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MATERIAL SAFETY DATA SHEET

1. Product and Company Identification


Materia name 'er(ion ) I((ue date Re*i(ion date Super(ede( date CAS ) Product code Product u(e Synonym+(, Manufacturer information Manufacturer Addre(( Te ep-one Supp ier Addre(( Te ep-one ./ Hour Emer0ency Te ep-one PR!PA"E# LI$%EFIED PETR!LE%M &AS 01 07-19-2012 Mixture 127 Various. Unstenched Propane * Stenched Propane * HD-5 Propane * Standard Propane onsu!ers" o-operati#e $e%ineries &i!ited P.'. (ox 2)0* 9th +#enue ,orth $e-ina. S/ S0P 1+1 anada 210)3 721-5151 4ederated o-operati#es &i!ited P.'. (ox 1050. 001 - 22nd Street 5ast Sas6atoon S/ S7/ 1M9 anada 210)3 200-1007 2)113 99)-)))) - anutec

.. Ha1ard( Identification
P-y(ica (tate Appearance Emer0ency o*er*ie2 7as. o8or8ess 8i9ue%ied -as. D+,75$ 5xtre!e8: %8a!!a;8e -as. Hi-h pressure -as. 7as reduces ox:-en a#ai8a;8e %or ;reathin-. ontact <ith 8i9ue%ied -as !i-ht cause %rost;ites. in so!e cases <ith tissue da!a-e. =n a %ire or i% heated. a pressure increase <i88 occur and the container !a: ;urst or exp8ode. Static accu!u8atin- %8a!!a;8e !ateria8s can ;eco!e e8ectrostatica88: char-ed e#en in ;onded and -rounded e9uip!ent. Spar6s !a: i-nite !ateria8 and #apor !a: cause %8ash %ire 2or exp8osion3. !SHA re0u atory (tatu( Potentia -ea t- effect( Route( of e3po(ure Eye( S4in In-a ation >his product is ha?ardous accordin- to 'SH+ 29 =nha8ation. 5:es. S6in. 5xposure to rapid8: expandin- -as or #apori?in- 8i9uid !a: cause %rost;ite 2@co8d ;urn@3. 5xposure to rapid8: expandin- -as or #apori?in- 8i9uid !a: cause %rost;ite 2@co8d ;urn@3. Su%%ocation 2asph:xiant3 ha?ard - i% a88o<ed to accu!u8ate to concentrations that reduce ox:-en ;e8o< sa%e ;reathin- 8e#e8s. ,asa8 and respirator: tract irritation. centra8 ner#ous s:ste! e%%ects inc8udin- excitation. euphoria. contracted e:e pupi8s. di??iness. dro<siness. ;8urred #ision. %ati-ue. nausea. headache. 8oss o% re%8exes. tre!ors. con#u8sions. sei?ures. 8oss o% consciousness. co!a. respirator: arrest and sudden death cou8d occur as a resu8t o% 8on- ter! andAor hi-h concentration exposure to #apors. Ma: a8so cause ane!ia and irre-u8ar heart rh:th!. >his !ateria8 is a -as under nor!a8 at!ospheric conditions and in-estion is un8i6e8:. $espirator: tract. 5:es. entra8 ner#ous s:ste!. Ma: cause centra8 ner#ous s:ste! e%%ects. o!ponents ha#e ;een sho<n to ;e <ea6 cardiac sensiti?ers <hich can resu8t in cardiac arrh:th!ia and #entricu8ar %i;ri88ation. ,ot expected to ;e har!%u8 to a9uatic or-anis!s. 4$ 1910.1200.

In0e(tion Tar0et or0an( C-ronic effect( Potentia en*ironmenta effect(

P$'P+,5- &=BU54=5D P5>$'&5UM 7+S 909005 Version CD 01 $e#ision dateD - =ssue dateD 07-19-2012

PH PH MSDS MSDS,+ ,+ 1A)

5. Compo(ition 6 Information on In0redient(


Component( Propane 5thanethio8 CAS ) 70-9E-) 75-0E-1 Percent 100 0.005

/. Fir(t Aid Mea(ure(


Fir(t aid procedure( Eye contact S4in contact In-a ation In0e(tion "ote( to p-y(ician =!!ediate8: %8ush e:es <ith p8ent: o% <ater %or at 8east 15 !inutes. $e!o#e contact 8enses. i% present and eas: to do. ontinue rinsin-. 7et !edica8 attention i!!ediate8:. Fash %rost-;itten areas <ith p8ent: o% <ater. Do not re!o#e c8othin-. 7et !edica8 attention i!!ediate8:. Mo#e to %resh air. =% ;reathin- is di%%icu8t. -i#e ox:-en. =% not ;reathin-. -i#e arti%icia8 respiration. a88 a ph:sician or poison contro8 center i!!ediate8:. =n-estion is not a t:pica8 route o% exposure %or -ases or 8i9ue%ied -ases. >reat s:!pto!atica88:.

