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P1-13-3
'Wflf: 3
Time : .3 Hours

PAPER-1
cooe0
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A
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PART I : PHYSICS
SECTION -1 :(Only One option correct Type)
1 : (a,CI(if w<61'<)
This section contains 10 multiple choice questions. Each question has four choices (A),
(8}, (C) and (D) out of which ONLY ONE is correct.
WJi -q 10 t I -q -:qT{ (A), (B), (C) 3ftx (D)%,

1. A particle of mass m is projected from the ground with an initial speed u
0
at an angle
a with the horizontal. At the highest point of its traJectory, it makes a completely
inelastic collision with another identical particle, which was thrown vertically upward
from the ground with the same initial speed u
0
The angle that the composite system
makes with the horizontal iml')1ediately after the collision is
(A) :

(C) ; -a
*3
(D) 2
m s;Cll'il'i "$" cpuf q;)' TTfa u
0
a-<mur tR fcnm \1ffilT
1 w cpur \i'6'qC1'"f tR -qqr m "$" <POl
CfR(fT \itT fcn l) m 1@r Uo
TJ<n I P!4>1ll d(tf)lcl 6l1G Cf>TuT 611JqJII :
1!
1r
(A) 4
(D) 2
Space for Rough Work l6'1'
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2.
PHYSICS
The image of an object, formed by a plano-convex lens at a distance of 8 m behind
the lens. is real and is one-third the size of the object. The wavelength of light inside
2 .
the lens is 3 times the wavelength in free space. The radius of the curved surface
of the lens is
I
(A) 1 m (B) 2m .(_C,'j 3m (D) 6 m
fl C'1 cffr cH td fcl CfJ Q Rl "$ 8 m tft9 -g- viT fcn CffiJ -ij)
3ITCJ)ff cnT i I cffr q5T 11 f.Tclli:r ctl d 11
:fiT t 1 Bfl 1hcf)l1 crn>CIT i:
(A) 1m (B) 2m (C) 3m (D) 6 m
3. The diameter of a cylinder is measured using a Vernier callipers with no zero error. It
is found that the zero of the Vernier scale lies between 5.10 em and 5.15 em of the
main scale. The Vernier scale has 50 divisions equivalent to 2.45 em. The 24th
division of the Vernier scale exactly coincides with one of the main scale divisions .
The diameter of the cylinder is
(A) 5.112 em (B) 5.124 em 5.136 em (D) 5.148 em
*3
'PI Clffi1 l=f"T"CA -ij) we q Pi W< C)J R;i q x4 cnT \34 <Ill!
i I qrll1'< tP1A cnT tmA 5.10 em otR 5.15 em -ij)
WTr vm=IT i I qr:)l1'< tP1R 50 '+fTlT 2.45 em "$ E I
cpJ if'l4)flq1 (24th) 'lWT tP1R 'qT1T -xr t 1 cpf
Clffi1 % :
(A) 5.112 em (B) 5.124 em (C) 5.136 em
Space for Rough Work
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(D) 5.148 em
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4.
*3
PHYSICS
The work done on a particle of mass m by a force, K[ x i + Y }]
(x2 + l )'2 (x2 + l)J/2
(K being a constant of appropriate dimensions), when the particle is taken from the
point (a, 0) to the point (0, a) along a circular path of radius a about the origin in the
x-y plane is
'
I
2Kn
Kn
'\ {/J.J'
(B)
'
. '
a
a . ..
I ."\
. ' l
Kn
--.-.....
... )
(C)
2a
{D) 0
K[( x )'2 [ + 2 Y 2 312 ;] (K fctlTI q;r m
x
2
+ / (x + Y)
q;ur <ffl' (a, o) (0, a) (fq) a '!R B
\ifRIT t fGHiCf>l R x-y q;r t I 6fR IDn fclRrr 11m <PT<f t :
(A)
(C)
2Kn
a
Kn
2a
Kn
(8)
a
(D) 0
Space for Rough Work
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PHYSICS
5. One end of a horizontal thick copper wire of length 2L and radius 2R is welded to an
end of another horizontal thin copper wire of length L and radius R. When the
arrangement is stretched by applying forces at two ends, the ratio of the elongation in
the thin wire to that in the thick wire is
1/
(A) 0.25 (B) 0.50 (0) 2.00 (D) 4.00
2L Cf 2R "$ -.nt CfR "$ -qq> fut q;) L Cf R f?rvm
qffi -qcp &NT lTm t l "$ GFn ftm
tR CfA1 \1ITffi t I q 111Z ";{ CPT -g-:
(A) 0.25 (B) 0.50 (C) 2.00 (D) 4.09
6. A ray of light travelling in the direction .!.(i +J3J) is incident on a plane mirror. After
2
*3
reflection, it travels along the direction .!.(i -J3J). The angle of incidence is
/ 2
Glfur tR 3li4RIC1 "QCt>ffi <f>'T WTf1fi .!.(i +J3J) I 4'1Uqd1
2
6ITG WTflfi .!. ( 1 f3;) m vmft t 1 cpy 3lltKR cmur t :
2
Space for Rough Work
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PHYSICS
7. Two rectangular blocks, having identical dimensions, can be arranged either in
8.
*3
configuration .I or in configuration n as shown in the figure. One of the blocks has
thermal conductivity K and the other 2K. The temperature difference between the
ends aiong the x-axis is the same in both the configurations. It takes 9 s to transport
a certain amount of heat from the hot end to the cold end in the configuration I. The
time to transport the same amount of heat-in the configuration n is
Gl tPi'{i)q) 3illH11<PI'< lJCCPT em ciT I 3tff II -q
11m t I lJCCPT qft 'qJ(1Cf>(11 K q 2K t I GRT qT;;f
tffl1 1R "W111R em 3RN m t 1 m 1 if. \JlSlT q,'T PI C1 TRl1
tm 9 s I II if. m *t

'.)
Configuration I
I

II
. '.

