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I- TNH CHAT HOA HOC: OXIT BAZ 1) Oxit baz + nc dung dch baz Vd : CaO + H2O Ca(OH)2 2) oxit baz + axit muoi + nc Vd : CuO + 2HCl CuCl2 + H2O Na2O + 2HNO3 2NaNO3 + H2O 3) Oxit baz (tan) + oxit axit muoi Vd : Na2O + CO2 Na2CO3 OXIT AXIT 1) Oxit axit + nc dung dch axit Vd : SO3 + H2O H2SO4 2) Oxit axit + dd baz muoi + nc Vd : CO2 + Ca(OH)2 CaCO3 + H2O 3) Oxit axit + oxit baz (tan) muoi Vd : ( xem phan oxit baz )
Lu y : - Cac oxit trung tnh ( CO,NO,N2O ) khong tac dung vi nc, axit, baz ( khong tao muoi ) - Mot so oxit lng tnh ( Al2O3, ZnO, BeO, Cr2O3 ) tac dung c vi ca axit va dd baz Vd : Al2O3 + 2NaOH 2NaAlO2 + H2O Al2O3 + 6HCl 2AlCl3 + 3H2O - Cac oxit lng tnh tao ra goc axit co dang chung : RO2 , co hoa tr = 4 hoa tr kim loai R - Mot so oxit hon tap khi tac dung vi axit hoac dung dch baz th tao ra nhieu muoi Vd: Fe3O4 la oxit hon tap cua Fe(II) va Fe(III) Fe3O4 + 8HCl FeCl2 + 2FeCl3 + 4H2O Vd 2 : NO2 la oxit hon tap tng ng vi 2 axit HNO2 va HNO3 2NO2 + 2NaOH NaNO2 + NaNO3 + H2O Natri nitrit Natri nitrat II- PHNG PHAP IEU CHE TRC TIEP 1)ot cac kim loai hoac phi kim trong kh O2 ( tr Ag,Au,Pt va N2 ): t0C 2) Nhiet phan baz khong tan V du : 2Fe(OH)3 Fe2O3 + 3H2O 3) Nhiet phan mot so muoi : Cacbonat ,nitrat , sunfat cua mot so cac kim loai ( Xem bai P nhiet phan) t0C V du : 2Cu(NO3)2 2CuO + 4NO2 + O2 t0C CaCO3 CaO + CO2 4) ieu che cac hp chat khong ben phan huy ra oxit V du : 2AgNO3 + 2NaOH 2NaNO3 + AgOH Ag2O H2O -------------------------------------
BAZ
I- TNH CHAT HOA HOC BAZ TAN 1) Lam oi mau chat ch th QT xanh dd baz + Phenolphtalein : hong 2) dd baz + axit muoi + nc NaOH + HNO3 NaNO3 + H2O 3) dd baz + oxit axit muoi + nc Ba(OH)2 + CO2 BaCO3 + H2O 4) dung dch baz tac dung vi muoi ( xem bai muoi ) 5) dd baz tac dung vi chat lng tnh 2Al + 2NaOH + 2H2O 2NaAlO2 + 3H2 BAZ KT 1) Baz KT + axit muoi + nc Cu(OH)2 + 2HCl CuCl2 + 2H2O t0C 2) Baz KT oxit baz + nc 0 tC 2Fe(OH)3 Fe2O3 + 3H2O
II- PHNG PHAP IEU CHE TRC TIEP 1) ieu che baz tan * Kim loai tng ng + H2O dd baz + H2 V du : Ba + 2H2O Ba(OH)2 + H2 * Oxit baz + H2O dd baz * ien phan dung dch muoi ( thng dung muoi clorua, bromua ) pdd V du : 2NaCl + 2H2O 2NaOH + H2 + Cl2
co ma ng nga n
* Muoi + dd baz muoi mi + baz mi V du : Na2CO3 + Ba(OH)2 BaCO3 + 2NaOH 2) ieu che baz khong tan * Muoi + dd baz muoi mi + baz mi V du : CuCl2 + 2NaOH Cu(OH)2 + 2NaCl -----------------------------------------
Thang pH
Thang pH cho biet mot dung dch co tnh baz hay tnh axit: - Neu pH < 7 moi trng co tnh axit ( pH cang nho th axit cang manh ) - Neu pH = 7 moi trng trung tnh ( nc cat, mot so muoi : NaCl, Na2SO4 ) - Neu pH > 7 moi trng co tnh Baz ( pH cang ln th baz cang manh ) -------------------------------------
