
\ .
1
2
=
3/2
2
1
r
r
 

\ .
=
3/2
2r
r
 

\ .
= 2 2 : 1.
8. (a) E
1
=
1
hc
= 1.81 eV = hc =
1
2
mv
2
+ W
0
E
2
=
2
hc
=
1
2
;
2
=
1
2
1
=
1
2
686 = 343nm.
9. (c) E =
hc
or
2
1
E
E
=
1
2
E
2
= E
1
1
2
2.5
5000
1
 

\ .
= 2.5 5000 eV
10. (a) K.E = hu h
0
u =
hc
 W
0
=
34 8
7
6.6 10 3 10
5 10
 1.9 1.6 10
19
=
6.6 3
5
10
19
3.1 10
19
=(3.9  3.1)eV ~ 0.58ev
11. (c) W
0
=hc/
0
0
= hc/ W
0
=
34 8
19
6.6 10 3 10
3.1 1.6 10
=
7 0
4.0 10 4000 m A
=
12. (b) Vs . e = E w
0
Vs . e = 6 ev 2.1ev
Vs = 3.9 V but stopping potential is always negative hence Vs = 3.9V.
13. (c)
1
u = 4 10
15
Hz
2
u = 6 10
15
Hz
h
1
u = h
0
u + E
1
h
2
u = h
0
u + E
2
...(i)
3h
1
u = 3h
0
u + E
2
...(ii)
3h
1
u  h
2
u = 2h
0
u
3h
1
u 
2
u = 2
0
u
= 3 10
15
Hz
14. (a)
1
u = 5v
0
, v
1
= 8 10
6
m/s,
2
u = 2
0
u . V
2
= ?
h
1
u = h
0
u +
s
5h
0
u = h
0
u +
2
1
mv
4h
0
u =
2
1
mv
In second case,
2h
0
u = h
0
u +
1
2
2
2
mv
h
0
u =
1
2
2
2
mv
2
2
2
1
v
v
=
1
4
v
2
=
1
v
2
=
6
8 10
2
= 4 10
6
m/s
15. (c) Energy of photon,
E =
hc
=
34 8
6.62 10 3 10
198.6
= 10
27
No.of photons emitted per sec =
3
27
10
10
= 10
30
16. (b) Energy of photon emitted = hc/ ; the energy of light falling per second per unit
area of a metal surface = P/(4t r
2
)
No. of photons falling per second per unit area of metal surface =
2
P
4r
hc
=
7
2 34 8
20 4.8 10
4 3.14 2 6.6 10 3 10
= 9.64 10
17
20. (a) r
n
= n
2
r
1
n
2
=
n
1
r
r
=
10
10
2.12 10
0.53 10
= 4
n = 2
21. (b) T
1
=
1
1
2r
v
=
10
6
2 3.14 0.53 10
2.2 10
= 1.5 10
6
second
22. (b) E = E
4
 E
2
=
1 1
E E

16 4
= 2.55ev
23. (c) For
H line p = 2, n = 4
For
H line p = 2, n = 6
H
=
16
3R
,
H
=
36
8R
H
=
H
36 3R
8R 16
=
4860 27
32
= 4100A
24. (c)
0
N
N
=
n
1
2
 

