Jee Advance 2013 (Paper II)

NARAYANA IIT/PMT ACADEMY
JEE ADVANCE : 2013

(PAPER II) This booklet contains 40 printed pages XYZ PAPER -1 : PHYSIC, CHEMISTY & MATHEMATICS Please Read the Instructions carefully You are allotted 5 minutes specifically for this purpose Important Instructions: INSTRUCTIONS A General : This booklet is your Questions Paper Do not break the seals of this booklet before being instructed to do so by the invigilators The question paper CODE is printed on the right hand top corner of this sheet and on the back page (Page No 44) of this booklet Blank spaces and blank pages are provided in the question paper for your rough work No additional sheets will be provided for rough work Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers and electronic gadgets are NOT allowed inside the examination hall Write your name and roll number in the space provided on the back cover of this booklet Answers to the questions and personal details are to be filled on a two part carbon less paper, which is provided separately These parts should only be separated at the end of the examination when instructed by the invigilator The upper sheet is machine gradable objective Response Sheet (ORS) which will be retained by the invigilator You will be allowed to take away the bottom sheet at the end of the examination Using a black ball point pen darken the bubbles on the upper original sheet Apply sufficient pressure so that the impression is created on the bottom duplicate sheet DO NOT TAMPER WITH/MUTILATE THE ORS OR THE BOOKLET On breaking the seals of the booklet check that it contains 44 pages and all the 60 questions and corresponding answers choices are legible Read carefully the instruction printed at the beginning of each section and TOTAL MARKS 180 B, Filling the right part of the ORS The ORS also has a CODE printed on its left and right parts Check that the CODE printed on the ORS (on both sheets) is the same as that on this booklet and put your signature affirming that you have verified this IF THE CODES DO NOT MATCH, ASK FOR A CHANGE OF THE BOOKLET
CODE: 0
Test Booklet Code
NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

JEE ADVANCE : 2013
(PAPER II)
CODE: 0
PART I : PHYSICS
SECTION -1 : (One or more options correct Type) The section contains 8 multiple choice questions Each question has four choices (A), (B), (C) and (D) out of which ONE and MORE are correct 1 The figure below shows the variation of specific heat capacity (C) of a solid as a function of temperature (T) The temperature is increased continuously from 0 to 500 K at a constant rate Ignoring any volume change, the following statement(s) is (are) correct to a reasonable approximation (A) the rate at which heat is absorbed in the range 0-100 K varies linearly with temperature T (B) heat absorbed in increasing the temperature from 0-100 K is less than the heat required for increasing the temperature from 400-500 K (C) there is no change in the rate of heat absorption in the range 400-500 K (D) the rate of heat absorption increases in the range 200-300 K
100 200 300 400 500

T(K)
Ans Sol:
A, B, C, D dQ CdT and C varies linearly with T (A) is correct Area under the graph in the range O-100 k is less than area under 400-500 K range (B) is correct In the range 400 500 K, C is constant (C) is correct In the range 200 300 K, C is increasing (D) is correct The radius of the orbit of an electron in a hydrogen-like atom is 45 a0, where a0 is the Bohr 3h radius Its orbital angular momentum is It is given that h is Planck constant and R is Rydberg 2 constant The possible wavelength(s), when the atom de-excites, is (are) 9 9 (A) (B) 32R 16R 2

JEE ADVANCE : 2013
9 5R A, C aon2 4.5 ao Z nh 3h 2 2 n 3, z 2
(C) Ans Sol: Now, (PAPER II) 4 (D) 3R
CODE: 0
Ans Sol:
1 1 2 x1 x2 2 Possible wavelengths are 9 9 1 , and 5R 32R 3R Using the expression 2d sin = , one calculates the values of d by measuring the corresponding angles in the range 0 to 90o The wavelength is exactly known and the error in is constant for all values of As increases from 0o (A) the absolute error in d remains constant (B) the absolute error in d increases (C) the fractional error in d remains constant (D) the fractional error in d decreases D Rz 2
2sin d
cos ec cot 2 d Now cot d As increases, fractional error decreases Two non-conducting spheres of radii R1 and R2 and carrying uniform volume charge densities + and , respectively, are placed such that they partially overlap, as shown in the figure At all points in the overlapping region, (A) the electrostatic field is zero (B) the electrostatic potential is constant (C) the electrostatic field is constant in magnitude (D) the electrostatic field has same direction
R1 R2

JEE ADVANCE : 2013
(PAPER II) Ans Sol: C, D In the overlapping region r1 r2 E 3 o 3 o
r r
l
CODE: 0
r1
r2
Ans Sol:
C and D are correct 3 o A steady current I flows along an infinitely long hollow cylindrical conductor of radius R This cylinder is placed coaxialy inside an infinite solenoid of radius 2 R The solenoid has n turns per unit length and carries a steady current I Consider a point P at a distance r from the common axis The correct statement (s) is (are) (A) In the region 0 < r < R, the magnetic field is non-zero (B) In the region R < r < 2R, the magnetic field is along the common axis (C) In the region R < r < 2R, the magnetic field is tangential to the circle of radius r, centered on the axis (D) In the region r > 2R, the magnetic field is non-zero A, C, D B Bhollow Bsolenoid
E
conductor
B due to hollow conductor is zero inside the conductor and non-zero outside (co-axial) while B due to solenoid is zero outside the solenoid and non-zero inside the solenoid (axial)
R 2R
Ans
A, C & D Two vehicles, each moving with speed u on the same horizontal straight road, are approaching each other Wind blows along the road with velocity w One of these vehicles blows a whistle of frequency f1 An observer in the other vehicle hears the frequency of the whistle to be f2 The speed of sound in still air is V The correct statement (s) is (are) (A) If the wind blows from the observer to the source, f2 > f1 (B) If the wind blows from the source to the observer, f2 > f1 (C) If the wind blows from observer to the source, f2 < f1 (D) If the wind blows from the source to the observer, f2<f1 A, B v w vo f 2 f1 v w vs A & B are correct 4