,
1

2K
, '
_______ -+/ ________

K

K
2K
(B) 3.0 s C) 4.5 s
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(D) 6.0 s
A pulse of light of duration 100 ns is absorbed completely by a small object initially at
rest. Power of the pulse is 30 m Wand the speed of light is 3 x 10
8
ms-
1
. The final
momentum of the object is
(A) / 0.3 x I0-
17
kg ms-
1
(B) 1.0 x I0-
17
kg ms-
1
{C)/ 3.0 x 10-
17
kg ms-
1
(D) 9.0 x I0-
17
kg ms-
1
Cffij, vfr fcmll ll t WPM q,'T 100 ns q,'T
t I q,'T 30 mW t Cf Wl>m ctl llfa
3 x 10
8
ms-
1
t I cpr t :
(A) 0.3 x I0-
17
kg ms-
1
(C) 3.0 X 1 o-
17
kg ms-
1
(B) 1.0 x I0-
17
kg ms-
1
(D) 9.0 x to-11 kg ms-1
Space for Rough Work 1 . t ,
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PHYSICS
9. In the Young's double slit experiment using a monochromatic light of wavelength A,
the path difference (in terms of an integer n) corresponding to any point having half
the peak intensity is
(A) (2n+l)A . .(_" (2n+l)A (C) (2n+l)A (D)
. 2 . 4 8 16
fG-fu>rc mWl A .mT Cf>T VfffiT t I
Cf>T lN "Q'CPm cCr -arnm fmR cfurcn qft 3Wfi t. t n
qG1 Tf) :
A
(A) (2n + 1}-
2
A
(B) (2n+l}-7
4
A
(C) (2n+ 1)-
8
A
(D) {2n+l)-
16
10. Two _non-reactive monoatomic ideal gases have their atomic masses in the ratio
2 : 3. The ratio of their partial pressures, when enclosed in a vessel kept at a
constant temperature, is 4 : 3. The ratio of their densities is
/
*3
/
(A) 1 : 4 (B) 1 : 2 iC) 6 : 9 (D) 8: 9
m -qcJ>-4'<Jilujq; 3TTG'fl1Rfl q;r 4'<+=tluj 2: 3 if t I
-qcp ffi if 4R61e& fcmrr 'GfffiT t, Cf6T GT6lT qrr
4 . ,
t I _, -,,
(A) 1 : 4 (B) 1 : 2 (C) 6 : 9 (D) 8 : 9
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PHYSICS
--
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SECTION- 2: (One or more options correct Type)

. 2 : m "fltt QC61'<)
section contains 5 multiple choice questions. Each question has four choices (A),
{B), (C) and (D) out of which ONE or MORE are correct.
if 5 t I if "ilR (A), (B), (C) 3tff (D)
"ffift 5 I
11. Two non-conducting solid spheres of radii R and 2R, having uniform volume charge
densities p
1
and p
2
respectively, touch each other. The net electric field at a distance
*3
2R from the centre of the smaller sphere, along the line joining the centres of the
PI
spheres, is zero. The ratio P
2
can be
{A) -4
(B)
32
25
ci')
32
( . ,,
' .\ t
{C)
25
(D) 4 .- ' ) .
err R q 2R om em fvr;:r lR" p
1
p
2

. 3WR 3ITffi m 1fliT t 1 GFTt l0<14>1
:JV1'h1l rt m t 1 tm lR m-e zR lR

32
(A) - 4
(B) 25
32
(C) 25
(D) 4
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PHYSICS
12. A horizontal stretched string, fixed at two ends, is vibrating in its fifth harmonic
according to the equation, y(x, t) = (0.01 m) sin [(62.8 m-
1
) x] cos [(628 .r
1
)t].
Assuming ;r= 3.14, the correct statement(s) is {are) -..
*3
(A) The number of nodes is 5.
(B) ;he length of the string is 0.25 m.

(.q/ The maximum displacement of the midpoint of the string, from its equilibrium
position is 0.01 m.
iQ,}/ The fundamental frequency is 100 Hz.
GFIT fffi1 lR 4 R 61Ci; -qfqcft :xu II qlfl '{14) Cfj'( Of
y(x, t) = (0.01 m) sin [(62.8 m-
1
) x] cos [(628 s-
1
)t] &m ID -m t I
tr= 3.14 +JFIT \1fT<r ffi mft
(A) qft 5 I
(B) 0.25 m I
(C) q;-r 0.01 m I
(D)
I
Space for Rough Work
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PHYSICS
' 13. In the circuit shown in the figure, there are two parallel plate capacitors each of
capacitance C. The switch S
1
is pressed first to fully charge the capacitor C
1
and
*3
then released. The switch S
2
is then pressed to charge the capacitor C
2
. After some
time, S
2
is released and then S
3
is pressed. After some time,
(A) the charge on the upper plate of C
1
is 2CV
0
.
(g) the charge on the upper plate of C
1
is CV
0
.
(C) the charge on the upper plate of c2 is 0.
(D) the charge on the upper plate of C
2
is - CV
0
.
Vo
G1 c.t 1
>Jffq s
1
vmrr t mfcp c
1
1
6ITG S
1
cp1 \ifTdT t 1 C
2
cp1
fc;n) ft<rq S
2
cp1 \JffilT t 1 9 "fJ111l fiTG S
2
cp1 umrr t cm1 S
3
cp1 Vffifr t I Wl<f 6llG
(A) C
1
W lN 2CV
0
arrrn t I
(B) C
1
\3iW lN CV
0
t I
(C) C
2
q5T tR 3Wffi t I
(D) C
2
qtt lN

