TALIGAMAN NATIONAL HIGH SCHOOL Taligaman, Butuan City SECOND PERIODIC EXAM ADVANCED CHEMISTRY Choose the letter

of the best answer. 1. Radio waves, infrared waves, visible light, and X-rays are types of _____________________. a. Electromagnetic radiation c. Black radiation b. Wavelength d. Amplitude 2. The distance between two similar points on two successive waves (such as the distance from crest to crest or trough to trough. a. frequency c. wavelength b. amplitude d. intensity 3. The speed of a wave depends on the type of wave and the nature of the medium through which the wave is traveling (e.g., air, water, or a vacuum). a. False b. True c. Undetermined 4. Of the waves pictured, ____________ has the greatest frequency, ______________ has the greatest wavelength, and ______________ has the greatest amplitude. a. i, ii, iii b. i, iii, ii c. ii, i, ii d. ii, i, iii e. ii, iii, ii

5. What is the frequency of red light with a wavelength of 700 nm? a. 2.49 x 1014/s b. 4.29 x 1014/s c. 9.24 x 1014/s d. 9.42 x 1014/s 6. A ray of white light is spread out into a wide band. a. Line spectrum b. Continuous spectrum c. Electromagnetic spectrum d. none of the above 7. Proposed a theory for the electronic structure of the hydrogen atom that explained the line spectrum of the hydrogen element. a. Albert Einstein b. Neils Bohr c. Max Planck d. De Broglie 8. When the atoms are heated in an electric arc or Bunsen flame, electrons absorb energy and jump to outer levels, which are higher energy states. The atoms are said to be in ___________________. a. Ground state b. excited state c. paschen series d. balmer series 9. Are the emissions of light only at specific wavelength? a. Line spectrum b. continuous spectrum c. paschen series d. balmer series 10. Calculate the wavelength (in nm) of the photon emitted when an electron transitions from n = 4 state to the n = 2 state in a hydrogen atom. a. 55.20 x 106/m b. 5.520 x 106/m c. 4.87 x 10-7 nm d. 8.47 x 10-7nm 11. The Bohr Theory is highly successful in interpreting the spectrum of hydrogen but it fails to explain the spectra of atoms that contain more than one electron. a. True b. Undetermined c. False 12. Which wavelength corresponds to the transition of an electron in a hydrogen atom from n = 2 to n = 1? a. 182 nm b. 91.2 nm c. 724 nm d. 122 nm 13. He proposed that radiant energy could only be emitted or absorbed in discrete quantities, like small packages or bundles. a. Neils Bohr b. Max Planck c. Albert Einstein d. De Broglie 14. Energy is always emitted in whole number multiples of hv. a. Bohrs Theory b. Quantum theory c. Blackbody radiation d. photoelectric effect 15. How many orbitals are there in the 5f subshell? a. 5 b. 7 c. 14 d. 16 16. In a hydrogen atom, which orbitals are higher in energy than a 3s orbital? a. 3p b. 4s c. 2p d. 3d 17. Which of the following sets of quantum numbers, n, l, and ml, correspond to a 3p orbital?

18. 19.

20.

21.

22.

23. 24. 25.

26. 27. 28. 29.

30.

31.

