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MITTAL SIR
Maximum Marks : 75
Roll No. ____________________
SECTION I (Total Marks : 75) Single Correct Answer Type(+3/-1) This section contains 25 multiple choice questions. Each question has 4 choices (a), (b), (c) and (d) for its answer, out of which ONLY ONE is correct. 1. Relation between COOH OH CH2OH CH3 is (a) Enantiomer 2.
N H H
(b) Diasteriomer
NH
2
&
N H
(I) (II) The most acidic among these (a) i (b) ii 3. Most acidic among these OH OH (a) NO2 (b) Cl
COOH
Cl
4. Which will give CO2 on heating (a) Malic acid (b) Fumaric acid
SHAKUNTALAM 2013
P , P is
(a)
C O
(b)
COOH
(c)
C O
C=O
O
(d)
COOH
6. Among CH CH, CH3CH2OH, H2O & CH2 = CH2 which has lowest pKa (a) CH CH (b) CH3CH2OH (c) H2O (d) CH2 = CH2 7. Which has highest boiling point (a) CH3CH2CH2CH2CH3 (c) CH3COOH (b) CH3CH2 O CH2 CH3 (d) CH2 CH CH2 OH OH OH CH3 C2H5 (d) All have same value H H
8. Which has highest boiling point CH3 CH3 H H H H H (a) (b) (c) CH3 CH3 H CH3 H H CH3
9. The bad smelling substance formed by the action of alcoholic caustic potash on chloroform and aniline is (a) nitrobenzene (b) phenyl isocyanide (c) phenyl cyanide (d) phenyl isocynate 10. In the following raction
+ OH N
CH3 CH3
(b)
N(CH3)2
(c)
N(CH3)2
(d)
Br2/CH3COOH
H+/H2O X
(a)
(b)
Br NH2
(c)
(d)
COCH3 NH2
(b) NH3 > RNH2 > HS > I (d) HS > RNH2 > NH3 > I
SHAKUNTALAM 2013
MITTAL SIR
CH3CH2CH2NH2, (b) Ni/H2 X is (c) LiAlH4 (c) 3 amine (d) Zn (d) quaternary salt
16. Regular use of the following fertilizers increasing the acidity of soil?
(b) Potassium nitrate (d) Superphosphate of lime. (c) CH3NO2 (d) CH2
17. When methyl amine is treated with HNO2 the main product formed is : 18. Which of the following has lowest boiling point
(a) CH3CH2CH2NH2 (b) CH3 CH CH3
NH2
19.
OH
Zn canc HNO3 conc HNO3 (NH4)2S NaNO2 + HCl H2O
A
duist H2SO4
B
H2SO4
Compound F is : (a) OH
OH
(b) OH
OH
(c) OH
OH
(d) NO2
OH
20.
A
NaNO2,HCl
HBF4
B
NH2
Compound A is : (a)
NO2
NO2
(b)
NO2
(c)
OH
(d)
22. Which of the following compound will dissolve in an alkali solution after it has
undergone reaction with Hinsberg reagent? (a) (C2H5)2NH (b) CH3 N C6H5
CH3 (c) CH3NH2 (d) C6H5NHC6H5
25. The correct sequence for the complex formation of aliphatic amines with B(CH3)3 is
(a) (CH3)2NH > CH3NH2 > NH3 > (CH3)3N (c) (CH3)2NH > NH3 > CH3NH2 > (CH3)3N (b) (CH3)3N > (CH3)2NH > CH3NH2 > NH3 (d) CH3NH2 > (CH3)2NH > (CH3)3N > NH3.
SHAKUNTALAM 2013
SHAKUNTALAM
MITTAL SIR
ANSWER SHEET
SECTION I Straight Objective type (+3/-1) 1. 2. 3. 4. 5. a a a a a b b b b b c c c c c d d d d d 6. 7. 8. 9. 10. a a a a a b b b b b c c c c c d d d d d SECTION - II Multiple Choice type (+4/0) 11. 12. 13. 14. a a a a b b b b c c c c d d d d
SHAKUNTALAM 2013
SHAKUNTALAM 5
MITTAL SIR
11th /Test-