Material Safety Data Sheet

Terralin(TM)
MSDS No.
OEM000102

1.

Product and Company Identification

Terralin(TM)

Product Trade Name Synonyms

Validation Date Product Code

19 February 2004

E700011; E700022

Product Information

800-242-3233

U.N. No. Manufactured/ Supplied Schlke & Mayr Robert-Koch-Strasse 2 D-22851 Norderstedt Germany In Case of Emergency
Transportation: (800) 424-9300 (CHEMTREC) Medical: (800) 228-5635 ext. 284 (Prosar)

2924

2.

Composition and Information on Ingredients

Conc. (% w/w) 35 CAS No. 770-35-4 U.N. No. Not applicable. EU Symbol Not controlled.
C Xi F Xn

Ingredient Name
1) Phenoxypropanole

2) Ammonium, alkyldimethylbenzyl-, chloride 20 8001-54-5 Not applicable. 3) Tridecylpolyethylenglycolether 5-15 69011-36-5 Not applicable. 4) Isopropanol. 3-8 67-63-0 UN1219 5) Isodecanpolyethyleneglycol(11)ether 1-5 61827-42-7 Not applicable. Note: See section 8 for occupational exposure limits and section 11 for LC50/LD50 information.

R-Phrases Not controlled under dsd (Europe). R21/22, R34 R36/38 R11 R22, R36/38

3.

Hazards Identification
: CAUTION! CAUSES EYE AND SKIN IRRITATION. CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS: LIVER, GASTROINTESTINAL TRACT, CARDIOVASCULAR SYSTEM, RESPIRATORY TRACT, SKIN, EYES. VAPOR MAY CAUSE FLASH FIRE. MAY BE HARMFUL IF SWALLOWED. Keep away from heat, sparks and flame. Avoid contact with eyes, skin and clothing. Do not ingest. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling.

Primary Hazards and Critical Effects

4.

First Aid Measures

: If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical attention immediately. : Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately.

Inhalation Ingestion Skin Contact

Eye Contact

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5.

Fire-Fighting Measures
: In case of fire, use water spray (fog), foam, dry chemical, or CO2. Use foam or all purpose dry chemicals to extinguish. : Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear. : Flammable liquid and vapor. Vapor may cause flash fire. Vapors may accumulate in low or confined areas, travel considerable distance to source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. : These products are carbon oxides (CO, CO2).

Extinguishing Media Fire-Fighting Procedures Fire/Explosion Hazards

Hazardous Decomposition Products

6.

Accidental Release Measures

: Eliminate all ignition sources. Keep unnecessary personnel away. Use suitable protective equipment (Section 8). Follow all fire fighting procedures (Section 5). Do not touch or walk through spilled material. Hazard of slipping on spilled product. : For small spills add absorbent (soil may be used in the absence of other suitable materials) and use a non-sparking or explosion proof means to transfer material to a sealed, appropriate container for disposal.

Personal Precautions

Environmental Precautions and Clean-up Methods

Note: See section 1 for emergency contact information and section 13 for waste disposal.

7.

Handling and Storage

: Keep away from heat, sparks and flame. Avoid prolonged contact with eyes, skin, and clothing. Do not ingest. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. : Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame).

Handling

Storage

8.

Exposure Controls and Personal Protection

Occupational Exposure Limits Ingredient Name 1) Phenoxypropanole 2) benzalkonium chloride

OEL Canada OEL United States Not available. Not available. TWA: 15 (mg/m3) from OSHA (PEL) [United Not available. States] Total. TWA: 5 (mg/m3) from OSHA (PEL) [United States] Respirable. 3) Tridecylpolyethylenglycolether Not available. Not available. 4) Isopropyl alcohol TWA: 400 STEL: 500 (ppm) from ACGIH (TLV) Not available. [United States] [1994] Inhalation TWA: 983 STEL: 1230 (mg/m3) from ACGIH (TLV) [United States] [1994] Inhalation TWA: 400 STEL: 500 (ppm) from NIOSH [United States] [1994] Inhalation TWA: 980 STEL: 1225 (mg/m3) from NIOSH [United States] [1994] Inhalation TWA: 400 STEL: 500 (ppm) from OSHA (PEL) [United States] [1989] Inhalation TWA: 980 STEL: 1225 (mg/m3) from OSHA (PEL) [United States] [1989] Inhalation Not available. Not available. 5) Isodecanpolyethyleneglycol(11)ether Engineering Controls : Keep only in the original container in a cool, well-ventilated place. Personal Protective Equipment Respiratory System Skin and Body Hands Eyes : A respirator is not needed under normal and intended conditions of product use : Disposable outer garments, or impervious garments of equal or greater protection. : Gloves, Chemical resistant. : Safety glasses. Goggles, face shield, or other full-face protection if potential exists for direct exposure to aerosols or splashes.

