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*N = no; Y = yes; F = fast; S = slow; M = medium; V = variable (depends on the adhesive). *positive-displacement pump or pressure-time dispensing value.
Although adhesively bonded joints can be engineered for high strength, adhesive bonding may not be suitable if strength requirements or temperature variations are extreme. Other fastening methods also may be indicated if provision must be made for disassembly and reassembly of the component. Adhesives are used routinely to bond parts of extremely diverse size, shape, and composition to one another. Parts generally must tolerate a surfacecleaning operation prior to bonding, and they must be rather stable chemically in the intended service environment. The majority of adhesively bonded parts are not load-bearing because other assembly techniques historically have been more economical for these applications. This situation is changing, however, and there is now increasing use of loadbearing adhesives in the automotive, aircraft, and construction industries. Adhesive
use is unrelated to the size of the assembled objects. Adhesives perform well in applications ranging from minute electronic assemblies to large building panels. Part geometry is usually not a problem because special applicators are available for hard-to-reach surfaces. Typical adhesively bonded assemblies include brake-band and brake-disk assemblies, helicopter blades, plywood and wood furniture, aircraft honeycomb structures, paper bags and other paper products, and pulleyshaft and gear-shaft assemblies. Adhesives are used to fasten bushings, nameplates, decorative appliance panels, insulating and sound-deadening parts, oor tiles, and automobile rear-view mirrors to glass windshields and to lock threaded fasteners permanently. Figure 7.5.1 illustrates typical adhesively bonded assemblies.
Figure 7.5.1. Some typical adhesively bonded assemblies. (a) Automotive brake lining. (b) Pocket calculator faceplate. (c) Beverage can with bonded side seam. (d) Glass fruit bowl with adhesively bonded stem. (Courtesy GMI Technical Institute.) Table 7.5.3. Adhesives Commonly Used for Joining Various Materials
Materials to be joined ABS Polyesters Adhesive Table 7.5.4 reference
Epoxy Alpha-cyanoacrylate Nitrile phenolic Aluminum and its alloys UV/radiation curing adhesives Epoxy Epoxy-phenolic Nylon-epoxies Polyurethane rubber Polyesters Alpha-cyanoacrylate Polyamides Polyvinyl-phenolic Neoprene-phenolic Brick Epoxy Epoxy-phenolic Polyesters Ceramics Acrylics Epoxy Cellulose esters Vinyl chloride-vinyl acetate Polyvinyl butyral Chromium Concrete Epoxy Polyesters Epoxy Acrylics
e c b w
e d g a c h i b e d a w e j k l e a e
a e c h i m e b t e w d c j x
Fluorocarbons
Glass
Epoxy Acrylics Epoxy-phenolic Alpha-cyanoacrylate Cellulose esters UV/radiation curing adhesives Vinyl chloride-vinyl acetate Polyvinyl butyral
k l
Table 7.5.3 lists a number of materials that are commonly bonded with adhesives and indicates the adhesives commonly used. Table 7.5.4 describes the characteristics of common adhesives. The bond strength of adhesives that use a catalyst or curing agent is often inversely related to the cure time. Fast-curing adhesives (including hot melts) may cause production problems by setting up too quickly. Cleanup also may be a problem with fastcuring adhesives.
(Continued)
Materials to be joined Lead Epoxy Vinyl chloride-vinyl acetate Polyesters Leather Vinyl chloride-vinyl acetate Poly vinyl butyral Polyhydroxyether Polyvinyl acetate Flexible adhesives Alpha cyanoacrylate Magnesium Polyesters Epoxy Polyamide Polyvinyl-phenolic Neoprene-phenolic Nylon-epoxy Nickel Epoxy Neoprene Polyhydroxyether Paper Animal glue Starch glue Urea, melamine, resorcinol, and phenol formaldehyde Epoxy Polyesters Adhesive Table 7.5.4 reference
a k a k l m n g c a e h i h e g m
P q
e a
Cellulose esters Vinyl chloride-vinyl acetate Polyvinyl butyral Polyvinyl acetate Polyamide Flexible adhesives Phenolic and melamine Epoxy Alpha-cyanoacrylate Flexible adhesives Polyamide Epoxy Flexible adhesives Phenol and resorcinol formaldehyde Polyesters Polycarbonate Polyesters Acrylics UV/radiation curing adhesive Epoxy Alpha-cyanoacrylate Polyurethane rubber
j k l n h g e c g e g q
a a w x e c g
Table 7.5.3. Adhesives Commonly Used for Joining Various Materials (Continued)
Materials to be joined Polyester, glassPolyesters Adhesive Table 7.5.4 reference
reinforced Epoxy Acrylics Polyacrylates Nitrile-phenolic Polyethylene Polyester, isocyanate modied UV/radiation curing adhesives Butadiene-acrylonitrile Nitrile-phenolic Alpha-cyanoacrylate Polyformaldehyde Polyester, isocyanate modied Butadiene-acrylonitrile Nitrile-phenolic Polymethyl methacrylate Alpha-cyanoacrylate UV/radiation curing adhesive Polyester Nitrile-phenolic Polypropylene Polyester, isocyanate modied Nitrile-phenolic Butadiene acrylonitrile Alpha-cyanoacrylate Polystyrene Vinyl chloride-vinyl acetate Epoxy
e w t b a
g b c a
g b e
c x a b a
b g c x
UV/radiation curing adhesives Polyesters Alpha-cyanoacrylate Polyvinyl chloride, rigid UV/radiation curing adhesives Polyesters Epoxy Polyurethane Acrylics Alpha-cyanoacrylates Rubber, butadiene styrene Epoxy Urethane rubber Alpha-cyanoacrylates Rubber, natural Epoxy Flexible adhesives Alpha-cyanoacrylates Rubber, neoprene Epoxy Flexible adhesives Alpha-cyanoacrylates Butadiene-acrylonitrile
e g x
a e g w c g
e g c e h c e h c
Table 7.5.3. Adhesives Commonly Used for Joining Various Materials (Continued)
Materials to be joined Adhesive Table 7.5.4 reference
t h c t e g m e w a l c h i b b d
Silver
Steel
Epoxy Acrylics Polyesters Polyvinyl butal Alpha-cyanoacrylate Polyamides Polyvinyl-phenolic Nitrile-phenolic Neoprene-phenolic Nylon epoxy
See Brick Epoxy Animal glue Polyvinyl acetate Ethylene-vinyl acetate Urea, melamine, resorcinol, and phenol formaldehyde
e o n u q
Source: Adapted from Robert O. Parmley, Standard Handbook of Fastening and Joining, McGraw-Hill, New York, 1989.
Figure 7.5.2. The designs shown in b utilize shear, tensile, and compressive stresses instead of cleavage and peel stresses and are
Figure 7.5.3. Butt joints. Simple butt joints leave little resistance to cleavage stresses. Some common modications are shown here.
Figure 7.5.4. Generation of cleavage or peel stresses in simple lap joints in tension.
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