Titanium

Titanium
Titanium Ti 22

Ti
Zr scandium titanium vanadium Appearance silvery grey-white metallic

General properties Name, symbol, number Pronunciation Element category Group, period, block Standard atomic weight Electron configuration titanium, Ti, 22 /tatenim/ ty-TAY-nee-m transition metal 4, 4, d 47.867(1) [Ar] 3d2 4s2 2, 8, 10, 2

History Discovery First isolation Named by William Gregor (1791) Jns Jakob Berzelius (1825) Martin Heinrich Klaproth (1795)

Titanium

2
Physical properties Phase Density (near r.t.) Liquid density at m.p. Meltingpoint Boilingpoint Heatoffusion Heat of vaporization Molar heat capacity solid 4.506 gcm3 4.11 gcm3 1941K, 1668C, 3034F 3560K, 3287C, 5949F 14.15 kJmol1 425 kJmol1 25.060 Jmol1K1 Vapor pressure P (Pa) 1 10 100 1k 10 k 100 k

at T (K) 1982 2171 (2403) 2692 3064 3558 Atomic properties Oxidation states 4, 3, 2, 1 (amphoteric oxide) 1.54 (Pauling scale) 1st: 658.8 kJmol
1 1

[1]

Electronegativity Ionization energies (more)

2nd: 1309.8 kJmol 3rd: 2652.5 kJmol Atomic radius Covalent radius 147 pm 1608 pm Miscellanea Crystal structure

hexagonal close-packed

Magnetic ordering Electrical resistivity Thermal conductivity Thermal expansion

paramagnetic (20C) 420 nm 21.9Wm1K1 (25 C) 8.6 mm1K1

Speed of sound (thin rod) (r.t.) 5,090ms1 Young's modulus Shear modulus Bulk modulus Poisson ratio Mohs hardness Vickers hardness 116 GPa 44 GPa 110 GPa 0.32 6.0 970 MPa

Titanium

3
Brinell hardness CAS registry number 716 MPa 7440-32-6 Most stable isotopes Main article: Isotopes of titanium iso
44

NA syn

half-life DM 63 y

DE (MeV) 0.07D, 0.08D

DP
44

Ti

Sc

46 47 48 49 50

Ti 8.0% Ti 7.3% Ti 73.8% Ti 5.5% Ti 5.4%

46 47 48 49 50

Ti is stable with 24 neutrons Ti is stable with 25 neutrons Ti is stable with 26 neutrons Ti is stable with 27 neutrons Ti is stable with 28 neutrons

Titanium is a chemical element with the symbol Ti and atomic number 22. It is a lustrous transition metal with a silver color, low density and high strength. It is highly resistant to corrosion in sea water, aqua regia and chlorine. Titanium was discovered in Cornwall, Great Britain, by William Gregor in 1791 and named by Martin Heinrich Klaproth for the Titans of Greek mythology. The element occurs within a number of mineral deposits, principally rutile and ilmenite, which are widely distributed in the Earth's crust and lithosphere, and it is found in almost all living things, rocks, water bodies, and soils.[] The metal is extracted from its principal mineral ores via the Kroll process[] or the Hunter process. Its most common compound, titanium dioxide, is a popular photocatalyst and is used in the manufacture of white pigments.[] Other compounds include titanium tetrachloride (TiCl4), a component of smoke screens and catalysts; and titanium trichloride (TiCl3), which is used as a catalyst in the production of polypropylene.[] Titanium can be alloyed with iron, aluminium, vanadium, molybdenum, among other elements, to produce strong lightweight alloys for aerospace (jet engines, missiles, and spacecraft), military, industrial process (chemicals and petro-chemicals, desalination plants, pulp, and paper), automotive, agri-food, medical prostheses, orthopedic implants, dental and endodontic instruments and files, dental implants, sporting goods, jewelry, mobile phones, and other applications.[] The two most useful properties of the metal are corrosion resistance and the highest strength-to-weight ratio of any metal.[2] In its unalloyed condition, titanium is as strong as some steels, but 45% lighter.[] There are two allotropic forms[] and five naturally occurring isotopes of this element, 46Ti through 50Ti, with 48Ti being the most abundant (73.8%).[] Titanium's properties are chemically and physically similar to zirconium, as both of them have the same number of valence electrons and are in the same group in the periodic table.