7. Fire Fi0-tin0 Mea(ure(


F amma8 e propertie( 5xtre!e8: %8a!!a;8e -as. 7as %or!s !ixtures <ith air <hich can catch %ire and ;urn <ith exp8osi#e #io8ence. Vapors are hea#ier than air and in#isi;8e !ixture spreads easi8: and !a: accu!u8ate in 8o< or con%ined areas. tra#e8 considera;8e distance to source o% i-nition and %8ash ;ac6. $uno%% to se<er !a: create %ire or exp8osion ha?ard. Dr: che!ica8. '2. <ater spra:. %o-. or %oa!.

E3tin0ui(-in0 media Suita8 e e3tin0ui(-in0 media Fire fi0-tin0 e9uipment6in(truction(

Se8%-contained ;reathin- apparatus. operated in positi#e pressure !ode and %u88 protecti#e c8othin- !ust ;e <orn in case o% %ire. Mo#e container %ro! %ire area i% it can ;e done <ithout ris6. Do not extin-uish %ires un8ess -as %8o< can ;e stopped sa%e8:* exp8osi#e re-i-nition !a: occur. Pro!pt8: iso8ate the scene ;: re!o#in- a88 persons %ro! the #icinit: o% the incident. ,o action sha88 ;e ta6en in#o8#in- an: persona8 ris6 or <ithout suita;8e trainin-. 4or %ires in#o8#in- this !ateria8. do not enter an: enc8osed or con%ined %ire space <ithout proper protecti#e e9uip!ent. inc8udin- se8%-contained ;reathin- apparatus. Stop %8o< o% !ateria8. Use <ater to 6eep %ire exposed containers coo8 and to protect personne8 e%%ectin- shuto%%. =% a 8ea6 or spi88 has not i-nited. use <ater spra: to disperse the #apors and to protect personne8 atte!ptin- to stop 8ea6. Pre#ent runo%% %ro! %ire contro8 or di8ution %ro! enterin- strea!s. se<ers or drin6in- <ater supp8:.

Ha1ardou( com8u(tion product(

ar;on oxides.

:. Accidenta Re ea(e Mea(ure(


Per(ona precaution( 5#acuate the area pro!pt8:. ,o action sha88 ;e ta6en in#o8#in- an: persona8 ris6 or <ithout suita;8e trainin-. /eep unnecessar: personne8 a<a:. 5nsure ade9uate #enti8ation. =n case o% inade9uate #enti8ation. use respirator: protection. Fear appropriate persona8 protecti#e e9uip!ent 2See Section E3. En*ironmenta precaution( Met-od( for c eanin0 up Shou8d not ;e re8eased into the en#iron!ent. Pre#ent %urther 8ea6a-e or spi88a-e i% sa%e to do so. Pre#ent %ro! enterin- into soi8. ditches. sanitar: se<ers. <ater<a:s andAor -round<ater. Venti8ate <e88. stop %8o< o% -as or 8i9uid i% possi;8e. =!!ediate8: contact e!er-enc: personne8.

;. Hand in0 and Stora0e


Hand in0 58i!inate sources o% i-nition. +#oid spar6 pro!oters. 7roundA;ond container and e9uip!ent. >hese a8one !a: ;e insu%%icient to re!o#e static e8ectricit:. Fear appropriate persona8 protecti#e e9uip!ent 2See Section E3. 5atin-. drin6in-. and s!o6inshou8d ;e prohi;ited in areas <here this !ateria8 is hand8ed. stored. and processed. Do not ;reathe -as. Do not -et in e:es. on s6in. on c8othin-. Use on8: <ith ade9uate #enti8ation. Store in accordance <ith 8oca8. re-iona8. nationa8. and internationa8 re-u8ations. Secure c:8inders in an upri-ht position at a88 ti!es. c8ose a88 #a8#es <hen not in use. Store in a coo8. dr:. <e88-#enti8ated p8ace. /eep container ti-ht8: c8osed and sea8ed unti8 read: %or use. Protect c:8inders %ro! da!a-e.
PH PH MSDS MSDS,+ ,+ 2A)

