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Definition
Mole
The amount of any substance containing the same number of identical entities as there
are in exactly 12g of the carbon-12 isotope.
The average mass of an atom of an element relative to 1/12 the mass of a carbon-12
atom.
Avogadro constant
The number of atoms in exactly 12g of the carbon-12 isotope, which is equal to
6.021023 mol-1.
For very small concentrations, percentages become less useful, eg a 0.01% solution is difficult to visualize. Parts
per million is useful for low concentrations.
concentration =
Example
1. Blood plasma typically contains 20 parts per
[Ca = 40]
in %.
ppm % : multiply by (
)
1
reading?
Reason
maximum yield.
There are side reactions and side product, especially in organic reaction
The theoretical yield is calculated using the balanced chemical equation and the following formula
percentage yield =
100%
The theoretical yield is the mass that calculated according to mole ratio
in the reaction, assuming that all reactant is converted into the product.
Example 1
Ethanol reacts with hydrogen bromide to form bromoethane and water. In a reaction, 2.30g of ethanol reacts to form
4.00g of bromoethane. Find the percentage yield of bromoethane.
Example 2
Ethanol is manufactured by the hydration of ethene. In a typical process 28 tonnes of ethene produces 43.7 tonnes of
ethanol. Find the percentage yield.
A 100% atom economy means that all atoms in reactants turn into products. There are no unwanted products.
For example, methanol and carbon monoxide reacts to form ethanoic acid with 100% atom economy.
CH3OH + CO CH3COOH
A low atom economy means that are side reactions and form unwanted products.
b) H2O2 H2O + O2
Example 1
State, with a reason, the atom economy for the production of a poly(alkene) from an alkene. (1)
............................................................................................................................................................................................
............................................................................................................................................................................................
............................................................................................................................................................................................
Example 2
Chloroethane, C2H5Cl, can be made from either ethane or ethene.
(a) (i) What reagent and condition would be used to make chloroethane from ethane? (2)
Reagent .............................................................................................................................................................................
Condition ............................................................................................................................................................................
(b) (i) What reagent would be used to make chloroethane from ethene? (1)
............................................................................................................................................................................................
3
There are always a built-in error when using apparatus such as electronic balance, burette and thermometer.
For example, the manufacturer of a balance may state that the mass of an object is accurate to 0.01g. Therefore,
a reading of 1.23g may mean a mass anywhere between 1.22g and 1.24g.
100%
Example
A thermometer is labelled as having an accuracy of 0.2 oC. In an enthalpy of neutralization reaction, the temperature
before the reaction was 17.4oC and after the reaction was 24.5oC. The mass of liquid used was 100g. the specific heat
capacity of the liquid is 4.18J g-1 oC-1.
(a) Calculate the percentage error caused by the thermometer
(b) Find the error in the evaluation of the heat produced.