Titanium

Characteristics
Physical properties
A metallic element, titanium is recognized for its high strength-to-weight ratio.[] It is a strong metal with low density that is quite ductile (especially in an oxygen-free environment),[] lustrous, and metallic-white in color.[] The relatively high melting point (more than 1,650C or 3,000F) makes it useful as a refractory metal. It is paramagnetic and has fairly low electrical and thermal conductivity.[] Commercial (99.2% pure) grades of titanium have ultimate tensile strength of about 63,000 psi (434 MPa), equal to that of common, low-grade steel alloys, but are 45% lighter. Titanium is 60% more dense than aluminium, but more than twice as strong[] as the most commonly used 6061-T6 aluminium alloy. Certain titanium alloys (e.g., Beta C) achieve tensile strengths of over 200,000 psi (1,400MPa).[3] However, titanium loses strength when heated above 430 C (806F).[] Titanium is fairly hard (although not as hard as some grades of heat-treated steel), non-magnetic and a poor conductor of heat and electricity. Machining requires precautions, as the material will soften and gall if sharp tools and proper cooling methods are not used. Like those made from steel, titanium structures have a fatigue limit which guarantees longevity in some applications.[] Titanium alloys have lower specific stiffnesses than in many other structural materials such as aluminium alloys and carbon fiber. The metal is a dimorphic allotrope whose hexagonal alpha form changes into a body-centered cubic (lattice) form at 882 C (1,620F).[] The specific heat of the alpha form increases dramatically as it is heated to this transition temperature but then falls and remains fairly constant for the form regardless of temperature.[] Similar to zirconium and hafnium, an additional omega phase exists, which is thermodynamically stable at high pressures, but is metastable at ambient pressures. This phase is usually hexagonal (ideal) or trigonal (distorted) and can be viewed as being due to a soft longitudinal acoustic phonon of the phase causing collapse of (111) planes of atoms.[4]

Chemical properties
Like aluminium and magnesium metal surfaces, titanium metal and alloy surfaces oxidize immediately when they are exposed to air. Titanium readily reacts with oxygen at 1,200 C (2,190F) in air, and at 610 C (1,130F) in pure oxygen, forming titanium dioxide.[] However, it is slow to react with water and air, as it forms a passive and protective oxide coating that protects it from further reaction.[] When it first forms, this protective layer is only 12 nm thick but continues to slowly grow; reaching a thickness of 25nm in four years.[] When exposed to nitrogen clean titanium metal is covered with a titanium nitride layer. The thin titanium dioxide and nitride layers on titanium surfaces are very hard and inert. The most noted chemical property of titanium is its excellent resistance to corrosion; it is almost as resistant as platinum, capable of withstanding attack by dilute sulfuric acid and hydrochloric acid as well as chlorine gas, chloride solutions, and most organic acids.[] However, it is soluble in concentrated acids.[5] The Pourbaix diagram in the image shows that titanium is actually thermodynamically a very reactive metal. The metal cannot be melted in open air since it burns before the melting point is reached. Melting is only possible in an inert atmosphere or in a vacuum. At 550 C (1,022F), it combines with chlorine.[] It also reacts with the other halogens and absorbs hydrogen.[] Titanium is one of the few elements that burns in pure nitrogen gas, reacting at 800 C (1,470F) to form titanium nitride, which causes embrittlement.[] Titanium powder can form an explosive suspension in air. Because clean titanium metal is highly reactive and titanium binds strongly to oxygen, nitrogen and many other gases, titanium filaments are applied in titanium sublimation pumps. Titanium sublimation pumps are inexpensive and reliable devices which are applied as the last step to create extremely low pressures in ultra-high vacuum systems.

Titanium Experiments have shown that natural titanium becomes radioactive after it is bombarded with deuterons, emitting mainly positrons and hard gamma rays.[]

Compounds
The +4 oxidation state dominates titanium chemistry,[] but compounds in the +3 oxidation state are also common.[] Because of this high oxidation state, many titanium compounds have a high degree of covalent bonding. Star sapphires and rubies get their asterism from the titanium dioxide impurities present in them.[] Titanates are compounds made with titanium dioxide. Barium titanate has piezoelectric properties, thus making it possible to use it as a transducer in the interconversion of sound and electricity.[] Esters of titanium are formed by the reaction of alcohols and titanium tetrachloride and are used to waterproof fabrics.[] Titanium nitride (TiN), having a hardness equivalent to sapphire and carborundum (9.0 on the Mohs Scale),[6] is often used to coat cutting tools, such as drill bits.[7] It also finds use as a gold-colored decorative finish, and as a barrier metal in semiconductor fabrication.[8] Titanium tetrachloride (titanium(IV) chloride, TiCl4[9]) is a colorless liquid which is used as an intermediate in the manufacture of titanium dioxide for paint.[10] It is widely used in organic chemistry as a Lewis acid, for example in the Mukaiyama aldol condensation.[11] Titanium also forms a lower chloride, titanium(III) chloride (TiCl3), which is used as a reducing agent.[12] Titanocene dichloride is an important catalyst for carbon-carbon bond formation. Titanium isopropoxide is used for Sharpless epoxidation. Other compounds include titanium bromide (used in metallurgy, superalloys, and high-temperature electrical wiring and coatings) and titanium carbide (found in high-temperature cutting tools and coatings).[]

