SOUTHWESTERN UNIVERSITY College of Arts and Sciences Department of Chemistry

QUALITATIVE AND QUANTITATIVE CHEMISTRY LECTURE Chem 3 Midterm Examination 1st semester
DIRECTION: Read and understand carefully. SHADE the letter of your choice COMPLETELY (covering the entire box). Use the separate sheet and DO NOT write anything on your questionnaire. Pencils are NOT allowed for shading. ERASURES in any form are NOT ALLOWED. Always choose the BEST answer. I: MULTIPLE CHOICE (2 points each) 1. Which of the following is NOT true about chemical reaction equation? a. Products are the substances that are formed during the chemical change b. Reactants are the substances that are present before the chemical change takes place c. Single direction arrow indicates reversible type of reaction d. Coefficients are placed before each participating substances and can be adjusted (2-4) Consider the following problem: When a solution of Barium nitrate, Ba(NO 3)2, is added to a solution of Potassium sulfate, K2SO4, 6.50 grams white precipitate of Barium sulfate, BaSO 4 (233.39 g/mol), form. Ba(NO3)2(aq) + K2SO4(aq) --------- BaSO4(s) + KNO3(aq) 2. Give the corresponding coefficients of the participating substances: a. 2, 1, 2, and 2 b. 1, 1, 1, and 2 c. 2, 1, 2, and 1 d. 2, 2, 2, and 4 3. How many grams of Barium nitrate (261.35 g/mol) are used up? a. 14.6 b. 7.28 c. 5.63 d. 3.64 4. How many grams of Potassium nitrate (101.11 g/mol) are produced? a. 11.27 b. 5.63 c. 2.81 d. 1.41 5. What quantity is a collection of atoms with a mass equal to the atomic weight in grams? The number of atoms in this quantity is 6.02 x 1023. a. Ion b. Compound c. Mole d. Molecule 6. The reaction: H2SO4 + 2NH4OH ------------ (NH4)2SO4 + 2H2O, is what type of metathesis reaction? a. Acid to salt b. Acid to base c. Salt to base d. Salt to salt (7 and 8) The magnesium (Mg) in a 50.00-mL sample of river water was determined by precipitating the cation as MgCO3. The precipitate was filtered, washed, and ignited in a crucible with an empty mass of 28.1200 grams. The mass of the crucible plus MgO (40.31 g/mol) was 30.0194 g. 7. What is the mass of Mg present in the amount of sample? a. 22.91 b. 4.980 c. 48.62 d. 1.150 8. What is the mass of MgO collected after the ignition of MgCO 3? a. 28.12 b. 30.02 c. 1.900 d. 2.00 9. Which among the following statements is NOT a step in determining the amount of mass product? a. Make use of the molar mass to calculate number of moles b. Make use of the molar mass to come up with a mass product c. Compare the moles of reactant and moles of product d. Use the Avogadros number to calculate for the number of moles (10 and 11) Consider the following problem: About 2.55 grams of silver nitrate (169.878 g/mol) and 1.97 grams of potassium iodide (166.0023 g/mol) are each dissolved in water

and combined. The solutions react to form a precipitate of silver iodide and an aqueous solution of potassium nitrate. AgNO3(aq) + KI(aq) ---------- AgI(s) + KNO3(aq) 10. How many grams of Silver iodide (234.772 g/mol) formed after the reaction? a. 3.10 b. 2.79 c. 2.96 d. 2.55 11. What is the ratio between the moles of Silver nitrate and Potassium iodide participating in the reaction? a. 2:2 b. 1:1 c. 2:1 d. 1:2 12. How many atoms of Fe (55.845 g/mol) are in a sample with a mass of 7.33 grams? a. 7.90 x 1022 b. 6.80 x 10-22 c. 2.18 x 1025 -25 d. 2.18 x 10 13. How many atoms of Oxygen are in a sample of C 12H22O11 (342 g/mol) with a mass of 9.74 grams? a. 6.11 x 10-20 b. 2.05 x 1023 c. 5.22 x 10-25 d. 1.89 23 x 10 14. How many grams can be produced from 4.65 x 10 21 Ca2+ ions? a. 0.12 b. 1.81 c. 0.31 d. 1.92 15. In balancing a chemical equation, a big number before the number is placed to balance the relative number of molecules, formula units, or moles of compound involved in the chemical reaction. What is this number? a. Avogadros number b. Molar Ratio c. Coefficient d. Subscript 16. Give the correct reaction equation of Magnesium phosphate solution reacts with hydrogen gas to form solid magnesium and phosphoric acid solution: a. Mg(PO4)2(aq) + H2(g) -------- Mg(s) + 2HPO4(aq) b. 2Mg3PO4(aq) + 3H2(g) -------- 6Mg(s) + 2H3PO4(aq) c. Mg3(PO4)2(aq) + 3H2(g) -------- 3Mg(s) + 2H3PO4(aq) d. MgPO4(aq) + H2(g) -------- Mg(s) + H2PO4(aq) e. None of the above 17. Calculate the amount of Hydrogen atoms there are in 4.28 grams of glucose (C 6H12O6) MW=180 g/mol: a. 2.40 x 10-2 b. 1.70 x 1023 c. 3.80 x 103 d. 1.40 x 1023 18. How many atoms of oxygen are participating in both sides for the reaction: (NH4)2SO4 + Al2S3 ----- (NH4)2S + Al2(SO4)3? a. 4 b. 8 c. 12 d. 16 19. Suppose a solution containing Na 3PO4 is mixed with a solution containing Ba(NO 3)2. Which of the following mole to mole ratio is CORRECT? a. 3 moles of Na3PO4 and 2 moles of Ba(NO3)2 is to 6 moles of Ba3(PO4)2 and 1 mole of NaNO3 b. 3 moles of Na3PO4 and 6 moles of Ba(NO 3)2 is to 2 moles of Ba 3(PO4)2 and 4 moles of NaNO3 c. 2 moles of Na3PO4 and 3 moles of Ba(NO 3)2 is to 1 mole of Ba3(PO4)2 and 6 moles of NaNO3 d. 2 moles of Na3PO4 and 3 moles of Ba(NO 3)2 is to 6 moles of Ba 3(PO4)2 and 2 moles of NaNO3 20. Which of the following statements BEST describes the Atomic weight of an element? a. The total mass of the atoms of an element taking into account the masses of the various isotopes and their relative abundance b. The average mass of the atoms of an element taking into account the masses of the various isotopes and their relative abundance c. The minimum mass of the atoms of an element taking into account the masses of the various isotopes and their relative abundance d. The maximum mass of the atoms of an element taking into account the masses of the various isotopes and their relative abundance 21. What is the formula weight of Ammonium sulfate in g/mol? (N=14.01;H=1.01;S=32.06;O=16) a. 98.06 b. 132.06 c. 114.06 d. 210.12 22. What sub-atomic particle do these isotopes differ in number? a. Electron b. Proton c. Neutron d. Orbital 23. Calculate the molecular weight of Ferrous sulfide in g/mol (Fe=55.845; S=32.06):