JEE ADVANCE : 2013
7 (PAPER II) CODE: 0 Two bodies, each of mass M, are kept fixed with a separation 2L A particle of mass m is projected from the midpoint of the line joining their centres, perpendicular to the line The gravitational constant is G The correct statement(s) is (are) (A) The minimum initial velocity of the mass m to escape the gravitational field of the two GM bodies is 4 L (B) The minimum initial velocity of the mass m to escape the gravitational field of the two GM bodies is 2 L (C) The minimum initial velocity of the mass m to escape the gravitational field of the two 2GM bodies is L (D) The energy of the mass m remains constant B,D 1 2GMm 2 mve 0 2 L GM ve 2 L
M ve M
Ans Sol:
A particle of mass m is attached to one end of a mass-less spring of force constant k, lying on a frictionless horizontal plane The other end of the spring is fixed The particle starts moving horizontally from its equilibrium position at time t = 0 with an initial velocity u0 When the speed of the particle is 05 u0, it collides elastically with a rigid wall After this collision, (A) the speed of the particle when it returns to its equilibrium position is u0 (B) the time at which the particle passes through the equilibrium position for the first time is m t . k
Ans Sol:
4 m . 3 k (D) the time at which the particle passes through the equilibrium position for the second time is m t . 3 k A, D 3u using v A2 x 2 , we get x 2 (x : distance between mean position & the wall) Now using x = A sin t 5
(C) the time at which the maximum compression of the spring occurs is t

JEE ADVANCE : 2013
(PAPER II)
CODE: 0
2 3
m k 2 3
4 3
time for option (B) = time for option (C) time for option (D) =
m k
m k
2 3
m 2 k
m k
7 6
4 3
m k
m k
7 6
m k
m 2 k
5 3
m k
SECTION 2 : (Paragraph Type) This section contains 4 paragraphs each describing theory, experiment, data etc Eight questions relate to four paragraphs with two questions on each paragraph Each question of a paragraph has only one correct answer among the four choices (A), (B), (C) and (D) A small block of mass 1 kg is released from rest at the top of a rough track the track is a circular arc of radius 40 m the block slides along the track without toppling and a frictional force acts on it in the direction opposite to the instantaneous velocity The work done in overcoming the friction up to the point Q, as shown in the figure below, is 150 J (Take the acceleration due to gravity, g = 10 ms2)
y R 30
o
Q O
Ans Sol:
10
Ans Sol:
The speed of the block when it reaches the point Q is (A) 5 ms1 (B) 10 ms1 (C) 10 3ms 1 (D) 20ms 1 B From work-kinetic energy theorem 1 2 mgR sin 30o Wf mv 2 v = 10 m/s The magnitude of the normal reaction that acts on the block at the point Q is (A) 75 N (B) 86 N (C) 115 N (D) 225 N A At Q: 6

JEE ADVANCE : 2013
(PAPER II)
CODE: 0
N mg cos 60o
mv R
N 7.5N
Paragraph for questions 11 and 12

A thermal power plant produces electric power of 600 kW at 4000 V, which is to be transported to a place 20 km away from the power plant for consumers usage It can be transported either directly with a cable of large current carrying capacity or by using a combination of step-up and step-down transformers at the two ends The drawback of the direct transmission is the large energy dissipation In the method using transformers, the dissipation is much smaller In this method, a step-up transformer is used at the plant side so that the current is reduced to a smaller valu e At the consumers end, a stepdown transformer is used to supply power to the consumers at the specified lower voltage It is reasonable to assume that the power cable is purely resistive and the transformers are ideal with a power factor unity All the currents and voltages mentioned are rms values 11 If the direct transmission method with a cable of resistance 04 dissipation (in%) during transmission is (A) 20 (B) 30 (C) 40 (B) P 600 103 watt Vrms 4000 volt Total resistance R = 04 20 = 80 2 PL I rms R Power lost
P 600 103 R Vrms 4000 = 180000 watt = 180 kW 180 = 100 30 600 = 30%
2
km-1 is used, the power (D) 50
Ans Sol
So % loss
12
In the method using the transformers, assume that the ratio of the number of turns in the primary to that in the secondary in the step-up transformer is 1 : 10 If the power to the consumers has to be supplied at 200 V, the ratio of the number of turns in the primary to that in the secondary in the step-down transformer is (A) 200 : 1 (B) 150 : 1 (C) 100 : 1 (D) 50 : 1
Ans (A) Sol Step up

JEE ADVANCE : 2013
(PAPER II)
CODE: 0
NS VS=?
NP
For Step down
4000V VS 10 4000 1
VS
40, 000 volt

1 200
So
NS Vout 200 N P Vinput 40, 000 NP : NS = 200 : 1
Paragraph for Questions 13 and 14

A point charge Q is moving in a circular orbit of radius R in the x-y plane with an angular velocity This can be considered as equivalent to a loop carrying a steady current A uniform magnetic field 2 along the positive z-axis is now switched on, which increases at a constant rate from 0 to B in one second Assume that the radius of the orbit remains constant The application of the magnetic field induces an emf in the orbit The induced emf is defined as the work done by an induced electric field in moving a unit positive charge around a closed loop It is known that, for an orbiting charge, the magnetic dipole moment is proportional to the angular momentum with a proportionality constant 13 The magnitude of the induced electric field in the orbit at any instant of time during the time interval of the magnetic field change is BR BR (A) (B) (C) BR (D) 2BR 4 2
Ans(B) Sol Induced emf =

e
d dt
dB R2 dt e B R2 E.2 R B. R 2 BR E 2
14
The change in the magnetic dipole moment associated with the orbit, at the end of the time interval of the magnetic field change, is

JEE ADVANCE : 2013
(PAPER II) (A) Ans (C or B) Sol
CODE: 0
BQR 2
2
BQR 2
(B)
BQR 2
(C)
(D) BQR 2
B 2 R t B 2 E.2 R R t B R2 E 2 R. t L t m L QBR 2 m 2 Sign may be taken as +ve/-ve also depending upon direction of angular velocity e
Paragraph for questions 15 and 16

X is less than the sum of the masses of (A-Z) number of neutrons and Z number The mass of a nucleus A Z of protons in the nucleus The energy equivalent to the corresponding mass difference is known as the binding energy of the nucleus A heavy nucleus of mass M can break into two light nuclei of masses m1 and m2 only if (m1 + m2) < M Also two light nuclei of masses m3 and m4 can undergo complete fusion and form a heavy nucleus of mass M ' only if (m3 + m4) > M ' The masses of some neutral atoms are given in the table below :
1 1
6 3
1007825 u 6015123 u 151919803 u
2 1
7 3
2014102 u 7016004 u 205974455 u
3 1
3016050 u 69925325 u 208980388 u
4 2
He
4002603 u 81916709 u 209982876 u
Li
Gd
Li
Pb
70 30
Zn
Bi
82 34
Se
Po
152 64
206 82
209 83
210 84
15
The correct statement is 6 Li can emit an alpha particle (A) The nucleus 3
210 Po can emit a proton (B) The nucleus 84 (C) Deuteron and alpha particle can undergo complete fusion 70 Zn and 82 Se can undergo complete fusion (D) The nuclei 30 34 Ans (C)
Sol from data given only option C is correct m3 m 4 M '