TiN coated drill bit

Occurrence 2011 production of rutile and ilmenite[]

Country thousand % of total tonnes 1300 1160 700 574 516 500 490 357 6700 19.4 17.3 10.4 8.6 7.7 7.5 7.3 5.3 100

Australia South Africa Canada India Mozambique China Vietnam Ukraine World

Titanium is always bonded to other elements in nature. It is the ninth-most abundant element in the Earth's crust (0.63% by mass)[] and the seventh-most abundant metal. It is present in most igneous rocks and in sediments derived from them (as well as in living things and natural bodies of water).[][] Of the 801 types of igneous rocks analyzed by

Titanium the United States Geological Survey, 784 contained titanium. Its proportion in soils is approximately 0.5 to 1.5%.[] It is widely distributed and occurs primarily in the minerals anatase, brookite, ilmenite, perovskite, rutile and titanite (sphene).[] Of these minerals, only rutile and ilmenite have economic importance, yet even they are difficult to find in high concentrations. About 6.0 and 0.7 million tonnes of these minerals have been mined in 2011, respectively.[] Significant titanium-bearing ilmenite deposits exist in western Australia, Canada, China, India, Mozambique, New Zealand, Norway, Ukraine and South Africa.[] About 186,000 tonnes of titanium metal sponge were produced in 2011, mostly in China (60,000 t), Japan (56,000 t), Russia (40,000 t), United States (32,000 t) and Kazakhstan (20,700 t). Total reserves of titanium are estimated to exceed 600 million tonnes.[] Titanium is contained in meteorites and has been detected in the sun and in M-type stars;[] the coolest type of star with a surface temperature of 3,200 C (5,790F).[] Rocks brought back from the moon during the Apollo 17 mission are composed of 12.1% TiO2.[] It is also found in coal ash, plants, and even the human body.

Isotopes
Naturally occurring titanium is composed of 5 stable isotopes: 46Ti, 47Ti, 48Ti, 49Ti, and 50Ti, with 48Ti being the most abundant (73.8% natural abundance). Eleven radioisotopes have been characterized, with the most stable being 44 Ti with a half-life of 63 years, 45Ti with a half-life of 184.8 minutes, 51Ti with a half-life of 5.76 minutes, and 52Ti with a half-life of 1.7 minutes. All of the remaining radioactive isotopes have half-lives that are less than 33 seconds and the majority of these have half-lives that are less than half a second.[] The isotopes of titanium range in atomic weight from 39.99 u (40Ti) to 57.966 u (58Ti). The primary decay mode before the most abundant stable isotope, 48Ti, is electron capture and the primary mode after is beta emission. The primary decay products before 48Ti are element 21 (scandium) isotopes and the primary products after are element 23 (vanadium) isotopes.[]

History
Titanium was discovered included in a mineral in Cornwall, Great Britain, in 1791 by the clergyman and amateur geologist William Gregor, then vicar of Creed parish.[] He recognized the presence of a new element in ilmenite[] when he found black sand by a stream in the nearby parish of Manaccan and noticed the sand was attracted by a magnet.[] Analysis of the sand determined the presence of two metal oxides; iron oxide (explaining the attraction to the magnet) and 45.25% of a white metallic oxide he could not identify.[] Gregor, realizing that the unidentified oxide contained a metal that did not match the properties of any known element, reported his findings to the Royal Geological Society of Cornwall and in the German science journal Crell's Annalen.[] Around the same time, Franz-Joseph Mller von Reichenstein produced a similar Martin Heinrich Klaproth named substance, but could not identify it.[] The oxide was independently rediscovered titanium for the Titans of Greek in 1795 by Prussian chemist Martin Heinrich Klaproth in rutile from Boinik mythology. (German name of unknown place) village of Hungary (Now in Slovakia).[] Klaproth found that it contained a new element and named it for the Titans of Greek mythology.[] After hearing about Gregor's earlier discovery, he obtained a sample of manaccanite and confirmed it contained titanium. The processes required to extract titanium from its various ores are laborious and costly; it is not possible to reduce the ore in the normal manner, by heating in the presence of carbon, as that produces titanium carbide.[] Pure metallic titanium (99.9%) was first prepared in 1910 by Matthew A. Hunter at Rensselaer Polytechnic Institute by heating TiCl4 with sodium at 700800C in the Hunter process.[] Titanium metal was not used outside the laboratory until 1932 when William Justin Kroll proved that it could be produced by reducing titanium tetrachloride (TiCl4) with

