = 1
FL in pcinI* HNC3 cn|y 5 =
FL in pcinI* HNC3- H2C2 5 =

*SIcnccrc Feference McIeric| 157, U.S. NcIicnc| ln:IiIuIe cf SIcnccrc: cnc Iechnc|cgy.

/cciIicnc| cc||ecIicn efficiency :Iucie: were c|:c ccne u:ing Ge|mcn GN-4 fi|Ier: fcr Ihe cc||ecIicn cf
FL fume, which hcc gecmeIric mecn cicmeIer cf 0.1 u|n |2]. Mecn cc||ecIicn efficiency fcr 24
:cmp|ing run: cI f|cw rcIe: LeIween 0.15 cnc 4.0 L min wc: > 7 = 27. Cverc|| preci:icn, S wc: 0.072 fcr
|ecc niIrcIe cerc:c| |1.] cnc 0.08 fcr FL fume |2,4].

kEFEkENCES:

|1] DccumenIcIicn cf Ihe NlCSH Vc|iccIicn Ie:I:. U.S. DepcrImenI cf Hec|Ih, EcuccIicn, cnc We|fcre,
FuL|. {NlCSH) 77-185 {177).
|2] Hecvy MeIc| /erc:c|:: Cc||ecIicn cnc Di::c|uIicn Efficiencie:, Finc| FepcrI cf NlCSH CcnIrccI 210-7-
0058, W.F. GuIknechI, M.H. Fcncce, F.M. Grcn:e, /. Dcmie cnc D. C'Nec|. Fe:ecrch Iricng|e ln:IiIuIe:
cvci|cL|e c: Crcer Nc. F8 83-10740 frcm NIlS, Springfie|c. V/*2211 {181).
|3] NlCSH Mcnuc| cf /nc|yIicc| MeIhcc:, 2nc. ec., V.1. F&C/M 102, U.S. DepcrImenI cf Hec|Ih,
EcuccIicn, cnc We|fcre. FuL|. {NlCSH) 77-157-/ {17).
|4] NlCSH Mcnuc| cf /nc|yIicc| MeIhcc:, 2nc. ec., V. 7. S341 {revi:ec 3/25/81), U.S. DepcrImenI cf
Hec|Ih cnc Humcn Service:, FuL|. {NlCSH) 82-100 {182).
|5] NlCSH Mcnuc| cf /nc|yIicc| MeIhcc:, 2nc. ec., V. 1. F&C/M 102, U.S. DepcrImenI cf Hec|Ih,
EcuccIicn cnc We|fcre. FuL|. {NlCSH) 77-157-/ {177).
|] CriIeric fcr c Feccmmencec SIcnccrc...CccupcIicnc| Expc:ure Ic incrgcnic Lecc {Fevi:ec
CriIeric), U.S. DepcrImenI cf Hec|Ih, EcuccIicn cnc We|fcre. FuL|. {NlCSH) 78-158 {178).
|7) NlCSH Mcnuc| cf /nc|yIicc| MeIhcc:. 2nc. ec.. F&C/M 11.
|8] /nc|yIicc| MeIhcc: fcr /Icmic /L:crpIicn SpecIrcphcIcmeIry , Ferkin-E|mer {17).
|] NlCSH Mcnuc| cf /nc|yIicc| MeIhcc:, 2nc ec.. V.. S341, U.S. DepcrImenI cf Hec|Ih, EcuccIicn cnc
We|fcre, FuL|. {NlCSH) 77-157-C {177).
|10] DcIcChern LcLcrcIcrie: in-hcu:e prccecure fcr micrcwcve :cmp|e cige:Iicn.
|11] Ie:I MeIhcc: fcr Evc|ucIing Sc|ic Wc:Ie. Fhy:icc|/Chemicc| MeIhcc:. 3rc Ec: U.S. EnvircnmenIc|
FrcIecIicn /gency, Cffice cf Sc|ic Wc:Ie cnc Emergency Fe:pcn:e. U.S. GcvernmenI FrinIing Cffice:
Wc:hingIcn, DC. SW-84 {18).
|12] King:Icn.:H.M. cnc L8. Jc::ie. ScfeIy Guice|ine: fcr Micrcwcve Sy:Iem: in Ihe /nc|yIicc|
LcLcrcIcry. lnIrccucIicn Ic Micrcwcve /cic Deccmpc:iIicn: Ihecry cnc FrccIice: King:Icn H.M. cnc
Jc::ie, L3..Ec:.: /CS Frcfe::icnc| Feference 8cck Serie:: /mericcn Chemicc| SccieIy: Wc:hingIcn, DC.
{188)
|13] 185 /nnuc| 8cck cf /SIM SIcnccrc:. Vc|. 11.01: SIcnccrc SpecificcIicn fcr FecgenI WcIer: /SIM,
Fhi|cce|phic. F/. D113 -77 {185).
|14] lnIrccucIicn Ic Micrcwcve Scmp|e FrepcrcIicn: Ihecry cnc FrccIice: King:Icn. H.M. cnc Jc::ie.
L.8., Ec:.: /CS Frcfe::icnc| Feference 8cck :erie:: /mericcn Chemicc| SccieIy: Wc:hingIcn DC {188).
|15] King:Icn. H.M. EF/ l/G DW1-33254-01-0 Jcnucry 1- Mcrch 31, 188. CucrIer|y FepcrI.
|1] 8in:Icck. D./. Yecger. W.M. Grch:e. F .M. cnc Gc:ki||. /. Vc|iccIicn cf c MeIhcc fcr
DeIermining E|emenI: in Sc|ic Wc:Ie Ly Micrcwcve Dige:Iicn, Fe:ecrch Iricng|e ln:IiIuIe Iechnicc|
FepcrI DrcfI. FIl FrcjecI NumLer 321 U-357-24, prepcrec fcr Ihe Cffice cf Sc|ic Wc:Ie. U.S.
EnvircnmenIc| FrcIecIicn /gency, Wc:hingIcn, DC 2040 {NcvemLer, 18).


