Before Mixing

0.287

kJ/kgK

Before Mixing

Vessal A
P1A
bar
0.05
0.05
0.05
0.05
0.05
0.05
0.05

V1A
m3
0.012
0.012
0.012
0.012
0.012
0.012
0.012

T1A
degC
37.2
38.3
37.1
38.2
38.5
37.8
39.1

T1A
K
310.2
311.3
310.1
311.2
311.5
310.8
312.1

m1A
PV/(RT)
kg
0.000674
0.000672
0.000674
0.000672
0.000671
0.000673
0.000670

Initial
P1g
bar
0.4
0.2
0
-0.2
-0.4
-0.6
-0.8

0.020

P1B
bar
1.4
1.2
1
0.8
0.6
0.4
0.2

Chart

R = 0.9413

0.015

0.010

0.005

0.000
0.000

0.002

0.004

0.006

0.008

P1V1/RT1

0.010

0.012

0.014

After Mixing

Vessal B

0.025

P2V2/RT2

Initial
P1g
bar
-0.950
-0.950
-0.950
-0.950
-0.950
-0.950
-0.950

X-axis
m1=m1B

Y-axis
m2 Expt

kg
0.011133
0.009562
0.007976
0.006395
0.004801
0.003206
0.001604

kg
0.021341
0.016422
0.013906
0.012908
0.012332
0.008242
0.003992

V1B
m3
0.007
0.007
0.007
0.007
0.007
0.007
0.007

T1B
degC
33.7
33.1
32.8
32.1
31.8
31.3
31.2

T1B
K
306.7
306.1
305.8
305.1
304.8
304.3
304.2

m1B
PV/(RT)
kg
0.01113
0.009562
0.0080
0.006395
0.004801
0.003206
0.00160

Final
P2Ag
bar
-0.004
-0.225
-0.335
-0.379
-0.410
-0.586
-0.774

Vessal A
P2A
bar
0.996
0.775
0.665
0.621
0.59
0.414
0.226

After Mixing
V2A
m3
0.012
0.012
0.012
0.012
0.012
0.012
0.012

T2A
degC
32.2
31.7
31.8
31.7
31.9
31.5
31.6

T2A
K
305.2
304.7
304.8
304.7
304.9
304.5
304.6

mA
PV/(RT)
kg
0.013645
0.010635
0.009122
0.008522
0.008091
0.005685
0.003102

Final
P2Bg
bar
-0.007
-0.242
-0.370
-0.418
-0.441
-0.646
-0.853

Vessal B
P2B
bar
0.993
0.758
0.63
0.582
0.559
0.354
0.147

After Mixing
V2B
m3
0.007
0.007
0.007
0.007
0.007
0.007
0.007

T2B
degC
38.8
40.3
38.7
39.3
38.9
39.4
41.0

T2B
K
311.8
313.3
311.7
312.3
311.9
312.4
314

mB
PV/(RT)
kg
0.007768
0.005901
0.00493
0.004545
0.004371
0.002764
0.001142

Final A+B
P2M
bar
0.9945
0.7665
0.6475
0.6015
0.5745
0.384
0.1865

V2
m3
0.019
0.019
0.019
0.019
0.019
0.019
0.019

T2M
K
308.5
309
308.25
308.5
308.4
308.45
309.3

PV/(RT)
kg
0.021341
0.016422
0.013906
0.012908
0.012332
0.008242
0.003992

Before Mixing
R

0.287

kJ/kgK

Initial
P1g
bar
-0.950
-0.950
-0.951
-0.949
-0.952
-0.951
-0.950

Vessal A
P1A
bar
0.05
0.05
0.049
0.051
0.048
0.049
0.05

V1A
m3
0.012
0.012
0.012
0.012
0.012
0.012
0.012

T1A
degC
30.6
30.4
30.8
30.7
30.9
30.9
30.7

T1A
K
303.6
303.4
303.8
303.7
303.9
303.9
303.7

m1A
PV/(RT)
kg
0.000689
0.000689
0.000674
0.000702
0.000660
0.000674
0.000688

Before Mixing

Chart
X-axis

Y-axis

m1=m1A+m1B

m2 Expt

kg
0.011815
0.010252
0.008696
0.006981
0.005392
0.003850
0.002252

kg
0.012443
0.010745
0.008945
0.007188
0.005441
0.003773
0.001412

0.011815
0.010252
0.008696
0.006981
0.005392
0.003850
0.002252

Initial
P1g
bar
0.4
0.201
0.01
-0.211
-0.405
-0.601
-0.804

Vessal B
P1B
bar
1.4
1.201
1.01
0.789
0.595
0.399
0.196

V1B
m3
0.007
0.007
0.007
0.007
0.007
0.007
0.007

T1B
degC
33.9
33.3
34.1
33.5
33.7
33.4
32.8

T1B
K
306.9
306.3
307.1
306.5
306.7
306.4
305.8

m1B
PV/(RT)
kg
0.011126
0.009563
0.008022
0.006279
0.004732
0.003176
0.001563

0.014

0.012

0.010

Green Line shows

P1V1/(RT1) = P2V2/(RT2)