t I
Space for Rough Work
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PHYSICS
14. A particle of mass M and positive charge Q. moving with a constant velocity
ii
1
= 4[ ms-
1
, enters a region of uniform static magnetic field normal to the x-y plane.
The region of the magnetic field extends from x = 0 to x = L for all values of y. After
passing through this region. the particle emerges on the other side after 10
*3
milliseconds with a velocity ii
2
= z(J3l + J) ms-
1
The correct statement(s) is (are)
(A) The direction of the magnetic field is -z direction.
(B) The direction of the magnetic field is +z direction.
S01rM
(C) The magnitude of the magnetic field
3
Q units.
l001rM
(D) The magnitude of the magnetic field is
3
Q units.
'CfCP M S{ClP111 Q CfiT Cf>UT, ii, = 4[ ms-
1
q'Hil1
qtP111 CfffiiT W "161c61{l aGr x-y oo t'
(f2fl at;r X= 0 X= L (fCf)' y ft;rq I
'ij61 ct) <l af5r en) 'lffi" Cf>UT 10 qff q;x am-
u 2 = z(.J3l + J) ms-
1
.. >rCPC I "fflft :
(A) aGr -z 'B I
(B) 'ij61l{l el?f +z I
(C) 'ij61J<l af?r 'PT 4RJil01

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n\--,- JOOJr M
(D) C<l?t CJ>1 4 01101
3
Q t> l
Space for Rough Work
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PHYSICS
15. A solid sphere of radius R and density pis attached to one end of a mass-less spring
of force constant k. The other end of the spring is connected to another solid sphere
of radius R and density 3 p. The complete arrangement is placed in a liquid of density
*3
2pand is allowed to reach equilibrium. The correct statement(s) is (are)
;,:
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, he net elongation of the spring is 3k .
1
:; , ( , , _ ', _
,', f } ' ''\ '< ' I
87! R
3
pg
(B) the net elongation of the spring is
3
k
(C) the light sphere is partially submerged .
. light sphere is completely submerged.
... J.-
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Tf"m fWT k t I ft.R' cnT
R Cf 3p I wf em 2p
-q \iffiiT 3fR -q vmiT t I 'fift
8tr R
3
pg
furrr qft -;)c
3
k t I
(c)
(D) I
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SECTION- 3: (Integer value _correct Type)
UU\S- 3 : ('{Oifq; 1IR" lllft UCbl'<)
PHYSICS
This section contains 5 questions. The answer to each question is a single digit integer,
ranging from 0 to 9 (both inclusive).
il 5U"H t w.l <PT "ffiR 0 g ' qcp- (ctAl Eft'q cpf

16. A uniform circular disc of mass 50 kg and radius 0.4 m is rotating with an angular
velocity of 10 rad s-
1
about its own axis, which is vertical. Two uniform circular rings,
each of mass 6.25 kg and radius 0.2 m, are gently placed symmetrically on the disc
in such a manner that they are touching each other along the axis of the disc and are
horizontal. Assume that the friction is large enough such that the rings are at rest
relative to the disc and the system rotates about the original axis. The new angular
velocity (in rad s-
1
) of the system is f)\
\.-
50 kg q 0.4 m II:Cf)f1Jil1 3N4t 3rel 10 rad s-
1

Cf>lUftll m t 1 "GT lR f!Jiftla
sq WPR 1R w \ifRl FcP
'41 mT I Cf>T 6.25 kg CT 0.2 m t I em
Cf>lUftll (rad s-lil) m (lfR fcp 'ij;-
t q t 3fR f.1Cf>lll 3re lR wR

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( PHYSICS
17. The work functions of Silver and Sodium are 4.6 and 2.3 eV, respectively. The ratio of
the slope of the stopping potential versus frequency plot for Silver to that of Sodium
is
$ cm<f Wlm: 4.6 CJ 2.3 eV t I T.lTcft CJ

18. A bob of mass m, suspended by a string of length /
1
is given a minimum velocity

,i \ .
required to complete a full circle in the vertical plane. At the highest point, it colli9es
elastically with another bob of mass m suspended by string of length /
2
, which is
initially at rest. Both the strings are mass-less and inextensible. If the second bob,
after collision acquires the minimum speed required to complete a full circle in the
. /1
vertical plane, the ratio 1 is
2.
m sF4'iH q;r /
1
Cfft ."clVf>T t I
vmn t viT fcn CWl Cfl' WT <tR'R t- t I 3ftA \j vi:lC1JO!
lR m t" <Rffi t
lffi;rq; /
2
q,'l S3Tf t ll lR t I GFIT
CJ t I t" 611G <PT 71fa
/ I
mcfi t vrr fij) cwr 1l wf wr q;rt i\1C1'"l t. Ofl - rm
/2
4 ,
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PHYSICS
19. A particle of mass 0.2 kg is moving in one dimension under a force that delivers a
0
constant power 0.5 W to the particle. If the initial speed (in ms-
1
) of the particle is
zero, the speed (in ms-
1
) after 5 sis
0.2 kg ClPi H <Pf (f)U1 \'(f) 61'<1 "$ viT fcl> Wffi 0.5 W CfJUT
-g-, 1f t I q;-crr oqft 'llfu <161" 5 s 6fiG
Tfftf (ms-1'if) -gFft :
t.. , o,oo 0'
' , .
I'"''
, _1
20. A freshly prepared sample of a radioisotope of half-life 1386 s has activity 10
3
disintegrations per second. Given that In 2 = 0.693, the fraction of the initial number
of nuclei (expressed in nearest integer percentage) that will decay in the first 80 s
after preparation of the sample is
*3
S3TI amgik)q Riixi$1 3l't1-3WJ 1386 s t . ctt
fflffi4(11 10
3
IDa I In 2 = 0.693 t . Wi 80s it
CJ CJ>T 'if)
' '
- . ( ( , \
/ ' 1 ,f 0 --
'( ,I ' ; .. - rl
... .
I I
,. . i .
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PART II: CHEMISTRY
SECTION- 1 : (Only One option correct Type)
1 : mft fciCbW QCbl'<)
This section contains 10 multiple choice quest.ions. Each question has four choices {A),
(8), (C) and (D) out of which ONLY ONE is correct.
lf 10 f4fc)Cht>Q t I lf fctcn(>q (A), (B), (C) 3tff (D) 6,
I
21. The standard enthalpies of formation of COlg). H
2
0(!) and glucose(s) at 25 oc are
-400 kflmol, -300 kflmol and -1300 kJ/mol, respectively. The standard enthalpy of
*3
combustion per gram of glucose at 25 oc is /
(A) +2900 kJ -2900 kJ
(C) -16.11 kJ (D) + 16.11 kJ
COlg). H
2
0(1)
4
i{ct>'lti (ORr} fcRT.R 1fRCP 25 oc tR - 400
- 300 kJftfrB. -1300 kf/Jffi;r t I l<'j\Cf>lti Cfft 25 oc tR l1ACP t
(A) +2900 kJ
(C) -16.11 kJ
(B) -2900 kJ
(D) + 16.11 kJ
Space for Rough Work
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.. . \ \ .
\ ... . .
r
i' ' \
r _, , \ , )
. ... ' ... -
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I : ;
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(
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(
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! .. \ "\
. I
->
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( CHEMISTRY)
22. KI in acetone, undergoes S,P. reaction with each of P, Q, R and S. The rates of the
*3
reaction vary as
p
>-CI
Q
P>Q>R>S
P>R>Q>S