Titanium calcium.[] Eight years later he refined this process by using magnesium and even sodium in what became known as the Kroll process.[] Although research continues into more efficient and cheaper processes (e.g., FFC Cambridge), the Kroll process is still used for commercial production.[][] Titanium of very high purity was made in small quantities when Anton Eduard van Arkel and Jan Hendrik de Boer discovered the iodide, or crystal bar, process in 1925, by reacting with iodine and decomposing the formed vapors over a hot filament to pure metal.[13] In the 1950s and 1960s the Soviet Union pioneered the use of titanium in military and submarine applications (Alfa Class and Mike Class)[14] as part of programs related to the Cold War.[15] Starting in the early 1950s, titanium began to be used extensively for military aviation purposes, particularly in high-performance jets, starting with aircraft such as the F100 Super Sabre and Lockheed A-12.

Titanium sponge, made by the Kroll process

In the USA, the Department of Defense realized the strategic importance of the metal[16] and supported early efforts of commercialization.[17] Throughout the period of the Cold War, titanium was considered a strategic material by the U.S. government, and a large stockpile of titanium sponge was maintained by the Defense National Stockpile Center, which was finally depleted in the 2000s.[18] According to 2006 data, the world's largest producer, Russian-based VSMPO-Avisma, was estimated to account for about 29% of the world market share.[19] As of 2009, titanium sponge metal was produced in six countries: China, Japan, Russia, Kazakhstan, USA and Ukraine (in order of output).[20] In 2006, the U.S. Defense Agency awarded $5.7 million to a two-company consortium to develop a new process for making titanium metal powder. Under heat and pressure, the powder can be used to create strong, lightweight items ranging from armor plating to components for the aerospace, transport, and chemical processing industries.[21]

Production and fabrication

The processing of titanium metal occurs in 4 major steps:[22] reduction of titanium ore into "sponge", a porous form; melting of sponge, or sponge plus a master alloy to form an ingot; primary fabrication, where an ingot is converted into general mill products such as billet, bar, plate, sheet, strip, and tube; and secondary fabrication of finished shapes from mill products. Because the metal reacts with oxygen at high temperatures it cannot be produced by reduction of its dioxide.[] Titanium metal is therefore produced commercially by the Kroll process, a complex and expensive batch process. (The relatively high market value of titanium is mainly Titanium (mineral concentrate) due to its processing, which sacrifices another expensive metal, [] magnesium. ) In the Kroll process, the oxide is first converted to chloride through carbochlorination, whereby chlorine gas is passed over red-hot rutile or ilmenite in the presence of carbon to make TiCl4. This is condensed and purified by fractional distillation and then reduced with 800C molten magnesium in an argon atmosphere.[] A more recently developed method, the FFC Cambridge process,[23][24] may eventually replace the Kroll process. This method uses titanium dioxide powder (which is a refined form of rutile) as feedstock to make the end product which is either a powder or sponge. If mixed oxide powders are used, the product is an alloy manufactured at a much lower cost than the conventional multi-step melting process. The FFC Cambridge process may render titanium a less rare and expensive material for the aerospace industry and the luxury goods market, and could be seen in many

Titanium products currently manufactured using aluminium and specialist grades of steel. Common titanium alloys are made by reduction. For example, cuprotitanium (rutile with copper added is reduced), ferrocarbon titanium (ilmenite reduced with coke in an electric furnace), and manganotitanium (rutile with manganese or manganese oxides) are reduced.[] 2 FeTiO3 + 7 Cl2 + 6 C 2 TiCl4 + 2 FeCl3 + 6 CO (900C) TiCl4 + 2 Mg 2 MgCl2 + Ti (1100C) About 50 grades of titanium and titanium alloys are designated and currently used, although only a couple of dozen are readily available commercially.[25] The ASTM International recognizes 31 Grades of titanium metal and alloys, of which Grades 1 through 4 are commercially pure (unalloyed). These four are distinguished by their varying degrees of tensile strength, as a function of oxygen content, with Grade 1 being the most ductile (lowest tensile strength with an oxygen content of 0.18%), and Grade 4 the least (highest tensile strength with an oxygen content of 0.40%).[] The remaining grades are alloys, each designed for specific purposes, be it ductility, strength, hardness, electrical resistivity, creep resistance, resistance to corrosion from specific media, or a combination thereof.[26] The grades covered by ASTM and other alloys are also produced to meet Aerospace and Military specifications (SAE-AMS, MIL-T), ISO standards, and country-specific specifications, as well as proprietary end-user specifications for aerospace, military, medical, and industrial applications.[27] In terms of fabrication, all welding of titanium must be done in an inert atmosphere of argon or helium in order to shield it from contamination with atmospheric gases such as oxygen, nitrogen, or hydrogen.[] Contamination will cause a variety of conditions, such as embrittlement, which will reduce the integrity of the assembly welds and lead to joint failure. Commercially pure flat product (sheet, plate) can be formed readily, but processing must take into account the fact that the metal has a "memory" and tends to spring back. This is especially true of certain high-strength alloys.[28][29] Titanium cannot be soldered without first pre-plating it in a metal that is solderable.[30] The metal can be machined using the same equipment and via the same processes as stainless steel.[]