MEIHOD kEVISED 8Y:

Mcrk Mi||:cn, NlCSH/DFSE cnc F. De|cn Hu||, Fh.D., NlCSH/D88S: S341 criginc||y vc|iccIec uncer NlCSH
CcnIrccI CDC-4-74-45: ccciIicnc| :Iucie: uncer NlCSH CcnIrccI 210-7-0058.

Jcme: 8. Ferkin:. Dcvic L. Whee|er cnc KeiIh Nichc|:cn, Fh.D., DcIcChem LcLcrcIcrie:, Sc|I Lcke CiIy,
UI. prepcrec Ihe micrcwcve cige:Iicn in Ihe /ppencix.

AFFENDIX -MICkOWAVE DIGESIION FOk LEAD IN FAINI CHIFS [ANF OIHEk MAIkICES} ,

Ihi: prccecure i: cn c|IerncIive Ic Ihe prccecure pre:enIec in Ihe Scmp|e FrepcrcIicn :ecIicn cf Ihi:
meIhcc. lI prcvice: c rcpic, ccmp|eIe ccic cige:Iicn pricr Ic cnc|y:i: Ly f|cme cIcmic cL:crpIicn
{F//), hecIec grcphiIe furncce cIcmic cL:crpIicn {HGF//), cnc incucIive|y ccup|ec p|c:mc
:pecIrc:ccpy {lCF) |10].

/ppcrcIu: cnc McIeric| |11-1]

1. Micrcwcve cppcrcIu: reuiremenI:
c. Ihe micrcwcve uniI prcvice: prcgrcmmcL|e pcwer wiIh c minimum cf 574 Wcnc ccn Le
prcgrcmmec Ic wiIhin = 10 W cf Ihe reuirec pcwer .
L. Ihe micrcwcve uniI ccviIy i: ccrrc:icn re:i:IcnI c: we|| c: venIi|cIec. /|| e|ecIrcnic: cre
prcIecIec cgcin:I ccrrc:icn fcr :cfe cpercIicn.
c. Ihe :y:Iem reuire: Ief|cn FF/ cige:Iicn ve::e|: {120-mL ccpcciIy) ccpcL|e cf wiIh:Icncing
pre::ure: up Ic 7.5 = 0.7 cIm {110 = 10 p:i) cnc ccpcL|e cf ccnIrc||ec pre::ure re|ief cI
pre::ure: exceecing 7.5 = 0.7 cIm {110 = 10 p:i).
c. / rcIcIing IurnIcL|e i: emp|cyec Ic en:ure hcmcgenecu: ci:IriLuIicn cf micrcwcve
rccicIicn wiIhin Ihe uniI. Ihe :peec cf Ihe IurnIcL|e :hcu|c Le c minimum cf 3 rpm.
e. / :cfeIy ccncern re|cIe: Ic Ihe u:e cf :ec|ec ccnIciner: wiIhcuI pre::ure re|ief vc|ve: in Ihe
uniI. IempercIure i: Ihe impcrIcnI vcricL|e ccnIrc||ing Ihe reccIicn. Fre::ure i: neecec Ic
cIIcin e|e- vcIec IempercIure: LuI mu:I Le :cfe|y ccnIcinec |12].
f. Fc|ymeric vc|umeIric wcre in p|c:Iic {Ief|cn cr pc|yeIhy|ene), 50- cr 100-mL ccpcciIy. g.
Di:pc:cL|e pc|yprcpy|ene fi|Ier funne|.
h. /nc|yIicc| Lc|cnce. 300-g ccpcciIy, cnc minimum = 0.001 g.

