Vol. 72, March 2013, pp. 186-192 *Author for correspondence E-mail: umadevi.rongali@gmail.com a Laboratory performance of stone matrix asphalt containing composite of fly ash and plastic waste Umadevi Rongali a , Gagandeep Singh b , Anita Chourasiya c and P.K. Jain d CSIR-Central Road Research Institute, New Delhi-110025, India Received 11 May 2012; revised 06 November 2012; accepted 03 January 2013 In this paper, the optimum composition of fly ash and plastic waste in a composite has been established based on various performance tests. The optimum dose of plastic waste in composite is 8% weight of fly ash. Laboratory tests indicated increased resistance to moisture damage in stone Matrix Asphalt (SMA) mixture containing composite as filler. The values of resilient modulus of the SMA mixture containing composite are fairly high compared to SMA mixture containing lime as filler. The rutting in SMA mixture containing composite is reduced to one third as compared to conventional SMA mixture without composite. The results of mechanistic analysis indicate that there is an increase in allowable number of traffic on modification of SMA with fly ash plastic waste composite as filler in place of lime. Keywords: Stone Matrix Asphalt, Fly Ash, Plastic waste, Composite, Resilient Modulus, Rutting. Introduction Stone Matrix Asphalt (SMA) is a gap graded mixture that maximizes the coarse aggregate content to the tune of 70-80% in the mixture to ensure stable stone-on-stone contact 1-8 . The requirement of filler in SMA mixture is of the order of 10-12 percent and binder content is high (more than 6 %), so that to form mortar in voids of SMA structure and achieve better durability. Cellulose fiber is added to prevent drain down of the binder at high operating temperatures. The increase of contact points in aggregate matrix of SMA mixture produce high resistance to rutting in bituminous surface. IRC: SP: 79- 2008 specify requirements of design and construction of bituminous surface using SMA mixture 9 . The sources of good quality mineral aggregate and traditional filler like lime are depleting due to large scale development of road infrastructure. Therefore, a need is felt to explore alternate materials for conservation of available mineral materials. Highway sector has potential to utilize sufficient quantity of waste materials 10 , if their effect on performance of pavement proves to be technically, economically and environmentally acceptable and meet the requirement of standards and specifications. Presently, about 100 thermal power plants operating in India are producing over 170 million tones of fly ash every year, which is dumped in the land adjoining to thermal power plants, adversely affecting nearby environment besides consuming useful land. Nearly, 65,000 acre of land is occupied by ash ponds in the country. It is estimated that production of ash will reach to 600 million tons in 2030 10 . Fly Ash (FA) and Plastic Waste (PW) are two abundantly available waste materials with several good characteristics, which make them suitable for bituminous road construction 10-18 . Incorporation of 10% fly ash as filler is reported by researchers 14 . Some studies also reported significant improvement in fatigue life of mixes upon addition of fly ash 17 . Particle size of fly ash has been found to make significant effect on viscosity of fly ash and bitumen blend. The viscosity values of finer blends are observed higher. Better performance in terms of resistance to rut depth, tensile strength and fatigue life 26. Use of fly ash as filler also leads to reduction in rolling temperature and thus consumption of lesser energy 27 . Use of plastic waste in bituminous mixes has been found acceptable on the basis of several studies 19-25 . The bituminous mix containing 8% waste polymer modifier (WPM) leads to considerable improvement in properties of mix 20 . Regarding availability of plastic waste, the per capita consumption of solid plastic in developing countries like India is 10kg in a year. Solid plastic litter generated from plastic goods is non bio-degradable 19. Since requirement and other pertinent physical properties of fly ash and fly ash plastic waste composite as filler for 187 RONGALI et al: LABORATORY PERFORMANCE OF STONE MATRIX ASPHALT bituminous mixture are acceptable and SMA mixture consume 10-12% filler by weight of total mineral aggregate, a study was undertaken to explore use of alternate filler materials such as fly ash and its composite with plastic waste as a substitute of traditional filler lime. In view of above cited literature and associated problems for disposal of fly ash and plastic waste, a study on use of these solid waste materials in roads construction was taken up. The main objectives of this study were to evaluate mechanistic properties addressing performance of fly ash plastic waste composite with different compositions as alternate to conventional lime filler in bituminous road construction. Experimental Details Materials Plastic waste in the shredded form (2-8 mm) was