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Summer Term End Examination - July 2013

Class NBR : 1040 Slot : A
Course Code : CHY101
Course Title : Engineering Chemistry
Time : Three Hours Max.Marks:100
PART - A (20 X 2 = 40 Marks)
Answer ALL Questions
1. Define Priming and Foaming.

2. Explain about the desalination.

3. Calculate the temporary hardness and permanent hardness of water sample having the
following values;Ca(HCO
3
)
2
= 32.4 mgs/L, Mg(HCO
3
)
2
= 14.6 mg/L,CaCl
2
= 22.2 mgs/L,
MgSO
4
= 60mgs/L.

4. What are the disadvantages of sludge and scale?

5. Write the mechanism of dry corrosion.

6. Define Pilling-Bedworth rule.

7. State the principle involved in CVD?

8. What is a sacrificial anode? How does it function?

9. Give the structure of polymer formed by the reaction between Formaldehyde and Phenol.

10. Give the formula and any two application of Cellulose nitrate.

11. Differentiate homochain and heterochain polymers.

12. What is biodegradable polymers and give any two examples.

13. Distinguish between the solid and liquid fuels.

14. Write note on calorific value.

15. Write the formula of diesel index and explain it.

16. Why is C
2
H
4
Br
2
added, when TEL is used as antiknock?

17. Differentiate primary and secondary cells.

18. Define redox reaction with appropriate examples.

19. What are the electrode, electrolyte and voltage output in NICAD Cell?

20. Give the overall cell reactions involved in alkaline dry cell.




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PART B (5 X 12 = 60 Marks)
Answer ALL Questions

21.(a) (i) How will you estimate the temporary, permananent, and total hardnesss of hard
water using EDTA titration method and briefly explain it.
[8]
(ii) Briefly explain about the reverse osmosis with a neat diagram.
[4]

OR
21.(b) (i) Calculate the amount of lime and soda required to soften of 50,000L of water
containing the following constituents per litter.
Mg(HCO
3
)
2
= 30 mg, Ca(HCO
3
)
2
= 20 mg, MgCl
2
= 8.0 mg, CaSO
4
= 20.6 mg,
MgSO
4
= 20 mg. [Atomic wts: Ca=40, Mg= 24, C=12, O=16, H=1, S=32, Cl= 35.5]
[6]

(ii) Explain Ion exchange process with neat diagram. Give their advantages and
disadvantages.
[6]
22.(a) (i) Discuss the wet corrosion with absorption of oxygen and libration of hydrogen.
[7]
(ii) What is galvanic corrosion? How is it prevented?
[5]

OR
22.(b) (i) Briefly explain the Physical Vapor Deposition.
[6]

(ii) What are factors affecting the corrosions. [6]
23.(a) (i) Differentiate between the thermoplastic and thermosetting polymers with suitable
examples.
[5]
(ii) With a neat sketch describe any two moulding methods used in polymer industries. [7]
OR
23.(b) How will synthesis the following polymers and write their applications. (i). PVC,
(ii) TEFLON, (iii) Nylon 6,6, and (iv) Urea Formaldehyde Resins.

24.(a) Describe the working principles and reaction involved in the analysis of calorific value of
solid and liquid fuels.


OR
24.(b) (i) Define about the Octane number and how is it related to chemical composition and
molecular structure of fuel.
[6]

(ii) Give the composition and application of LPG and CNC.
[6]
25.(a) Describe the working principle and applications of Leclanche cell and Lithium batteries.


OR
25.(b) (i) Briefly explain the construction and working of H
2
-O
2
fuel cell.
[6]

(ii) Give a brief account on solid oxide fuel cells.
[6]