RESONANCE RJPT1SOL270311-1

Hints & Solution

DATE : 27-03-2011 CLASS-XII/XIII
PAPER-1
PART-I (Chemistry)
1. At pressure less than 1 atm, conversion of ice into water is non
spontaneous.
2. (i) Higher the critical temperature of a gas, the more easily it will
be liquified and therefore, more readly it will be absorbed on the
solid. T
C
(NH
3
) > T
C
(H
2
)
(ii) The movement of collodial particles towards the oppositely
charged electrodes on passing electric current is known as
Electrophoresis.
3. At nodal surface,
+
2s
2
= 0 r =
Z
2
=
2
2
= 1
4. As value of n i.e. principal quantum number increases, the size
of atom increases and the distance between valence electrons
and nucleus increases. As a result, the attraction between the
valence electrons and nucleus decreases. This fascilitates the
easier removal of valence electrons.
5. (i) O
2
=
2
6 10
= 2; O
2
+
=
2
5 10
= 2.5
O
2

=
2
7 10
= 1.5; O
2
2
=
2
8 10
= 1
Bond strength Bond order
(ii) o1s
2
o*1s
2
o2s
2
o*2s
2
t2px
2
= t2py
2
; C C
(iii) Mixing of 2s-2p orbitals takes place in N
2
, B
2
and C
2
moleucles. No mixing of 2s-2p orbitals occurs in O
2
molecule.
(iv) N
2
, CO and NO
+
having 14 electrons possess bond order 3.
6. [Ti(CO)
6
]
2
has the metal with the smallest nuclear charge and
thus the weakest ability to attract electrons. The titanium in
[Ti(CO)
6
]
2
with the most negative formal charge, has the
strongest tendency to donate to CO.
7. (A) Cu + 2H
2
SO
4
(conc.) CuSO
4
+ 2H
2
O + SO
2
(B) 3S + 2H
2
SO
4
(conc.) 3SO
2
+ 2H
2
O
(C) KBr + H
2
SO
4
(conc.) KHSO
4
+ HBr ;
2HBr + H
2
SO
4
(conc.) 2H
2
O + Br
2
+ SO
2
(D) NH
4
ClO
4
+ H
2
SO
4
(conc.) NH
4
+
+ HSO
4

+ HClO
4
8.

+
H







Br

9. Benzil-belzilic acid rearrangement :


OH


JEE PREPARATORY TEST-1 (JPT-1)
TARGET IIT-JEE 2011
Nitro substituted benzene ring is more reactive for nucleophile.
10.
4
LiAlH
CH
2
NH
2
11. Given,Au Au
+
+ 1e

; E

1
= 1.68 V (i)
Au Au
3+
+ 3e

; E

2
= 1.50 V (ii)
By substracting eq. (ii) from eq. (i) a third half cell reaction can
be obtained as :
Au
3+
+ 2e

Au
+
AG = AG
1
AG
2
E =
n
E n E n
2 2 1 1

=
2
) 50 . 1 ( 3 ) 68 . 1 ( 1
=
2
68 . 1 50 . 4
= 1.41
2Fe
+2
2Fe
+3
+ 2e

+ + 2 3
Fe / Fe
E
= +0.77 V
Au
3+
+ 2e

Au
+
+ +
Au / Au
3
E
= 1.417 V
Net reaction :
2Fe
+2
(aq.) + Au
+3
(aq.) 2Fe
+3
(aq.) + Au
+
(aq.)
E
cel
= E
cathode
E
anode
= 1.41 0.77 = 0.64
E
cel
> 0. The reaction is spontaneous in standard
condition.
E
cel
=
2
591 . 0
log k
c
log k
c
=
0591 . 0
2 64 . 0
= 21.65
k
c
= 10
22
12. (A) AIN + 3H
2
O Al(OH)
3
+ NH
3
;
CaCN
2
+ 3H
2
O CaCO
3
+ 2NH
3
(B) Ca + 2H
2
O Ca(OH)
2
+ H
2
;
CaH
2
+ H
2
O Ca(OH)
2
+ H
2
(C) 2F
2
+ 2H
2
O 4HF + O
2
;
6XeF
4
+ 12H
2
O 2XeO
3
+ 24HF + 4Xe + 3O
2
(D) 2K + 2H
2
O 2KOH + H
2
;
2KO
2
+ 2H
2
O 2KOH + H
2
O
2
+ O
2
13. (C) Iron is obtained from Fe
2
O
3
by heating Fe with a mixture of
coke and CaCO
3
in a blast furnace in which CO formed reduce
Fe
2
O
3
to Fe.
Fe
2
O
3
+ CO Fe + CO
2
(D) KCl.MgCl
2
.6H
2
O (K
2
MgCl
4
.6H
2
O)
15.
CHO
|
CHO
reaction cannizaro
r ramolecula int
NaOH . conc

COO
|
OH CH
2
+
H
COOH
|
OH CH
2

A
Sol. (16 to 17)
For AgCl, [Ag
+
] =
] Cl [
AgCl K
sp

=
01 . 0
10
10
= 10
8
M
RESONANCE RJPT1SOL270311-2
For Ag
2
CrO
4
,
[Ag
+
] =
] CrO [
CrO Ag K
2
4
4 2 sp
=
02 . 0
10 4
14

=
12
10 2

= 1.41 10
-6
(1) Since required Ag
+
is smaller for AgCl
Cl

ion will precipitate first

(2) [Ag
+
] = 10
8
M
(3) [Cl

] =
6
10
10 2
10

=
2
10
4
% =
01 . 0
2
10
01 . 0
4
|
|
.
|

\
|

100 = 99.3 %
18. [Co(NH
3
)
5
H
2
O]Cl
3
(pink) [Co(NH
3
)
5
H
2
O]
3+
+ 3Cl

1 : 5 : 1
3Ag
+
+ 3Cl

3AgCl+ (white)
The following complex is obtained on heating and losing 1 mole
of H
2
O.
[Co(NH
3
)
5
Cl]Cl
2
(purple) [Co(NH
3
)
5
Cl]
2+
+ 2Cl

