0 оценок0% нашли этот документ полезным (0 голосов)
90 просмотров48 страниц
Crystal field theory models the interaction between ligands and metal d-orbitals in coordination complexes. It considers the ligands to be point negative charges that repel the d-electrons on the metal ion. In an octahedral complex, the ligands destabilize the two d-orbitals that point toward them, creating an energy gap Δ. The size of Δ depends on factors like the metal, its oxidation state, and the ligands. Δ influences the electron configuration and resulting properties such as color, magnetism, and thermodynamic stability.
Crystal field theory models the interaction between ligands and metal d-orbitals in coordination complexes. It considers the ligands to be point negative charges that repel the d-electrons on the metal ion. In an octahedral complex, the ligands destabilize the two d-orbitals that point toward them, creating an energy gap Δ. The size of Δ depends on factors like the metal, its oxidation state, and the ligands. Δ influences the electron configuration and resulting properties such as color, magnetism, and thermodynamic stability.
Авторское право:
Attribution Non-Commercial (BY-NC)
Доступные форматы
Скачайте в формате PDF, TXT или читайте онлайн в Scribd
Crystal field theory models the interaction between ligands and metal d-orbitals in coordination complexes. It considers the ligands to be point negative charges that repel the d-electrons on the metal ion. In an octahedral complex, the ligands destabilize the two d-orbitals that point toward them, creating an energy gap Δ. The size of Δ depends on factors like the metal, its oxidation state, and the ligands. Δ influences the electron configuration and resulting properties such as color, magnetism, and thermodynamic stability.
Авторское право:
Attribution Non-Commercial (BY-NC)
Доступные форматы
Скачайте в формате PDF, TXT или читайте онлайн в Scribd
Valence Bond Theory (VBT) Crystal Field Theory (CFT) Molecular Orbital Theory (MOT)
Valence Bond Theory (VBT)
Lewis bases (ligands) Lewis acids (metals or metal ions) The metal utilizes hybridization of metal s, p, and d valence orbitals to account for the observed structures and magnetic properties of complexes.
Pt2+ 2 PtCl42-
[Xe]4f145d8
dsp2 hybrid orbitals electrons from Cl-, square planar
Ni2+ NiCl42-
[Ar]3d8
sp3 hybrid orbitals electrons from Cl-, tetrahedral
Co3+ CoF63-
[Ar]3d6
sp3d2 hybrid orbitals electrons from F-, octahedral
Co3+
[Ar]3d6
Co(NH3)63+
d2sp3 hybrid orbitals electrons from NH3, octahedral