R
0

v .
s
(B) S>P>R>Q
(D) R>P>S>Q
Kl '$ qft P, Q, R 3fR- S SN2 m<fi i I
qft qRqcf1 w+1 t
p
(A) P> Q>R >S
(C) P>R>Q>S

R

v
s
(B) S>P>R>Q
(D) R>P>S>Q
Space for Rough Work q;rq
18

. ...... __ .,....,. __ ----- -------r
I
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(CHEMISTRY J
23. The compound that does NOT liberate C0
2
, on treatment with aqueous sodium
bicarbonate solution, is
(A) Benzoic acid (B) B.enzenesulphonic acid
(C} Salicylic acid w} Carbolic acid (Phenol)
1f)fTrcp urr 'ti)f.S<!l+i c f<rc;nR am C{R C0
2
t. ern- t
(A)
(C)
(B) 1 -t1 PI <t> 3f1=R
(D)
24. Consider the following complex ions, P, Q and R.
*3
The correct order of the complex ions, according to their spin-only magnetic moment
values (in B.M.) is
(A) R <Q<f,
(C) R <P<Q
(B/Q<R<P
-'
(D) Q<P<R
3TT<AT P, Q R lff fcr:tm- :
P = [FeF
6
)
3
-. Q = [V(H
2
0)
6
]
2
+ 3tR R = [Fe(H
2
0)
6
]
2
+.
3WAl em mft" Wl1 ;m;r 1Wi {B.M.
{A) R < Q<P (B) Q<R <P
(C) R < P < Q (D) Q < P < R
Space for Rough
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19
\
\
f
\ \
':
lllmllllllllllllllllllllll

ft
,_;
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.. .......... "'.:........: ... -- - -------- ------ --.. .. ..... ' . - - .. . .... .. . .
( CHEMISTRY)
25. In the reaction,
P+Q--+ R+S
*3
the time taken for 75% reaction of P is twice the time taken for 50% reaction of P.
The concentration of Q varies with reaction time as shown in the figure. The overall
order of the reaction is
(A) 2
(C) 0
[Q]o
[Q]
P+Q--+R +S
Time

(B) I 3
;(Dj 1
P<lft P <lft <lft 'WRT crrrn 6 1

(A) 2
(C) 0
(B) 3
(D) 1
_Space for Rough Work
20
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> I
\
(_ ,. \ _: i ., '
l " ( ' \ l' \
. ----) \ \ ./ .
'\, (CHEMISTRY J
26. Co;entrated nitric acid, upon long standing, turns yellow-brown due to the formation of
NO .@1' N0
2
(C) N
2
0 (D) N
2
0
4
(A) NO
27. The arrangement of X - ions around A+ ion in solid AX is given in the figure (not
, I
-'
\
*3
drawn, to scale). If the radius of x-is 250 pm, the radius of A+ is
(
-{t..! l04pm
':\ '
l .
<
(A) 104 pm
(B) 125 pm
(B) 125 pm
(C) 183 pm (D) 57 pm
.. '
I I \ \ ,.
-<. J I
, ..... ,.....
\
. ' .. '
I I .
..
. '.
I . '
. '
"'
... , , '\
. . , .. . .
(C) 183 pm (D) 57 pm
Space for Rough Work
21
www.examrace.com
(CHEMIST@
28. Upon treatment with ammoniacal H
2
S, the metal ion that precipitates as a sulfide is
I
t ,
..(A) Fe(III)
(B) Al(III) \
(C) Mg(II) (D) Zn(IJ)
,.
..
H
2
S "$' m 1R fGR:T tmJ 3WA cnr 3fClm +l Nm