1 : 5 : 1
2Ag
+
+ 2Cl

2AgCl+ (white)
So, pink (X) is [Co(NH
3
)
5
(OH
2
)]Cl
3
and IUPAC name would be
pentaammineaquacobal t(III) chl oride and purple (Y) i s
[Co(NH
3
)
5
Cl ]Cl
2
and IUPAC name woul d be
pentaamminechloridocobalt(III) chloride.
19. (X) [Co(NH
3
)
5
(H
2
O)]Cl
3
and [Co(NH
3
)
5
Cl]Cl
2
.H
2
O are hydrate
isomers. Complex (Y), [Co(NH
3
)
5
Cl]Cl
2
does not show ionization
as well as hydrate isomerism.
The effective atomic number of Co in both complexes
= 27 3 + 12 = 36
In both complexes, the cobalt is in +3 oxidation state with 3d
6
el ectron confi gurati on. Both compl exes are, therefore,
diamagnetic and inner orbital complexes (i.e. d
2
sp
3
hybridisation
of Co(III) in both complexes).
21.
Fe , Br
2

O Et / Mg
2

22. no. of tetrahedral voids = 8 ; no of octahedral voids = 4
so formula = AB
2
O
4
23.

1
= RZ
2

(
(

2
2
2
1
n
1
n
1
x
1
= R1
2
(

1
1
1
2
..... (i)

1
= R2
2
(

2 2
3
1
2
1
..... (ii)
From (i) and (ii)
=
4 ) 4 9 (
9 4 x


=
5
x 9
24.
25. 3MnSO
4

+

2KClO
3

+6Na
2
CO
3

3Na
2
MnO
4

+

2KCl

+

3Na
2
SO
4

+

6CO
2
|
PART-II (Mathematics)
28. Let m be a positive integer for which n
2
+ 96 = m
2
m
2
n
2
= 96 (m + n)(m n) = 96
(m + n) {(m + n) 2n} = 96
If m + n even then m n = (m + n) 2n must be even
m + n and m n must be both even
As 96 = 2 48 or 4 24 or 6 16 or 8 12, hence
number of solutions is 4.
29. |(x 2) + i(y 1)| = |z| u u sin
2
1
cos
2
1
where u = arg z.
2 2
) 1 y ( ) 2 x ( + =
2
1
| x y | which is a parabola.
30. [cos
1
x] > 0 x e [1, 1] and [cot
1
x] > 0 x e R
Hence [cos
1
x] + [cot
1
x] = 0
[cos
1
x] = [cot
1
x] = 0
If [cos
1
x] = 0 x e (cos 1, 1]
If [cot
1
x] = 0 x e (cot 1, )
x e (cot 1, 1]
31. Given parabola is x
2
= 4y
its focus S(0, 1)
tangent at (6, 9) is 6x = 2(y + 9)
3x = y + 9 3x y 9 = 0
Equation of circle (x 6)
2
+ (y 9)
2
+ (3x y 9) = 0
it passes through (0, 1) so 36 + 64 + (10) = 0
10 = 100 = 10
Required circle is
x
2
12x + 36 + y
2
18y + 81 + 30x 10y 90 = 0
x
2
+ y
2
+ 18x 28y + 27 = 0
r =
27 196 81 +
= 10 5
32. According to the equation
dt
dy
= y k
} }
=
t
0
0
4
dt k
y
dy

0
4
y 2 = kt =
15
t
0 4 =
15
t
t = 60 minutes
33. Let o be the common root
o
4
+ 2o
3
8o
2
6o + 15 = 0
o
3
+ 4o
2
o 10 = 0
Given equations are
(o
2
3) (o
2
+ 2o 5) = 0 & (o + 2) (o
2
+ 2o 5) = 0
for common roots o
2
+ 2o 5 = 0
Product of uncommon real roots is (3) (2) = 6
34.
dx
dy
+ k = 11
dx
dy
= 11 k

} }
= dx ) k 11 ( dy
= (11 k) x + c
curve passes through (0, 0)
c = 0
RESONANCE RJPT1SOL270311-3
where k =
}
3
0
dx y = always be constant.
k =
}
3
0
dx x ) k 11 ( , k = 9
y = 2x, if it is passes through (a, b) b = 2a
ways 5
10 5
8 4
6 3
4 2
2 1
b a

a and b can be chosen in 1010 = 100 ways

Probability that given curve passes through (a, b)=
100
5
=
20
1
35. Suppose the origin lies outside the triangle with vertices A(z
1
),
B(z
2
) and C(z
3
)
Let line
0 z a z a = +
be a line through the origin such that all
the three points A,B and C lie on one side of the line.
suppose A,B and C lie in the half plane
0 z a z a > +
dividing by both side by |z|
2
we get
z
a
z
a
+ > 0
we have
i i
z
a
z
a
+
> 0 for i = 1,2,3

|
|
.
|

\
|
+ +
3 2 1
z
1
z
1
z
1
a + a |
|
.
|

\
|
+ +
3 2 1
z
1
z
1
z
1
> 0
Thus
3 2 1
z
1
z
1
z
1
+ +
= 0
This is against the hypothesis
Hence origin lies inside the triangle.
36. Taking P(x
1
, y
1
) we get
Pair of tangents
(x
1
2
+ y
1
2
1) (x
2
+ y
2
1) (xx
1
+ yy
1
1)
2
= 0
Putting x = 1 and solving the quadratic equation in y, the differ-
ence of roots is 2.
Hence locus of P is y
2
= 2(x + 1) which is parabola.
37. Eccentricity of ellipse =
2
1
dt
de
= 0.1 given
eccentricity of auxiliary circle = 0
}
0
2 / 1
de
= 0.1 }
T
0
dt
T is time at which it will touch the auxiliary circle