Stora0e

P$'P+,5- &=BU54=5D P5>$'&5UM 7+S 909005 Version CD 01 $e#ision dateD - =ssue dateD 07-19-2012

<. E3po(ure Contro ( 6 Per(ona Protection


!ccupationa e3po(ure imit( %S. AC&IH T-re(-o d Limit 'a ue( Component( Propane 2 +S 70-9E-)3 Type >F+ 'a ue 1000 pp! 'a ue 1E00 !-A!1 1000 pp!

%S. !SHA Ta8 e =#1 Limit( for Air Contaminant( +.> CFR 1>1?.1???, Component( Type Propane 2 +S 70-9E-)3 P5&

Canada. A 8erta !EL( +!ccupationa Hea t- @ Safety CodeA Sc-edu e 1A Ta8 e ., Component( Type 'a ue Propane 2 +S 70-9E-)3 >F+ 1000 pp! Canada. Briti(- Co um8ia !EL(. +!ccupationa E3po(ure Limit( for C-emica Su8(tance(A !ccupationa Hea t- and Safety Re0u ation .>:6>;A a( amended, Component( Type 'a ue Propane 2 +S 70-9E-)3 >F+ 1000 pp! Canada. !ntario !EL(. +Contro of E3po(ure to Bio o0ica or C-emica A0ent(, Component( Type 'a ue Propane 2 +S 70-9E-)3 >F+ 1000 pp! Canada. $ue8ec !EL(. +Mini(try of La8or # Re0u ation Re(pectin0 t-e $ua ity of t-e Cor4 En*ironment, Component( Type 'a ue Propane 2 +S 70-9E-)3 En0ineerin0 contro ( >F+ 1E00 !-A!1 1000 pp!

Use process enc8osures. 8oca8 exhaust #enti8ation. or other en-ineerin- contro8s to contro8 air;orne 8e#e8s ;e8o< reco!!ended exposure 8i!its. >he en-ineerin- contro8s a8so need to 6eep -as. #apor. or dust concentrations ;e8o< an: 8o<er exp8osi#e 8i!its. Fear appro#ed sa%et: -8asses or -o--8es. Fear protecti#e c8othin- appropriate %or the ris6 o% exposure. =% en-ineerin- contro8s do not !aintain air;orne concentrations ;e8o< reco!!ended exposure 8i!its 2<here app8ica;8e3 or to an accepta;8e 8e#e8 2in countries <here exposure 8i!its ha#e not ;een esta;8ished3. an appro#ed respirator !ust ;e <orn. Do not eat. drin6 or s!o6e <hen usin- the product. Fash thorou-h8: a%ter hand8in-. Pro#ide e:e<ash station and sa%et: sho<er. Hand8e in accordance <ith -ood industria8 h:-iene and sa%et: practices.

Per(ona protecti*e e9uipment Eye 6 face protection S4in protection Re(piratory protection

&enera -y0iene con(ideration(

>. P-y(ica @ C-emica Propertie(


Appearance P-y(ica (tate Form Co or !dor !dor t-re(-o d pH 'apor pre((ure 'apor den(ity Boi in0 point Me tin0 point6Free1in0 point So u8i ity +2ater, Specific 0ra*ity F a(- point F amma8i ity imit( in airA upperA D 8y *o ume o8or8ess 8i9ue%ied -as. 7as. o!pressed 8i9ue%ied -as. o8or8ess (oi8in- ca;;a-e i% stenched. 0E00 pp! ,ot a#ai8a;8e. 1010.1 - 1201 6Pa 1.) -01.) G4 2-02 G 3 -292 G4 2-1E0 G 3 A -102.) G4 2-1E5.E9 G 3 ).5 H #A# 220 G 3 0.5E -150 G4 2-101.1 G 3 Pens6:-Martens 9.5 H 8osed up

P$'P+,5- &=BU54=5D P5>$'&5UM 7+S 909005 Version CD 01 $e#ision dateD - =ssue dateD 07-19-2012

PH PH MSDS MSDS,+ ,+ 1A)