\ .
=
15/5
1
2
 

\ .
=
1/3
1
2
 

\ .
=
1
8
Fraction decayed = N
0
N = N
0

0
N
8
=
7
8
N
0
25. (a) 32 days = 16 2 i.e 16 half lifes = 2
4
amount of simple left =
4
16gram
2
=
3
16 10 mg
16 16 16 16
= <1mg.
26. (c) =
h
mv
=
34
31 5
6.63 10
9.1 10 6.6 10 m/s
= 1.1 10
9
m (Here m ~ mo)
27. (a) =
12.26
V
=
12.26
60
=
12.26
7.746
= 1.582 A
28. (d) E = E
3
E
1
= 1.51 + 13.6 = 12.09eV
29. (d) I = mr
2
= m
2 4 4
0
2 2 4
n h
m e
=
2 4 4
0
2 4
n h
me
30. (d)
4 2
3 2
E  E
E  E
=
Rch Rch
+
16 4
Rch Rch
+
9 4
=
27
20
,
1
2
=
20
27
31. (c)
1
=
1
h
p
=
1
h
2mE
, E
1
=
1
2
mv
2
2
=
2
h
2mE
2
1
=
1
2
E
E
=
150
600
=
1
2
,
2
= 0.5 A
32. (d) r
2
4, r
3
9 n = 2 and n = 3
f
3
1
n
2
3
f
f
=
27
8
33. (b) u = RC
2 2
1 1

p n
(
(
= 10
7
3 10
8
1 1

4 16
(
(
=
15
9 10
16
Hz
34. (b) As e = L
dI
dt
= L
d
dt
(I
0
sin t)
e = LI
0
1
e
max
= 0.005 10 100t = 5 t .
35. (d) X
L
= L = 2t n L
= 2t 50 0.2 = 2t ohm
Z =
2 2
L
R + X =
2 2
20 + (20 ) = 65.96 t
I =
e
Z
=
220
65.96
= 3.3A
36. (b) Max. energy stored in a capacitor, E
1
=
2
Q
2C
.
When energy is stored equally between the electric and magnetic fields, then energy
in the capacitor is E
2
=
1
2
E
1
If Q is the charge on the capacitor in this
case, then E
2
=
2
Q'
2C
2
Q'
2C
=
1
2
2
Q
2C
Q =
Q
2
37. (b) Maximum power is imparted at resonance .
f
r
=
1
2 LC
C =
2 2
r
1
4 f L
=
2
1
4 3.14 3.14 (50) 2
= 10
6
F = 1 F
38. (d) e =
d
dt

=
d
dt
(6t
2
5t + 1)
= 2 6t 5 = 12t 5; at t = 0.25
e = 12 0.25 5 = 2V
I =
e
R
=
2
10
= 0.2A
39. (a) =
output power
input power
100%
=
2 2
1 1
I V
I V
100% =
90 11
5 220
100% = 90%
40. (d) At resonance Z = R I
o
=
o
e
R
41. (a) X
L
= 2t fL = 2 3.14 50 0.5= 157O
42. (b) X
L
= 2t fL =
1
2
L
L
X
X
=
1
2
f
f
X
L2
=
1 2 L
1
f X
f
=
200 10
50
= 40O
43. (a) Resistance of bulb
R =
V
I
=
2
V
IV
=
2
V
P
=
2
(200)
100
= 400O
Power consumed by bulb e.I = e
e
R
=
160 160
400
= 64W
44. (a) X
L
= 2 3.14 50 0.011 = 31.10O
Z =
2 2
L
R + X
=
4
10 + 967.2
= 10967.2 = 104.72
cos  = R/Z
cos  =
100
104.72
cos  = 0.954
Alternative Method :
The value of  is always less than 1.
The answer must be 0.954
45. (b) Power = e.1 cos  =
2
e
Z
cos  =
220 220
110
0.5
= 220W
47. (a) Z =
2 2
L C
R + (X  X )
R = 0; X
L
= X
C
Z = 0
48. (a) In series LR circuit, power factor,
cos
1
 =
R
Z
=
2 2
L
R
R + X
as X
L
= 3R
=
2 2
R
R 9R +
=
R
R 10
=
1
10
When capacitor with X
c
= R is added in series new power factor,
cos
1
 =
R
Z
=
2 2
L C
R
R + (X  X )
cos
2
 =
2 2
L C
R
R + (X  X )
=
R
R 5
cos
cos
2
1