JEE ADVANCE : 2013
16 (PAPER II) The kinetic energy (in keV) of the alpha particle, when the nucleus decay, is (A) 5319 (B) 5422 (C) 5707
CODE: 0
210 84
Po at rest undergoes alpha

(D) 5818
Ans (A) Sol From data given Po 210 82 Pb 206 2 He 4 84 m=00058184 u E = 0005818 932 =5422376 MeV E 206 KE of particle 210 = 5319 MeV = 5319 KeV
SECTION 3 : (Matching List Type)

This section contains 4 multiple choice questions Each question has matching lists The codes for the lists have choices (A), (B), (C) and (D) out of which ONLY ONE is correct 17 One mole of a monatomic ideal gas is taken along two cyclic processes E F G E and E F H E as shown in the PV diagram The processes involved are purely isochoric, isobaric, isothermal or adiabatic
Match the paths in List I with the magnitudes of the work done in List II and select the correct answer using the codes given below the lists List I G E G H F H List II 160 P0 V0 ln2 36 P0 V0 24 P0 V0 10
P Q R
1 2 3

JEE ADVANCE : 2013
S Codes : P Q (A) 4 3 (B) 4 3 (C) 3 1 (D) 1 3 R 2 1 2 2 S 1 2 4 4 F G (PAPER II) 4 31 P0 V0
CODE: 0
Ans (A) Sol = 5/3 FH is steeper therefore it is adiabatic process FG is isothermal PF VF PH VH FH FG
(32P0 )V0 PH VH PFVF = PGVG (32P0)V0 = P0VG
VH
8V0
VG = 32 V0
GE
Isobaric Process Work = P V = P0 (32V0 V0) = 31 P0V0 Work = P0 (32V0 8V0) = 24 P0V0 P V P V (32P0 )V0 P0 8V0 Work 1 1 2 2 36P0 V0 1 5/3 1 V Work PF VF ln G 32P0 V0 ln 32 160 ln 2 VF
GH FH FG 18
Match List I of the nuclear processes with List II containing parent nucleus and one of the end products of each process and then select the correct answer using the codes given below the lists List I List II 15 P Alpha decay 1 O 15 N .... 8 7 238 234 Q 2 decay U 90 Th .... 98 R S Codes : P Q (A) 4 2 (B) 1 3 (C) 2 1 (D) 4 3 Fission Proton emission 3 4
185 83
239 94
Bi
Pu
184 82
140 57
Pb ....
La ....
R 1 2 4 2
S 3 4 3 1 11

JEE ADVANCE : 2013
(PAPER II) Ans Sol (C)
CODE: 0
O 1 15 8
2 3 4 19
238 92
15 7
0 1
X
4 2
x is x is
particle particle
234 90
Th
185 83
239 94
Bi
Pu
184 82
140 57
Pb
La
1 1
X
X
X is Proton
Fission
1
99 47
A right angled prism of refractive index

2
is placed in a rectangular block of refractive index
, which is surrounded by a medium of refractive index 3 , as shown in the figure A ray of light e enters the rectangular block at normal incidence Depending upon the relationships between 1, 2 and 3 , it takes one of the four possible paths ef, eg, eh or ei
Match the paths in List I with conditions of refractive indices in List II and select the correct answer using the codes given below the lists : List I List II P 1 e f 2 2 1 Q 2 e g and 2 2 1 3 R S Codes : P Q (A) 2 3 (B) 1 2 (C) 4 1 (D) 2 3 Ans (D) Sol S-1 e e h i 3 4
1 2
and
R 1 4 2 4
S 4 3 3 1
e i case of TIR which is possible only when
45o is
ic
12

JEE ADVANCE : 2013
(PAPER II)
CODE: 0
sin iC
Q3 R4 P2 20 e g is [
2 1
1
if
2 2
, iCis 45o
] rays undergo undeviated for any angle of incidence
e h is 1 prism, (prism e f 1
and not undergoing (TIR) light ray bends towards base of block) and 2 3 (Snells law)
Match List I with List II and select the correct answer using the codes given below the lists : List I Boltzmann constant Coefficient of viscosity Planck constant Thermal conductivity List II [ML2T-1] [ML-1T-1] [MLT-3K-1] ML2T-2K-1]
P Q R S Codes : P Q (A) 3 1 (B) 3 2 (C) 4 2 (D) 4 1 Ans (C) Sol
1 2 3 4
R 2 1 1 2
S 4 4 3 3
energy ML2 T 2 = ML2T-2K-1 Kelvin K Planks constant = energy time = ML2T-2 T = ML2T-1 F MLT 2 ML 1T 1 Co-efficient of viscosity = L LT 1 L2 T 1 Energy Length Thermal conductivity = MLT-3K-1 Area Kelvin Time P 4 Q 2 R 1 S 3
Boltzmann constant =
13

JEE ADVANCE : 2013
(PAPER II)
CODE: 0
PART II : CHEMISTRY
SECTION 1 : (One or more options correct Type)
This section contains 8 multiple choice questions Each question has four choices (A), (B), (C) and (D) out of which ONE or MORE are correct 21 The carbon-based reduction method is NOT used for the extraction of (A) tin from SnO2 (B) iron from Fe2O3 (C) aluminium from Al2O3 (D) magnesium from MgCO3CaCO3 (C), (D) Al is extracted by electrolytic reduction MgCO3, CaCO3 are extracted by electrolytic reduction The thermal dissociation equilibrium of CaCO3 (s) is studied under different conditions CaCO3 (s) CaO (s) + CO2 (g) For this equilibrium, the correct statement(s) is(are) (A) H is dependent of T (B) K is independent of the initial amount of CaCO3 (C) K is dependent on the pressure of CO2 at a given T (D) H is independent of the catalyst, if any (A), (B), (D) Conceptual The correct statement(s) about O3 is(are) (A) O O bond lengths are equal (B) Thermal decomposition of O3 is endothermic (C) O3 is diamagnetic in nature (D) O3 has a bent structure (A), (B), (C), (D) (A) bond length are equal due to resonance
O O
+
Ans Sol
22
Ans Sol 23
Ans Sol
No unpaired electrons so diamagnetic 24 In the nuclear transmutation 9 X 8 Y 4 Be 4 Be (X, Y) is(are) (A) , n (B) p, D (A), (B) 8 1 (A) 9 4 Be 4 Be 0 n
(C) n, D
(D)
,p
Ans Sol
14

