No 1

Procedure Solubility Test tube 1 : 0,5 mL ethanol Test tube 2 : 0,5 mL n-buthyl alcohol Test tube3 : 0,5 mL siclohexanol Test tube 4 : 0,5 mL ethylen-glycol Test tube 5 : 0,5 mL phenol

Result Before: ethanol is colourless n-buthyl alcohol is colourless siclohexanol is colourless ethylen-glycol is colourless phenol is orange after:

hypothesis

Conclution

The solubility priority: Ethylen Glycol> ethanol + H2O(l) > n-Buthyl alcohol > CH3CH2OH(aq) syclohexanol > fenol tube 2 : C4H9OH(aq) + ethylen glycol more soluble in water because H2O(l) C4H9OH(aq) ethanol is dissolved in water with tube 3 : C6H11OH(aq) + it has 2 hydroxyls and has short carbonil chain

tube 1 : CH3CH2OH(aq)

Put in test tube 1-5 Added with 2mL aquadest in each test tube Shaked Observed
Result

solubility (+++) and the solution H O(l) C H OH(aq) 2 6 11 colour is colourless n-buthyl alcohol is dissolved in tube 4 : HOC2H4OH(aq) water with solubility (++) and the + H2O(l) colour of solution is colourless HOC2H4OH(aq) siclohexanol is dissolved in water tube 5 : C H OH(aq) + 6 5 with solubility is (+) and the H2O(l) C6H5OH(aq) solution colour is colourless ethylen-glycol is colourless and dissolved in water with solubility (++++) phenol is in soluble solution among other those solution tested and the colour is white turbid and there is white precipitate

N o 2

Procedure
Test tube 1 : 0,5 mL n-buthyl alcohol Test tube 2 : 0,5 mL syclohexlnol Test tube 3 : 0,5 mL fenol Tabung 4 : 0,5 g naftol Added with 5 mL NaOH 10% Shaked Observed

Result Before:

Hypothesis

Conclution

Result

The priority of alcohol Test tube 1 : and fenol to react with NaOH is colourlessnol C4H9OH(aq) + NaOH(aq) alkaly are: n-Buthyl alcohol is Test tube 2 : 1. Fenol colourless C6H11OH(aq) NaOH(aq) 2. Naftol fenol is orange C6H11ONa(aq) + H2O 3. N-buthyl syclohexanol is colourless Test tube 3 : alcohol naftol is colourless C6H5OH(aq) + NaOH(aq) 4. Siclohexanol After: C6H5ONa(aq) +H2O(aq) The acidic of alcohol is n-Buthyl alcohol+ NaOH: Test tube 4 : lower than fenol so not react but form two layer the C10H7OH(aq) + NaOH(aq) alcohol cannot react with upper layer is turbid and the lower NaOH strong base C10H7ONa(S) + H2O(l)

Syclohexanol + NaOH:

layer is colourless, time needed is 17.88 s

Fenol +NaOH : Greenish brown solution and time needed to react is 3,02 s Naftol +NaOH: Brown solution wi th time to react is 4,63 s

Not react and form two layer the upper layer is turbid and the lower layer is colourless time needed to react is 18,85 S

N o 3

Procedure
Test tube 1 : 2 mL ethanol Test tube 2 : 2 mL 1-propanol Test tube 3 : 2 mL 2-propanol

Result Before: Na(s) = silver metal PP indicator is colourless

Hypothesis

Conclution All alcohol group thet react with Na(s) produce gas H2 The fastest solution that react with Alkaly metal is primer alcohol

1. Ethanol= colourless 2. 1-propanol= colourless 3. 2-propanol= colourless

After:

Tube 1 : C2H5OH(aq)+Na(s)C2H5ONa(a q) + H2(g) Tube 2 : HOCH2CH2CH3(aq)+Na(s) NaOCH2CH2CH3(aq) + H2(g)

Put sodium metal litle ammount Observed Added 2 drops of indicator PP Observed

Result

1. Ethanol+Na+PP The priority of rectivity Purpke solutio(+)n and the Tube 3 : is : CH CHOHCH CH (aq)+ Na(s) 3 2 3 solution is hot and there is Ethanol CH3CHONaCH2CH3(aq) + H2(g) bubles, time needed to react 1-propanol is 14,44 s 2-propanol 2. 1-Propanol+Na+PP Purple solution(++), the solution is hot and the is bubles. Time to react is 20,45 s 3. 2-Propanol+Na+PP Purple solution (++), there is buble and the time needed to react is 47,16 s

N o 4

Procedure

Result

Hypothesis

Coclution

2 mL reagent lucas

Before : Lecas reagent is colourless

C4H9OH(aq) + HCl(aq) CH3CHOHCH2CH3 + HCl CH3CHOClCH2CH3 + H2O

1butha nol

2butha nol

sychlo hexan ol

Tetriary buthyl alcohol

1-buthanol = colourless 2-buthanol=colourless Sychlohexanol=colourless Tetriary buthyl alcohol= colourless

After : Lucas reagent+1-buthanol= colorless

C6H11OH + HCl C6H11OCl + H2O

Shaked Note the time until the solution turbid or separated into 2 layers Noted the resut

Time to react (x) Lucas reagent+2-buthanol= colourles (CH3)3COH + HCl (CH3)3CCl +H2O Time to react (x) Lucas reagent + Sychlohexanol = Colorless, time to react (x) Lucas reagent+ tert-buthyl alcohol= colourless

result

N o 5

Procedure
0,1 g fenol Added with aquadest 2 ml Added with bromine water Shaked untill yellow colour disappear Result

Result Before : Fenol= orange Brome= yellow H2O = colourless After : Fenol+H2O+Bromine water = yellow solution

Hypothesis
C6H5OH + Br2 C6H2OHBr3

Conclution Reaction of fenol and bromine water produce 2,4,6-tribromo fenol that difficult to dissolved in water. And the yellow solution occure is Brom

6
1-2 drops of fenol 1-2 drops of resoisinol
1-2 drops of 2propanol

Poured into test tube Dilute with some water Added with 1-2 drops of iron (III) chloride Shaked Notetd the result

Before: FeCl3 :yellow H2O : colourless 1.Fenol: orange 2.resorsinol : brown 3. 2-propanol: colourless After

FeCl3 will form a complex compound which will produce different colour if react with hydroxyls

result

Fenol+H2O+FeCl3= purple solution Resorsinol +H2O+ FeCl3= colourless solution then become clear yellow 2propanol+H2O+FeCl3=Clea r yellow

FeCl3 will only react with fenol and resorsinol because they have OH that reactive 2-propanol not react with FeCl3 because it less reactive