Applications
Titanium is used in steel as an alloying element (ferro-titanium) to reduce grain size and as a deoxidizer, and in stainless steel to reduce carbon content.[] Titanium is often alloyed with aluminium (to refine grain size), vanadium, copper (to harden), iron, manganese, molybdenum, and with other metals.[] Applications for titanium mill products (sheet, plate, bar, wire, forgings, castings) can be found in industrial, aerospace, recreational, and emerging markets. Powdered titanium is used in pyrotechnics as a source of bright-burning particles.
A titanium cylinder, "Grade 2" quality

Titanium

Pigments, additives and coatings

About 95% of titanium ore extracted from the Earth is destined for refinement into titanium dioxide (TiO 2), an intensely white permanent pigment used in paints, paper, toothpaste, and plastics.[] It is also used in cement, in gemstones, as an optical opacifier in paper,[31] and a strengthening agent in graphite composite fishing rods and golf clubs. TiO 2 powder is chemically inert, resists fading in sunlight, and is very opaque: this allows it to impart a pure and brilliant white color to the Titanium dioxide is the most commonly used compound of titanium brown or gray chemicals that form the majority of household plastics.[] In nature, this compound is found in the minerals anatase, brookite, and rutile.[] Paint made with titanium dioxide does well in severe temperatures, and stands up to marine environments.[] Pure titanium dioxide has a very high index of refraction and an optical dispersion higher than diamond.[] In addition to being a very important pigment, titanium dioxide is also used in sunscreens due to its ability to protect skin by itself.[] Recently, titanium oxide has been put to use in air purifiers (as a filter coating), or in film used to coat windows on buildings so that when titanium oxide becomes exposed to UV light (either solar or artificial) and moisture in the air, reactive redox species like hydroxyl radicals are produced so that they can purify the air or keep window surfaces clean.[32]

Aerospace and marine

Due to their high tensile strength to density ratio,[] high corrosion resistance,[] fatigue resistance, high crack resistance,[] and ability to withstand moderately high temperatures without creeping, titanium alloys are used in aircraft, armor plating, naval ships, spacecraft, and missiles.[][] For these applications titanium alloyed with aluminium, vanadium, and other elements is used for a variety of components including critical structural parts, fire walls, landing gear, exhaust ducts (helicopters), and hydraulic systems. In fact, about two thirds of all titanium metal produced is used in aircraft engines and frames.[] The SR-71 "Blackbird" was one of the first aircraft to make extensive use of titanium within its structure, paving the way for its use in modern military and commercial aircraft. An estimated 59 metric tons (130,000 pounds) are used in the Boeing 777, 45 in the Boeing 747, 18 in the Boeing 737, 32 in the Airbus A340, 18 in the Airbus A330, and 12 in the Airbus A320. The Airbus A380 may use 77 metric tons, including about 11 tons in the engines.[33] In engine applications, titanium is used for rotors, compressor blades, hydraulic system components, and nacelles. The titanium 6AL-4V alloy accounts for almost 50% of all alloys used in aircraft applications.[34] Due to its high corrosion resistance to sea water, titanium is used to make propeller shafts and rigging and in the heat exchangers of desalination plants;[] in heater-chillers for salt water aquariums, fishing line and leader, and for divers' knives. Titanium is used to manufacture the housings and other components of ocean-deployed surveillance and monitoring devices for scientific and military use. The former Soviet Union developed techniques for making submarines largely out of titanium.[35]