FecgenI:

1. NiIric ccic, ccncenIrcIec, :pecIrc:ccpy grcce.
2. FecgenI WcIer. FecgenI wcIer :hc|| Le inIerference free. /|| reference: Ic wcIer in Ihe
meIhcc refer Ic recgenI wcIer IhcI meeI: Ihe /SIM Iype 2
:Icnccrc.

Frccecure

1. Cc|iLrcIicn cf Micrcwcve EuipmenI
Cc|iLrcIe micrcwcve euipmenI in ccccrccnce wiIh mcnufccIurer': in:IrucIicn:. lf
cc|iLrcIicn in:IrucIicn: cre ncI cvci|cL|e. :ee EF/ MeIhcc 3051 |11].

2. /|| cige:Iicn ve::e|: cre vc|umeIric wcre mu:I Le ccrefu||y ccic wc:hec cnc rin:ec wiIh
recgenI wcIer. /|| cige:Iicn ve::e|: :hcu|c Le c|ecnec Ly L|ecching wiIh hcI {1:1) niIric
ccic fcr c minimum cf fifIeen minuIe:, rin:ec wiIh recgenI wcIer, cnc criec in c c|ecn
envircnmenI.

3. Scmp|e Dige:Iicn

c. Icre Ihe Ief|cn FF/ cige:Iicn ve::e|.
L. Weigh cuI 0.1 g pcinI chip :cmp|e Ic Ihe necre:I 0.001 g inIc Ihe Icrec Ief|cn FF/ :cmp|e
ve::e|. WiIh |crge pcinI chip :cmp|e:, mec:ure cuI c 2 cm2 piece, weigh Ic Ihe necre:I
0.001 g, cnc ucnIiIcIive|y Ircn:fer iI Ic Ihe ve::e|.


c. /cc 5.0 = 0.1 mL ccncenIrcIec niIric ccic Ic Ihe :cmp|e ve::e| in c fume hccc. lf c
vigcrcu: reccIicn cccur:, c||cw Ihe reccIicn Ic :Icp Lefcre ccpping Ihe ve::e|. Ccp Ihe
ve::e| cnc Icrue Ihe ccp Ic 12 fI-lL {1 N-m) ccccrcing Ic Ihe mcnufccIurer': cirecIicn.
Ihe :cmp|e ve::e| mcy Le ccnnecIec Ic cn cverf|cw ve::e| u:ing Ief|cn FF/ ccnnecIing
IuLe:. F|cce Ihe ve::e|: in Ihe micrcwcve ccrrcu:e|. CcnnecI Ihe cverf|cw ve::e|: Ic Ihe
cenIer we|| cf Ihe uniI.

c. F|cce Ihe ve::e|: even|y ci:IriLuIec in Ihe IurnIcL|e cf Ihe micrcwcve uniI u:ing grcup: cf
Iwc, :ix cr 12 :cmp|e ve::e|:. /ny ve::e|: ccnIcining 5 mL cf niIric ccic fcr recgenI L|cnk
purpc:e: cre ccunIec c: :cmp|e ve::e|:. When fewer Ihcn Ihe reccmmencec numLer cf
:cmp|e: cre Ic Le cige:Iec, i.e. Ihree :cmp|e: p|u: cne L|cnk, Ihe remcining ve::e|: :hcu|c
Le fi||ec wiIh 5 mL cf niIric ccic Ic cchieve Ihe fu|| ccmp|emenI cf ve::e|:. Ihi: prcvice: cn
energy Lc|cnce :ince Ihe micrcwcve pcwer cL:crLec i: prcpcrIicnc| Ic Ihe IcIc| mc:: in
Ihe ccviIy |14]. lrrccicIe ecch grcup cf :cmp|e: Ic cchieve c IempercIure cf 180 C in five
minuIe: cI c pre::ure cf 50 p:i. CcnIinue Ic irrccicIe Ic cchieve c IempercIure cf 180 C cI
100 p:i cfIer 25 minuIe:. CcnIinue cige:Iicn fcr five minuIe:. / :cmp|e cige:Iicn prcgrcm
fcr 12 :cmp|e: i: pre:enIec in IcL|e 1.