2
1
= 0.1 (T 0) T = 5 seconds
38. Since OQ = 1 and OP = 2, so sin(ZOPQ) = 1/2 and hence ZQPR
=
3
t
. Then APQR is equilateral. Also, OM QR. Then from
AOMQ, OM = 1/2. Then centriod of APQR lies on |z| = 1.
As PQR is an equilateral triangle, so orthocentre, circumcentre
and centriod will coincide. Now,
3
z z z
3 2 1
+ +
= 1
|z
1
+ z
2
+ z
3
|
2
= 9
(z
1
+ z
2
+ z
3
) ) z z z (
3 2 1
+ + = 9

|
|
.
|

\
|
+ +
3 2 1
z
1
z
1
z
4
|
|
.
|

\
|
+ +
3 2 1
z
1
z
1
z
4
= 9
and ZQOR = 120
39. f(x) + f(x) = 2 + 6x
2
f(2) + f(2) = 2 + 24 = 26
f(2) = 26 f(2) = 26 32 = 6
40. Since the greatest integer function [x] is discontinuous (sensi-
tive) at integral values of x, then for a given limit to exist both left
and right-hand limit must be equal.
L.H.L. =

1 x
lim
(2 x + a[x 1] + b[1 + x])
= 2 1 + a(1) + b(1) = 1 a + b
R.H.L. =
+
1 x
lim
(2 x + a[x 1] + b[1 + x])
= 2 1 + a(0) + b(2) = 1 + 2b
On comparing we have a = b
41. AB + BC = AC
AB =
| u |
u 2

| u |
u

+
| v |
v

=
| u |
u

+
| v |
v

AB . BC = |
|
.
|

\
|
| v |
v

| u |
u

. |
|
.
|

\
|
+
| v |
v
| u |
u

= 1 1 = 0
ZB = 90
1 + cos2A + cos2B + cos2C = 0
42. c . a

c a

cos |
.
|

\
|
4
1
cos
1
c . a

=
4
1
..............(i)
taking dot product by a

, b

, c

we have b . a

2( c . a

) = k ( a . a

)
b . a

2
1
= k b . a

= k +
2
1
.........(ii)
RESONANCE RJPT1SOL270311-4
Similarly c . b

= 8
2
k
2

4
k
.................(iii)
and c . b

2 = k( c . a

) .................(iv)
from (ii), (iii) and (iv) we get
8
2
k
2

4
k
2 = k
|
.
|

\
|
4
1
k = 3, 4
43. g(f(x)) is not defined if
(i) 2 + a > 8 and (ii) b + 3 > 8
a > 10 and b > 5
44. x e [1, 2] 1 s x s 2
2 s 2x s 4 2 + a s 2x + a s 4 + a
2 + a s 2 and 4 + a s 4 , i.e. a = 0
b can take any value
45. As second row of all the options is same, we are to look at the
elements of first row. Let the left inverse be (

f
c
e
b
d
a
. Then
(

f
c
e
b
d
a
(
(
(

3
1
1
2
1
1
= (

1 0
0 1
a + b + 2c = 1 i.e. b =
2
c 5 1
, a =
2
c 1+
Thus matrices in the option (a), (b) and (d) are the inverse and
matrix in option (c) is not the left inverse.
46. Let right inverse be
(
(
(

f
d
b
e
c
a
. Then,
(

1
2
1
1
2
1

(
(
(

f
d
b
e
c
a
= (

1 0
0 1
now , a c + 2e = 1
b d + 2f = 0
2a c + e = 0
2b d + f = 1
This system of equations has infinite solutons.
47. y' = y + c, where c = }
1
0
dx ) x ( y
c y
dy
+
= dx
) c y ( n + = x + d
y(0) = 1 ) c 1 ( n + = d
y = (1 + c) e
x
c
c =
}
1
0
dx y = (1 + c)(e 1) c
c =
e 3
1 e
, 1 + c =
e 3
2
y(x) =
e 3
e 1 e 2
x
+
y' (x) =
e 3
e 2
x
> 0
y(x) increases and has no local maxima no local minima
48. Subnormal = y(0). y'(0) =
e 3
2
49. If (variable)
variable
and base is negative then limit does not exist
and
4
4 x
) 6 x ( lim

= 16.
50. By repeated differentiation y
2
= 4a(x + h)
yy
1
= 2a yy
2
+ y
1
2
= 0
degree is 1 and order 2
51. f(x
n
) is divisible by x 1 f (1)
n
= 0 by factor theorem
by factor theorem
f(1) = 0
Put x
n
= y , we have f(x
n
) = f(y) and f(1) = 0
Thus f(y) is divisible by y 1
f(x
n
) is divisible by x
n
1
52. 16x
2
9y
2
32x 128 = 0 can be written as
9
) 1 x (
2

16
y
2
= 1 so (1, 0) is centre
No any tangent can be drawn from (1, 0)
53. Since tan
1
x increasing function and
4
t
< tan1 tan
1

4
t
< 1.
54. Required probability =
1
5
1
3
C
C
=
5
3
PART-III (Physics)
55. Reading = main scale reading + vernier scale reading
= 5.0 + 0.08 = 5.08 cm.
56. The angular momentum of earth will remain conserved. Since
moment of inertia will reduce to one fourth the new angular
speed of the earth will become four times the old angular speed
e while the angular speed of the satellite will not change. The
relative angular speed will become 3e and hence it will take
three times less time to complete the cycle w.r.t earth.Since
earth moves from west to east, the satellite will be seen to move
in opposite direction i.e, westward with time period
e
t
3
2
=
( ) . hrs 24
3
1 2
3
1
= |
.
|

\
|
e
t
= 8 hrs.
57.