=
1
5
.
10
1
= 2
49. (a) Here, n = 80%
E
p
I
p
= 4kW = 4000W E
p
= 100 V, E
s
= 200V
I
p
=
p p
p
E I
E
=
4000
100
= 40A
=
s s
p p
E I
E I
80
100
=
s
200I
4000
=
s
I
20
I
s
=
20 80
100
= 16A
50. (d) Magnetic field at the centre of primary coil is B = I
1
/ 2R
1
. Considering it to be
uniform , magnetic flux passing through secondary coil is
2
 = BA =
0 1
1
I
2R
2
2
(R )
Now, M =
2
1
I

=
2
0 2
1
R
2R
M
2
2
1
R
R
EDUCATIONAL TRUSTS
Junior Science College
ANDHERI / BORI VALI / DADAR / NERUL / POWAI / THANE
STD: XII MTCET EXAMINATION 2013
DATE:20/04/2013 CHEMISTRY SOLUTION
Topics : Chemical Thermodynamics, Electrochemistry and Chemical Kinetics
Solution
8. Liquid to gas, An = 1 mole, W =  AnRT, W = 1 2 500
= 1000 cal.
For 3 mole W = 3 kcal
As expansion takes place W is negative, Latent heat of
vaporization for 3 moles = 3 10 = 30 kcal.
A u = q +w, Au = 30 3 = 27 kcal.
11. C + O
2
CO
2
, An = 0, AH = Au + AnRT
AH = Au
AH = 94 kcal.
15.
( )
2(s) 2
g
I I , AH
1
= 57.3 KJ eqn (1) (11)
2(s) 2
I I (l) AH
2
= 15 . 5 KJ AH = 57.3 15.5
( ) ( )
2 2
l g
I I ,AH= ? = + 41. 8 KJ.
22. sp. conductance = obs. Conductance cell constant
=
3
1
1.15
2.5 10
= 4.6 10
4
Equivalent conductance =
4
K 1000 4.6 10 1000
Normality 0.1
=
= 4.6
27. eq. wt of Ni =
At.mass 58.71
29.35
valency 2
= =
35. Q = It = 2 30 60 = 3600 C
If liberate
c
2
= 35.5 gm
3600 C will liberate =
35.5
3600
96500
= 1.32 gm.
40. r = K[A]
n
100 r = K [10A]
n
This
n
1 1
100 10
 
=

\ .
n = 2.
42.
1
2
2 t =30 min
1
2
t = 15 min
93.75% of Reaction to be completed
1
2
4 t = 4 15 = 60 min.
46. Applying r
1
= K [G]
x
[H]
y
X = 1 y = 2
Overall order = 3
50. 2.303 Log
2 2 1
1 1 2
k T T Ea
k R T T
(
=
(
T
1
=280 K.
T
2
= 290 K,
2
1
k
k
= 2
In same way factor will change
From 17
0
C to 27
0
C will be 1.91 (B)
Exp.
No
[G] [H] Rate
1. a b R
2. 2a 2b 8r
3. 2a b 2r
EDUCATIONAL TRUSTS
Junior Science College
ANDHERI / BORI VALI / DADAR / NERUL / POWAI / THANE
STD: XII MTCET EXAMINATION 2013
DATE:20/04/2013 MATHEMATICS & STATISTICS SOLUTION
Topics : Vector,3D, line, plane
Solution :
18. use legranges identity
(axb)
2
= a
2
.b
2
(a.b)
2
a.b= 11
correct option is (b)
14. pxq = qxr
Pxq qxr = 0
Pxq+rxq +qxq = 0
(P+q+r)xq = 0
p+q+r = 0 as q is non zero
Correct option is (b)
42. Given A=(3,8,2). Let P be any point on the line
Therefore P(2r+1,4r+3,3r+2)
D.R of AP are (2r2,4r5,3r)
If AP is parallel to plane 3x+2y2z+15 = 0, then it is perpendicular to its normal
Therefore (2r2)(3) +(4r5)(2) +3r(2) = 0
6r6+8r106r = 0
Therefore r = 2
Therefore P=(5,11,8)
And AP = 4 9 36 = 7
Correct option is (b)
44. base points (1,3,2) and (0,7,7) both must satisfy correct option
Correct option is (c)