P2V2/RT2

0.008

0.006

0.004

0.002

0.000
0.000

0.002

0.004

0.006

0.008

P1V1/RT

0.010

0.012

0.014

After Mixing
Final
P2Ag
bar
-0.407
-0.482
-0.561
-0.638
-0.715
-0.788
-0.861

Vessal A
P2A
bar
0.593
0.518
0.439
0.362
0.285
0.212
0.139

V2A
m3
0.012
0.012
0.012
0.012
0.012
0.012
0.012

T2A
degC
32.8
32.4
32.4
32.1
31.8
31.8
31.3

T2A
K
305.8
305.4
305.4
305.1
304.8
304.8
304.3

mA
PV/(RT)
kg
0.008108
0.007092
0.00601
0.004961
0.00391
0.002908
0.00191

After Mixing
Final
P2Bg
bar
-0.444
-0.527
-0.614
-0.699
-0.783
-0.864
-0.945

Vessal B
P2B
bar
0.556
0.473
0.386
0.301
0.217
0.136
0.055

After Mixing
V2B
m3
0.007
0.007
0.007
0.007
0.007
0.007
0.007

T2B
degC
32.5
32.2
32.2
32.5
33
32.8
332.4

T2B
K
305.5
305.2
305.2
305.5
306
305.8
605.4

mB
PV/(RT)
kg
0.004439
0.00378
0.003085
0.002403
0.00173
0.001085
0.000222

Final A+B
P2M
bar
0.5745
0.4955
0.4125
0.3315
0.251
0.174
0.097

V2
m3
0.019
0.019
0.019
0.019
0.019
0.019
0.019

T2M
K
305.65
305.3
305.3
305.3
305.4
305.3
454.85

PV/(RT)
kg
0.012443
0.010745
0.008945
0.007188
0.005441
0.003773
0.001412

Before Mixing
R

0.287

kJ/kgK

Initial
P1g
bar
-0.952
-0.952
-0.952
-0.953
-0.953
-0.953
-0.952

Vessal A
P1A
bar
0.048
0.048
0.048
0.047
0.047
0.047
0.048

V1A
m3
0.012
0.012
0.012
0.012
0.012
0.012
0.012

T1A
degC
28.1
28.4
28.6
29.1
28.9
29.1
29.4

T1A
K
301.1
301.4
301.6
302.1
301.9
302.1
302.4

m1A
PV/(RT)
kg
0.000667
0.000666
0.000665
0.000650
0.000651
0.000650
0.000664

Before Mixing

Chart
X-axis

Y-axis

m1=m1A+m1B
P1B

m2-m1

1.405
1.205
0.993
0.795
0.596
0.399
0.196

0.000819
0.000740
0.000617
0.000420
0.000327
0.000247
0.000148

Vessal B
P1B
bar
1.405
1.205
0.993
0.795
0.596
0.399
0.196

V1B
m3
0.007
0.007
0.007
0.007
0.007
0.007
0.007

T1B
degC
35.4
35.1
35.1
35.3
34.9
35.1
35.0

T1B
K
308.4
308.1
308.1
308.3
307.9
308.1
308.0

0.000900
0.000800
0.000700

Mass final - mass initial

kg
0.011778
0.010205
0.008526
0.006940
0.005372
0.003809
0.002216

Initial
P1g
bar
0.405
0.205
-0.007
-0.205
-0.404
-0.601
-0.804

0.000600
0.000500
0.000400
0.000300
0.000200
0.000100
0.000000
0.0

0.2

0.4

0.6

0.8

P1B

1.0

1.2

1.4

1.6

After Mixing
m1B
PV/(RT)
kg
0.011112
0.009539
0.007861
0.006289
0.004721
0.003159
0.001552

Final
P2Ag
bar
-0.4
-0.473
-0.553
-0.632
-0.706
-0.779
-0.854

Vessal A
P2A
bar
0.6
0.527
0.447
0.368
0.294
0.221
0.146

V2A
m3
0.012
0.012
0.012
0.012
0.012
0.012
0.012

T2A
degC
30.7
30.6
30.5
30.6
30.1
30.1
30

Mass initial & mass final are calculated assuming the Ideal Gas Law
mass initial = P1A*VA/(R*T1A) + P1B*VB/(R*T1B)
mass final = P2A*VA/(R*T2A) + P2B*VB/(R*T2B)

T2A
K
303.7
303.6
303.5
303.6
303.1
303.1
303

mA
PV/(RT)
kg
0.008260
0.007258
0.006158
0.005068
0.004056
0.003049
0.002015

After Mixing
Final
P2Bg
bar
-0.454
-0.536
-0.624
-0.711
-0.793
-0.873
-0.956

Vessal B
P2B
bar
0.546
0.464
0.376
0.289
0.207
0.127
0.044

V2B
m3
0.007
0.007
0.007
0.007
0.007
0.007
0.007

T2B
degC
34.1
33.9
34.2
34.5
34.2
34.5
34.6

T2B
K
307.1
306.9
307.2
307.5
307.2
307.5
307.6

mB
PV/(RT)
kg
0.004336
0.003688
0.002985
0.002292
0.001643
0.001007
0.000349

mA+mB
0.012597
0.010945
0.009143
0.007360
0.005699
0.004056
0.002364