Ad
dE
E
=
9
6
10 01 . 0
5
10 2

= 4 x 10
4
.
58. Applying snells law at C
1 sin i = sinr
or 1 sin 60
0
= 3 sin r
or
r sin 3
2
3
=

(2,5 ) 3
(5,0)
(60)
0
X axis
Y axis
B
E
C
A
D
r = 30
AC = 3 tan30
0
=
3
BD =
3 4 DE =
3 4
cot60
0
= 4
coordinate of point E=(9,0)
RESONANCE RJPT1SOL270311-5
59. Let the actual distance between the hook and the point A be d,
then from the relation
rel
n
d
d = '

3 / 4
d
3 =
or d = 4m. The time
taken to lower the hook by 4 m = 4/1 = 4 sec.In 4 sec the fish
moved a distance 1m. So the speed of the fish is 0.25 m/s.
60. Here the charges on the outer surfaces do not produce any
electric field between the plates and hence do not contribute in
making any potential diference between the plates.
C =
V
Q
=
12
24
= 2.
61. Binding energy = total energy of the satellite
=
(
(

2
mv
r
GMm
2
=
r 2
GMm
=
2
mgr
.
62. Torque about (0,0,0) = ) j 3 i 2 ( ) k

3 i ( F r
. . .
+ + =

=
) i ( 9 ) j ( 6 k 3
. . .
+ + +
A vector along the axis can be found by joining two pointss
lying on the line such as (0, 0) and (1, 3) . The vector can be
j

3 i

r + =

. Now we have to find the component of the torque

along r

i.e.,
r
r . t
=
10
9
.
63. V
R
2
= V
S
2
V
L
2
= 200
2
100
2
= 30000
The average power consumption in the circuit
=
R
V
2
R
= 3000 W = 3 KW..
64. Kinetic energy of product particles
= T
o
+ T
Y
= T
o
+
200
4
T
o
=
50
51
T
o
The excitation energy of the daughter nuclei = difference in
KE of product particles in the two cases
=
50
51
AT
o
=
50
51
x 0.4 = 0.408.
65.
N
F
mg
The FBD of the rod and the ball are shown. Applying t = Io about
the C.M of the rod, we have,
N
|
.
|

\
|
2

=
|
|
.
|

\
|
12
M
2

o
Writing newtons IInd law in the vertical direction on the CM of the
rod we have
T N 2mg = 0
and writing newtons II law in the vertical direction on the ball we
have
m g N= m
|
.
|

\
|
2

o
Solve these equations.
66. The relation between the stopping potential and the frequency
is hv = eV
S
+ | or V
S
=
e
h
v
e
|
From the graph slope =
a
b

a
b
=
e
h
h =
e
ab
From the graph y intercept = b
b =
e
|
| = b e
67. Let the normal force between the block and the ball be N.
M
N
a

mg
N
ma(pseudo force)
For the block, from Newtons II
nd
law , we have N = Ma = 2ma
For ball (with respect to the block), from Newtons II
nd
law , we
have N + ma =
R
mv
2
Solve the two equations.
68. The stress is max at the uppermost point and is equal to the
weight of the rod divided by the area.At the highest point stress
= breaking stress = o = weight of rod/area of cross section of
the rod =
A
g AL
= Lg L =
g
o
.
The stress decreases linearly to zero at the lowest end.
69. Before filling the dielectric medium the equivalent capacitance of
the circuit is C
i
=8/3 F .
After filling the dielectric medium the equivalent capacitance of
the circuit is C
f
=4 F
Aq = AC V = (48/3) 12 = 16 C.
Energy taken from the cell= charge flown through the cell x cell
voltage= 16x12 =192 J
U
i
=
2
1
CV
2
=
|
.
|

\
|
2
1
x
3
8
x 12
2
=192 J
U
f
=
2
1
CV
2
=
|
.
|

\
|
2
1
x 4 x 12
2
= 288 J.
Therefore increase in electrostatic energy stored in the
capacitors = 96 J.
Sol.(70 to 71)
Let the thermal energy produced be Q. As given 20% of Q is
used to increase the temperature by 1K .
0.2 Q = msAT = (20 + 80) 10
-3
4200 x 1 = 420 J
Q = 2100J.
Work done against friction in 2 min = f x 5 x 2 x 60
or 2100 = f x 5 x 2 x 60
f =3.5 N
But f = (total mass of beaker and water)g
3.5 = 0.1(total mass of beaker and water)g
total mass of beaker and water = 3 .5 kg
Mass of beaker = 3.5 0.08 = 3.42 kg
Sol.(72 to 73)
Intensity of radiations at a distance

from the point source I
=
2
4
P
t
where P = 4tr
2
o T
4
RESONANCE RJPT1SOL270311-6
Power falling on the hole of the cavity
=
4
d
2
t I
=
2
4
P
t 4
d
2
t
=
2
2
16
d P

=
2
4 2 2
4
T r d

o t
Let the temperature of the cavity be T'', the amount of radiation
falling from inside the cavity on the hole will be
4
1
td
2
o T''
4
. Equating the two powers we get,
2
4 2 2
4
T r d

o t
=
4
1
td
2
o T''
4
T''

= T

r
Sol.(74 to 75)
Since BC is shorted , potential difference across BC is zero.
Voltmeter reading= V
AB
+ V
B C
= V
AB
= 8Volt (given)
Since length CD = 2 x length AB, V
CD
= 2 x V
AB
= 16 Volt
Therefore emf of cell = V
AB
+ V
B C
+ V
CD
= 8 + 0 + 16 = 24 Volt
On removing the resistanceless wire connecting B and C.
AC = 40 cm, CD = 20 cm, R
AC
= 2R
CD
V
AC
= 2V
CD
V
AC
+ V
CD
= 24
V
AC
= 16
80. Slope =
Strain
Stress
= Y
PAPER-2
PART-I (Chemistry)
1. Cell reaction lsy vfHkf;k H
2
+ 2Ag
+
2H
+
+ 2Ag
E
cell
= (0 + 0.8)
2
059 . 0
log
2
H
2
2
p ] Ag [
] H [