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Industrial
Welded titanium pipe and process equipment (heat exchangers, tanks, process vessels, valves) are used in the chemical and petrochemical industries primarily for corrosion resistance. Specific alloys are used in downhole and nickel hydrometallurgy applications due to their high strength (e. g.: titanium Beta C alloy), corrosion resistance, or combination of both. The pulp and paper industry uses titanium in process equipment exposed to corrosive media such as sodium hypochlorite or wet chlorine gas (in the bleachery).[36] Other applications include: ultrasonic welding, wave soldering,[37] and sputtering targets.[38]

High-purity (99.999%) titanium with visible crystallites

Titanium tetrachloride (TiCl4), a colorless liquid, is important as an intermediate in the process of making TiO2 and is also used to produce the Ziegler-Natta catalyst, and is used to iridize glass and because it fumes strongly in moist air it is also used to make smoke screens.[]

Consumer and architectural

Titanium metal is used in automotive applications, particularly in automobile or motorcycle racing, where weight reduction is critical while maintaining high strength and rigidity.[39] The metal is generally too expensive to make it marketable to the general consumer market, other than high-end products, particularly for the racing/performance market. Late model Corvettes have been available with titanium exhausts.[40] Titanium is used in many sporting goods: tennis rackets, golf clubs, lacrosse stick shafts; cricket, hockey, lacrosse, and football helmet grills; and bicycle frames and components. Although not a mainstream material for bicycle production, titanium bikes have been used by race teams and adventure cyclists.[41] Titanium alloys are also used in spectacle frames.[] This results in a rather expensive, but highly durable and long lasting frame which is light in weight and causes no skin allergies. Many backpackers use titanium equipment, including cookware, eating utensils, lanterns, and tent stakes.[] Though slightly more expensive than traditional steel or aluminium alternatives, these titanium products can be significantly lighter without compromising strength. Titanium is also favored for use by farriers, since it is lighter and more durable than steel when formed into horseshoes.[] Titanium has occasionally been used in architectural applications: the 40 m (131foot) memorial to Yuri Gagarin, the first man to travel in space, in Moscow, is made of titanium for the metal's attractive color and association with rocketry.[42] The Guggenheim Museum Bilbao and the Cerritos Millennium Library were the first buildings in Europe and North America, respectively, to be sheathed in titanium panels.[] Other construction uses of titanium sheathing include the Frederic C. Hamilton Building in Denver, Colorado[43] and the 107 m (350foot) Monument to the Conquerors of Space in Moscow.[44] Because of its superior strength and light weight when compared to other metals traditionally used in firearms (steel, stainless steel, and aluminium), and advances in metalworking techniques, the use of titanium has become more widespread in the manufacture of firearms. Primary uses include pistol frames and revolver cylinders. For these same reasons, it is also used in the body of laptop computers (for example, in Apple's PowerBook line).[45] Some upmarket categories of tools made to be lightweight and corrosion-resistant, such as shovels and flashlights, are made of titanium or titanium alloys as well.

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Jewelry
Because of its durability, titanium has become more popular for designer jewelry (particularly, titanium rings).[] Its inertness makes it a good choice for those with allergies or those who will be wearing the jewelry in environments such as swimming pools. Titanium is also alloyed with gold to produce an alloy that can be marketed as 24-carat gold, as the 1% of alloyed Ti is insufficient to require a lesser mark. The resulting alloy is roughly the hardness of 14-carat gold and thus is more durable than a pure 24-carat gold item would be.[46] Titanium's durability, light weight, dent- and corrosion resistance makes it useful in the production of watch cases.[] Some artists work with titanium to produce artworks such as sculptures, decorative objects and furniture.[47] The inertness and ability to be attractively colored makes titanium a popular metal for use in body piercing.[48] Titanium may be anodized to produce various colors, which varies the thickness of the surface oxide layer and causes interference fringes.[49]

Medical
Because it is biocompatible (it is non-toxic and is not rejected by the body), titanium is used in a gamut of medical applications including surgical implements and implants, such as hip balls and sockets (joint replacement) that can stay in place for up to 20 years.[] The titanium is often alloyed with about 4% aluminium[50] or 6% Al and 4% vanadium. Titanium has the inherent ability to osseointegrate, enabling use in dental implants that can remain in place for over 30 years. This property is also useful for orthopedic implant applications.[] These benefit from titanium's lower modulus of elasticity (Young's modulus) to more closely match that of the bone that such devices are intended to repair. As a result, skeletal loads are more evenly shared between bone and implant, leading to a lower incidence of bone degradation due to stress shielding and periprosthetic bone fractures, which occur at the boundaries of orthopedic implants. However, titanium alloys' stiffness is still more than twice that of bone, so adjacent bone bears a greatly reduced load and may deteriorate.[51] Since titanium is non-ferromagnetic, patients with titanium implants can be safely examined with magnetic resonance imaging (convenient for long-term implants). Preparing titanium for implantation in the body involves subjecting it to a high-temperature plasma arc which removes the surface atoms, exposing fresh titanium that is instantly oxidized.[] Titanium is also used for the surgical instruments used in image-guided surgery, as well as wheelchairs, crutches, and any other products where high strength and low weight are desirable.

