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PRODUCT NAME: PV ALCOHOL #17 P / #24 F / #33 SF / #31-SF / #35-SF #28-TF / #29-TF / #30-TF / #26-F / #21-F CHEMICAL NAME: Polyvinyl Alcohol PREPARATION DATE: 01-07-97 DOT-- Hazard Classification: Non-toxic Shipping Name: UN No.: Not regulated DEGREE OF HAZARD: 1. slight; 2. moderate; 3. extreme; 4. potential carcinogen, teratogen, mutagen HEALTH ( 1 ) FLAMMABILITY ( 1 ) REACTIVITY ( 0 )
II.
Material or Component % CAS No. TLV (Units) HAZARD DATA ----------------------------------------------------------------------THIS PRODUCT NON-HAZARDOUS WITHIN OSHA HAZARD COMMUNICATION STANDARD 29CFR 1910.1200 THIS PRODUCT CONTAINS NO INGREDIENTS SUBJECT TO THE REPORTING REQUIREMENTS OF SARA 313, TITLE III, SARA 312. ---------------------------------------------------------------------PEL= OSHA Permissible Exposure Limit TLV= ACGIH Threshold Limit STEL= Short Term Exposure Limit TWA= Time Weighted Average ALL MATERIALS USED IN THIS MANUFACTURE ARE TSCA REPORTED AND CANADIAN D.S.L. REGISTERED -----------------------------------------------------------------------
III. PHYSICAL DATA Boiling Point: NONE Specific Gravity (water=1): N/E Vapor Pressure: N/A % Volatiles by Vol.: < 1 Vapor Density (air=1): N/A Evaporation rate (water=1): N/A Solubility in water: Soluble in hot water. Appearance and color: White to off-white amorphous powder - odorless.
Flash Point (test method): N/A Flammable Limits in air, % by volume: Lower- N/A Upper- N/A Extinguishing Media: CO 2 - Foam - Water Spray Special Firefighting equipment: Wear a self-contained breathing unit. Unusual Fire and Explosion Hazard: NONE
V. StabilityStable _X__
REACTIVITY DATA Unstable ____ May occur ____ Will not occur _X__
Hazardous Polymerization--
Conditions and Materials to Avoid-- Oxidizing Agents. Hazardous Decomposition Products: Irritating and Toxic fumes at elevated temperatures.
VI.
SPECIAL PROTECTION
Respiratory-- Particulate or dust respirator. Eye Protection-- Wear protective glasses or face shield. Protective Gloves-- Not required under normal conditions. Ventilation-- Normal room ventilation.
VII.
Steps to be taken in case material is spilled or released-Use dry absorbent. Ventilate area. Avoid high humidity. Keep away from sewers and water systems by diking. Spill may be slippery. Waste Disposal Method-Collect dry refuse into a suitable container for disposal (use nonmetallic utensils). Incinerate or bury in accordance with Federal or local regulations.
VIII.
Indoor:
__X___
Outdoor:
_______
Normal storage. Keep containers dry. Ventilate area. Do not breathe dust. Avoid dusting conditions. Page 2. CONT. PV ALCOHOL Routes of Entry: IX. HEALTH HAZARD DATA
HAZARD - ACUTE-Eye Contact: May cause mild irritation. Skin Contact: May cause mild irritation with repeated exposure. Ingestion: May be harmful if swallowed. Avoid ingestion. Inhalation: Excessive inhalation of dust may cause mild nasal and respiratory irritations.
HAZARD - CHRONIC-Toxicity: Generally non-toxic. Exposure Limits: N/E Carcinogenic Potential: NONE
X. Eyes: Skin:
FIRST-AID RESPONSES
Flush with water for at least 15 min. See physician of irritation persists. Remove contaminated clothing. Wash skin with soap and water; repeat. See physician if irritation persists. ____ Promote vomiting; head low; prevent liquid from draining into lungs; get medical attention. ____ Do not induce vomiting; contact physician. _X__ NONE REQUIRED
Ingestion:
Inhalation:
NONE REQUIRED.
While the information and recommendations set forth herein are believed to be accurate as of the date hereof, EASTERN COLOR & CHEMICAL COMPANY makes no warranty with respect thereto and disclaims all liability from reliance thereon. BE SAFE--read for product safety information and pass it on.
Page 3.
PV #24-F Hydrolyzed Polyvinyl Alcohol SPECIFICATIONS: Appearance % Hydrolysis Viscosity cps 4% solution pH (4% solution) % Solids Molecular Weight SOLUTION PROCEDURE: Disperse PV ALCOHOL #24-F in cold or room temperature water, to desired solids, while mixing vigorously. Heat while mixing to 85-90C and hold until all resin is dissolved . A biocide should be added if solution is kept for more than 24 hours to avoid spoilage. If a defoamer is desired, add to water before resin addition. White granular powder, no odor. 86-89 40-50 6.0 1.0 95% minimum 40,000-60,000
ECCO PV ALCOHOL #33-SF Super Hydrolyzed Polyvinyl Alcohol SPECIFICATIONS: Appearance % Hydrolysis Viscosity cps 4% solution pH (4% solution) % Solids Molecular Weight SOLUTION PROCEDURE: Disperse ECCO PV ALCOHOL #33-SF in cold or room temperature water, to desired solids, while mixing vigorously. Heat while mixing to 85-90C and hold until all resin is dissolved . A biocide should be added if solution is kept for more than 24 hours to avoid spoilage. If a defoamer is desired, add to water before resin addition. White granular powder, no odor. 98.5 min. 25-35 6.5 1.0 99% minimum 85,000-145,000