+
+
[H
+
]
2
= Ka C = 10
6
10
2
E
cell
= 0.8
2
059 . 0
log
2 2
8
) 10 (
10

= 0.8 + 2 0.059 = 0.918 volt

2. 0 30
30 20 15
k =
30
1
2.3 log
) 15 ( 20
) 15 ( 30


=
30
1
2.3 log
35
45
t
1/2
= 75 min
k =
t
1
2.3 log
) 15 ( 0
45

t = 120 min
) 15 ( x
) 15 ( 30


= 2 at half time

15 x
45
+
= 2 x + 15 =
2
45
x = 22.5 15 = 7.5
3. X
3
NaNO
NaOH

Na
2
XO
2
+ NH
3

4 2
SO H M 11 . 0 , ml 100
(NH
4
)
2
SO
4
+
) cess x e (
SO H
4 2

req
Excess
48 ml of 0.25M NaOH
Now, Reactions involved for part (i)
X

XO
2
2
NO
3


NH
3
On balancing above equation in basic medium we get
4X + NO
3
+ 7OH

4XO
2
2
+ NH
3
+ 2H
2
O ... (1)
10 mm
2NH
3
+ H
2
SO
4


(NH
4
)
2
SO
4
... (2)
(5mm) reacted
) moles m 6 (
) excess (
SO H
4 2 +
moles m 12
25 . 0 48
NaOH 2
=


Na
2
SO
4
+ 2H
2
O ... (3)
( Total m moles of H
2
SO
4
= 11)
m moles of X = 40
40 10
3
=
. wt . At
6 . 2
At. wt. = 65 Ans.
4. C
5
H
5
N SF
4
1 : 1
Square pyramidal (Pseudo octahedral)
5. Co
2+
+

7NO
2

+

2H
+
+

3K
+
K
3
[Co(NO
2
)
6
]+(yellow)

+ NO| + H
2
O
Sol. Co
2+
+ 7NO
2

+ 2H
+
+ 3K
+
K
3
[Co(NO
2
)
6
]+ (ihyk) + NO| + H
2
O
6.
7.
RESONANCE RJPT1SOL270311-7
8.
9. Fe + 2HCl FeCl
2
+ H
2
10. 1 forms osazone but 2 form hydrazone with phenyl hydrazine.
12.
(A)

O
OD




O D
2
(B)
(C)
(D) CH
2
=O

H

O H
2
13. Initial moles of air inside the tube =
300 082 . 0
3 . 12 4

= 2
moles of air after 20 minutes =
360 082 . 0
3 . 12 6 . 3

= 1.5
moles of air leaked in 20 minutes = 2 1.5 = 0.5
molecules of air leaked in 20 minutes = 0.5 N
A
Let the total surface area of tube = A cm
2
Total molecules escaped in 20 minutes
= (5 10
5
) A 6.023 10
8
20 = 0.5 N
A
A =
20 10 023 . 6 10 5
10 6.023 0.5
8 5
23


= 5 10
7
cm
2
= 5000 m
2
14. P = P
B
X
B
+ P
T
X
T
120 = 150(X
B
) + 50 (1 X
B
)
100 X
B
= 70
X
B
= 0.7
Y
B
=
P
P X
0
B B
=
120
150 x 7 . 0
= 0.875 Y
T
= 1 0.875 = 0.125
1
7
Y
Y
T
B
=
15. In complex, Ir with +1 oxidation state has 5d
8
configuration.
Hence, the complex would be square planar and diamagnetic. It
will have two geometrical isomers as given below.
16. [Mn(CN)
6
]
4
- 3d
5
, d
2
sp
3
; +2 oxidation sate
[Ni(NH
3
)
6
]
2+
- 3d
8
, sp
3
d
2
; +2 oxidation sate
[Co(ox)
3
]
3
- 3d
6
, d
2
sp
3
; +3 oxidation sate
[Cu(NO
2
)
6
]
4
- 3d
9
, sp
3
d
2
; +2 oxidation sate
[AgF
4
]

- 4d
8
, dsp
2
; +3 oxidation sate
[Ni(CN)
4
]
2
- 3d
8
, dsp
2
; +2 oxidation sate
[PdCl
4
]
2
- 4d
8
, dsp
2
; +2 oxidation sate
[Pd(CN)
4
]
2
- 4d
8
, dsp
2
; +2 oxidation sate
[Co(SCN)
4
]
2
- 3d
7
, sp
3
; +2 oxidation sate
17. ,
18. , , ,
PART-II (Mathematics)
19.
(AL
1
)
2
+ (L
1
M
1
)
2
= (a
2
+ 1
2
) + {(a 1)
2
+ 1
2
}
(AL
2
)
2
+ (L
2
M
2
)
2
= (a
2
+ 2
2
) + {(a 2)
2
+ 2
2
}

(AL
a 1
)
2
+ (L
a 1
M
a 1
)
2
= a
2
+ (a 1)
2
+ {1
2
+ (a 1)
2
}
Therefore, the required sum is
(a 1) a
2
+ {1
2
+ 2
2
+.....+ (a 1)
2
} + 2{1
2
+ 2
2
+...+ (a 1)
2
}
= (a 1) a
2
+ 3
6
) 1 a 2 ( a ) 1 a (
= a(a 1)
|
.
|

\
|
+
2
1 a 2
a
=
2
1
a(a 1)(4a 1)
20. For no solution or infinitely many solutions
a 1 1
1 a 1
1 1 a
= 0
a(a
2
1) (a 1) + 1(1 a) = 0 a(a
2
1) 2a + 2 = 0
a(a 1)(a + 1) 2(a 1) = 0 (a 1)(a
2
+ a 2) = 0
(a 1)(a + 2)(a 1) = 0 (a 1)
2
(a + 2) = 0
RESONANCE RJPT1SOL270311-8
a = 1, 1, 2
But for a = 1, there are infinite solutions. When a = 2,
we have
2x y z = 3
x + 2y z = 3
x y + 2z = 3
Addiing 0 = 9, where is not true
Hence no solution
21. We have
2 1
1 x ) x (cos
x 1
lim

=
) x 1 ( ) x (cos
) x 1 )( x 1 (
lim
2 1
1 x
+
+

=
) x 1 ( ) x (cos
x 1
lim
2 1
1 x
+

=
) cos 1 (
cos 1
lim
2
0
u + u
u
u
1, where x = cosu
[since x 1 cosu 1 u 0]
=
2
0
cos 1
lim
u
u
u ) cos 1 (
1
u +
=
4
4
) 2 / ( sin 2
lim
2
2
0
u
u
u |
|
.
|