JEE ADVANCE : 2013
(PAPER II) (B) Be 25
9 4 1
CODE: 0
8 4
Be
2 1
The major product(s) of the following reaction is(are)

OH
aqueous Br2 3.0 equivalents
SO3H OH
Br Br Br SO3H Br
OH Br
OH
OH Br
Br Br Br
Br
Br
Br SO3H
Q
(B) Q
Ans
(A) P (B)
OH
(C) R
OH Br Br
(D) S
Sol.
SO3H
aqueous Br2 3.0 equivalents
Br
26
After completion of the reactions (I and II), the organic compound(s) in the reaction mixtures is(are)
O
Reaction I: H3C
1.0 mol
CH3 O
Br2 1.0mol aqueous NaOH
Reaction II: H3C

1.0 mol
CH3
O
Br2 1.0mol CH3COOH
O H3C CH2Br H3C
O CBr 3 Br 3C CBr 3 CH2Br
O CH2Br H3C
O ONa H3C
O ONa
Ans
Q R S (A) Reaction I: P and Reaction II : P (B) Reaction I : U, acetone and Reaction II: Q, acetone (C) Reaction I: T, U, acetone and Reaction II: P (D) Reaction I: R, acetone and Reaction II: S, acetone (C)
15

JEE ADVANCE : 2013
(PAPER II)
O
CODE: 0
Sol
Reaction I: 1/3 mole of CH C CH react with 1 mole of Br2 to give Bromofarm and sodium 3 3 acetate and 2/3 mole of acetone itself Reaction II: Mono bromination at -carbon in acidic medium The Ksp of Ag2CrO4 is 11 10-12 at 298 K The solubility (in mol/L) of Ag2CrO4 in a 01 M AgNO3 solution is (A) 11 10-11 (B) 11 10-10 (C) 11 10-12 (D) 11 10-9 (B) 2 Ag 2CrO4 2Ag CrO4
27
Ans Sol
s' 0.1 2s ' Ksp = (01 + 2s )2 s 11 10-12 = 10-2 s s = 11 10-10

28
OH
CHCl3 OH
s'
In the following reaction, the product(s) formed is(are)
CH3
OH CHO CHO O OH OH CHO
CH3
H3C
CHCl 2
H3C
CHCl 2
CH3
Ans Sol
Q P (A) P (major) (B) Q (minor) (B), (D) It is Reimer Tiemann Reaction

O
OH CHO
R (C) R (minor)
S (D) S (major)
So
H3C
CHCl 2
is minor and
CH3
is major
S
16

JEE ADVANCE : 2013
(PAPER II)
CODE: 0
SECTION 2 : (Paragraph Type)

This section contains 4 paragraphs each describing theory, experiment, data etc Eight questions relate to four paragraphs with two questions on each paragraph Each question of a paragraph has only one correct answer among the four choices (A), (B), (C) and (D) Paragraph for Questions 29 and 30 An aqueous solution of a mixture of two inorganic salts, when treated with dilute HCl, gave a precipitate (P) and a filtrate (Q) The precipitate P was found to dissolve in hot water The filtrate (Q) remained unchanged, when treated with H2S in a dilute mineral acid medium However, it gave a precipitate (R) with H2S in an ammoniacal medium The precipitate R gave a coloured solution (S), when treated with H2O2 in an aqueous NaOH medium 29 Ans Sol 30 Ans Sol The precipitate P contains (A) Pb2+ (B) Hg 2 (C) Ag+ 2 (A) Salt will be of PbCl2 as it is soluble in hot water The coloured solution S contains (A) Fe2(SO4)3 (B) CuSO4 (D) Cr3+ + H2S/NH4OH, NH4Cl Cr(OH)3 + H2O2 + NaOH (C) ZnSO4 Cr(OH)3 Na2CrO4 (yellow colour) (D) Hg2+
(D) Na2CrO4
Paragraph for Question 31 and 32 P and Q are isomers of dicarboxylic acid C4H4O4 Both decolorize Br2/ H2O On heating, P forms the cyclic anhydride Upon treatment with dilute alkaline KMnO4, P as well as Q could produce one or more than one from S, T and U 31 Compounds formed from P and Q are, respectively (A) Optically active S and optically active pair (T, U) (B) Optically inactive S and optically inactive pair (T, U) (C) Optically active pair (T, U) and optically active S (D) Optically inactive pair (T, U) and optically inactive S (B)
31
17

JEE ADVANCE : 2013
(PAPER II) Sol P and Q are
H C HOOC C COOH H H COOH C HOOC C H
CODE: 0
(Maleic -acid)
(Fumaric -acid)
COOH
Baeyers reagent, ie dilute alkaline KMnO4 will give syn addition product of alkene
H C HOOC C COOH H
KMnO4/OH dilute
H H
OH OH COOH
(cis)
(meso)
COOH H C HOOC C H COOH COOH COOH HO H H OH COOH
KMnO4/OH dilute
H HO
OH H
(trans)
(Racemic mixture)
32
In the following reaction sequences V and W are, respectively
Q
+ V
O
H 2 / Ni
V
W
AlCl3 (anhydrous)
1. Zn-Hg/HCl 2. H3PO4
(A) V
O and O
O
W
CH2OH
(B)
CH2OH
and
18

JEE ADVANCE : 2013
(PAPER II)
O
CODE: 0
(C) V
O and O
W
and
CH2OH
CH 2OH
HOH 2C
(D)
W
O
Ans
(A)
HOOC
H2/Ni
O COOH
Sol. Fumaric acid (Q)

O
(V)
O
+
O
AlCl3
anhydrous
HO
CH2 CH2 C O
1. Zn-Hg/HCl 2. H3PO4
O
Paragraph for Question 33 and 34 A fixed mass m of a gas is subjected to transformation of states from K to L to M to N and back to K as shown in the figure
K Pressure L
N Volume
19

