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ICCH 210 Practice Final Exam 1) Please select the most correct answer. (50 points) 1.1) Which one of the following species has the greatest number of unpaired electrons? a) Geo b) Clo b) Cr3+ c) Br- What is the bond order of diatomic fluoride F2 according to its MO diagram? a) 2.5 b) 1.5 c) 2 d) 1 Which of the following is isoelectronic (have the same number of electrons) with Rb+? a) Sio b) Alo c) Kro d) Cl- AA solution with an unknown concentration of 5 mL of HCl(aq) requires 100 mL of a 0.01 M solution of KOH(aq) for its titration to reach a neutral point. What is the molarity of the HCl(aq)? a) 0.20 M b) 3.25 M c) 5.0 M d) not enough information

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 1.5) What volume of water would be needed to dilute 50 mL of 3M HCl to 0.75M? a) 50 mL b) 100 mL c) 150 mL d) 200 mL 1.6) Which of the following compounds contains the greatest percentage of oxygen by weight? a) C3H6O5Cl b) C3H6O2 c) C5H10O5 d) C4H8O3 1.7) Na+ and F- have the same: a) atomic weight b) electronic configuration c) ionization constant d) number of protons and neutrons 1.8) Which of the following molecules contains both ionic and covalent bonds? a) C6H14 b) NaBr c) NH4Br d) H2O 1.9) Which one of the following bonds is the shortest? a) C-F b) C-Br c) C-I d) C-C 1.10) From the following reaction and thermodynamic data what is the energy released when a CH bond forms? (Note: Hfo CO2(g) = -393 kJ/mol, Hfo O2(g) = 0 kJ/mol and Hfo H2O(g) = -242 kJ/mol) CH4(g) + 2O2(g) CO2(g) + 2H2O(g) Hforxn = -802 kJ/mol a) -19 kJ/mol b) -75 kJ/mol c) 167 kJ/mol d) 0 kJ/mol

 1.11) Which of the following is NOT true in general as we move from potassium to bromine in the periodic table? a) Electronegativity increases b) Atomic radius increases c) Ionization energy increases d) Electron affinity increases 1.12) What is the characteristic valence-electron configuration of the alkali earth metal group? a) ns2 b) ns2np6 c) ns2np4 d) ns2np5 1.13) Please name the type of bond for the selected bond in the molecule below.

sp2-s sp2-sp sp2-sp2 sp-sp 1.14) According to VSEPR Theory, the H-O-H bond angle in H3O+ should be closest to? a) 120o b) 109.5o c) 90o d) 180o 1.15) Which of the following elements has the lowest first ionization energy? a) B b) Al c) I d) Br a) b) c) d)

1.16) What is the bond order of diatomic bromine Br2 according to its MO diagram? a.) 2.5 b.) 1.5 c.) 2 d.) 1 1.17) A flask contains three times as many moles of Cl2 gas as it does H2 gas. If hydrogen and oxygen are the only gases present, what is the total pressure in the flask if the partial pressure due to hydrogen is P1? a) 4P1 b) 3P1 c) .25 P1 d) P1 1.18) When elemental manganese metal is used to form KMnO4 the oxidation state of changes from: e) 0 to 7 f) 3 to 6 g) 2 to 6 h) 0 to 6 1.19) If the pressure of a gas sample is doubled at constant temperature, the volume will be: a) 4 times the original b) 2 times the original c) of the original d) of the original 1.20) Please choose the element with the biggest atomic size from the following group of elements. a) Mg b) Mn c) Bi d) Br 2) Rank the followings atoms in order of increasing electronegativity. (5 points) F Br Na K Cl

 3) Please identify the following type of bonds within the circle. (sp-s, sp-sp, etc). (5 points)
CH3 C O C Cl CH C C H H2C N H

5) In a particular experiment, 20.0 g of CH3COOH was allowed to react with 60 g of CH3OH: CH3COOH(l) + CH3OH(l) CH3COOCH3(l) + H2O(l) a) Please determine the limiting agent and find out the theoretical yield of CH3COOCH3. (3 points) b) If the experimental yield of CH3COOCH3 is 18.5 g, what is the percent yield? (2 points)

 6) Please write the total electron configuration of the following elements according to the correct energy level and sketch the shape of their corresponding orbitals. (5 points) Bo 6) Please draw the Lewis Dot structure of the following compounds and determine their VSEPR geometry and notation. (10 points) H2SO3 CH3O-Na+ XeF4

Na+

 HClO4

C6H6

7) Please draw the molecular orbital diagram of the following compounds. Please determine their bond order. (10 points) CO

 F2 8) Calculate heat (q) for the process in which 6.022 x 1023 atoms of water is converted from ice at 0C to vapor at 100.0C. (cwater = 4.184 J/g Co, Heat of vaporization of water is 44 kJ/mol, and Heat of fusion of water is 6 kJ/mol) (5 points)

9) Between HCl and HI, which one is the strongest acid and why? (5 points)