used in this study. The Thermo Gravimetric Analysis (TGA) and Differential Scanning Calorimeter (DSC) study of plastic waste indicated initial decomposition temperature as 399C. The melting temperature was observed in the range of 124-129C from DSC analysis Fly ash used in this study was obtained from NTPC Ltd. Dadri, (U.P). To check the suitability of fly ash various tests were performed on fly ash such as bulk density(IS:2386 Part 1),specific gravity(IS:2386 Part 1), water absorption(IS:2386 Part 3), fineness modulus(IS:2720 Part 4), methylene blue(IS:2720 Part 26) and plasticity index tests(IS:2720 Part 6) and values obtained were 1.21, 2.1, 1.59, 2.44, 0.59 and non plastic respectively. Bitumen VG-30 grade paving bitumen from Mathura refinery conforming to IS: 73-2006 was used. Various physical properties of bitumen were found such as penetration value, softening point, ductility, specific gravity, viscosity at 60C and 150C as per IS: 1201 to 1210. The values obtained are 61, 47, 75+, 1.01, 2449 and 360 respectively. Aggregate The mineral aggregate (granite) was obtained from the local quarry and various physical properties were obtained, as per IS:2386 to check the quality such as aggregate impact value (11.23), water absorption test (0.85%), specific gravity (2.63), combined (elongation and flakiness) index (29.5%) and stripping (99%). Mixture design method In the present study, three different SMA mixtures were designed and made according to IRC SP: 79-2008 standards. The aggregates were blended to obtain the values of grading as specified in IRC: SP-79-2009 9 . Three different mixes, controlled SMA (with lime filler), SMA containing fly-ash and SMA containing fly ash- plastic waste composite were made and are designated as SMA 1, SMA 2 and SMA 3 respectively. Effect of plastic waste on VCA and air voids is shown in Figure 1. Specimen preparation Fly ash was coated by pre decided quantity of plastic waste at different dosage level. The design of optimum bitumen content was done by standard Marshall Method (ASTMD: 1559). Specimens of mixes were prepared by heating aggregates at 150 C. The fly ash pre coated with plastic waste in requisite quantity was then added and mixed thoroughly in a mixing pan followed by addition of melted bitumen at 164 C. Ingredients were then mixed thoroughly and poured in Marshall mould assembly at 150 C. Samples were prepared using Marshall Method Fig. 1Effect of plastic waste on VCA and air voids of SMA mixture containing fly ash 188 J SCI IND RES VOL 72 MARCH 2013 50 blows on both faces. The properties of designed SMA mixtures are given in Table 1. Test procedures I ndirect tensile strength (I TS) test Indirect tensile strength test is significant to evaluate resistance of compacted bituminous mixture to cracking as well as sensitivity of mixture to moisture damage. To identify whether the coating of bitumen binder and aggregate is susceptible to moisture damage, Tensile Strength Ratio (TSR) is determined according to AASHTO T 283, Results of indirect tensile strength and TSR are plotted in Figure 2 and Figure 3. Resistance to deformation The aspect of deformation at high temperature has been investigated by conducting rutting test. Rutting is an important parameter for design of a SMA mixture. To check the rutting resistance of the mixture, test was performed by Wheel Tracking Device (WTD). The WTD is destructive test and it involves direct contact between the loaded wheel and the rectangular test specimens. The test was conducted on the prepared slab specimen of 300X300X50 mm at optimum binder content containing lime, fly ash and fly ash - plastic waste composite as filler. The test was conducted as per BS: 598-1998. The total numbers of 20,000 passes were applied at 45 C and resulting rut depth was measured. The data of rut depth of different mixes are plotted in Figure 4. Table 1Properties of designed SMA mixture Properties Requirements SMA1 SMA 2 SMA 3 Bitumen content, % 5.8 min 6.0 6.2 6.0 Stabilizing additive, % Min 0.3%, 0.3 0.3 0.3 Air void content, % 4 4.4 4.1 4.3 Void in mineral aggregate, % 17min 17.0 17.5 18.8 Compactive effort, No of blows 50 50 50 50 Drain down, % <0.3% 0.21 0.14 0.14 Voids in Coarse aggregate, % Less than VCA 30.3 32.53 32.5 (Dry rodded) VCA by dry rodded method, % Min 45% 45.7 45.7 45.7 VCA Ratio <1 0.66 .711 0.71 Tensile Strength, Ratio 85% min 86.0 92.1 92.3 Fig. 2Effect of plastic waste on indirect tensile strength values of SMA mixture containing fly ash Fig. 3Effect of plastic waste on TSR of SMA mixture contain- ing fly ash Fig. 4Progression of rutting as a function of passes in com- pacted SMA mixtures 189 RONGALI et al: LABORATORY PERFORMANCE OF STONE MATRIX ASPHALT Resilient modulus (M R ) test To check the effect of fly ash and plastic waste and their composite with different composition on the resilient modulus values, the repeated loading indirect tensile test on compacted bituminous mixtures was performed as per ASTM D-4123. The test was conducted by applying the compressive load in the form of haversine