JEE ADVANCE : 2013
33 (PAPER II) CODE: 0 The succeeding operations that enable this transformation of states are (A) Heating, cooling, heating, cooling (B) Cooling, heating, cooling, heating (C) Heating, cooling, cooling, heating (D) Cooling, heating, heating, cooling (C)
Ans Sol
K Pressure
N Volume
34
The pair of isochoric processes among the transformation of states is (A) K to L and L to M (B) L to M and N to K (C) L to M and M to N (D) M to N and N to K (B) According to following graph the proven L M isochoric and N K also isochoric
Ans Sol
Paragraph for Question 35 and 36 The reactions of Cl2 gas with cold-dilute and hot-concentrated NaOH in water give sodium salts of two (different) oxoacids of chlorine, P and Q, respectively The Cl2 gas reacts with SO2 gas, in presence of charcoal, to give a product R R reacts with white phosphorous to give a compound S On hydrolysis, S gives an oxoacid of phosphorus, T 35 P and Q, respectively, are the sodium salts of (A) hypochlorus and chloric acids (B) hypochlorous and chlorous acids (C) chloric and perchloric acids (D) chloric and hypochlorous acids (A) Cl2 + cold NaOH(aq) Cl2 + (hot) NaOH NaCl + NaOCl, (oxiacid HOCl) hypochlorous acid NaCl + NaClO3, (oxiacid HClO3) chloric acid P HOCl Q HClO3 SO2Cl2 P PCl5 H O H3PO4
4
Ans Sol
Cl2 + SO2 + Coke
20

JEE ADVANCE : 2013
(PAPER II) 36 R, S and T, respectively, are (A) SO2Cl2, PCl5 and H3PO4 (C) SOCl2, PCl3 and H3PO2 (A) (B) SO2Cl2, PCl3 and H3PO3 (D) SOCl2, PCl5 and H3PO4
CODE: 0
Ans
SECTION 3 (Matching List Type)

This section contains 4 multiple choice questions Each question has matching lists The codes for the lists have choices (A), (B), (C) and (D) out of which ONLY ONE is correct 37 An aqueous solution of X is added slowly to an aqueous solution of Y as shown in List I The variation in conductivity of these reaction is given in List II Match List I with List II and select the correct answer using the code given below the lists: List I P (C2H5)3N + CH3COOH X Y Q KI(01M) + AgNO3(001M) X Y R CH3COOH + KOH X Y S NaOH + HI X Y Code : P Q R S (A) 3 4 2 1 (B) 4 3 2 1 (C) 2 3 4 1 (D) 1 4 3 2 Ans 38 (A) Factual The standard reduction potential data at 250C is given below E0 (Fe3+, Fe2+) = +077 V E0 (Fe2+, Fe) = 044 V E0 (Cu2+, Cu) = +034 V; E0 (Cu2+, Cu) = +052 V E0[O2(g) + 4H+ + 4e 2H2O] = +123 V E0[O2(g) + 2H2O + 4e 4OH ] = +040V 0 3+ E (Cr , Cr) = 074 V; E0 (Cr2+, Cr) = 091 V; Match E0 of the redox pair in List I with the values given in List II and select the correct answer 21 List II 1 Conductivity decreases and then increases 2 Conductivity decreases and then doest not change much 3 Conductivity increases and then does not change much 4 Conductivity does not change much and then increases

JEE ADVANCE : 2013
(PAPER II) using the code given below the lists: List I P E ( Fe , Fe)
0 3+
CODE: 0
List II
Q E (4H2O 4H + 4OH ) 0 2+ R E (Cu + Cu 2Cu+) S E0 (Cr3+, Cr2+) Code : P Q R S (A) 4 1 2 3 (B) 2 3 4 1 (C) 1 2 3 4 (D) 3 4 1 2 Ans Sol (D) (P) E0 (Fe3+, Fe) Fe3+ + e Fe2+ + 2e Fe3+ + 3e
G3
3E
0 E3
1 2 3 4
018 V 04 V 004 V 083 V
Fe2+ Fe Fe
0 E1
0.77V 0.44V
E
0 E3
0 2
G1
G2
0 3
1 0.77 (2 0.44) 0.11 0.0366 0.04 V 3
(Q) E0 (4H2O 2H+ + 4OH ) 2H2O O2 + 4H+ + 4e O2 + 2H2O + 4e 4OH 4H2O 4H+ + 4OH
E0 = 123 V E0 = +04 V E0 = 083 V
(R) E0 (Cu2+ + Cu 2Cu+) Cu2+ + 2e Cu + 2(Cu Cu + e) E0 = 052 V Cu2+ + Cu 2Cu+ 0 3+ 2+ (S) E (Cr , Cr ) Cr3+ + 3e Cr 2+ Cr + 2e Cr Cr3+ + e
G3 G1 G2
E0 = +034 V
E0 = 034 052 = 018 V

0 = 074 V E1
E0 2 = 091V
0 E3
Cr2+
22

JEE ADVANCE : 2013
(PAPER II) 1
0 3
CODE: 0
E = 3
0 3
(074)
( 2
091)
E = 222 182
0 = 04V E3
39
The unbalanced chemical reactions given in List I show missing reagent or condition (?) which are provided in List II Match List I with List II and select the correct answer using the code given below the lists List I List II P PbO2 + H2SO4 Q Na2S2O3 + H2O R N2H4 S XeF2 Code : P (A) 4 (B) 3 (C) 1 (D) 3
? ? ? ?
PbSO4 + O2 + other product NaHSO4 + other product
1 NO 2 I2 3 warm 4 Cl2
N2 + other product Xe + other product R 3 1 2 2 S 1 4 3 1
Q 2 2 4 4
Ans Sol
(D) (i) PbO2 + H2SO4

2
warm
PbSO4 + H2O2
2
H2O +
1 O2 2
Cl (ii) Na2S2O3 + H2O 2NaHSO4 + NaCl I (iii) N2H4 N2 + 2HI (iv) XeF2 + NO Xe + NOF
40
The unbalanced chemical reactions given in List I show missing reagent or condition (?) which are provided in List II Match List I with List II and select the correct answer using the code given below the lists List I List II 1 (i) Hg(OAc)2; (ii) NaBH4 2 NaOEt 3 Et Br
P.
Q.
Cl
ONa
OEt
OH
R.
23

JEE ADVANCE : 2013
(PAPER II) 4 (i) BH3; (ii) H2O2/NaOH
S.
OH
CODE: 0
Code : P (A) 2 (B) 3 (C) 2 (D) 3 Ans (A)
Q 3 2 3 2
R 1 1 4 4
S 4 4 1 1
Sol. P.
Cl
NaOEt Elimination
Q.
ONa
Et-Br Substitution
OEt
(i) Hg(OAc)2
R.
(ii) NaBH4 Follows markownikov's product
OH
(i) BH3
S.
(ii) H2O2/NaOH Follows antimarkownikov's product

OH
24

JEE ADVANCE : 2013
(PAPER II)
CODE: 0
PART III : MATHEMATICS

SECTION 1 (Only or more options correct Type)
This section contains 8 multiple choice questions Each question has four choices (A) (B), (C) and (D) out of the which ONE or MORE are correct 41 Let be a complex cube root of unity with
1 and P
pij
be a n n matrix with pij (D) 56
i j
Ans
Then P2 (A) 57 (B,C,D)

