Science - Paper - 2

CHEMISTRY ( One hour and a half ) Answers to this Paper must be written on the separate paper.

Guess paper

The time given at the head of this paper is the time allowed for writing the answers. Attempt all questions from Section I and any four from Section II The intended marks for questions or parts of questions are given in brackets [ ]. SECTION - I ( 40 Marks ) Attempt all questions from this section Question 1 A. From the following list of substances, choose the one substance in each case which matches the description (1) to (6) given below. (Write down the names exactly as they are given in the list. Do not write formulae.) ammonium nitrate, calcium hydrogen carbonate, copper carbonate, lead carbonate, lead nitrate, potassium nitrate, sodium carbonate, sodium hydrogen carbonate, zinc carbonate.
1) A hydrogen carbonate which exists in the solid state. 2) A carbonate not decomposed by heat. 3) A green coloured carbonate which turns black on heating. 4) A nitrate which gives off only oxygen when heated. 5) A nitrate which on heating decomposes into dinitrogen oxide (nitrous oxide) and steam. 6) A nitrate which gives off oxygen and nitrogen dioxide when heated.

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B. Write balanced equations for the following reactions : 1) Iron (III) chloride solution with sodium hydroxide solution. 2) Ammonium chloride and warm sodium hydroxide solution. 3) Zinc hydroxide solution and sodium hydroxide solution. 4) Hydrochloric acid and sodium hydroxide solution. 5) Aluminium metal and sodium hydroxide solution. i.testseries@gmail.com Mr. Rajendra Burriwar, M.Sc., B.Ed. [5] Ph : +919892196963

C. Answer the following : 1) What is an electrolyte ? 2) Classify following substance under three headings : Strong Electrolytes, Weak Electrolytes, Non Electrolytes acetic acid, ammonium chloride, ammonium hydroxide, carbon tetrachloride, dilute hydrochloric acid, sodium acetate, dilute sulphuric acid, acetone. 3) What is electroplating ? D. Some methods used for the laboratory preparation of salts are : active metal + dil. acid, carbonate + carbon dioxide, precipitation (double decomposition), [6]

direct combination, titration, insoluble base + dil. Acid. Copy and complete the following table: Salt 1) Sodium sulphate 2) Copper (II) sulphate 3) Iron (III) chloride 4) Sodium hydrogen carbonate 5) Zinc sulphate 6) Lead chloride [6] E. What do you see when : 1) Concentrated nitric acid is added to copper. 2) Concentrated sulphuric acid is added to copper sulphate . 5 water. 3) Concentrated hydrochloric acid is added to lead (IV) oxide with warming. 4) Lead nitrate crystals are heated strongly. 5) Piece of calcium metal is added to phenolphthalein solution. 6) Ammonia gas is passed through Nesslers reagent. i.testseriesr@gmail.com [6] Mr. Rajendra Burriwar, M.Sc., B.Ed. Method of Preparation

F. Copy and complete the following table which summarizes the effect of adding a small amount of sodium hydroxide to various salt solutions followed by an excess of the reagent, and then adding ammonium hydroxide (ammonia solution) in a small amount followed by an excess to another sample of each of the salt solutions. Solutions Effect of adding sodium hydroxide solutions Small amount 1) Calcium nitrate 2) Zinc nitrate 3) Lead nitrate
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Effect of adding ammonium hydroxide Small amount No precipitate In excess No change

In excess

G. Solve the following 1) What is the volume (measured in dm3 or litres) occupied by one mole of a gas at STP ? 2) 112 cm3 (at STP) of a gaseous fluoride of phosphorus has a mass of 0.63 g. Calculate the relative molecular mass of the fluoride. If the molecule of the fluoride contains only one atom of phosphorus, then determine the formula of the phosphorus fluoride. (F = 19; P = 31) 3) Determine the empirical formula of the compound whose composition by mass is 42 % nitrogen, 48 % oxygen and 9 % hydrogen. (H = 1, N = 14, 0 = 16) [6]

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Mr. Rajendra Burriwar, M.Sc., B.Ed.

SECTION - I ( 40 Marks ) Attempt all questions from this section

Question 2 A. This question refers to elements and their variation of properties : 1) 2) 3) 4) 5) 6) 7) Name the elements in period 1. What happens to atomic size of elements on moving from left to right in a period ? What happens to ionization potential of elements on moving from left to right in a period ? What happens to reactivity of metals on moving down in a group ? Name two metalloids one from period 2 and one from period 3. Name one element which is a fuming red-brown liquid at room temperature. What is the common feature of the electronic configurations of the elements at the end of period 2 and period 3 ? 8) If an element is in group 7 (or group 7A), is it likely to be metallic or non-metallic in character ? [2] [8]

B. Supply the missing word from those in brackets : 1) If an element has one electron in its outermost energy level (shell) then it is likely to be .... (metallic / nonmetallic ). 2) The group of ( alkali metals / halogens ) is the only group in periodic table which contains elements in all three familiar states of matter at standard temperature and pressure.