II- PHNG PHAP IEU CHE TRC TIEP 1) oi vi axit co oxi : * oxit axit + nc axit tng ng * axit + muoi muoi mi + axit mi * Mot so PK ran + Axit co tnh oxi hoa manh
(2 )
2) oi vi axit khong co oxi * Phi kim + H2 hp chat kh ( Hoa tan trong nc thanh dung dch axit ) * Halogen (F2 ,Cl2,Br2) + nc : V du : 2F2 + 2H2O 4HF + O2 * Muoi + Axit muoi mi + axit mi V du : Na2S + H2SO4 H2S + Na2SO4 -------------------
I- TNH CHAT HOA HOC 1) Tac dung vi kim loai Dung dch muoi + kim loai KT muoi mi + Kim loai mi V du : Fe + Cu(NO3)2 Fe(NO3)2 + Cu ieu kien : kim loai tham gia phai KT va manh hn kim loai trong muoi 2) Tac dung vi muoi : Hai dung dch muoi tac dung vi nhau tao thanh 2 muoi mi V du: CuCl2 + 2AgNO3 Cu(NO3)2 + 2AgCl
3) Tac dung vi baz Dung dch muoi + dung dch baz V du: Fe2(SO4)3 + 6NaOH
dd vang nau KT nau o 4) Tac dung vi axit Muoi + dung dch axit muoi mi + axit mi V du : H2SO4 + BaCl2 BaSO4 + 2HCl ( trang ) CaCO3 + 2HCl CaCl2 + H2O + CO2 5) Muoi b nhiet phan huy: ( Xem bai phan ng nhiet phan ) II- PHAN NG TRAO OI TRONG DUNG DCH 1) Khai niem Phan ng trao oi la phan ng hoa hoc trong o hai hp chat trao oi thanh phan cau tao e tao ra cac san pham Vd : phan ng cua muoi vi : muoi, baz, axit ( ke ca phan ng cua axit vi baz hoac oxit baz ) 2) ieu kien e phan ng trao oi xay ra c San pham sinh ra co t nhat mot chat khong tan, hoac chat kh, hoac nc Lu y : -a so muoi cua axit yeu hn thng b tan trong axit manh hn ( do xay ra phan ng hoa hoc) V du : AgNO3 + H3PO4 Ag3PO4 + HNO3 ( Ag3PO4 b tan trong HNO3 nen khong ton tai ket tua ) -Rieng muoi sunfua cua cac kim loai t Pb ve sau trong day hoat ong hoa hoc cua kim loai khong tan trong cac axit thng gap. V vay p sau ay xay ra c: CuCl2 + H2S CuS ( en ) + 2HCl
III- PHNG PHAP IEU CHE TRC TIEP 1) Cac phan ng thong thng Co the ieu che cac muoi bang s o tom tat nh sau:
Kim loai
(1 )
( 1 )
Phi kim
Muoi (2 ) Oxit baz (3) Muoi + H2 Hoac kh khac (4) (4) Muoi
+ KL, Axit, muoi, dd baz
Baz
Muoi + H2O
Giai thch : Cac chat nhanh trai tac dung cac chat cung so nhanh phai tao san pham trung tam. V du : ( 2 ) + ( 2) : oxit baz + oxit axit muoi 2) Cac phan ng chuyen oi gia muoi trung hoa va muoi axit. * Muoi axit + kiem muoi trung hoa + nc v du : NaHCO3 + NaOH Na2CO3 + H2O 2NaHCO3 + Ca(OH)2 CaCO3 + Na2CO3 + 2H2O * Muoi trung hoa + oxit tng ng / H2O muoi axit V du : 2CaCO3 + CO2 + H2O Ca(HCO3)2 (1) 3) Phan ng chuyen mc hoa tr cua kim loai
+ PK m a nh ( Cl 2 , Br2 ... )
* Amoni cua axit co tnh oxi hoa manh : NH3 chuyen hoa thanh N2O hoac N2 tuy thuoc nhiet o 2500 C V du : NH4NO3 N2O + 2H2O 0 400 C 2NH4NO3 2N2 + O2 + 2H2O -------------------------------------
I- DAY HOAT ONG HOA HOC CUA KIM LOAI K, Ba, Ca, Na,Mg,Al, Zn, Fe, Ni, Sn, Pb 144424443 Cu , Hg, Ag, Pt, Au 1 4 44 2 4 4 43 (1) 14444 4 4 4 2 4 4 4 4 4 4 43 H (3)
(2)