a. 55.85 b. 87.91 c. 207.87 d. 175.81 24. Give the correct reaction equation of Ferric nitrate solution reacts with sodium sulfide solution to form ferric sulfide precipitate and sodium nitrate solution: a. 2Fe(NO3)3(aq) + 3Na2S(aq) -------- Fe2S3(s) + 6NaNO3(aq) b. Fe2(NO3)3(aq) + 6NaS(aq) -------- 2FeS3(s) + 3Na2NO3(aq) c. 2FeNO3(aq) + Na2S(aq) -------- Fe2S(s) + 2NaNO3(aq) d. Fe2NO3(aq) + Na2S(aq) -------- Fe2S(s) + Na2NO3(aq) 25. Which of the following is a salt to base type of Metathesis reaction? a. NaBr + LiOH -------- NaOH + LiBr c. MgCO3 + HCl --------- MgCl2 + H2CO3 b. H2SO4 + NaOH -------- Na2SO4 + H2O d. Al2S3 + HI -------- AlI3 + H2S 26. Which of the following is NOT a salt to acid type of Metathesis reaction? a. HBr + LiF -------- HF + LiBr c. MgCO3 + HCl --------- MgCl2 + H2CO3 b. H2SO4 + NaNO3 -------- Na2SO4 + HNO3 d. Al2S3 + NaI -------- AlI3 + Na2S (27-30) Consider the following chemical reactions: I. CH3Br(g) + HCl(g) --- CH3Cl(g) + HBr(g) II. N2(g) + 3H2(g) ---- 2NH3(g) III. CaCO3(s) ----- CaO(s) + CO2(g) + H2O(g) IV. Zn(s) + 2HCl(aq) ----- ZnCl2(aq) + H2(g) 27. Which is a decomposition reaction? a. I b. II c. III d. IV 28. Which is a combination reaction? a. I b. II c. III d. IV 29. Which is a single displacement reaction? a. I b. II c. III d. IV 30. Which is a double displacement reaction? a. I b. II c. III d. IV (31-35) One of the steps in the commercial process for converting ammonia to nitric acid involves the conversion of NH3 to NO: 4NH3(g) + 5O2(g) --------- 4NO(g) + 6H2O (balanced) In a certain experiment, 2.500 grams of NH 3 (17 g/mol) reacts with 2.850 grams of O 2 (32 g/mol); 31. How many grams of NO (30 g/mol) formed? a. 2.910 b. 4.410 c. 4.860 d. 2.140 32. How many grams of H2O (18 g/mol) formed? a. 2.910 b. 4.410 c. 4.860 d. 2.140 33. Which of the following is NOT one of the products when CaC 2O4 undergoes decomposition reaction by ignition? a. CaO b. CO3 c. CO2 d. CO 34. What gaseous element will hydrogen gas combine to produce water molecule? a. IO2 b. O3 c . O2 d. N2 35. How many atoms of Fe are there in one molecule of Ferric oxide? a. 4 b. 2 c. 3 d. 1 36. What is the number of moles present in 25.0 grams NaCl (58.35 g/mol)? a. 2.33 b. 58.35 c. 25.0 d. 0.0983 37. What is the number of grams present in 0.0116 moles H 2CO3 (62 g/mol)? a. 10.33 b. 0.719 c. 15.0 d. 1.16 38. When sucrose, a table sugar, is heated in in intense flame; a black residue is produced and liquid water. What general type of reaction there occurred? a. Metathesis b. Synthesis c. Displacement d. Decomposition

39. Al metal reacts with HCl in this manner: 2Al(s) + 6HCl(aq) ----- 2AlCl3(aq) + 3H2(g). Why metal is able to displace hydrogen ion? a. It is more electronegative c. It is a stronger oxidizing agent b. It has greater ionic bond d. It is more reactive than H+ 40. What is the correct mole to mole ratio for this reaction: Al(OH) 3 + H2SO4 -- Al2(SO4)3 + H 2O a. 2, 3, 3, 1 c. 2, 3, 1, 6 c. 2, 2, 2, 3 d. 3, 2, 1, 3 II: ENUMERATION 1. Give at least 3 ways to decrease solubility of precipitates. 2. Give at least 3 sources of precipitate impurities. 3. Give at least 2 criteria of a precipitate. 4. Define digestion (2 points).

Cultivate contentment because what you say is enough will never be enough. -ANONYMOUS

Prepared by:

Ms. Aphryl Danril B. Demco Instructor