F amma8i ity imit( in airA o2erA D 8y *o ume Auto#i0nition temperature '!C E*aporation rate Mo ecu ar 2ei0-t Mo ecu ar formu a !t-er data Critica temperature

2.2 H E09.) G4 2012 G 3 100 H I 1 25ther 2anh:drous3J13 00.11 -A!o8 1-HE 205.9 G4 29).) G 3

1?. C-emica Sta8i ity @ Reacti*ity Information


C-emica (ta8i ity Condition( to a*oid Incompati8 e materia ( Ha1ardou( decompo(ition product( Po((i8i ity of -a1ardou( reaction( Sta;8e under nor!a8 te!perature conditions and reco!!ended use. =n a %ire or i% heated. a pressure increase <i88 occur and the container !a: ;urst or exp8ode. 'xidi?in- a-ents. $educin- a-ents. +cids. +86a8is. ,one 6no<n. Po8:!eri?ation <i88 not occur.

11. To3ico o0ica Information


To3ico o0ica data Component( Propane 2 +S 70-9E-)3 Acute Inhalation & 50 Sen(iti1ation Acute effect( Specie( Te(t Re(u t(

$at ,ot a#ai8a;8e.

I 1002.E07 !-A8. 15 Minutes

Su%%ocation 2asph:xiant3 ha?ard - i% a88o<ed to accu!u8ate to concentrations that reduce ox:-en ;e8o< sa%e ;reathin- 8e#e8s. 5xposure to rapid8: expandin- -as or #apori?in- 8i9uid !a: cause %rost;ite 2@co8d ;urn@3. Ma: cause centra8 ner#ous s:ste! e%%ects.

C-ronic effect(

1.. Eco o0ica Information


Ecoto3icity Per(i(tence and de0rada8i ity Bioaccumu ation 6 Accumu ation Partition coefficient Propane ,ot expected to ;e har!%u8 to a9uatic or-anis!s. ,ot a#ai8a;8e. ,ot a#ai8a;8e.

2.1)

15. Di(po(a Con(ideration(


Ca(te code( Di(po(a in(truction( D001D Faste 48a!!a;8e !ateria8 <ith a %8ash point K100 G4 Dispose in accordance <ith a88 app8ica;8e re-u8ations. 5!pt: containers !a: contain product residues. Do not puncture or incinerate e#en <hen e!pt:. >his !ateria8 andAor its container !ust ;e disposed o% as ha?ardous <aste. $eturn the e!pt: c:8inder to the supp8ier.

1/. Tran(port Information


D!T Ba(ic (-ippin0 re9uirement(E U,197E %" num8er Propane Proper (-ippin0 name 2.1 Ha1ard c a(( Additiona informationE 19. >50 Specia pro*i(ion( 10) Pac4a0in0 e3ception(
P$'P+,5- &=BU54=5D P5>$'&5UM 7+S 909005 Version CD 01 $e#ision dateD - =ssue dateD 07-19-2012 PH PH MSDS MSDS,+ ,+ 0A)

Pac4a0in0 non 8u 4 Pac4a0in0 8u 4 Reporta8 e 9uantity IATA %" num8er %" proper (-ippin0 name Tran(port -a1ard c a((+e(, ER& code IMD& %" num8er %" proper (-ippin0 name Tran(port -a1ard c a((+e(, EmS "o. TD& Proper (-ippin0 name Ha1ard c a(( %" num8er Marine po utant

100 110. 115 100 U,197E Propane 2.1 10& U,197E P$'P+,5 2.1 4-D. S-U P$'P+,5 2.1 U,197E ,o

17. Re0u atory Information


%S federa re0u ation( >his product is a @Ha?ardous he!ica8@ as de%ined ;: the 'SH+ Ha?ard Standard. 29 4$ 1910.1200. +88 co!ponents are on the U.S. 5P+ >S + =n#entor: &ist. o!!unication