\
|
u + ) cos 1 (
1
=
2
1
0
lim
u
2
2 /
) 2 / sin(
|
.
|

\
|
u
u
|
|
.
|

\
|
u + ) cos 1 (
1
=
2
1
(1)
2

) 1 1 (
1
+
=
4
1
22. Let focus S be (0, 0) and ZM be a directrix then
ZS = constant, for all ellispe
e
a
ae = constant or
ae
b
2
= (say) .........(i)
But if (x, y) be the end of minor axis then x = ae,y = b or b
from (i) locus of the end of minor axis is y
2
= x which
is parabola.
23. Since f is defined on (0, )
2a
2
+ a + 1 > 0 which is true as D < 0
also 3a
2
4a + 1 > 0
(3a 1) (a 1) > 0 a < 1/3 or a > 1
as f is increasing hence
f(2a
2
+ a + 1) > f(3a
2
4a + 1)
2a
2
+ a + 1 > 3a
2
4a + 1
0 > a
2
5a
a(a 5) < 0 (0, 5)
from (1) & (2) , we get
hence a e (0, 1/3) (1, 5)
possible integers {2, 3, 4}
24. To calculate number of zeros at the end we have to find how
many 2 and 5 are there. Because one pair of 2 and 5 makes 10
(i.e. 2 5 = 10) which gives one zero at the end.
Here 5
6
, 10
11
, 15
16
, 20
21
, 25
26
, 30
31
contain 6, 11, 16, 21
2 26, 31 fives. No other term contain five.
Thus total number of five = 6 + 11 + 16 + 21 + 2 26 + 31 = 137
Clearly number of zeros is equal to the number of 5
Thus, number of zeros at the end = 137
25. f(e) =
1 e
e
2
, f(f(e)) = e
}
|
|
.
|

\
|
+
2
1
2
e
1 e
e
de =
2
1
2
2
2
e
1 e
(
(

+
=
2
3
26. Let O(o, |, ) be orthocentre AO

BC
b| = c likewise ao = b| = c = k
o =
a
k
, | =
b
k
, =
c
k
The plane
c
z
b
y
a
x
+ +
= 1 contain (o, |, )
k |
.
|

\
|
+ +
2 2 2
c
1
b
1
a
1
= 1
27. Coefficient of x
14
in (1 + 2x + 3x
2
+....+ 16x
15
)
2
= Coefficient of x
14
in
(1 + 2x + 3x
2
+....+ 16x
15
)(1 + 2x + 3x
2
+ ....+ 16x
15
)
= 1 15 + 2 14 +....+ 15 1 =
=
15
1 r
) r 16 ( r
also
=
n
1 r
) r n ( r
=
= =
n
1 r
n
1 r
2
r nr
= n
2
) 1 n ( n +

6
) 1 n 2 )( 1 n ( n + +
=
6
) 1 n ( n +
(3n (2n + 1)) =
6
) 1 n ( n
2

=
15
1 r
) r 16 ( r
=
6
) 1 15 ( 15
2
= 560
Hence option (A) is correct.
28. a
2
+ b
2
+ c
2
> ab + bc + ca
3(a
2
+ b
2
+ c
2
) > (a + b + c)
2
> d
2

2
2 2 2
d
c b a + +
>
3
1
29. (A) f(x) =
n
lim
| |
n
2
) x 2 ( cos t
+
)
`

+
2
1
x
Obviously ,
+

2
1
x
lim
f(x) = 0 + 0 = 0
And

2
1
x
lim

f(x) = 0 + 1
f(x) is discontinuous at x =
2
1
(B) f(x) = (log
e
x) (x 1)
1/5
Obviously, f(x) is continuous at x = 1
f '(1
+
) =
0 h
lim

h
) 1 ( f ) h 1 ( f +
=
0 h
lim

h
h ) h 1 log(
5 / 1
+
= 0
f '(1

)

=
0 h
lim

h
) 1 ( f ) h 1 ( f
=
0 h
lim

h
) h ).( h 1 log(
5 / 1

= 0
Hence, f(x) is differentiable at x = 1
(C) f(x) = [cos 2tx] +
)
`

|
.
|

\
| t
2
x
sin

1 x
lim
f(x) =

1 x
lim
[cos 2tx] +

1 x
lim
)
`

|
.
|

\
| t
2
x
sin
= 0 + 1 = 1
+
1 x
lim
f(x) =
+
1 x
lim
[cos(2tx)] + +
1 x
lim

)
`

|
.
|

\
| t
2
x
sin
= 0 + 1 = 1
RESONANCE RJPT1SOL270311-9
Also f(1) = 1 + 0 = 1
f(x) is continuous at x = 1
f '(1
+
) =
0 h
lim

h
1
2
) h 1 (
sin )] h 1 ( 2 [cos
)
`

|
.
|

\
| + t
+ + t
=
0 h
lim

h
1
2
h
cos ] h 2 [cos
)
`

|
.
|

\
| t
+ t
=
0 h
lim

h
1
2
h
cos |
.
|

\
| t
=
0 h
lim

|
.
|

\
| t
|
.
|

\
| t t

2
h
cos 2
2
h
sin
2
= 0
Similarly , f '(1

) = 0
(D) f(x) =

t
e/
e
6
at
Q x , x sin
Q x , x 2 cos
f(x) is continuous when cos 2x = sin x which has x =
6
t
as one
of the solutions. Hence, It is continuous
If neighbourhood of x =
6
t
is rational then f '(x) =
3
and if
neighbourhood is irrational then f '(x) =
2
1
.
Here , f '

6
|
.
|

\
| t
= f '
+
|
.
|

\
| t
6
f(x) is not differentiable at x =
6
t
(E)
from graph of f(x)
f(x) is continuous but not differetiable at x = 0
30. (A)

AD =
i

2
5 h
|
.
|

\
|
+ j

+
k

4
2
k
|
.
|

\
|

AD || (i 2j + 5k)