.
(J\) l'e(IIl)
(C) Mg(II)
(B) A/(III)
(D) Zn(II)
29. Methylene blue, from its aqueous solution, is adsorbed on activated charcoal at
25 oc. For this process, the correct statement is
*3
(A} The adsorption requires activation at 25 C.
/
{S) The adsorption is accompanied by a decrease in enthalpy.
(C) The adsorption increases with increase of temperature.
(D) The adsorption is irreversible.
25 oc (114'11'1 1N cpf 1N
ll<n 1 ft;n) -mft t
(J\) q;) 25 C 1N ttlffitJOI 3JICI!lllct>dl M t I
(B) I
(C) dl4'114 1R I
(0) 3lj&>"' OfttJ ! I
Space for Rough Work
22
m
- . ...... .. - --..----.- -- ----- -.. - --- .
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)
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1
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30. Sulfide ores are common for the metals
I
Cu and Pb (B) Ag, Cu and Sn (C) Ag, Mg and Pb (D) Al, Cu andPb
(A) Ag, Cu 3tR Pb (B) Ag, Cu 3tR Sn (C) Ag, Mg 3tR Pb (D) AI, Cu 31R Pb
. ;,
'- .
.
.. . .
. . \ ,.
i )
Space for Rough Work C6Tlf ct;fmrl1QR
*3
23
fll

.
.
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.
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( CHEMISTRY J
SECTION - 2 : (One or more options correct Type)
2 : m 3JfUq; 1T<PR)
This section contains 5 multiple choice questions. Each question has four choices (A),
{B), (C) and (D) out of which ONE or MORE are correct.
-q 5 61f4Cb<>Q -g. 1 >rFf -q -:qrx fclct>(>t! (A), (B), (C) 3fR (D) -g., ftr;r:l
1
31. Benzene and naphthalene form an ideal solution at room temperature. For this
process, the true statement(s) is(are)
*3
(A) b.G is positive (B) b.S is positive
-oystcm
(C) !lS = 0
suno .. ndin,gs
(D) Ml= 0
3tR. "fiNRUT lff t I -4:; fC;rir W

(A) llG I (B) tl11Ci1Cfl t I
(D) Ml = 0
_Space for Rough Work t"ft;nr
24 lllmllllllllllllllllllllltlll
--- ------ - ----- _ ..... -- - --- ---
..
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j
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i
J
-.. ,. : .
(CHEMISTRY)
32. The pair(s) of coordination complexes/ions exhibiting the same kind of isomerism
is( are)
(J [Cr(NH
3
)
5
Cl]C/
2
and [Cr(NH
3
)
4
Cl
2
]Cl
(B) [Co(NH
3
)
4
C/
2
]+ and [Pt(NH
3
)iH
2
0)CI]+
.
(9) [CoBr
2
C/
2
]2- and [PtBr
2
Cl
2
]2-
(D) [Pt(NH
3
)i N0
3
)]C/ and [Pt(NH
3
)
3
Cl]Br
vtT tJ >fC15'R fl'ilCI <Fldl t %' t
(A) [Cr(NH
3
)
5
Cl]C/
2
3tR [Cr(NH
3
)
4
Cl
2
]C/
(B) [Co(NH
3
)
4
Cl
2
]+ 3tR [Pt(NH
3
h(H
2
0)Cl]+
(C) [CoBr
2
C/
2
]2- 3fR [PtBr
2
C/
2
]2-
(D) [Pt(NH
3
)
3
(N0
3
)]C/3fR [Pt(NH
3
)
3
C[jBr
33. The initial rate of hydrolysis of methyl acetate (l.M) by a weak acid (HA, 1M) is
l /100
1
h of that of a strong acid (HX, IM), at 25 C. The K
0
of HA is
* 3
(A) 1 X I0-4
(B) 1 X I0-
5
(C) 1 X {D) 1 X I0-
3
(1M) Clft (HA, 1M) &m VR>T qft G{ 25 C 1R
(HX, l.M) qft "FIT -q 11100 i I HA Ka em 'j\c;qiq,1 i
(A) 1 X I0-
4
(B) 1 X I0-5 (C) 1 X (D) 1 X to-
3
Space for Rough Work
25 111111111111111111 Ill
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... .:r..: .
. . . ---------- ---- ... -- .
( CHEMISTRY)
34. The hyperconjugative stabilities of tertbutyl cation and 2-butene, respectively, are
due to
(
.- .
(A) (empty) and electron delocalisations.
.- .
\_
\. :.
(B) and electron delocalisations.
\ '-
\
{C) {filled) and electron delocalisations.
(D) p and electron delocalisations.
Space for Rough Work
*3
26
www.examrace.com
i
-i
l
l
'l
\
l
-;
l
i
35. Among P, Q, RandS, the aromatic compound{s) is/ate
{A) p
{B) Q
Cl

0
'i'r
0 0
(A) p
(B) Q
(C) R

NaH
(NH4)2C03
100-115 C
HCI
(C) R
p
Q
R
s
Space for Rough Work
*3
27
- .. ....
(CHEMISTRY)
(D) S
(D) S
1111111111111111 m _
www.examrace.com

, .
1.
.::.
-.
.. -- ... -- - -- --- ---- .. . _________ ,_ ___ _
. - ...- ---. ....... . ,_ ...... _
SECTION- 3: (Integer value correct Type)
3 : (l{OifCb 'fftfi UCbl'()
( CHEMISTRY)
: hi:; 8ection contains 5 questions. The answer to each question is a single digit Integer,
mnging from 0 to 9 (both inclusive).
:rx=r if 5 w-r t I cnT \Tiff o 9 CfCf) (GFIT m- -cp-r
I
36. The total number of lone-pairs of electrons in melamine is
37. The total number of carboxylic acid groups in the product Pis
' ..
.
0 0
p
for Rough Work
(i
* 3
28