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Nuclear waste storage

Due to its extreme corrosion resistance, titanium containers have been studied for the long-term storage of nuclear waste (containers lasting over 100,000 years are possible under proper manufacturing conditions to reduce defects in the process).[52] A titanium "drip shield" could also be placed over other types of containers to further contain the waste.[53]

A titanium body piercing.

Characteristic weld beads on a handmade titanium bicycle frame.

The Guggenheim Museum Bilbao is sheathed in titanium panels.

A titanium ring.

A titanium spork useful for backpackers. About 16 grams, lighter than a steel utensil but stronger than a plastic implement.

A fracture of the eye socket was repaired by stabilizing the fractured bones with small titanium plates and screws.

Precautions
Titanium is non-toxic even in large doses and does not play any natural role inside the human body.[] An estimated quantity of 0.8 milligrams of titanium is ingested by humans each day, but most passes through without being absorbed.[] It does, however, have a tendency to bio-accumulate in tissues that contain silica. One study indicates a possible connection between titanium and yellow nail syndrome.[54] An unknown mechanism in plants may use titanium to stimulate the production of carbohydrates and encourage growth. This may explain why most plants contain about 1 part per million (ppm) of titanium, food plants have about 2 ppm, and horsetail and nettle contain up to 80 ppm.[]

Nettle contains up to 80 parts per million of titanium.

As a powder or in the form of metal shavings, titanium metal poses a significant fire hazard and, when heated in air, an explosion hazard.[55] Water and carbon dioxidebased methods to extinguish fires are ineffective on burning titanium; Class D dry powder fire fighting agents must be used instead.[]

Titanium When used in the production or handling of chlorine, care must be taken to use titanium only in locations where it will not be exposed to dry chlorine gas which can result in a titanium/chlorine fire.[56] A fire hazard exists even when titanium is used in wet chlorine due to possible unexpected drying brought about by extreme weather conditions. Titanium can catch fire when a fresh, non-oxidized surface comes in contact with liquid oxygen.[57] Such surfaces can appear when the oxidized surface is struck with a hard object, or when a mechanical strain causes the emergence of a crack. This poses the possible limitation for its use in liquid oxygen systems, such as those found in the aerospace industry.

13

References
[20] "Roskill Information Services: Global Supply of Titanium is Forecast to Increase", Titanium Metal: Market Outlook to 2015 (5th edition, 2010), October 19, 2010, http:/ / www. prnewswire. com/ news-releases/ roskill-information-services-global-supply-of-titanium-is-forecast-to-increase-105243193. html, accessed 2013-05-10. [24] The Economist magazine 16th February 2013 page 74

Bibliography
Barksdale, Jelks (1968). "Titanium". In Clifford A. Hampel (editor). The Encyclopedia of the Chemical Elements. New York: Reinhold Book Corporation. pp.732738. LCCN 68-29938 (http://lccn.loc.gov/68-29938). Emsley, John (2001). "Titanium". Nature's Building Blocks: An A-Z Guide to the Elements. Oxford, England, UK: Oxford University Press. ISBN0-19-850340-7. Flower, Harvey M. (2000). "Materials Science: A moving oxygen story". Nature 407 (6802): 305306. doi: 10.1038/35030266 (http://dx.doi.org/10.1038/35030266). PMID 11014169 (http://www.ncbi.nlm.nih. gov/pubmed/11014169). Greenwood, N. N.; Earnshaw, A. (1997). Chemistry of the Elements (2nd ed.). Oxford: Butterworth-Heinemann. ISBN0-7506-3365-4.

External links
"Titanium: Our Next Major Metal" (http://books.google.com/books?id=7iwDAAAAMBAJ&pg=RA2-PA46), Popular Science, October 1950one of first general public detailed articles on Titanium Titanium (http://www.periodicvideos.com/videos/022.htm) at The Periodic Table of Videos (University of Nottingham) A Cleaner, Cheaper Route to Titanium (http://techreview.com/read_article.aspx?id=16963&ch=nanotech) International Titanium Association (http://titanium.org) Metallurgy of Titanium and its Alloys, Cambridge University (http://www.msm.cam.ac.uk/phase-trans/2003/ titanium.movies/titanium.html) World Production of Titanium Concentrates, by Country (http://indexmundi.com/en/commodities/minerals/ titanium/titanium_table15.html) "Truth in Sparks: Titanium or Plain Ol' Steel?" (http://www.popsci.com/popsci/how20/ 85f145ef7d2f6110vgnvcm1000004eecbccdrcrd.html), Popular Science Metal of the gods (http://seekingalpha.com/article/194965-titanium-metal-of-the-gods?source=email)