2
0 , when n =
(B) 55 (C) 58
2
1
2 2
... ...
1
2 2
... ...
1
2
1 ...
... ... ...
1
2
1 ...
... ... ...
Sol
1 ...
... ... .....
1 ...
... ... .....
Clearly P2 will be O if n is a multiple of 3, then only, the elements of P2 will be reduced to 2 1 0 2 If P 0 n is not multiple of 3 42 The function y (A) 2 Ans Sol (A, B) y 2| x | | x 2| | x x 2 Case (i) y 2x x 2 y 3x 2 | x y 2x 4 Case (ii) 2 x 0 y x 2 | 3x 2 So for x 3 y 2x 4
2 | x | | x 2 | | x 2 | 2 | x | has a local minimum or a local maximum at x =
(B)
2| 2| x |
2 3
(C) 2
(D)
2 3
| x 2 2x | 2| (1) 2|
(2) 25

JEE ADVANCE : 2013
(PAPER II) And for x
2 ,0 3
CODE: 0
(3) y 4x Case (iii) 0 x y 2x x 2 | x 2 2x | y 3x 2 | x 2 | For 0 x 2 (4) y 4x And for, x 2 (5) y 2x 4 So graph is
(0,8) y= -2x-4
4 2x+
4 y = 2x +
y=
y= -
4x
(0,8/3) (0, 0)
y=4x x (2,0)
(-2, 0)
(-2/3,0)
From graph x 2,0 , are point of minimum, 2 & x is point of maxima 3 43

3 i 1 n : n 1, 2,3,... Further H1 and P and z C : Re z 2 2 1 , where C is the set of all complex numbers If z1 P H1 , z 2 H2 z C : Re z 2 and O represents the origin, then z1O z 2 2 5 (A) (B) (C) (D) 2 6 3 6 (C, D)
Let w
H2
Ans Sol
26

JEE ADVANCE : 2013
(PAPER II)
CODE: 0
Clearly from the figure, 44 If 3x
z1Oz 2
2 5 or or 3 6
(C)
1 1 log 4 3
Ans Sol
4 x 1 , then x = 2 log 3 2 2 (A) (B) 2 log 3 2 1 2 log 2 3 (A, B, C) 3x 4x 1 Taking log both sides with base 3 log3 3 log3 4x 1
(D)
2 log 2 3 2 log 2 3 1
x log3 3 x
x
x 1 log 3 4
x 1 log 3 4
x log 3 4 log 3 4
log 3 4
x log 3 4 1
x x
log3 4 log3 4 1 2log3 2 2log3 2 1
3x 4x 1 Taking log both sides with base 4 log 4 3x log 4 4x 1 x log 4 3 x 1

1 x x log 4 3 x 1 log 4 3 1
1 or x 1 log 4 3
2 2 log 2 3
27

JEE ADVANCE : 2013
45 Two lines L1 : x value(s) (A) 1 (A, D) x 5 y L1 : 0 3 x y L2 : 0 1 5 0
5,
y 3
(PAPER II) z y z and L2 : x , 2 1 2 (B) 2 (C) 3
CODE: 0
are coplanar Then (D) 4 can take
Ans Sol
z 2 z 2 0 2
0 0
5,
2
3 1
3
0
2 0
2 2
2
5;6 5
2 0
5 1
4 0 4 0 1, 4,5
46
Ans Sol
47
1 Further the incircle of the triangle touches 3 the sides PQ, QR and RP at N, L and M respectively, such that the lengths of PN, QL and RM are consecutive even integers Then possible length(s) of the side(s) of the triangle is (are) (A) 16 (B) 18 (C) 24 (D) 22 (B, D) 1 Cos P 3 2 2 2 4n 2 4n 4 4n 6 1 3 2 4n 2 4n 4 n 4 or n 1 Hence, the possible length of side of PQR will be 18, 20 or 22 For a R (the set of all real numbers), a 1,
In a triangle PQR, P is the largest angle and cos P
n
Lt n 1
1a
a 1
2a .... n a na 2 ... na n
na 1
1 then a = 60
(A) 5 Ans (B, D)
(B) 7
(C)
15 2
(D)
17 2
28

JEE ADVANCE : 2013
(PAPER II)
n
CODE: 0
Sol
Lt
1 n 1
a 1 n
ra
r 1
na r
r 1
Lt
na n 1
a 1
r 1 n
r n a
n
r 1
r n
a
Lt
na
1 a 1
n 1
1 n r nr1 n 1 n r a nr1 n
Lt 1
1
1 1 n
a 1
1 n r nr1 n 1 n r a nr1 n
x a dx
0 1
a x dx
0
1 60
2a 2 3a 119 0
48
Ans Sol
17 2 Circles(s) touching x axis at a distance 3 from the origin and having an intercept of length 2 7 on y-axis is (are) (A) x 2 y 2 6x 8y 9 0 (B) x 2 y 2 6x 7y 9 0 (C) x 2 y 2 6x 8y 9 0 (D) x 2 y 2 6x 7y 9 0 (A, C) Let circle be x 2 y 2 2gx 2fy c 0 a 7, a
g2 c, 2 f 2 c 2 7 g 3,c 9,f 4 So circle will be x 2 y 2 6x 8y 9 0
29

JEE ADVANCE : 2013
(PAPER II)
CODE: 0
SECTION 2 (Paragraph Type)

This section contains 4 paragraphs each describing theory, experiment, data etc Eight questions relate to four paragraphs with two questions on each paragraph Each question of a paragraph has only one correct answer among the four choices (A), (B), (C) and (D) Paragraph for Questions 49 to 50 R (the set of all real numbers) be a function Suppose the function f is twice
f x f x x 0,1
Let f : 0,1
differentiable, f 0 f 1 0 and satisfies f x 2f ' x 49 Which of the following is true for 0 < x < 1 ? 1 1 (A) 0 f x (B) f x 2 2 Ans (D) e x f " x 2f ' x e x e x f x 1 Sol
e xf " x f' x e
x
(C)
1 4
f x
(D)
f x
e xf ' x
e xf x
d d e xf ' x e xf x dx dx d d e xf x 1 dx dx Let e x f x g x
g" x 1
Since g 0 g 1 0 and g" x Possible graph for g(x) is
positive
1 O
Since g x
0for x 0,1 0,1 f x 0
Therefore f x is negative for x Which satisfies 50
If the function e x f x following is true? (A) f ' x
assumes its minimum in the interval {0, 1] at x
1 , which of the 4 1 4
30
f x ,
1 4
3 4
(B) f ' x
f x ,0 x