wave at 25, 30, 35, 40 and 45 C for controlled SMA mixture (SMA 1), SMA with fly ash filler (SMA 2) and SMA with fly ash plastic waste composite filler (SMA 3). The specimens were conditioned for 24 h in the environmental chamber at the given temperature and then subjected to repeated loading pulse width of 100 ms, and pulse repetition period of 1000 ms the results are plotted in Figure 5. Mechanistic analysis KENPAVE software is used to calculate the tensile strain at the bottom of bituminous layer and the compressive strain at the top of the sub grade layer. These values are used in the fatigue and rutting model to estimate the pavement life and the benefits are presented in the form of Traffic Benefit Ratio (TBR) [34]. In this study, 8 tonne axle load having two sets of dual tires with 800 kPa tire pressure and 30 cm dual spacing is taken as input for the analysis. Based upon test result values of resilient modulus, mechanistic analysis of three layer structure with 10 cm of SMA layer as top layer and 40 cm aggregate layer having resilient modulus value of 200 MPa and sub grade having CBR of 8% is analyzed. Results are presented in Table 2. Discussion of test results Properties of ingredients Result of test performed on different ingredients of SMA mixture indicates that fly ash used in this study is non plastic. A lower value of methylene blue shows fewer amounts of clay and organic material in fly ash. The fly ash used as filler meet MoRTH requirements. Classification tests on bitumen were performed and results of test are given earlier. Test data indicate that bitumen used in this study can be graded as VG-30. The particle size of shredded plastic is in the range of 2-8 mm, which lies in conformity of findings reported earlier 19 . The TGA test indicates that decomposition of plastic waste does not occur below 399 C, indicating its safer use in bituminous construction. The melting, behavior is important parameter from mixing point of view. From DSC analysis the melting range of 124C - 129C of Table 2Mechanistic analysis of three layered structure Composition Tensile strains at bottom of Compressive strains on TBR bituminous layer () top of sub grade() SMA with lime filler 448 520 - SMA with fly ash 461 524 0.96 SMA with 5% plastic waste by weight 319 469 1.65 of fly ash SMA with 8% plastic waste by weight 313 466 1.70 of fly ash Fig. 5Effect of plastic waste on resilient modulus value of SMA mixture containing fly ash and different dosage of plastic waste 190 J SCI IND RES VOL 72 MARCH 2013 plastic waste is favorable for preparation of mix at 140 to 160 C. The endothermic peaks in DSC curves around 260 C indicate initiation of decomposition process. Design of SMA mixes It can be seen from the data given in Table 1 that the optimum bitumen content is in the range of 6.0 to 6.2 % by weight of aggregate and also meet requirements described in IRC: SP: 79-2008. It can be seen from the data that VCA mix values of all the SMA mixtures are less than/equal to VCA DRC and VMA are more than specified value of 17 %. Therefore, designed SMA mixtures are having fairly good stone-on-stone contact to control rutting in mixture. Figure 1show effects of plastic waste on VCA and air voids in the compacted mixture. There is increase in air voids and VCA, if plastic waste content is exceed 8% by weight of ash. Drain down studies Prevention of draining of bitumen in SMA mixture during transportation is an important parameter. It can be seen from the data given in Table 1 that fly ash as well as fly ash plastic waste composite as filler in place of lime reduce draining tendency of binder from mixture. Moisture sensitivity studies TSR is widely acceptable test to address damage caused by the ingress of moisture. The TSR value of traditional SMA with lime as filler (SMA 1) is 86%, which is in conformity to IRC standard. The values of TSR of SMA containing fly ash (SMA 2) and fly ash plastic waste composite(SMA 3) are recorded 92 and 93%, which are 7-8% higher than traditional SMA mixture (SMA 1), indicating better resistance to moisture damage. Therefore, SMA mixes containing fly ash and composite of fly ash plastic waste as fillers may be used in locations of higher rainfall. Results plotted in Figures 2 and 3 further indicate that highest value of indirect tensile strength and TSR are observed using a composite containing 5 to 8 % plastic waste in fly ash plastic waste composite, used as filler in SMA mixture. Resilient modulus Test, M R Resilient modulus is the most important variable for mechanistic design of flexible pavement structure. It is the measure of pavement response in forms of dynamic stress and corresponding strains. Figure 5, show the obtained M R values. The data plotted in Figure 5 indicate that plastic waste modification has improved the resilient modulus of the modified mixes as compared to traditional SMA mixture containing lime as filler for all the test temperatures. The average resilient modulus of traditional mixture at 35C was found to be 3503 MPa for the mixture containing 