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1
l

;
j
l


l

1
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1
1
l
l
]
l
1
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j
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............ ---..... -- . .... ... . .. _., . .
(CHEMISTRY J
38. The atomic masses of He and Ne are 4 and 20 a.m.u., respectively. The value of the
de Broglie wavelength of He gas at -73 oc is "M" times that of the de Broglie
wavelength of Neat 727 oc. M is '() .
He 3iR Ne tWnUJ sF4'il1 4 3ftx 20 a.m.u. t" I He tRl Cfft -73 oc lR
Ne Cfft 727 oc "Cff "M" "TfT t I Mq;r l1R t
39. EDTA4- is ethylenediaminetetraacetate ion. The total number of N-Co-0 bond
angles in [Co(EDTA)]
1
- complex ion is
EDTA
4
- 3ll1R t" I WA [Co(EDTA)]
1
- -q N-Co-.0
cp)uTI qft F- t
40. A tetrapeptide has -COOH group on alanine. This produces glycine (Giy), valine
(Val), phenyl alanine (Phe) and alanine (Ala), on complete hydrolysis. For
tetrapeptide, the number of possible s(;!quences (primary structures) with -NH
2
group
*3
attached to a chiral center is
1) Q<'11411 lR -COOHTJ,O. fclEI'il1 t I VJ<>f &m
(Giy), 'Cfc;fR q<11f.i1 (Phe) q<11f.i1 (Ala) t I
ctft -NH
2
Wf f$tc;r

\ , 0
l
/ .'
. \ ,}
\ .
f
'\
..
' "- l \
.. \
Space for Rough Work
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., : .i' ...
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PART Ill : MATHEMATICS
SECTION -1 :(Only One option correct Type)
-1 : "ift UCbl"()
This section contains 10 multiple choice questions. Each question has four choices (A),
(B), (C) and (D) out of which ONLY ONE is correct.
-q 10 lfR g. I -q T.fR j4cpc;q (A), (B), (C) 3fR (D) g.,
I
--. 1\ 1\ 1\ --. 1\ 1\ 1\
"
J . ' \ ,. / ' .:
' ., . I
. . \
l..
24
(D) 23
24
(D) 23
42. Let PR = 3 i + j - 2k and SQ = i - 3}- 4k determine diagonals of a parallelogram
--. 1\ 1\ 1\
PQRS and PT= i + 2j + 3k be another vector. Then the volume of the
--. --. --.
parallelepiped determined by the vectors PT, PQ )ind PS is
(A) 5 (B) 20 {cy 10 (D) 30
--. 1\ 1\ 1\ --. 1\ 1\ 1\
l1RT fq) PR = 3 i + j - 2k SQ = i - 3}- 4k ttlikl'< PQRS
--. 1\ /\ 1\
--. --.
cp-) t 3fR PT = i+2j +3k i I (fEl PT ,PQ
--.
PS &m fP"I kt'< q;r WRA t:
(A) 5 (B) 20 (C) 10 (D) 30
Space for Rough Work
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{ . _ t t . 1 -t L : J i
i , } . . It :' , . - I l .) . c{;J .:-
! _j ' '\. .
l
* 3
, I \
( ' \ .
) l \ . ...
.. _
1. \
. --- ----.-- --- . . . .. .
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43. Let complex numbers a and lie on circles (x - x
0
)
2
+ (y - y
0
)
2
= ,2 and
(x - x
0
)2 + (y - y
0
)1 = 4r
2
, respectively. If z
0
= x
0
+ iy
0
satisfies the equation
2 lz
0
1
2
= -,2 + 2, then lal =
1
(A) -

1
(B) 2
1
(C) (D) t
. "' 1
lJRT I(() fi"1H-1J>l a a (x- x
0
)2 + (y- y
0
) 2 = r2 (x- x
0
)2 +
(y- y
0
)
2
= 4r2 -g- I z
0
= x
0
+ iy
0
{14)cp'{OI 2 lz
0
1
2
= r
2
+ 2 CJJT
CJR"ill W{ I al =
1
(A) -

1
(C)
(D) }
'\._ / ;
' i . . \
,...;: \
. .\ l, '
. ' ' :", 4
. i ' 1 . ' ;
44. For a > b > c > 0, the distance between ( 1, 1) and the point of the
'
lines ax + by + c = 0 and bx + ay + c = 0 is less than 2-[2 . Then

{Af a + b - c > 0 (B) a - b + c < 0
(C) a- b -+- c > 0 (D) a+ b- c < 0
. \ '
."""\ / _.r
I . .. .
/
/ t'
{' ... \_ \ .f

a > b > c > 0 -ij) fRq, ( 1, 1) ax + by + c = 0 q bx + ay + c = 0 -ij) Rl :q:
(A) a + b- c > 0
(C) a- b + c > 0
(B) a- b + c < 0
(D) a + b- c < 0
' ...
,, - \ \; . ' ( . ' / i .. .
j
'. i
-, ' t } -
. ' . ! ' _,
. \

