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CHM130 (Analytical Chemistry)

Prof. Abi Rodelas-Angelia Consultation schedule: T-F 1:00-3:30

CHM021 CHEMISTRY 1
http://www.improve-education.org

You are expected to

COME TO CLASS on TIME.

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The course that deals with the theory and practice of gravimetric and volumetric methods of analysis, including an introduction to instrumental methods of analysis, and the relevance of analytical chemistry in solving chemical problems in todays world.

eliminate all DISTRACTIONS. Participate in online and face-to-face activities take down notes (especially solutions to problems)! demonstrate proficiency in solving mathematical problems demonstrate competency in both oral and written

communications
read journal articles answer quizzes and exams independently. submit required documents, seat works and assignments ON

TIME.
present official excuse slips during ABSENCES.

Grading system
CLASS STANDING Minor quizzes Learning Tasks* Long Examinations FINAL EXAMINATION 40% 60% 10% 30%
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Tasks / Requirements
Course Syllabus Journal article / discussion Other handouts, presentations Problem sets Seat works /Assignments Exams Quizzes

20%

AVERAGE (%) FINAL GRADE

Above 91.51 87.01 82.51 78.01 73.51 69.01 64.51 60.00 Below 96.00 96.00 91.50 87.00 82.50 78.00 73.50 69.00 64.50 60.00 1.00 1.25 1.50 1.75 2.00 2.25 2.50 2.75 3.00 5.00

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The main thing to teach (in all subjects but especially in the sciences) is a sense of wonder.

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Course portfolio
All exams, quizzes, assignments, seatwork, notes and other requirements for the course are to be compiled by the students as part of their portfolio. This must be made available for inspection before the end of the term Textbook
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Other requirements

Information data sheet (with picture) Join e-MCL CHM130/Create an edmodo account

CHM130 TOPICS
Data Manipulations and Gravimetry
(www.ru.nl)

CHM130 OUTLINE
Week 1 2 3 4 CHM130 Course Introduction and Policies Making decisions with data Chemical Activity Gravimetry Acid Base reactions Buffers First Exam (1st Week of July) Titrimetry Applications of neutralization titration Complexometric Titration Applications of EDTA titration Second Exam (4th week of July) Precipitation Titration Electrochemical Analysis Redox Titration Spectrochemical Methods Third Long (3rd week of August) Exam 3 Discussion / Portfolio Final Exam

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6 7 8 9 10 11 12

Potentiometry and Redox

Spectrochemical and Instrumental Methods
www.indiana.edu

Introduction to Chemical Analysis

Chemical analysis includes any aspect of the chemical characterization of a sample material. Analytical Chemistry? Science of Chemical Measurements

CHAPTER 1 An Overview of Analytical Chemistry

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Acid-Base, Complexometric Tirations and Precipitimetry

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Hage, D.S. and J.D. Carr (2011). Analytical Chemistry and Quantitative Analysis. Pearson Education, Inc.

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ASSN 1. Journal Articles

Use of analytical chemistry in various fields of science Gist of the paper Techniques used Impact of Analytical Chemistry in the study Online submission on e-MCL (doc file)

Areas of Chemical Analysis and Questions They Answer

Quantitation:
How much of substance X is in the sample?
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Detection:
Does the sample contain substance X?

Identification:
What is the identity of the substance in the sample?

Separation:
How can the species of interest be separated from the sample matrix for better quantitation and identification?

The Original CSI?

From A Study in Scarlet by Sir Arthur Conan Doyle (1887), when Sherlock Holmes first meets Dr. Watson Hage and Carr, 2011

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At the sound of our steps he glanced around and sprang to his feet with a cry of pleasure. Ive found it! Ive found it! he shouted to my companion, running toward us with a test-tube in his hand. I have found a reagent which is precipitated by hemoglobin and nothing else.

Figure 1.4 Hage and Carr, 2011

How Many Fs Appear in the Sentence Below? Observe

carefully Watson, there are six.

Statistics and data analysis

FINISHED FILES ARE THE RESULT OF VERY CAREFUL PREPARATION AND YEARS OF SCIENTIFIC STUDY.

Hage and Carr, 2011

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Quality and safety

Animal and plant research

History and Forensics

Monitoring mercaptan levels in LPG

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http://www.sciencedaily.com/releases/2012/03/12 0301103802.htm

Instrumentation

Medicine

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Divisions of A-Chem
Analytical Chemistry: A term noted in an 1821 textbook by C.H. Pfaff (concepts go back to ancient times1300 BC Babylonian)
classical versus instrumental see page 7
GRAVIMETRIC TITRATIONS SPECTROSCOPIC SEPARATIONS OTHERS Hage and Carr, 2011 Hage and Carr, 2011

ELECTROCHEMICAL

Making measurements is critical for quantitative analysis.

Standards of length were once represented by the distance between two marks on a solid metal bar. Copies of these standards were displayed in public places so that people could check the accuracy of the rules they were using. In 1588, Elizabeth I issued a new standard yard that remained the legal British yard for over 300 years. Every measurement involves three components: Object to be measured Device used to make the measurement Comparison to a known standard This means that there will be an error associated with EVERY measurement! In AChem this is explained and reported.
Hage and Carr, 2011

General Terms: A-Chem Talk

Sample-Related Terms
SAMPLE representative of the tested material MATRIX all substances in the sample ANALYTE specific substance we measure MAJOR: >1% MINOR: 0.01% to 1% TRACE: below 0.01%
Hage and Carr, 2011

Method-Related Terms
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ANALYTICAL TECHNIQUE an approach to the assay which involves - determining what question is being asked - using an appropriate sample - sample preparation - gathering measurements - reporting results

Introduction to Analytical Chemistry

1. Definition: ANALYTICAL CHEMISTRY: The Science of Chemical Measurements Types of Questions Asked in Analytical Chemistry a) What is in the sample? (qualitative analysis) b) How much is in the sample? (quantitative analysis) c) Chemical Identification (unknown chemical in sample) d) Structural Analysis (mass, composition, structure of analyte) e) Property Characterization (chem/physical properties of analyte) f) Spatial Analysis (distribution of analyte through sample) g) Time-Dependent (change of analyte or property over time)

2.

3 Techniques used in Analytical Chemistry: a) Classical (Wet Chemical Methods): titrations, colorforming reactions, precipitations, etc. b) Instrumental Methods: spectrometry, chromatography, etc. Hage and Carr, 2011

Over-all
CHEM IS TRY!!!