8% plastic waste by weight of added fly ash in SMA mixture. However, M R values without plastic waste containing 10% fly ash at 35 C is observed 1331 MPa in comparison to 1431 MPa of SMA mixture containing lime as filler. The average resilient modulus values at 45 C increased from 409 MPa to 1407 MPa upon addition of 8% plastic waste in fly ash which is quite high. The addition of 2 to 10 % plastic waste in fly ash resulted progressive increase in M R value from 1331 MPa at 2% PW to 3503 MPa at 8% PW. The value of M R at 5% plastic waste is 2951 MPa at 35 C compared to 1431 MPa of traditional SMA mixture. Values of M R at 45C are very high and support to rutting behavior of their mixtures, when tested by wheel tracking test at same temperature. The pozzolanic properties of fly ash together with elastic properties of plastic waste contributed to high values of M R at 35 and 45 C, resulting to overall performance. Rutting studies Rutting is key factor for design and evaluation of the performance of SMA mixtures. It can be seen from Figure 4 that observed rut depth values of SMA mixtures are in the range of 1 to 5 mm using VG 30 bitumen binder and lime, fly ash/fly ash plastic waste composite as filler. Table 3Rutting in SMA mixtures Composition of Composite Rutting in mm for different cycle range 0 - 5000 5000 -10000 10000 - 20000 A. 10% Fly Ash (SMA 2) 1.79 2.04 2.29 B. Fly Ash+ Plastic Waste (5%)(SMA 3A) 1.57 1.79 2.01 C. Fly Ash+ Plastic Waste (10%) (SMA 3B) 0.64 0.77 1.09 D. SMA with Lime (SMA 1) 3.48 4.09 4.71 191 RONGALI et al: LABORATORY PERFORMANCE OF STONE MATRIX ASPHALT Data plotted in Figure 6 indicate that higher resistance to rutting is observed when fly ash is used. However, lesser rut depth values of SMA mixtures is attributed to higher percentage of coarse aggregates and development of stone on stone contact in the matrix. Data given in Table 3 indicates that SMA mixture containing fly ash plastic waste as filler, rut depth in mixture specimen is further reduced to about 1 mm which is attributed to higher value of resilient modulus at 45 C. Data given in Table 4 indicates that rate of rutting is highest during 0- 5000 cycles for SMA mixture containing lime as filler as compared to SMA 2 and SMA 3 containing fly ash. The rate of rutting is lowest (Table 4) for SMA mixture containing filler of composite and presented in Figure 6. Mechanistic analysis of data The results of mechanistic analysis of three layered structure are presented in Table 5. It can be seen that the modification of SMA with only fly ash leads to increase in the tensile strains at the bottom of the SMA layer from 448.2 to 461.8 but modification of SMA with fly ash and plastic waste show the positive results with the decrease in tensile strain to 318.9 and 313.3 in case of 5% and 8% dosage level of waste plastic as compare to unmodified SMA. The compressive strain on the top of sub grade also reduces for SMA modified with fly ash and waste plastic as compare to unmodified SMA and SMA modified with fly ash only. The compressive strain falls from 519.7 to 468.8 and 466.2 on modification with 5% and 8% dosage level of waste plastic respectively and giving the TBR of 1.65 and 1.70. These reductions in the strain values are due to increase in the resilient modulus values of SMA when modified with the fly ash and plastic waste composite. Conclusions and Recommendations This study has been done for the performance of Asphalt with fly ash and the following conclusions are drawn: Fly ash can be used as filler in place of traditional lime in Stone Matrix Asphalt. Properties of fly ash as well as SMA can be improved by coating fly ash with plastic waste. The optimum content of plastic waste in composite is 8% by weight of fly ash. Incorporation of plastic waste in excess of 8% led to increase in VMA and air voids in compacted mixture. Plastic waste in fly ash led to increase in values of indirect tensile strength to resist cracking. Incorporation of plastic waste in fly ash enhances values of M R at 35 C and 45 C. Table 4Rate of rutting in SMA mixture Composition of Composite Rate of rutting per 1000 cycles 0 - 5000 5000- 10000 10000 -20000 A. 10% Fly Ash (SMA 2) 0.358 0.050 0.025 B. Fly Ash + Plastic Waste (5%) (SMA3A) 0.314 0.044 0.022 C. Fly Ash + Plastic Waste (10%)(SMA 3B) 0.130 0.026 0.013 D. SMA with Lime (SMA 1) 0.690 0.034 0.062 Fig. 6Rate of Rutting in different SMA mixture. 192 J SCI IND RES VOL 72 MARCH 2013 Mechanistic analysis of three layered structure indicate TBR in the range of 1.65 to 1.70. Plastic waste reduces rutting in SMA mixture considerably. SMA containing composite can be used as wearing surface and bituminous base course subjected to heavy traffic for flexible pavements. Acknowledgements Sincere thanks are due to Dr. S. Gangopadhyaya Director CSIR-Central Road Research Institute, New Delhi 110025 for permission to publish this paper. Thanks are due to Dr. Divesh Tiwari for the assistance during testing of mechanistic properties. 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