! l, ' ., . .- r,:
0
. ; >,,,.
'
1
: .' -.. f .. -.', ... . / . f"l . I )
-. ' . -: ,. I - /- - ..., _ c . \ __ , l ' . . . i ,, \ ; . .,
. ' ' .) \. . \ . ..
( ... \-\ \ .
-.d.; ,\ ( . {())- -\s
/ './ . i 1' ' t . .
() :t l ',_:} ' .. 1. -./ l' -,,)
- \j \ ' _' ./ "I
'
\ ! ..
' .
'. . ( . ! - \
I ' . _. ' '
! ' .
' !\
- '
( ' 1
.. _;
: ) .
:' \ < / \ ', ;
.. _i ' i .
\ -
r:-. ... l '\
\ .. / . ; ) ' ) ,.
( l .
*3
I
l ) \) (
31
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..
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.
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. . ' . 1 '/
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( MATHEMATICS )
x+2 l2J. z
45. Perpendiculars are drawn from points on the line --= =- to the plane
2 -1 3
*3
x + y + z = 3. The feet of perpendiculars lie on the line
X .!:..::..1 Z- 2
(A)
-- ---
- -
5 8 -13
(C)
x L:J. z-2
- - --
4
- -
3 -7
(
A) z - 2
5 - 8 - -13
x z- 2
(C) 4= 3 = -7
(B)
x c.! z - 2
-- --
2
- -
- 5 3
(D)
x Ll_ z - 2
-- ---
2
- -
5 - 7
x z - 2
(B) 2= 3 =--=5
x l.=J.. z -2
(D) 2= -7 =-s-
r 1
Space for Rough Work
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. .
, .. - '\1
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. ; . \
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(
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i
........... pt;p.;,- ----------=
( MATHEMATICS )
46. Four persons independently solve a certain problem correctly with probabilities
1 3 1 1 . . . . . . . .
2 , 4 , 4 , 8 . Then the probabthty that the problem is solved correctly by at least one
of them is
21
(B) 256
3"
(C) 256
253
(D) 256
'i1R C2lfcm -em k, i cficn 6(1
cpffl G6f I cp1f <P11 ClJfcffi &m cftq;- 5R fcn<l \1fR
S:llftl<PCil t :
235
(A) 256
21
(B) 256
3
(C) 256
253
(D) 256
47. The area enclosed by the curves y = sin x + cos x and y = Ieos x - sin xl over the
interval [ 0 , I] is
(A) 4(Vl- 1)
(D) 2"-fi ( V2 + 1)
[ 0 i] CJWl y= sinx+ cosx y= lcosx-sinxl Gm "t:
{A) 4(0- 1) (B) 2\[2 - 1) (C) 2("-fi + 1) (D) ( \[2 + 1)
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' : ( .\ ..... : ,) . ( / I . ' ; .. ,:
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--' " '\" -: /. . -\ \ \ : '' ,<
) 1 .. -; '
I ' " ' I ,, .
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*3
, ' .
.
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f.'
( MATHEMATICS)
48. A curve passes through the point ( 1 , . Let the slope of the curve at each point
(x, y) be x > 0. Then the equation of the curve is
*3
logx+! (B) logx + 2
(C) sec = log x + 2 (D) cos = log x +
crw (1, I TfFtT fcp (x, y) tR crw ctT
.!:: +sec (.tJ', x > 0 t (f6T w cpr 'f141Cf5"! 01 :
X X
(A) sin(;)= log x + t (B) cosec(;)= log x + 2
(C) sec(?)=logx+2 (D)
Space for Rough Work
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, 1 . ( \
.
l _. . \ \. . .
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49
. \
v '
( MATHEMATICS)
let f: [t, 1 J .R (the set of all real numbers) be a positive, non-constant and
differentiable function such that f'(x) < 2 f(x) and t(t)= . Then the value of
I
f f(x) dx lies in the interval
112
(A) (2 e - 1, 2e) '. (6{' (e- 1, 2e- 1)
(C) (e;
1
, e-1) (D) (o, e;_
1
)
11AT fcp f : [t, 1 J R qlffifclq> <Pl tFil<"'ict>, 31ilh H
I
<m! QiWI t f'(x) < 2f(x) <m1 t(&) = It, G'f f f(x) dx
<PT 1Wf lct -q t :
(A) (2 e-1, 2e)
(
e- 1 )
(C) -
2
-, e-1
1/2
(B) (e-1,2e-1)
(D) (o,e;t)
. 50. The number of points in (- 'f' ), for which x
2
- x sin x x = 0, is
(A) 6 {9-i 4 (C) 2 . (0) 0
(- oo, oo) -q ctl fuq x
2
-x sin x- cos x = 0, t _:
(A) 6 (B) 4 (C) 2 (D) 0
Space for Rough Work
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(
' i 1'
- '
.. (;.. . -. )
..
'
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.\ '
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.... _ .. ;
( MATHEMATICS)
SECTION- 2: (One or more options correct Type)
2 = 3lftrq; UCbl'<)
This section contains 5 multiple choice questions. Each question has four choices (A),
(B), (C) and (D) out of which ONE or MORE are correct.
ll 5 1TR t . I ll -:rrR (A), (B), (C) 3fR (D) t, fGAll
(JT 3lfErcJ; 00 -g- I
51. A rectangular sheet of fixed perimeter with sides having their lengths in the ratio
8 : 15 is converted into an open rectangular box by folding after removing squares of
equal area from all four comers. If the total area of removed squares is I 00, the
resulting box has maximum volume. Then the lengths of the sides of the rectangular
sheet are
(A) 24 (B) 32 (C) 45 (D) GO
4Rfll4 em. ftlt1c6l ctr s : 1s "$"
3fjtffi'f -q t. Trn1 Fct> 11 '<1 'fi11R Q5 (>j crt PI Cf) I (>j (j?{ \fCP
3llllctl1'< -4 fcmrr \;ffifT I cpff em Cf>(q 100
v
t . '({1 qRons:fl -qi) 'CPT I G6T 3i lll d1Cf>l'< 'PI :pn31l q,(
f.1l4 -g- :
(A) 24
(B) 32 (C) 45
(D) 60
Space for Rough Work
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'
},
j
;
I
l

!
l
i
j
l
J
.... , . _., ,
4n !1!.:!:...ll
52. LetS,= L (-1)
2
fil. Then Sn can take value(s)
k l
(A) 1056 (B) 1088 (Cr 1120
4n Mtt.Jl
l1RT S"= L (-1)
2
Jc2, tfil sn lfR 5:
k = l
(A) 1056
(B) 1088
(C) 1120
53. A line I passing through the origin is perpendicular to the lines