* (1) Cac kim loai manh * (2) Cac kim loai hoat ong ( trong o : t Zn en Pb la kim loai trung bnh ) * (3) Cac kim loai yeu II- TNH CHAT HOA HOC 1) Tac dung vi nc ( nhiet o thng) * Kim loai ( K Na) + H2O dung dch baz + H2 V du : Ca + 2H2O Ca(OH)2 + H2 2) Tac dung vi axit * Kim loai hoat ong + dd axit (HCl,H2SO4 loang) muoi + H2 V du : 2Al + 6HCl 2AlCl3 + 3H2 * Kim loai khi tac dung vi HNO3 va H2SO4 ac thng khong giai phong kh H2 a c, no ng V du : Ag + 2HNO3 AgNO3 + NO2 + H2O * Al,Fe,Cr : Khong tac dung vi HNO3 ac, H2SO4 ac nhiet o thng: 3) Tac dung vi muoi : * Kim loai (KT) + Muoi Muoi mi + Kim loai mi V du : Cu + 2AgNO3 Cu(NO3)2 + 2Ag 4) Tac dung vi phi kim nhiet o cao: a) Vi O2 oxit baz t0C V du: 3Fe + 2O2 ( Ag,Au,Pt khong P ) Fe3O4 b) Vi phi kim khac ( Cl2,S ) muoi t0C V du: 2Al + 3S Al2S3 5) Tac dung vi kiem : * Kim loai lng tnh ( Al,Zn,Cr) + dd baz muoi + H2 V du: 2Al + 2NaOH + 2H2O 2NaAlO2 + 3H2 III- PHNG PHAP IEU CHE TRC TIEP. 1) Nhiet luyen kim * oi vi cac kim loai trung bnh va yeu : Kh cac oxit kim loai bang H2,C,CO, Al t0C V du: CuO + H2 + H2O Cu * oi vi cac kim loai manh: ien phan nong chay muoi clorua pnc V du: 2NaCl 2Na + Cl2 2) Thuy luyen kim: ieu che cac kim loai khong tan trong nc * Kim loai manh hn ay kim loai yeu hn ra khoi dd muoi V du: Fe + CuSO4 FeSO4 + Cu * ien phan dd muoi cua kim loai trung bnh va yeu: pdd V du: FeCl2 Fe + Cl2 3) ien phan oxit kim loai manh :
pnc V du: 2Al2O3 4Al + 3O2 4) Nhiet phan muoi cua kim loai yeu hn Cu: t0C V du: 2AgNO3 2Ag + O2 + 2NO2 -----------------------------------------------------
-Long : Br2 II- TNH CHAT HOA HOC CUA PHI KIM 1) Tac dung vi oxi oxit: t0C V du: 4P + 5O2 2P2O5 Lu y : N2 khong chay, cac /c Cl2,Br2,I2 khong tac dung trc tiep vi oxi 2) Tac dung vi kim loai muoi (2) V du : xem bai kim loai 3) Tac dung vi Hiro hp chat kh t0C V du: H2 + S H2S a.s H2 + Cl2 2HCl H2 + F2 2HF ( Xay ra ngay trong bong toi ) 4) Mot so tnh chat ac biet cua phi kim a) Cac phi kim F2,Cl2 : Tac dung c vi nc V du : Cl2 + H2O HCl + HClO ( khong ben de huy ra : HCl + O
2F2 + 2H2O 4HF + O2 Lu y : HF co kha nang an mon thuy tinh : SiO2 + 4HF 2H2O b) Cac phi kim Cl2,F2 ,Si : Tac dung c vi kiem V du : Cl2 + 2NaOH NaCl + NaClO + H2O a c, no ng 3Cl2 + 6NaOH 5NaCl + NaClO3 + 3H2O c) Cac phi kim ran C,S,P tan trong HNO3, H2SO4 ac: a c no ng V du : P + 5HNO3 H3PO4 + 5NO2 + H2O
SiF4
III- C S ANH GIA O MANH YEU CUA PHI KIM Phi kim nao de phan ng vi H2 hn , hoac de phan ng vi kim loai hn th phi kim o manh hn t0C V du: H2 + S H2S a.s H2 + Cl2 2HCl H2 + F2 2HF ( Xay ra ngay trong bong toi ) Suy ra : F2 > Cl2 > S ( chu y : F2 la phi kim manh nhat ) IV- IEU CHE PHI KIM * Cac phi kim c ieu che chu yeu da vao cac phan ng ien phan , nhiet phan * Dung phi kim manh ay phi kim yeu hn khoi hp chat ( thng dung muoi ) ------------------------------
