Processing Parameters for the Formation of Luminescent Porous Silicon

Nanostructures.

S.NO
ORIEN RESSISTIVITY DOPIN CURRENT TIME HF CONCENTRATION
T- G
ATION

1 (100) 0.8-1.2,mΩ P++ 200mA/cm 200s 3:1(v/v) 48 %HF in

cm-1 2 300s ethanol
50mA/cm2 150s
400mA/cm
2

2 (100) 0.005 Ω/cm P++ 320mA/cm 6s 2:5 (v/v) 49%HF in

2 ethanol

0.75-0.95Ω P++ 74mA/cm2 180s 24% ethanolic HF

/cm 24% ethanolic HF,
3 --------- P++ 37mA/cm2 1hrs
- 0.010 Ω/cm Constant
replacement each
20min

4 (100) 0.008–0.02 Ω P++ 5mA/cm2 1-2 25%HF/Ethanol

/cm (Under min
white
light)

5 (100) 0.65-0.95 Ω P++ 8.5 90s 1:1 49%HF/EtOH

/cm mA/cm2 and
(under 120s
white
light)

P++ 7.6 mA/ 90sec 24% HF/26%

6 (100) 0.65-0.95 Ω cm2 H2O/50%
/cm 120s
75.9 (Deferent time
mA/cm2 intervals with
varying kind of
illumination)

7 (100) 3-6 Ω/cm P++ 44mA/cm2 2min 25%HF in ethanol

8 (100) 0.008-0.020 Ω P++ 74mA/cm2 3 min 1:1 aqua HF in
/cm (Under ethanol
illuminatio
n)

9 (100) 0.64 Ω/cm P++ 4 mA/cm2 30mi 1:1 aqua HF in

& n ethanol
40 5min
mA/cm2

10 (100) 0.70 Ω/cm P++ 71.4 3 min 1:1 aqua HF in EtOH

mA.cm2
(Under
illuminatio
n)

REFFERANCE
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silicon nanoparticles for in vivo applications, Nat.Nanotech 2;2009, AOP

2. Tasciotti.E,Liu.X, et al, Mesoporous silicon particles as a multistage

delivery system for imaging and therapeutic applications, Nat. Nanotech, 3,
2008, 151-157

3. Stewert.M.P, Robbins.E.G, Et al, three methods for the surface

modification of mesoporous silicon, Phys.Sta.Sol.(a),182,2000:109-155

4. Guibin Jiang et al., Preparation of a biochip on porous silicon and

application for label-free detection of small molecule-protein interactions
Rapid Commun. Mass Spectrom. 2007; 21: 1277–1281

5. Buriak. J.M, et al., Hydride Abstraction Initiated Hydrosilylation of

Terminal Alkenes and Alkynes on Porous Silicon Langmuir 2002, 18, 2971-
2974

6. Buriak J.M., Exciton-Mediated Hydrosilylation on Photoluminescent

Nanocrystalline Silicon J. Am. Chem. Soc. 2001, 123, 7821-7830

7. S.P. Low et al. Evaluation of mammalian cell adhesion on surface-

modified porous silicon Biomaterials 27 (2006) 4538–4546

8. Choi and Buriak ., Effects of Organic Monolayer Formation on

Electrochemiluminescence Behavior of Porous Silicon, Chem. Mater., 12, 8,
2000
9. Sailor M.J., Using Porous Silicon as a Hydrogenating Agent:
Derivatization of the Surface of Luminescent Nanocrystalline Silicon with
BenzoquinoneJ. Am. Chem. Soc. 1997, 119, 6943-6944

10. Buriak J.M., M.J. Allen, Photoluminescence of porous silicon surfaces

stabilized through Lewis acid mediated hydrosilylation Journal of
Luminescence 80, 1999, 29--35