,2006 ,14 ( 1) :6670

SCIENCE & TECHNOLO GY IN CHEM ICAL INDUSTR Y

MTO

( , 100011)

: ( Met hanol To Olefin ,M TO)

( FCC) ,
,

, ,
: ; FCC ;
: TQ 221. 21 + 1 ; TQ 221. 21 + 2 : A : 100820511 (2006) 0120066205

1. 1. 1 Mo bil

, ,

Mobil ZSM25 ,

, 1 t ,

1984 9 ,

100 / d ,

, , ,

,
,

, ,

( Met hanol To Olefin ,M TO)

60 % ,

2 ,

M TO

1. 1. 2 BASF

80 % ,/

BASF ,1980

30 t/ d

300 450 , 0. 1 0. 5

[ 1 ,2 ]

1 MTO
1. 1

M Pa , , C2

C4 50 %60 % ,
1. 1. 3 UOP
UOP M TO2100 ,M TO2
100 SAPO234

( Mobil)
(BASF)
( Exxon)

SAPO234 M TO2

( UOP)
( Norsk Hydro )

100 , 20 80 U nion

M TO ,

Carbide , Si
Al

M TO
:2005210225
: ( 1969 - ) , , ,
,

P
O

,
,

SPAO234
,

. M TO

67

,M TO2100

SAPO234

2. 1. 3

, H YDRO

C4 ,
m ( ) m ( ) =

UOP ,

0. 75 1. 5 , +

, , ,

( 80 % ) ,

, ,

99. 6 % ,

, ,

1. 2

, ,

20 80 ,
M TO ,

; , ,
0. 07 0. 3 M Pa , m ( ) m (

) = 11. 5 ; ,

M TO , UOP

2 ,

, ,

, 20 90
( TEA) ( D EA) TEA (

10 ,

D EA) ( TEAO H)

M TO DO123

10

2. 2

DO123

2 MTO
2. 1 Norsk Hydro
2. 1. 1

[3 ]

2005 3

M TO
, M TO
, M TO

Norsk Hydro 1995 6 UOP

2005

0. 75 t/ d M TO

, 90 d ,

90 d 450 2

, ,
, ,

99. 6 % ,

3 MTO FCC
3. 1 MTO
M TO Mobil 20

80 ,UOP Hydro 1992

2. 1. 2

M TO ,

:
750 kg/ d ( 1 000 kg/ d) ,

SAPO234

460 , 0. 105 MPa , 600 ,

, ,

0. 108 MPa ,

SAPO234 M TO


68

M TO2100

14

DO123

20 80
M TO 1993 ZSM2

3. 2 MTO

5 , 1 t/ d M TO

M TO :

,20 90

, , , ,

SD TO SD TO

, ,

M TO ,2

, M TO

3. 2. 1
M TO 1

1 MTO

3. 2. 2

,M TO 2 :
2CH3 O H

C2 H4 + 2 H2 O

;
( 5) ,

97 % ,

H = - 11. 72 kJ / mol

3CH3 O H

3. 3 MTO FCC

C3 H6 + 3 H2 O

H = - 30. 98 kJ / mol
3. 2. 3 UOP/ HYDRO MTO
(1) ,

3. 3. 1
M TO
FCC , M TO FCC

;
( 2) ;
( 3)

( 0. 751. 5) , +
( 80 %) ;

, , M TO

(4) AA

1 , M TO FCC
, FCC
, M TO

. M TO

69

1 MTO FCC

FCC

M TO

FCC

M TO

/
/ MPa

/m

480550
0. 10. 3
( )
200

400500
0. 10. 3
( )
2833
( )
/
23

650 760
0. 10. 3

600 700
0. 10. 3

30

30

SAPO234
FCC

/
160

70

40100

160

M TO FCC
,
FCC ;
, M TO ,
M TO , M TO
, ,
100 %
UOP M TO ,
M TO , M TO
, ,
, FCC

M TO FCC ,
M TO , FCC
,
FCC ,
M TO
3. 3. 2
M TO FCC 2
2 MTO FCC

M TO

FCC

( )

( )

C4

C5

3. 3. 3
SAPO234

, ,
M TO FCC ,

28

28

, ,
,
,
,

FCC ,
M TO
, ,

4 MTO
4. 1

M TO
UOP ,M TO
,
, UOP
7 / t
, M TO ,
UOP 20 % [ 4 ]

M TO ,
UOP
,
1. 6 t/ a
M TO ,

UOP ,
M TO
4. 2
M TO + ,
C4
C5

,
(
)
( ) ,


70

5
(1) FCC ,

M TO ,
, FCC

FCC ,
,
( 2)
M TO
, ,
,
2 : ,
,
,
;
, ,

( 3)
M TO
, ,
, M TO
,
, M TO
,
,
70100 t/ d ,
2 (


,2 ,
)
,

14

6
( 1) UOP M TO
, : UOP
, FCC , FCC
, M TO

FCC , M TO
, ,

,
,
,
,
FCC
(2) M TO
;
,

( 3) 30 t/ a ,
,

,
( 4) UOP
, ,
50 t/ a
[ ]
[1 ] . [ J ] . ,
2004 ,30 (4) :57.
[ 2 ] , . [ J ] . ,
2005 ,33 (1) :15.
[ 3 ] Chen J Q ,Bozzano A , Glover B ,Fuglerud T ,et al. Recent ad2
vancements in et hylene and propylene production using t he
UOP/ Hydro M TO process[J ] . Catalysis Today ,2005 ,106 (1

4) :103107.
[ 4 ] , , . ( M TO)

[J ] . ,2005 ,33 ( 5) : 6
11.

The feasibil ity analysis on MTO technology commercial ization

TON G J un2peng
( Chi na S henhua Coal L iquef action Corporation , Beiji ng 100011 , Chi na )

Abstract : The feasibility of commercializing t he M TO technology was analyzed in t his work. The reliability
of t he M TO technology was exhibited f rom t he aspect s of process , catalyst selection and ot her technical in2
dexes via being compared to t he t raditional FCC technology ; The riskes related to catalyst consumption and
product dist ribution , which may arise during t he indust ry scale2up process , were discussed ; Finally , t he
corrsponding resolutions were brought out to avoid such risks.
Key words : Met hand to olefin ( M TO) ; FCC ;Analysis