Viec giai bai toan xac nh loai muoi tao thanh trong trng hp oxit axit hoac a axit tac dung vi dung dch baz co the c tom tat theo cac bc sau ay : B1 : Tm so mol cua kiem va so mol oxit B2 : Lap t so T xac nh loai muoi tao thanh , viet PTHH tao ra muoi o. B3 : Tnh toan theo PTHH Neu tao mot muoi : Tnh theo 1 PTHH da vao so mol cua chat p het. Neu tao 2 muoi : at x, y la so mol moi muoi , Tnh theo 2 PTHH da vao x,y B4: Hoan thanh yeu cau cua e bai. Lu y : Neu e bai cho biet kiem d th luon tao muoi trung hoa, con oxit axit d th tao muoi axit. ---------------------------------
Chat can nhan biet dd axit dd kiem Axit sunfuric va muoi sunfat Axit clohiric va muoi clorua
Muoi cua Cu (dd
Xanh lam)
Dau hieu ( Hien tng) *Qu tm o *Qu tm xanh *Phenolphtalein hong *Co ket tua trang : BaSO4 *Co ket tua trang : AgCl *Ket tua xanh l : Cu(OH)2 *Ket tua trang xanh b hoa nau o trong nc :
* Ket tua nau o Fe(OH)3 *Ket tua keo tan c trong kiem d : Al(OH)3 ( trang , Cr(OH)3 (xanh
xam) Al(OH)3 + NaOH NaAlO2 + 2H2O
* Dung dch kiem, d * dd kiem, un nhe * dd AgNO3 * Axit manh * dd CuCl2, Pb(NO3)2 * Axit (HCl, H2SO4 )
* Nc voi trong
Muoi Amoni Muoi Photphat Muoi Sunfua Muoi Cacbonat va muoi Sunfit Muoi Nitrat Kim loai hoat ong Kim loai au day : K , Ba, Ca, Na Kim loai lng tnh: Al; Zn; Be; Cr Kim loai yeu : Cu, Ag, Hg ( thng li sau cng) Cac hp chat co kim loai hoa tr
NH3 Ag3PO4
*Kh mui trng thoi : H2S *Ket tua en : CuS , PbS *Co kh thoat ra : CO2 , SO2 ( mui hac) * Nc voi b uc: do CaCO3,
CaSO3
* ddH2SO4 ac / Cu * Dung dch axit * H2O * ot chay, quan sat mau ngon la
*Dung dch mau xanh , co kh mau nau NO2 *Co kh bay ra : H2 * Co kh thoat ra ( H2 ) , toa nhieu nhiet * Na ( vang ) ; K ( tm ) ; Li ( o ta ); Ca ( o cam) ; Ba (luc vang ) *Kim loai tan ra va co sui bot kh H2
( neu phai phan biet cac Kim loai nay vi nhau th chon thuoc th e phan biet cac muoi). V du : muoi tao ket tua vi NaCl la AgNO3 suy ra kim loai ban au la Ag.
*HNO3 ac
*Co kh bay ra :
Lu y : * Dung dch muoi cua Axit yeu va Baz manh lam qu tm hoa xanh ( V du: Na2CO3) * Dung dch muoi cua Axit manh va Baz yeu lam qu tm hoa o. ( V du : NH 4Cl ) * Neu A la thuoc th cua B th B cung la thuoc th cua A. * Dau hieu nhan biet phai ac trng va dau hieu ro rang, khong giong cac chat khac . -------------------------
3 e tang bang
Suy ra he so tam thi la : 1Fe + 3HNO3 1Fe(NO3)3 + 3NO2 + H2O Bu 3(NO3) cho ve trai ta c 6HNO3, suy ra he so cua nc la 3H2O Fe + 6HNO3 + 3NO2 + 3H2O Fe(NO3)3
TEN THNG GOI CUA MOT SO CHAT VOC Diem tieu: KNO3 Muoi an: NaCl a voi: CaCO3 Voi song: CaO Voi toi: Ca(OH)2 Thach cao song: CaSO4.2H2O Thach cao nung: 2CaSO4.H2O Thach cao khan: CaSO4 Quang : Hematic: Fe2O3 Quang Manhetic: Fe3O4 Quang pyric: FeS2 Qang cupit : Cu2S Diem sinh: S Xut : NaOH Potat: KOH Thach anh: SiO2 Oleum: H2SO4.nSO3