1
1
: (3 + t) i + ( -1 + 2t)j + ( 4 + 2t)k , - oo < t < oo

1
2
: (3 + 2s)i + (3 + 2s)j + (2 + s)k,- oo < s < oo
( MATHEMATICS )
(0) 1332
(D) 1332
Then, the coordinate(s) of the point(s) on /
2
distance from the point of
intersection of I and /
1
is (are)
(
7 7 5)
(A) 3, 3, 3 (B) (- 1, -1, 0) (C) (1, 1, 1)
m-r 1. vil



II : (3 + t)i + (-1 + 2t)j + (4 + 2t)k'- CXl < t < CXl

1
2
: (3 + 2s)i + (3 + 2s)j + (2 + s)k,- oo < s < oo
tR cl+i.lq\1 5 I 1
2
tR W vtT Wlafl I wm /
1

{17 clft tR 5 {t}, 5 (t) :
(B) (-1, -1, 0) (C) (1, 1, 1)
Space for Rough Work lfi1'lf
. l (I ... l)- \b . i
1-t ,-t
i
*3
37
t

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l

3


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.... --- - ----- ----- ----
( MATHEMATICS )
54. Letf(x) =x sin 1rx, x > 0 . Then for all natural numbers n,f'(x) vanishes at
(A) a unique point in the interval ( n, _n + !)
' .
. '
;'i;
\
(
1 ) /
(B) a unique point in the interval n + 2, n + 1 .
'
..
(C) a unique point in the interval (n, n + 1)
{D) two points in the interval (n, n + 1)
+JRT f<f>/(x)=xsin7rx,x>O,(fif"ff4t n "$ tR
(C) (n, n + 1) it -q<P #q lR
(D) (n, n +I) it Gl #q3ll tR
Space for Rough Work cn1i cli-'fmrletR
38
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..... . .... ..... ... -.. , .... -.. - _r . ...,...,..,. __ ..
; ,:
..
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( MATHEMATICS J
55. For 3 x 3 matrices M and N, which of the following statement( s) is (are) NOT correct ?
(A) Nr M N is symmetric or skew symmetric, according as M is symmetric or skew
symmetric
(B) M N- N M is skew symmetric for all symmetric matrices M and N
(C) M N is symmetric for all symmetric matrices M and N
{D) (ad} M) (ad} N) = adj (M N) for all inVertible matrices M and N
(D) Wfi M N (adj M) (ad} N) = adj (M N) I
Space for Rough Work c6''ft;nrtelR
*3
39

- _, ---- -- - - ------ ---- ----- ---- - - ...
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( MATHEMATICS J
SECTION- 3: (Integer value correct Type)
3 : ('{OifC6 1I1";J ll'ift QCbl'<)
This section contains 5 questions. The answer to each question is a single digit integer,
ranging from 0 to 9 {both inclusive).
-q s I em o 9 (GFIT "$ <PT

y} i
56. A vertical line passing through the point (h. 0) intersects the ellipse 4 +
3
== 1 at
the points P and Q. Let the tangents to the ellipse at P and Q meet at the point R.
. max min
If !1(h) = area of the tnangle PQR, .1
1
=
112
h
1
!1(h) and 11
2
=
112
h
1
.1(h ), then
}s /11 - 8/12 =
(h, 0) "tT cm;ft tr cfltfqt1; +f= 1 q;l p Q
lff Cf)lctft t I lJRT fcn P Q 'tR C1>'T R tR
t I il(h) = PQR em a)?IQ)C'I, 6
1
=


1
11(h) 3fR L\
2
=


1
il(h)
8
t, -J5 - 8.12 =
57. The coefficients of three consecutive terms of (1 + x)n +
5
are in the ratio 5 : lO : 14.
*3
Then n =
(1 +x)n+S "$ cfi;f qGl t' S: 10: 14 1l n =
space for Rough Work l6l'1f
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-.:. ,._- J, .,
( MATHEMATICS)
58. Consider the set of eight vectors V = {at+ b] + ck: a, b, c e {-1, 1}}. Three non-
coplanar vectors can be chosen from V in i' ways. Then p is
3lTO <PI V= {at + bl + ck: a, b, c e {-1, 1}} I V xl cft;:r
3i xiiie1 2P WPR -xl ' \ill t 1 "d6l' p <PI 1fR 6 :
59. Of the independent events Ep E
2
and
3
, the probability that only E
1
occurs is
a, only
2
occurs is P and only E
3
occurs is y. Let the probability p that none of
events E
1
,
2
or
3
occurs satisfy the equations (a- 2P) p = ap and CP- 3y) p = 2py.
All the given probabilities are assumed to lie in the interval (0, 1 ).
*3
Probability of occurrence of 1-
Then Probability of occurrence of E
3
=
'df.1
1
,
2

3
-q xl E
1
!JIIfllif>dl a 6-,
2
cpl !JIIfllif>dl p t
3
trc-f cpl y t I l1RT fcf> trCriT3Tf
E
1
, E
2
111
3
it '1ft 1' cpl !JIIfllif>dl p, t1tfl4>'<on (a- 2P) p = ap
(B- 3y) p = 2Py cp) I QlftlcnC11Q (0, 1) +1
llffi vmfi "(161'
E
1
-$- cpl !JIIfllif>dl
, ifi @ "cift >II ffi if> d I =
.
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\') - < 1 -
, . . .
1
4f
1m1111111111111111111
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( MATHEMATICS)
60. A pack contains n cards numbered .from 1 to n. Two consecutive numbered cards are
-J. 3
removed from the pack and the sum of the numbers on the remaining cards is 1224.
If the smaller of the numbers on the removed cards is k, then k - 20 ==
lf n t vfl I n &m fi!Pi5d t I ciT wJOIPid "ffl5m311
m t 3tR cPt q;r <IT11 1224 t
1N Cf>l filP5d x=t&n k C16f k - 20 =
' i '
( " ' i )
\..
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