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Mr. Rajendra Burriwar, M.Sc., B.Ed.

Question 3 A. Give the names and structural formulae of : 1) 2) A saturated hydrocarbon with two carbon atoms. The first member of an unsaturated hydrocarbon with a double bond. [2] [4]

B. Copy and complete the following sentence: A saturated hydrocarbon will undergo ..................................................... reactions whereas the typical reaction of an unsaturated hydrocarbon is ......................................................... . C. Answer the following : 1) 2) 3) 4) Write the equation for the laboratory preparation of ethyne (acetylene) from calcium carbide. What is the special feature of the structure of ethyne ? What would you see when ethyne is bubbled through a solution of bromine in carbon tetrachloride ? What would you see when ethyne is bubbled through a solution of ammonical cuprous chloride ?

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Question 4 A. X is an element in the form of a powder. X burns in oxygen and the product formed is soluble in water. The solution is tested with litmus. Write down only the word which will correctly complete each of the following sentences. 1) 2) 3) 4) 5) 6) If X is a metal, then the litmus will turn ........................................................ If X is a non-metal, then the litmus will turn ................................................. If X is a reactive metal, then .. gas will be evolved when X reacts with dilute H2SO4. If X is a metal it will form ..................... oxide, which will form ..................... solution with water. If X is a .... metal it will react with sodium hydroxide to liberate .. . If X is . it produces a purple or lilac colored flame in the flame test. [4]

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Mr. Rajendra Burriwar, M.Sc., B.Ed.

B. The ore zinc blende is an important source of the metal zinc. 1) What is the name of the zinc compound in zinc blende? 2) What is the zinc compound obtained by roasting zinc blende ? 3) What is the type of chemical reaction carried out after roasting in order to obtain zinc ? 4) Are liquid zinc and liquid lead miscible or immiscible ? 5) What is the name of the alloy formed by zinc and copper ? 6) The zinc metal was used for galvanization. Give reason.

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Question 5 A. Questions given below are related with lab-preparation of hydrochloric acid : 1) What must be added to sodium chloride to obtain hydrogen chloride in laboratory preparation ? 2) Write the equation for the reaction which takes place in (A) (i) above. 3) What would you see when hydrogen chloride mixes with ammonia ? B. Hydrogen chloride dissolves in water forming an acidic solution. 1) Name the experiment which demonstrates that hydrogen chloride is very soluble in water. 2) Give three distinct tests (apart from using an indicator) you would carry out with this solution to illustrate the typical properties of an acid. C. Write the equation for the reaction of hydrochloric acid with each of the following: 1) Bleaching powder 2) Silver nitrate solution 3) Manganese (IV) oxide [3] [4] [3]

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Mr. Rajendra Burriwar, M.Sc., B.Ed.

Question 6 A. Give reasons : 1) Lead (II) oxide required to convert into lead (II) nitrate before adding dilute HCl for preparing insoluble lead chloride from. 2) Electrovalent compounds are usually hard crystals. 3) Electrovalent compounds dissolve in water whereas covalent compounds do not. 4) Concentrated HNO3 prepared in laboratory is yellow in colour. B. Solve the following : 1) If 112 cm3 of hydrogen sulphide is mixed with 120 cm3 of chlorine at STP what mass of sulphur is formed ? H2S + Cl2 2 HCl + S [2] [4]

2) When excess lead nitrate solution was added to a solution of sodium sulphate, 15.15 g of lead sulphate were precipitated. What mass of sodium sulphate was present in the original solution ? Na2SO4 + Pb(NO3)2 PbSO4 + 2 NaNO3 [4]

(H = 1; C = 12; O = 16; Na = 23; S = 32; Pb = 207)

Question 7 A. Questions given below are related with contact process : 1) 2) 3) What is the purpose of the contact process ? Name the catalyst used in the contact process. Write the balanced equation for the reaction in the contact process which takes place in the presence of the catalyst. [3]

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Mr. Rajendra Burriwar, M.Sc., B.Ed.

B. Questions given below are related with Haber process estimated to be responsible for sustaining one-third of the Earth's population. 1) 2) What is the purpose of the Haber process ? Name the gaseous inputs of the Haber process and state the ratio by volume in which the gases are mixed. 3) 4) 5) What is done to increase the rate of the reaction in the Haber process ? Give two different ways by which the product can be separated from the reactants. Name the most popular catalyst and promoter combination for Haber process. [6]

C. With reference to the reduction of copper oxide, iron (II) oxide, lead (II) oxide and magnesium oxide by hydrogen, place the oxides in order of increasing case of reduction. That is, put first the oxide that is most difficult to reduce, and last, the oxide that is most easily reduced. [1]

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Mr. Rajendra Burriwar, M.Sc., B.Ed.