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9.
Color Odor

Physical and Chemical Properties

: Liquid. : Green. : Pleasant : May start to solidify at -5C (23F) : 2.3 (Isopropyl alcohol) compared to Solvent : 100% (v/v). (Isopropyl alcohol.) : The highest known value is 2.07 (Air = 1) (Isopropyl alcohol). : The highest known value is 4.4 kPa (@ 20C) (Isopropyl alcohol). : 1.015 g/cm3 : Soluble in cold water, hot water, methanol, diethyl ether, acetone. : Dynamic: 33mPa.s : Not available : 52 C (126F) : The greatest known range is LOWER: 2% UPPER: 12% (Isopropyl alcohol)

Physical State and Appearance

Melting Point Evaporation Rate Volatility Vapor Density Vapor Pressure Density Solubility Viscosity Auto-Ignition Temperature Flash Point Explosion Limits

10. Stability and Reactivity

Stability Conditions and Materials to Avoid Hazardous Decomposition Products : The product is stable. : Slightly reactive to reactive with oxidizing agents, metals, acids, alkalis. : Not available.

11. Toxicological Information

Toxicity Data Ingredient Name 1) Phenoxypropanole 2) benzalkonium chloride Test Not available. LD50 LD50 LD50 LD50 LDLo Not available. LD50 LD50 LD50 LD50 LDLo LDLo LDLo LC50 Not available. Result Not available. 240 mg/kg 175 mg/kg 200 mg/kg 1560 mg/kg 13125 mg/kg Not available. 3600 mg/kg 5045 mg/kg 6410 mg/kg 12800 mg/kg 3570 mg/kg 5272 mg/kg 1537 mg/kg 17000 (4 hours) Not available. Route Not available. Oral Oral Oral Dermal Oral Not available. Oral Oral Oral Dermal Oral Oral Oral Inhalation Not available. Species Not available. Rat Mouse Guinea pig Rat Dog Not available. Mouse Rat Rabbit Rabbit Human Male. Dog Rat Not available.

3) Tridecylpolyethylenglycolether 4) Isopropyl alcohol

5) Isodecanpolyethyleneglycol(11)ether
Routes of Entry Acute Effects Inhalation Ingestion Skin Contact Eye Contact Chronic Effects Adverse Effects Target Organs Carcinogenic Effects Other Information :

Dermal contact. Eye contact. Inhalation. Ingestion.

: Irritant. : Harmful if swallowed. : Iritant : May cause severe eye irritation. : Not available. : Contains material which causes damage to the following organs: liver, gastrointestinal tract, cardiovascular system, respiratory tract, skin, eyes. : Not applicable. : Not available.

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Page: 4/5 Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs.

12. Ecological Information

Ecotoxicity Data Ingredient Name 1) Phenoxypropanole 2) benzalkonium chloride 3) Tridecylpolyethylenglycolether 4) Isopropyl alcohol 5) Isodecanpolyethyleneglycol(11)ether Environmental Hazards Species Not available. Fish. Not available. Brown Shrimp Not available. Period Not available. 24 hours Not available. 48 hours Not available. Result Not available. 1.5 ppm Not available. 1400 mg/l Not available.

: No known significant effects or critical hazards.

13. Disposal Consideration

Waste Handling and Disposal : Waste must be disposed of in accordance with federal, state and local environmental control regulations.

14. Transport Information

United States Shipping Description Canada Shipping Description : Combustible Liquid, n.o.s. 3 UN2924 I, 8, 3, 2924, I : Combustible Liquid, n.o.s. 3 UN2924 I, 3, 2924, I

15. Regulatory Information

US Regulations Haz-Com Standard : CLASS: Irritating substance. CLASS: Target organ effects. CLASS: Combustible liquid having a flash point between 37.8C (100F) and 93.3C (200F). : TSCA 4(a) final test rules: Isopropyl alcohol TSCA 8(a) PAIR: Isopropyl alcohol TSCA 8(b) inventory: Isopropyl alcohol; Deionized Water TSCA 8(d) H and S data reporting: Isopropyl alcohol: December 15,1986 TSCA 12(b) one time export: Isopropyl alcohol SARA 302/304/311/312 hazardous chemicals: benzalkonium chloride; Isopropyl alcohol SARA 311/312 MSDS distribution - chemical inventory - hazard identification: benzalkonium chloride: immediate health hazard, delayed health hazard; Isopropyl alcohol: fire, immediate health hazard, delayed health hazard SARA 313 toxic chemical notification and release reporting: Isopropyl alcohol 5.5% CERCLA: Hazardous substances.: Isopropyl alcohol; : Pennsylvania RTK: Isopropyl alcohol: (environmental hazard) Florida: Isopropyl alcohol Minnesota: Isopropyl alcohol Massachusetts RTK: Isopropyl alcohol New Jersey: Isopropyl alcohol : Not a WHMIS controlled material. : CEPA DSL: Isopropyl alcohol; Deionized Water : No products were found.

EPA

State

Canadian Regulations WHMIS CEPA Provincial

16. Other Information

Validated by schneidermartin on 02/19/2004. Version Date of Printing : 1.3 : 02/19/2004.

Notice to Reader

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Information contained herein is based solely on data provided by the manufacturer. Neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.