JEE ADVANCE : 2013
(PAPER II) (C) f ' x Ans Sol (C) For x
0, 1 4 g' x
e xf x
CODE: 0
(D) f ' x
f x ,0 x
1 4
0
0
f x ,
3 4
x 1
e xf ' x f' x
f x for x
0,
1 4
Paragraph for Question 51 and 52 Let PQ be a focal chord of the parallel y 2 4ax. The tangents of the parabola at P and Q meet at a point lying on the line y 2x a, a 0. 51 Ans Sol Length of chord PQ is (A) 7a (B) 5a (B)
(C) 2a
(D) 3a
y=2x+a (0, 0) (-a, -a)
(at2, 2at) P S
Q a 2a Q 2, t t
1 PQ a t (i) t Eq of tangent at P ty x at 2 As it passes through (a, a) at = a + at2 t2 + t 1 = 0 5 1 (for p, t > 0) t 2
2
PQ
5 1 2
2 5 1
5 1 5 1
31

JEE ADVANCE : 2013
(PAPER II)
a 5 1 2 5 1 = 5a 2
CODE: 0
52
Ans Sol
If chord PQ subtends an angle at the vertex of y 2 4ax, then tan 2 2 2 2 (A) (B) (C) (D) 7 5 7 5 3 3 3 3 (D) 2 m1 = slope of OP 5 1 t m2 = slope of OQ 2t 5 1
m1 m2 2 5 3 1 m1m2 Where is Acute angle between line OP and OQ but as 2 tan 5 3 tan
POQ obtuse
Paragraph for Question 53 and 54 Let S

S1
S3
S1 S2 S3 , where
z
z
:z
: Re z
4 ,
0 .
S2
: Im
z 1 3i 1 3i
53
Ans Sol
Area of S = 10 (A) 3 (B)
(B)
20 3
(C)
16 3
(D)
32 3
|z|=4
600 B A (1, -3)
3x
32

JEE ADVANCE : 2013
(PAPER II) S1 represent the inside part of circle |z| = 4 3x y 0 By putting z = x + iy, we get S2 S3 represent the right part of y-axis S is the shaded region in above diagram r2 2 r2 r 2 20 Now A 4 3 4 3 4 3 54
min 1 3i z
z S
CODE: 0
(A) Ans Sol
2 2 2 (C) Min |1 3i z| = minimum distance of point A 1, 3 z = AB distance in diagram 3 3 3 3
(B)
(C)
(D)
3 2
S from region S
2
Paragraph for Question 55 and 56
A box B1 contains 1 white ball, 3 red balls and 2 block balls Another box B2 contains 2 white balls, 3 red balls and 4 black balls A third box B3 contains 3 white balls, 4 red balls and 5 black balls 55 If 1 balls is drawn from each of the boxed B1, B2 the probability that all 3 drawn balls are of the same colour is 82 90 558 566 (A) (B) (C) (D) 648 648 648 648 (A) Required probability 1 2 3 3 3 4 2 4 5 6 9 12 6 9 12 6 9 12 82 648 If 2 balls are drawn (without replacement) from a randomly selected box and one of the balls is white and the other balls is red, the probability that these 2 balls are drawn from box B2 is 116 126 65 55 (A) (B) (C) (D) 181 181 181 181 (D) Required probability
Ans Sol
56
Ans Sol
33

JEE ADVANCE : 2013
(PAPER II)
CODE: 0
1 3 1 3
1
C1. C1 9 C2 C1. C1 9 C2
3 3
C1. C1 6 C2
C1. C1 12 C2
55 181
SECTION 3: (Matching list Type) This section contains 4 multiple choice question Each question has matching lists The codes for the lists have choice (A), (B), (C) and (D) out of which ONLY ONE is correct 57 P List-I Volume of parallelepiped determined by vector a, b and c is 2 Then the volume of the parallelepiped determined by vectors 2 a b , 3 b c and c a is 1 List-II 100
Volume of parallelepiped by vectors a, b and c is 2 5 Then the volume of the parallelepiped determined by vectors 3 a b , 3 b c and 2 c a is Area of a triangle with adjacent sides determined by vectors a and b is 20 Then the area of the triangle with adjacent sides determined by vectors 2a 3b and a b is Area of a parallelogram with adjacent sides determined by vectors a and b is 30 Then the area of the parallelogram with adjacent sides determined by vectors a b and a is 3
30
24
60
Codes P Q R S (A) 4 2 3 1 (B) 2 3 1 4 (C) 3 4 1 2 (D) 1 4 3 2 (C) (P) volume of parallelepiped = 2 Volume
Ans Sol
2 a b . 3 b c
6 a b . b c .a c
c a
b c .c a
34

JEE ADVANCE : 2013
(PAPER II)
CODE: 0
6 a b . abc c
6 abc
= 24 (Q) a b c Volume
3 a b .
b c
2 c a
6 a b . b c b a c a
= 60 (R) Area of triangle
1 a b 2
40
a b
1 2a 3b 2 a b
Required area
1 2a a 2a b 3b a 3b b 2 = 100 (S) Area of pallelogram a b
30
a b
Required area
a b
a a b a 0 a b
= 30 58
x 1 y z 3 x 4 y 3 z 3 and the planes , L2 : 2 1 1 1 1 2 P y 2 z 3, P2 : 3 x 5 y 6 z 4. Let ax by cz d be the equation of the plane passing 1 : 7x through the point of intersection of lines L1 and L2, and perpendicular to planes P1 and P2 Match List-I with List-II and selected the correct answer using the code given below the lists: List-I List-II P a= 1 13 Q b= 2 3 R c= 3 1 S d= 4 2
Consider the lines L1 : 35
Codes