2
5 h
=
2
1
=
5
4
2
k
|
.
|

\
|

h = 4 and k = 3
2 2
k h +
= 5
(B) Area =
2
1

| AC AB |
=
2
1
1 2 5
3 0 3
k j i
=
2
1
| i (6) j (12) + 6k |
=
2
1
36 144 36 + +
=
2
1

216
(C) C (4, 5, 3)
Distance =
25 4 1
7 15 10 4
+ +
+
=
30
4
=
15
2
(D) Equation of plane ABC is x 2y z = 9
so distance from origin =
6
9
(E) Distance of plane 2x + y z 11 = 0 from A is
6
11 5 3 4 +
=
6
9
31. Since angle bisector divides opossite sides in ratio of sides
containing the angle, hence
BA' =
c b
ac
+
, CA' =
c b
ab
+
now BI is also an angle bisector of ZB for triangle ABA'.

I '
I
A
A
=
a
c b +

A A
A
'
I
=
c b a
c b
+ +
+
Similarly,
B B
B
'
I
=
c b a
c a
+ +
+
and
C C
C
'
I
=
c b a
b a
+ +
+

C C B B A A
C B A
' ' '
I I I
=
) c b a (
) a c )( c b )( b a (
+ +
+ + +
Using A.M. > G.M. we get
) c b a ( 3
) c b a ( 2
+ +
+ +
>
3 / 1
) c b a (
) a c )( c b )( b a (
(

+ +
+ + +

3
) c b a (
) a c )( c b )( b a (
+ +
+ + +
s
27
8
maximum value
C C B B A A
) C B A ( 27
' ' '
I I I
= 8
32. x can be 2,3,4,5,6. The number of ways in which sum of
2,3,4,5,6 can occur is given by the coeffiicents of
x
2
, x
3
, x
4
, x
5
, x
6
in (3x + 2x
2
+ x
3
) ((x + 2x
2
+ 3x
3
)
= 3x
2
+ 8x
3
+ 14x
4
+ 8x
5
+ 3x
6
This shows that sum that occurs most often is 4.
33. Let
d

= x ) c b (

+ y ) a c (

+ z ) b a (

Take dot product with c , b , a

one by one
d . a

= x ] c b a [

+ 0 + 0 x =
] c b a [
d . a

similarly y =
] c b a [
d . b

, z =
] c b a [
d . c

RESONANCE RJPT1SOL270311-10

d

=
] c b a [
) b a )( d . c ( ) a c )( d . b ( ) c b )( b . a (

+ +

] c b a [
) b a )( d . c ( ) a c )( d . b ( ) c b )( d . a (

+ +
= 1
34. L =
0 x
lim
3
x x
x
) x 1 ( n c be ae x sin + + + +


=
0 x
lim

3
3 2 3
x
! 3
x
! 2
x
! 1
x
1 a
! 3
x
x
|
|
.
|

\
|
+ + + +
|
|
.
|

\
|

3
3 2 3 2
x
3
x
2
x
x c
! 3
x

! 2
x
! 1
x
1 b
|
|
.
|

\
|
+ +
|
|
.
|

\
|
+ +
=
0 x
lim

3
2
x
x
2
c
2
b
2
a
x ) c b a 1 ( ) b a ( |
.
|

\
|
+ + + + + +

3
3
x
x
3
c
! 3
b
! 3
a
! 3
1
|
|
.
|

\
|
+ + +
a + b = 0, 1 + a b + c = 0,
2
a
+
2
b

2
c
= 0 and
L =
! 3
1
+
! 3
a

! 3
b
+
3
c
Solving first three equations, we get c = 0, a = 1/2, b = 1/2
(a + b + c) = 0
35. Equation of tangent is y = 2x
2 2
b a 4 +
this is normal to the circle x
2
+ y
2
+ 4x + 1 = 0
this tangent passes through (2, 0)
0 = 4
2 2
b a 4 +
4a
2
+ b
2
= 16
using AM > GM , we
2
b a 4
2 2
+
>
2 2
b . a 4 ab s 4
36. 175 = 5
2
.7, 245 = 5.7
2
, 875 = 5
3
.7
1715 = 5 .7
3
Let o = log5, | = log7
a =
245 log
175 log
=
| + o
| + o
2
2
b =
1715 log
875 log
=
| + o
| + o
3
3
b a
ab 1
=
) 3 )( 2 ( ) 3 )( 2 (
) 3 )( 2 ( ) 3 )( 2 (
| + o | + o | + o | + o
| + o | + o | + o | + o
=
2 2
2 2

) ( 5
o |
o |
= 5
PART-III (Physics)
37. W =
r d . F
}
=
( )
( )
} |
|
.
|

\
|
+
|
|
.
|

\
|
+
. . . .
3 , 3
0 , 0
2
j dy i dx . j x i y
=
} }
+ dy x dx y
2
The equation of the path line joining the origin & the point (3, 3) is
y = x
W =
} }
+
3
0
2
3
0
dy y dx x
=
3
y
2
x
3 2
+
=
3
27
2
9
+
= 13.5 J
38. Net emf in the frame ABCD is zero. Therefore current in the
frame will also be zero. So potential difference across A and C
is equal to the emf induced between the two points A and D
which is the emf induced in the rod AD.
39. From Lenzs law the loop will move in the direction where magnetic
field is decreasing with position to avoid increasing flux with
time.
40. Take the system as the rod, the string, the spring and the
horizontal rod with the pulley . On this system the external force
is only the weight of the vertical rod whose torque about the
upper hinge is zero.
41. Writing voltage equation from A to B,
B A
V
C
q
dt
di
L V =
or
5
C
20
) 1 ( 1 2 = +
C = 5F.
42. AU = (1/2)f
1
n
1
RAT + (1/2)f
2
n
2
RAT = (1/2)(f
1
n
1
+f
2
n
2
)RAT = (1/2) (5
x 2 +3 x 5) 2 AT= 25 AT
Since W = 0 , AU = Q = 25 Cal
AT = 1K
43. r =
qB
Km 2

q
m
, if particles have same KE.
44. < i
2
> = 2
2
+ 4
2
< sin
2
et > + 16 < sinet > = 2
2
+ 4
2
|
|
.
|