Article Sources and Contributors

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Image Sources, Licenses and Contributors

file:Titan-crystal bar.JPG Source: http://en.wikipedia.org/w/index.php?title=File:Titan-crystal_bar.JPG License: Creative Commons Attribution-Sharealike 3.0 Germany Contributors: Alchemist-hp ( pse-mendelejew.de) File:Electron shell 022 Titanium - no label.svg Source: http://en.wikipedia.org/w/index.php?title=File:Electron_shell_022_Titanium_-_no_label.svg License: Creative Commons Attribution-Sharealike 2.0 Contributors: DePiep File:Hexagonal close packed.svg Source: http://en.wikipedia.org/w/index.php?title=File:Hexagonal_close_packed.svg License: Creative Commons Attribution-Sharealike 3.0 Contributors: DePiep File:Titanium nitride coating.jpg Source: http://en.wikipedia.org/w/index.php?title=File:Titanium_nitride_coating.jpg License: GNU Free Documentation License Contributors: Peter Binter Original uploader was Binter at de.wikipedia File:Martin Heinrich Klaproth.jpg Source: http://en.wikipedia.org/w/index.php?title=File:Martin_Heinrich_Klaproth.jpg License: Public Domain Contributors: Foroa, Gabor, Kresspahl, Mu, Stern, Vsk, File:TitaniumMetal jpg.jpg Source: http://en.wikipedia.org/w/index.php?title=File:TitaniumMetal_jpg.jpg License: Public Domain Contributors: Ra'ike, Rursus, Saperaud, Svdmolen File:TitaniumUSGOV.jpg Source: http://en.wikipedia.org/w/index.php?title=File:TitaniumUSGOV.jpg License: Public Domain Contributors: Beao, Ra'ike, Rursus, Saperaud, 1 anonymous edits File:Titanzylinder.jpg Source: http://en.wikipedia.org/w/index.php?title=File:Titanzylinder.jpg License: Creative Commons Attribution-Sharealike 3.0 Germany Contributors: Alchemist-hp ( pse-mendelejew.de) File:Titanium(IV) oxide.jpg Source: http://en.wikipedia.org/w/index.php?title=File:Titanium(IV)_oxide.jpg License: unknown Contributors: Original uploader was Walkerma at en.wikipedia File:Hochreines Titan (99.999) mit sichtbarer Kristallstruktur.jpg Source: http://en.wikipedia.org/w/index.php?title=File:Hochreines_Titan_(99.999)_mit_sichtbarer_Kristallstruktur.jpg License: unknown Contributors: Lotje, Martin H., Metalle-w, NatiSythen, Sreejithk2000, Trelio, 3 anonymous edits File:Titanium Piercing.JPG Source: http://en.wikipedia.org/w/index.php?title=File:Titanium_Piercing.JPG License: Creative Commons Zero Contributors: User:Kial File:Titanium welds.jpg Source: http://en.wikipedia.org/w/index.php?title=File:Titanium_welds.jpg License: Creative Commons Attribution-Sharealike 3.0,2.5,2.0,1.0 Contributors: Keanu @ no:wp File:GuggenheimBilbao.jpg Source: http://en.wikipedia.org/w/index.php?title=File:GuggenheimBilbao.jpg License: GNU Free Documentation License Contributors: E. Goergen aka en:User:VisiGrad File:Titanium-Rings-plain.jpg Source: http://en.wikipedia.org/w/index.php?title=File:Titanium-Rings-plain.jpg License: Public Domain Contributors: Eric Pless

Image Sources, Licenses and Contributors

File:Titanium-spork 1.jpg Source: http://en.wikipedia.org/w/index.php?title=File:Titanium-spork_1.jpg License: Creative Commons Attribution-Sharealike 3.0 Contributors: Wtshymanski (talk). Original uploader was Wtshymanski at en.wikipedia File:Lateralcephplated.JPG Source: http://en.wikipedia.org/w/index.php?title=File:Lateralcephplated.JPG License: Public Domain Contributors: Original uploader was DRosenbach at en.wikipedia File:Kopiva.JPG Source: http://en.wikipedia.org/w/index.php?title=File:Kopiva.JPG License: Creative Commons Attribution-ShareAlike 3.0 Unported Contributors: Pokrajac

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