JEE ADVANCE : 2013
(PAPER II) P Q R S (A) 3 2 4 1 (B) 1 3 4 2 (C) 3 2 1 4 (D) 2 4 1 3 (A) Point of intersection of the lines L1 and L2 x 1 y z 3 x 4 r1 2 1 1 1 x = 2r1 + 1 y = - r1 z = r1 3 2r1 + 1 = r2 + 4 2r1 r2 = 3 (i) - r1 = r2 - 3 (ii) Solving (i) and (2) r1 = 2, r2 = 1 So point is (5, - 2, -1) Now the equation of the plane is a(x 5) + b(y + 2) + c(z + 1) = 0 Also this plane is perpendicular to P1 & P2 So 7a + b + 2c = 0 3a + 5b 6c = 0 a b c 1 3 2 - 1(x 5) + 3(y + 2) + 2(z 1) = 0 - x + 3y + 2z + 13 = 0 x 3y 2z = 13 by comparing we get, a = 1, b = - 3, c = - 2, d = 13
CODE: 0
Ans Sol
y 3 z 3 1 2 x = r2 + 4 y = r2 3 z = 2r2 3
r2
59
Match List I with List II and select the correct answer using the code given below the lists List-I List-II 1/2 P 1 2 1 5 1 1 13 1 cos tan y y sin tan y 4 y 2 3 2 1 1 y cot sin y tan sin y Q If cos x cos y cos z 0 sin x sin y sin z then x y possible value of cos is 2 If
cos 4 x cos 2 x sin x sin 2 xsexx cos x sin 2 x sec x
1 2
36

JEE ADVANCE : 2013
(PAPER II)
cos 4 x cos 2 x then possible value of sec x is
1
CODE: 0
If cot sin
1 x2
sin tan
x 6 ,x
0, then
possible value of x is Codes (A) (B) (C) (D) (B) (P) P 4 4 3 3 Q 3 3 4 4

1
R 1 2 2 1
S 2 1 1 2
1 2 1/2
Ans Sol
1 cot tan y y sin tan y y 2 cot sin 1 y tan sin 1 y

1/2
y4
1 1 y2 1 y2 1 y y
2
y2 1 y2 y 1 y2
2 1/2
y4
1 y2 1 y2 1 y2 1 y2 y2 y 1 y2
y4
=1
(Q) cos x + cosy = - cos z, sin x + sin y = - sin z cos 2 x cos 2 y 2 cos x cos y cos 2 z sin 2 sin 2 y 2sin x sin y sin 2 z
1 1 2cos x y 1
cos x y
1 2 x y 2 cos 2 1 2 x y 1 cos 2 2 4 x y 1 cos 2 2
1 2
37

JEE ADVANCE : 2013
(R) cos 2 x
cos x 2
cos 2 x
2 sin x
sin x cos x 2 2 2sin x cos x cos x sin x cos x

2 sin 2 x 1 x 4
(PAPER II) sin x sin 2 x sec x cos x sin x 2
CODE: 0
cos x sin x sec 4

1
2
1 x2 sin tan
1
(S) cot sin

cot cos
1
x 6 .
x 1 x
2
sin sin
x 6 6 x2 1
1
2
6
2
60
1 x 6x 1 12x2 = 5 1 5 x 2 3 A line L : y mx 3 meets y-axis at E(0, 2) and the arc of the parabola y2 = 16x, 0 y 6 at the point F(x0, y0) The tangent to the parabola at F(x0, y0) intersects the y-axis at G(0, y1) The slop m of the line L is chosen such that the area of the triangle EFG has a local maximum Match List I with List II and select the correct answer using the code given below the lists: List-I List-II P m= 1 1 2 Q 2 4 Maximum area of EFG is R y0 = 3 2 S y1 = 4 1
Codes (A) (B) (C) (D) (A) P 4 3 1 1 Q 1 4 3 3 R 2 1 2 4 S 3 2 4 2
Ans Sol
38

JEE ADVANCE : 2013
(PAPER II)
(0, 3)
CODE: 0
E (0, 3)
0, 0
F(x0 , y 0)
G
(0, y 1)
y2 =16x
Let Co-ordinate of F= (x0, y0) = (4t2 8t) Co-ordinate of E = (0, 3) given Equation of tangent at F ty = x + 4t2 Co-ordinate of G (0, 4t) 0 3 1 1 0 4t 1 Area of EFG 2 2 4t 8t 1
1 12t 2 16t 3 2 Let 1 t 12t 2 16t 3 2 1 ' t 24t 48t 2 2 1 ' t 0 t 2 1 " t 24 96t 2 1 1 1 " 24 96 12 2 2 2 Since (4t2, 8t) lies on the lie y = mx + 3 8t 3 m 4t 2 1 At t = 2 We get m 1 Maximum area will be at t = 1/2 maximum area of triangle = 1/2 y0 = 8t = 4 y1 = 4t = 2
at t
8t
1 t will be maximum , 2 4mt 2 3
39

JEE ADVANCE : 2013
(PAPER II)
CODE: 0
Answers Key PHYSICS Q. No.

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
CHEMISTRY Q. No.
21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
MATHEMATICS Q. No.
41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Answer
A, B,C,D A,C D C,D A,C,D A,B BD A,D B A B A B C or B C A A C D C
Answer
C,D A,B,D A,B,C,D A,B B C B B,D A B B A C B A A A D D A
Answer
B,C,D A,B C,D A,B,C A,D B,D B,D A,C D C B D B C A D C A B A
40

Jee Advance 2013 (Paper II)

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JEE ADVANCE : 2013

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100 200 300 400 500

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NARAYANA IIT/PMT ACADEMY

Paragraph for questions 11 and 12

km-1 is used, the power (D) 50

Ans (A) Sol Step up

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For Step down

40, 000 volt

NS Vout 200 N P Vinput 40, 000 NP : NS = 200 : 1

Paragraph for Questions 13 and 14

Ans(B) Sol Induced emf =

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Paragraph for questions 15 and 16

1007825 u 6015123 u 151919803 u

2014102 u 7016004 u 205974455 u

3016050 u 69925325 u 208980388 u

4002603 u 81916709 u 209982876 u

Sol from data given only option C is correct m3 m 4 M '

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NARAYANA IIT/PMT ACADEMY

Po at rest undergoes alpha

SECTION 3 : (Matching List Type)

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NARAYANA IIT/PMT ACADEMY

Ans (A) Sol = 5/3 FH is steeper therefore it is adiabatic process FG is isothermal PF VF PH VH FH FG

(32P0 )V0 PH VH PFVF = PGVG (32P0)V0 = P0VG

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A right angled prism of refractive index

is placed in a rectangular block of refractive index

e i case of TIR which is possible only when

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] rays undergo undeviated for any angle of incidence

P Q R S Codes : P Q (A) 3 1 (B) 3 2 (C) 4 2 (D) 4 1 Ans (C) Sol

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The major product(s) of the following reaction is(are)

aqueous Br2 3.0 equivalents

Br2 1.0mol aqueous NaOH

Reaction II: H3C

Br2 1.0mol CH3COOH

O H3C CH2Br H3C

O CBr 3 Br 3C CBr 3 CH2Br

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY

s' 0.1 2s ' Ksp = (01 + 2s )2 s 11 10-12 = 10-2 s s = 11 10-10