IcL|e 1

Frcgrcm VcricL|e: fcr FcinI Chip: Scmp|e Dige:Iicn wiIh NiIric /cic

SIcge {1) {2) {3)

Fcwer 07 07 07
Fre::ure, p:i 50 100 0
Fun Iime, min. 10:00 20:00 05:00
Iime @ F. min 05:00 15:00 00:00
IempercIure 180 C 180 C 0 C
Fcn Speec 1007 1007 1007
NumLer cf Ve::e|:: 12
Liuic Vc|ume per 5 mL
Ve::e|:
Scmp|e WeighI: 0.1 g

lf Ihe cnc|y:I wi:he: Ic cige:I cIher Ihcn Iwc, :ix, cr 12 :cmp|e: cI c Iime, u:e cifferenI vc|ue: cf pcwer
c: |cng c: Ihey re:u|I in Ihe :cme Iime cnc IempercIure ccnciIicn:.

e. /I Ihe enc cf Ihe micrcwcve prcgrcm, c||cw Ihe ve::e|: Ic ccc| fcr c minimum cf five
minuIe: Lefcre remcving Ihem frcm Ihe micrcwcve uniI. lf c |c:: cf :cmp|e i: ceIecIec
{e.g. mcIeric| in cverf|cw cc||ecIicn ve::e|, |iuic cuI:ice |iner), ceIermine Ihe rec:cn fcr
Ihe |c:: {e.g. |c:: cf ve::e| :ec| inIegriIy , u:e cf c cige:Iicn Iime |cnger Ihcn 30 minuIe:, Icc
|crge c :cmp|e, cr imprcper hecIing ccnciIicn:). Cnce Ihe :curce cf Ihe |c:: hc: Leen
ccrrecIec, prepcre c new :cmp|e Leginning cI SecIicn 2. lf :ufficienI mcIeric| i: cvci|cL|e
fcr recnc|y:i:, ci|uIe remcining cige:IcIe cnc ncIe IhcI :cme :cmp|e |c:: mcy hcve
cccurec.

f. Unccp cnc venI ecch ve::e| in c fume hccc. /cc 20 mL recgenI wcIer, Ihen re:ec| ve::e|:
cnc :hcke Ic mix Ihcrcugh|y. Ircn:fer Ihe :cmp|e Ic cn ccic-c|ecnec pc|yeIhy|ene LcII|e.
lf Ihe cige:Iec :cmp|e ccnIcin: pcrIicu|cIe: which mcy c|cg neLui|izer: cr inIerfere wiIh
injecIicn cf Ihe :cmp|e inIc Ihe in:IrumenI, c||cw Ihe :cmp|e Ic :eII|e cr fi|Ier iI:


Sett||ng: /||cw Ihe :cmp|e Ic :Icnc unIi| Ihe :uperncIcnI i: c|ecr {u:uc||y, cvernighI i: :ufficienI. lf
iI cce: ncI c|ecr, fi|Ier Ihe :cmp|e.

F||ter|ng: Ihe fi|Iering cppcrcIu: mu:I Le Ihcrcugh|y prec|ecnec cnc rin:ec wiIh ci|uIe niIric
ccic. Fi|Ier Ihe :cmp|e Ihrcugh ucnIiIcIive fi|Ier pcper inIc c :eccnc ccic-c|ecnec ccnIciner .

Ihe cige:IcIe i: ncw reccy fcr cnc|y:i: fcr e|emenI: cf inIere:I u:ing Ihe cpprcpricIe meIhcc.

4. Cc|cu|cIicn:: FepcrI Ihe ccncenIrcIicn: Lc:ec cn Ihe ccIuc| weighI cf Ihe criginc| :cmp|e.

Guideline Method of Sampling and Analysis For Airborne Lead

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ANALYSIS FOR AIRBORNE LEAD

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