Академический Документы
Профессиональный Документы
Культура Документы
Centre
No.
Initial(s)
Paper Reference
6 2 4 2
Candidate
No.
0 1
Signature
Paper Reference(s)
6242/01
Edexcel GCE
Chemistry
Advanced Subsidiary
Unit Test 2
Wednesday 6 June 2007 Morning
Time: 1 hour
Question Leave
Number Blank
1
2
3
4
5
Instructions to Candidates
In the boxes above, write your centre number, candidate number, your surname, initial(s) and
signature.
Answer ALL the questions. Write your answers in the spaces provided in this question paper.
Show all the steps in any calculations and state the units.
Advice to Candidates
You are reminded of the importance of clear English and careful presentation in your answers.
You will be assessed on your Quality of Written Communication in this paper.
Total
This publication may be reproduced only in accordance with
Edexcel Limited copyright policy.
2007 Edexcel Limited.
Printers Log. No.
N26022A
W850/R6242/57570 7/7/7/3/23,100
Turn over
*N26022A0112*
Leave
blank
Answer ALL the questions. Write your answers in the spaces provided.
1.
*N26022A0212*
Q1
Leave
blank
2.
(a) Chlorofluorocarbons, CFCs, are useful compounds as they are non-flammable and
unreactive. In the stratosphere, the CCl bonds are broken producing free radicals.
(i) Draw the structure of 1,1,2-trichloro-1,2,2-trifluoroethane.
(1)
(ii) Suggest why CF bonds are not broken in the stratosphere, whereas CCl
bonds are.
................................................................................................................................
(1)
(iii) What are free radicals and what is needed to produce them from CFCs?
................................................................................................................................
................................................................................................................................
(2)
(b) (i) Draw the repeating units in
poly(chloroethene)
poly(tetrafluoroethene).
(2)
(ii) Give ONE important use of each of these polymers.
poly(chloroethene)
................................................................................................................................
poly(tetrafluoroethene)
................................................................................................................................
(2)
Q2
(Total 8 marks)
*N26022A0312*
Turn over
3.
(a) Name each of the following organic compounds and the homologous series to which
it belongs.
H H H
H H H H
HCCCH
HCCCCH
H O H
H
H H
HCH
HCH
H
Name ....................................................
Name ....................................................
(2)
(ii) Identify which of the two structural isomers of C2H2Cl2 can exist as geometric
isomers. Explain why geometric isomerism can occur.
Identity
Explanation
................................................................................................................................
................................................................................................................................
................................................................................................................................
(2)
4
*N26022A0412*
Leave
blank
Leave
blank
Q3
(Total 11 marks)
*N26022A0512*
Turn over
Leave
blank
4.
(a) When excess chlorine and methane are mixed at room temperature and pressure no
reaction takes place but when ultraviolet light is shone into the mixture an explosion
occurs, producing carbon and hydrogen chloride.
CH4(g) + 2Cl2(g)
uv
C(s) + 4HCl(g)
H = 219 kJ mol1
(2)
(b) Draw a labelled reaction profile for the reaction between methane and chlorine
and use it to explain why the reaction does not take place unless ultraviolet light is
present.
Enthalpy
Progress of reaction
Explanation
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
(5)
6
*N26022A0612*
Leave
blank
(c) Hydrogen gas is manufactured by passing methane and steam over a heated catalyst.
CH4(g) + H2O(g)
CO(g) + 3H2(g)
H = +206 kJ mol1
Q4
(Total 12 marks)
*N26022A0712*
Turn over
Leave
blank
5.
Substance
Standard enthalpy of
combustion /kJ mol1
394
hydrogen, H2 (g)
286
1371
(i) Complete the Hesss Law cycle by filling in the box and labelling the arrows with
the enthalpy changes.
H f
C2H5OH(l) + 3O2(g)
...........................
...........................
...........................
...........................
............................... + ...............................
(3)
*N26022A0812*
Leave
blank
(ii) Use your Hesss Law cycle to calculate the standard enthalpy of formation of
ethanol.
(2)
(c) Ethanol, C2H5OH, can be converted into propanenitrile, CH3CH2CN in two steps.
Step 1
C2H5OH
Step 2
C2H5I
CH3CH2CN
Q5
(Total 11 marks)
*N26022A0912*
Turn over
Leave
blank
6.
The first step in the manufacture of nitric acid is the catalytic oxidation of ammonia. The
reaction is usually carried out at 900 C.
(a) (i) Balance this equation.
..........NH3 + ..........O2
..........NO + ..........H2O
H = 900 kJ mol1
(1)
*N26022A01012*
Q6
BLANK PAGE
*N26022A01112*
11
12
*N26022A01212*