\
|
2
1
= 12.
45. When upper part is smooth the velocity of the body will be more
when it comes on rough surface and hence slipping will be
more and less KE will be left at the lowest position.
46. The average energy stored in a capacitor is positive but average
consumption is zero, because the energy is taken and then
given back to the circuit equally.
47. (A) Applying Bernoullis equation between A and B

river
h
A B v

+ g s p
a
+
2
v
2
=

+ + g h g s p
a
v
2
= 2gh
(B) Applying Bernoullis equation between A and B
h
s
A B v
1 v
2

+ + g h g s p
a
+
2
v
2
1
=

+ g s p
a
+
2
v
2
2
v
2
2
v
1
2
= 2gh
Also from continuity eq, v
2
= 2v
1
v
1
2
=
3
gh 2
(C) (A) Applying Bernoullis equation between A and B
h
A
B

a
p
+ gh =

a
p
+
2
v
2
v
2
= 2gh
RESONANCE RJPT1SOL270311-11
(D) For accelerating liquids we have tanu = a/g
or
25 . 0
h
=
g
a
a = 4gh
(E)
g 2
r
h
2 2
e
=
v
2
= e
2
r
2
= 2gh.
48. (A)
0
A 414 . 0
30000
12420
eV
hc
= = =
(B)
m 10 6 . 8
10 6 . 1 2 10 1 . 9 2
10 626 . 6
mK 2
h
10
19 31
34

=


= =
(C)
) 1 Z (
4
Rc 3
) b Z ( a
c
= =

) 1 81 (
4
) 10 09 . 1 ( 3 1
7

= 0.19
(D) Energy of K

=Energy of K
o
+ Energy of L
|

or
| o

+

L K K
hc hc hc
| o

+

L K K
1 1 1

2 . 1
1
5 . 0
1 1
K
+ =

(E)
I
Nhc Nhc
=

= I =
7 . 5
10 3 10 6 . 6 10
8 34 15


=0.35 .
49.
The given circuit is like that shown. We have for such circuits,
RC
t
e
R
i

c
= or
8
t
0
e
2
10
2

=

5
2
e
8
t
0
=

. Charge on the capacitor in the circuit varies

with time as ) e 1 ( C q
RC / t
c =
Charge on the capacitor at time (t
0
+ 8) s will be
) e 1 ( 10 4 q
8 / ) 8 t (
0
+
= = ) e ) e ( 1 ( 40
1 8 / t
0

= 40
|
.
|

\
|

e 5
2
1
= 40
e
16
50. Energy released = increase in BE
= 6.5 120 + 7.0 80 6 203 = 122 MeV.
51. The horizontal force acting on the trolley system and the plate A
= kx = 1000 x 0.1 = 100N
The impulse imparted by this force in 3 sec = 300 Ns
The change in momentum of the sytem = 300 Ns
If the final speed of the trolley is v , we have 300v = 300
v = 1m/s
52.
16
N
Let the rod exerts a force N on the disc and let the acceleration
of the center of mass of the disc be a.Applying Newtons II law
we have
16 N = 2 a ......(1)
The free body diagram of the rod is as shown.
From t = Io , we have N 4 =
3
4 6
2

o ....(2)
Also a = 4 o ......(3)
Solve the three equations to get o = 1.
53. Effective phase difference between the two waves at P
= kA
2
t
=
4
2t
(4 2)
2
t
=
2
t
I
res
= I
1
+ I
2
+ 2
2 1
I I cos
2
t
= 1 + 4 = 5.
54. E =
0
c
o
o = E c
0
= 2c
0
.
RESONANCE RJPT1SOL270311-12
CODE - 0,1,2
PAPER-1
ANSWER KEY
PAPER-2
CODE - 0 ,1,2
Q.No. 1 2 3 4 5 6 7 8 9 10
Ans.
D B A B D A D D B B
Q. No. 11 12 13 14 15 16 17 18 19 20
Ans.
BC ABC C BC BD A B C C C
Q. No. 21 22 23 24 25 26 27 28 29 30
Ans. A T T T F F T A C C
Q. No. 31 32 33 34 35 36 37 38 39 40
Ans. B C D A B C C ABCD A BC
Q. No. 41 42 43 44 45 46 47 48 49 50
Ans. AC CD A D C D D C F T
Q. No. 51 52 53 54 55 56 57 58 59 60
Ans. T F T F B C A C A A
Q. No. 61 62 63 64 65 66 67 68 69 70
Ans. B A B A AC AC BC AB ABC A
Q. No. 71 72 73 74 75 76 77 78 79 80
Ans. C C A B B T T T F T
Q. No. 81
Ans. T
Q.No. 1 2 3 4 5 6 7 8 9 10
Ans. A C B B A D C B A C
Q.No. 11 12 13 14 15 16 17 18 19 20
Ans.
(A - p,s) ; (B - s) ;
(C - q, r, s) ; (D - p, r); (E - q)
(A - p,q) ; (B - s);
(C - p,q,r) ; (D - r,s) ; (E - s)
5 7 2 6 6 4 C B
Q.No. 21 22 23 24 25 26 27 28 29 30
Ans. E C C C C A A A
(A - q,s), (B - p,r),
(C - p,r), (D - p,s),
(E - p,s)
(A - p), (B - q),
(C - r), (D - s),
(E - s)
Q.No. 31 32 33 34 35 36 37 38 39 40
Ans. 8 4 1 0 4 5 A B A C
Q.No. 41 42 43 44 45 46 47 48 49 50
Ans. D A A D D D
(A-p) ; (B-q) ;
(C-p) ; (D-r) ; (E-p)
(A-r) ; (B-s) ;
(C-q) ; (D-p); (E-p)
8 2
Q.No. 51 52 53 54
Ans. 1 1 5 2