a. 3, 0, 0 b. 3, 1, 0 c. 3, 2, -1 d. 1, 1, -2 The energy of an orbital in the hydrogen atom depends on _________________. a. n, l, and ml b. n and l c. n only d. ml only Designates the size of the orbital. a. Principal quantum number c. Angular momentum quantum number b. Magnetic quantum number d. Electron spin quantum number Describes the shape of the atomic orbital. a. Principal quantum number c. Angular momentum quantum number b. Magnetic quantum number d. Electron spin quantum number Describes the orientation of the orbital in space. a. Principal quantum number c. Angular momentum quantum number b. Magnetic quantum number d. Electron spin quantum number Specify the electrons spin. a. Principal quantum number c. Angular momentum quantum number b. Magnetic quantum number d. Electron spin quantum number The numerical value of f orbital. a. 0 b. 1 c. 2 d. 3 Two electrons in the same orbital with opposite spins are referred to as _______________. a. Paired b. spin c. angular momentum d. magnetic spin Which of the following is a legitimate set of three quantum numbers: n, l, and ml? (Select all that apply.) a. 1, 0, 0 c. 1, 0, +1 e. 2, 2, -1 b. 2, 0, 0 d. 2, 1, +1 What is the total number of orbitals in the shell designated by n = 3? a. 1 b. 2 c. 3 d. 6 e. 9 How many orbitals are there in a subshell designated by the quantum numbers n = 3, l = 2? a. 2 b. 3 c. 5 d. 7 e. 10 How many subshells are there in the shell designated by n = 3 a. 1 b. 2 c. 3 d. 6 e. 9 Molecular structures are often drawn by using symbols of the elements along with dots to represent valence electron. a. Lewis structure b. Electron dot c. Formal charge d. valence-bond dot This theory emphasizes the attainment of a noble gas electronic configuration on the part of atoms in covalent molecules and for most atoms this means the attainment of an octet. a. Valence-bond theory b. Lewis theory c. Quantum theory d. Molecular geometry Identify the correct Lewis structure for formic acid (HCOOH).

32. Draw the Lewis structure for carbon disulfide (CS2). 33. This can be used to determine the most plausible Lewis structures when more than one possibility exists for a compound. a. Resonance b. Formal charge c. Lewis structure d. vsepr 34. Formal charges do not represent actual charges on atoms in a molecule. a. False b. True c. Undetermined 35. Determine the formal charges on H, C, and N, respectively, in HCN. a. 0, +1, and -1 c. 0, -1, and +1 e. 0, 0, and 0 b. -1, +1 and 0 d. 0, +1 and +1 36. Which of the Lewis structures shown is most likely preferred for NCO ?
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37. Is one of two or more Lewis structures for a single molecule that cannot be represented accurately by only one Lewis structure? a. Formal charge b. VSEPR c. valence-bond d. Resonance structure 38. Resonance is a human invention, designed to address the limitations of a simple bonding model. a. True b. False c. Undetermined 39. Indicate which of the following are resonance structures of Cl Be Cl . (Select all that apply)

40. How many resonance structures can be drawn for the nitrite ion (NO2-)? (N and O must obey the octet rule.) a. 1 b. 2 c. 3 d. 4 41. The basis of this model is the electron pairs in the valence shell of an atom repel one another. a. VSEPR model b. Electron domain c. Molecular geometry d. valence bond 242. What are the electron-domain geometry and molecular geometry of CO3 ? a. Tetrahedral, trigonal planar c. trigonal pyramidal e. tetrahedral, tetrahedral b. Tetrahedral, trigonal pyramidal d. trigonal planar, trigonal planar 43. What are the electron-domain geometry and molecular geometry of ClO3-? a. Tetrahedral, trigonal planar c. trigonal pyramidal e. tetrahedral, tetrahedral b. Tetrahedral, trigonal pyramidal d. trigonal planar, trigonal planar 44. Determine the shape of ICl4 . 45. Identify the polar molecules in the following group: HBr, CH4, CS2. a. HBr only b. HBr and CS2 c. HBr, CH4, and CS2 d. CH4 and CS2 46. Identify the nonpolar molecules in the following groups: SO2, NH3, XeF2. a. SO2, NH3, and XeF2 b. SO2 only c. XeF2 only d. SO2 and XeF2 47. Combination of atomic orbitals to form hybrid orbitals. a. Hybridization b. Combination c. Valence bond theory d. Molecular hybrid 48. What is the hybridization of CH4? a. sp b. sp2 c. sp3 d. dsp2 49. Which of the following molecules contain one or more pi bonds? (select all that apply.) a. N2 b. Cl2 c. CO2 d. CH3OH e. CCl4 50. From left to right, give the hybridization of each carbon atom in the allene molecule (H2C = C = CH2). a. sp2, sp2, sp2 b. sp3, sp2, sp3 c. sp2, sp, sp2 d. sp3, sp, sp3

************ GOOD LUCK **********

LINEAR

TRIGONAL PLANAR

TETRAHEDRON

TRIGONAL BIPYRAMIDAL

SQUARE PYRAMIDAL