THERMODYNAMICS

O1. Is there an ncrease or decrease n entropy when an onc

compound s dssoved n water?
O2. State frst aw of thermodynamcs & gve ts mathematca
expresson.
O3. What s the dfference b/w state functons & path functons?
gve an exampe for each.
O4. Mass & voume are extensve propertes but densty s an
ntensve property. Why ? Gve reason.
O5. Startng wth thermodynamc reatonshp G = H - TS, derve
reatonshp b/w free energy change & tota entropy change at a
constant temp.
O6. State Hesss aw of constant heat summaton. How does t
foow from the frst aw of thermodynamcs?
O7. What s average bond enthapy? How s t dfferent from bond
energy of a datomc moecue. Gve sutabe exampe.
O8. For the reacton 2A(g) + B (g) -------------- 2D (g) , Std.
nterna energy change & std. entropy change are -10.5 K| &
-44.10 |/k resp. Cacuate std. free energy change for the reacton
& predct whether the reacton w be feasbe?
O9. Enthapes of formaton of CO(g) , Co
2
(g) ,N
2
O(g) & N
2
O
4
(g)
are -110 , 393 ,81 & 9.7 K|/mo resp. Fnd the vaue of change of
enthapy of the foowng reacton
N
2
O
4
(g) + 3CO (g) ------------------ N
2
O (g) + 3CO
2
(g)
O10. Cacuate the entropy of fuson of ce, ts atent heat of
fuson s 6K|/moat ts meyng pont.
Chemical equilibrium
O1. What s the effect of ncrease of pressure on the soubty of
gases n qud?
O2. What s the vaue of free energy change at equbrum?
O3. The soubty product of AgC s found to be 1.4 x 10
-4
at a
temp. Equa to the bong pont of water. Cacuate the soubty
of AgC at that temp.
O4. Cacuate hydronum on conc. Of a souton whose pH s 4?
O5.PC
5
& C
2
are at 500K & havng conc. 1.59M PC
3
, 1.59M C
2
&
1.41M PC
5,
Cacuate K
c
for the reacton when dssocaton of PC
5

to gve PC
3
& C
2
s at equbrum.
O6. Defne a buffer souton. Gve exampe too.
O7. Expan Bronsted Lowry & Lews Acd concept wth exampes.
O8.How does a catayst affect the equbrum? Expan usng Le
Chateer Prncpe.
O9. Cacuate pH of: ------
(a) A souton contanng 2g of NaOH per tre.
(b) 0.01M NaOH son.
O10. For the reacton: ------
2NOC (g) < =========== 2No(g) + C
2
(g)
The vaue of the equbrum constant Kc = 3.75 x10
-6
at 1069K.
Cacuate the vaue of Kp for ths reacton at ths temp.