TSCA Section 1.+8, E3port "otification +/? CFR ;?;A Su8pt. D, ,ot re-u8ated. C ean Air Act +CAA, Section 11. Ha1ardou( Air Po utant( +HAP(, Li(t ,ot re-u8ated. CERCLA +Superfund, reporta8 e 9uantity + 8(, +/? CFR 5?../, PropaneD 100 Superfund Amendment( and Reaut-ori1ation Act of 1><: +SARA, Ha1ard cate0orie( =!!ediate Ha?ard - Les De8a:ed Ha?ard - ,o 4ire Ha?ard - Les Pressure Ha?ard - Les $eacti#it: Ha?ard - ,o Section 5?. e3treme y -a1ardou( (u8(tance +/? CFR 577A Appendi3 A, Section 511651. +/? CFR 5;?, C ean Cater Act +CCA, Section 11.+r, +/? CFR :<.15?, Dru0 Enforcement Admini(tration +DEA, +.1 CFR 15?<.11#17, Canadian re0u ation( CHMIS (tatu( CHMIS c a((ification CHMIS a8e in0 Les

Les Ha?ardous su;stance ,ot contro88ed

>his product has ;een c8assi%ied in accordance <ith the ha?ard criteria o% the contains a88 the in%or!ation re9uired ;: the P$. ontro88ed + - o!pressed 7as (1 - 48a!!a;8e 7ases

P$ and the MSDS

P$'P+,5- &=BU54=5D P5>$'&5UM 7+S 909005 Version CD 01 $e#ision dateD - =ssue dateD 07-19-2012

PH PH MSDS MSDS,+ ,+ 5A)

In*entory (tatu( Country+(, or re0ion +ustra8ia anada anada hina 5urope 5urope Mapan /orea ,e< Nea8and Phi8ippines United States O Puerto $ico State re0u ation( %S # Ca ifornia Propo(ition :7 # Carcino0en( @ Reproducti*e To3icity +CRT,E Li(ted (u8(tance ,ot 8isted. %S # "e2 Ger(ey RTH # Su8(tance(E Li(ted (u8(tance Propane 2 +S 70-9E-)3 &isted. %S. Ma((ac-u(ett( RTH # Su8(tance Li(t Propane 2 +S 70-9E-)3 &isted. %S. "e2 Ger(ey Cor4er and Community Ri0-t#to#Hno2 Act Propane 2 +S 70-9E-)3 500 &(S %S. Penn(y *ania RTH # Ha1ardou( Su8(tance( Propane 2 +S 70-9E-)3 &isted. In*entory name +ustra8ian =n#entor: o% he!ica8 Su;stances 2+= S3 !n in*entory +ye(6no,F Les Les ,o hina 2=5 S 3 he!ica8 Les Les ,o Les Les Les he!ica8s and he!ica8 Su;stances Les Les

Do!estic Su;stances &ist 2DS&3 ,on-Do!estic Su;stances &ist 2,DS&3 =n#entor: o% 5xistinhe!ica8 Su;stances in o!!ercia8 5uropean =n#entor: o% 5xistinSu;stances 25=,5 S3 5uropean &ist o% ,oti%ied 5xistin=n#entor: o% 5xistin- and ,e< he!ica8s &ist 25 &3 ,e< Nea8and =n#entor: Phi8ippine =n#entor: o% 2P= S3 >oxic Su;stances

he!ica8 Su;stances 25&=, S3 he!ica8 Su;stances 25, S3

ontro8 +ct 2>S +3 =n#entor:

*+ @Les@ indicates this product co!p8ies <ith the in#entor: re9uire!ents ad!inistered ;: the -o#ernin- countr:2s3

1:. !t-er Information


Furt-er information HMISI ratin0( HM=SP is a re-istered trade and ser#ice !ar6 o% the ,P +. Hea8thD 1 48a!!a;i8it:D 0 Ph:sica8 ha?ardD 0 Hea8thD 1 48a!!a;i8it:D 0 =nsta;i8it:D 0 >o the ;est o% our 6no<8ed-e. the in%or!ation contained herein is accurate. Ho<e#er. neither the a;o#e na!ed supp8ier nor an: o% its su;sidiaries assu!es an: 8ia;i8it: <hatsoe#er %or co!p8eteness o% the in%or!ation contained herein. 4ina8 deter!ination o% suita;i8it: o% an: !ateria8 is the so8e responsi;i8it: o% the user. +88 !ateria8s !a: present un6no<n ha?ards and shou8d ;e used <ith caution. +8thou-h certain ha?ards are descri;ed herein. <e cannot -uarantee that these are the on8: ha?ards that exist.

"FPA ratin0(

Di(c aimer

P$'P+,5- &=BU54=5D P5>$'&5UM 7+S 909005 Version CD 01 $e#ision dateD - =ssue dateD 07-19-2012

PH PH MSDS MSDS,+ ,+ )A)