Вы находитесь на странице: 1из 92

-

Refractory Products

Contents

Contents
Pages 2-5 6-13 14-21 22-27 28-33 34-37 38-41 42-43 44-45 46-47 48-79 80-83 84-85 Our Company Steel Industry Aluminium Industry Cement Industry Power Generation Refineries Lime Industry Foundry Glass Industry Ceramic Industry Refractory Specifications High Quality Solutions Research & Development
Refractory Products 3

Our Company

Our Company

Refractory Products

Our Company

Our Company since 1890...


MATHIOS REFRACTORIES S.A. Group of companies established in 1890, with 120 years of tradition in the industrial and building materials, refractories and acid-proof manufacturing is today one of the largest producing, trading and construction corporations in Greece. MATHIOS REFRACTORIES S.A began its activities as a specialized company in refractories, anti-acid installations and construction, servicing the biggest companies in the Greek industry. The highly experienced Construction Department is responsible for the construction of the biggest projects concerning refractory and chemical linings in the Greek industry and abroad (Germany, Bulgaria, Romania, Netherlands, Iran, Iraq, S.Arabia, Cyprus, Nigeria, Israel, Italy, France, India to name but a few). This is a very significant advantage because it makes MATHIOS REFRACTORIES S.A. the only company in the Greek market that is able to successfully provide turnkey solutions for customers service (engineering, supply and installation of refractories).

Refractory Products

Our Company

Our Products
The wide product range of MATHIOS REFRACTORIES is produced in the integrated refractory plant in Ritsona (former Ideal Refractories S.A.). This includes all the qualities of aluminosilicate based refractory bricks unshaped refractories (Conventional Castables and Gunning Materials, Low and Ultra Low Cement Castables, Self-flowing Castables), prefabricated shapes, chemically bonded, exfoliated vermiculite as well as insulating castables. They are applied in different industrial sectors such as steel, aluminium, cement, lime industries, power plant stations, refineries, incinerators, glass, foundry and dairys industries.

we are proud of our solutions


Steel Industry Aluminium Industry Cement Industry Power Generation Refineries Lime Industry Non - Ferrous Industry Foundry Glass Industry

Our Activities
The takeover of IDEAL REFRACTORIES from MATHIOS REFRACTORIES and the transfer of the entire refractory production activity to these facilities empowered the companys status quo. This merge resulted in the increasing of production capacity in order to successfully cover the increased demand of refractory materials in the Greek, world wide and European market as well. Thus, the last years MATHIOS REFRACTORIES plays a significant role in the production of unshaped / shaped aluminosilicate, prefabricated shapes and insulating refractories. Today MATHIOS is exporting to 53 countries world wide and not only has strong presence abroad, but its own sales and distribution organization in Germany and France. MATHIOS has also dynamic presence in Bulgaria with one production unit and its own sales organization. This is the reason that MATHIOS REFRACTORIES is the major refractories supplier in Greece. Through its unique experience in the refractories and acid proof construction sector MATHIOS has earned the market recognition with a leading position in the Greek Aluminium industry (Primary and secondary), Cement, Power Plant stations, Lime, Steel, Glass, Refineries.

Ceramic Industry Chemical Industry Waste Incinerators

Refractory Products

Our Company

Refractory Bricks
Fireclay High Alumina Andalusite-Mullite-Silimanite Silicon Carbide Acid Resistant

Monolithic Refractory
Regular Castables / Gunning Medium Cement Castables / Gunning Low Cement Castables Ultra Low Cement Castables Self flowing Castables Insulating Castables / Gunning Refractory Mortars Plastic Mouldable Materials

Raw Materials
Refractory Cements Refractory and Insulating Aggregates

Exfoliated Vermiculite

Refractory Products

Steel Industry

Steel Industry

Refractory Products

Steel Industry

Steel Plants (Mini Mills)

Electric Arc Furnace

Ladle for Secondary Metallurgy

Tundish

Pusher Type Reheating Furnace

Refractory Products

Steel Industry

E.A.F. (Electric Arc Furnace With Tap Hole)

(Roof-Delta Section) (Side Walls) (Bottom Lining) (Tap Hole / Runner) (Safety Lining) 10 Refractory Products

MAT PLUS 88 CR8 / MAT PLUS 90 CR4 / MAT PLUS 94 CR2 MgO-C BRICKS MgO BASED RAMMING MASS MAT PLUS 88 CR8 / MAT PLUS 90 CR4 MgO or MgO-Cr2O3 BRICKS

Steel Industry

E.A.F. (Electric Arc Furnace With E.B.T.)

(Roof-Delta Section) (Electrode Rings) (Side Walls) (Bottom Lining) (E.B.T Lining) (Safety Lining)

MAT PLUS 88 CR 8 / MAT PLUS 90 CR 4 / MAT PLUS 94 CR 2 / MAT PLUS 98 T IDEAL B 85 / IDEAL MU 80 S / IDEAL MU 60 / IDEAL B 80 MgO-C STANDARD BRICKS MgO BASED RAMMING MASS MgO-C SPECIAL SHAPES MgO or MgO-Cr2O3 BRICKS

Refractory Products

11

Steel Industry

Tundish

(Permanent Lining) (Working Lining) (Impact Pads) (Insulating Lining) (Slag Wares) 12 Refractory Products

MAT PLUS 80 E / MAT PLUS 80 EA / MAT PLUS 60 A MgO BASED SPRAYABLE MASS MAT PLUS 80 E / MAT PLUS 93 SP / MAT PLUS 95 T INSULATING MATERIALS MAT PLUS 90 / MAT PLUS 95 / MAT PLUS 93 SP / MAT PLUS 80 E

Steel Industry

Ladle for Secondary Metallurgy

(Filling Material) (Safety Lining) (Safety Lining of Slag Zone) (Metal Zone) (Slag Zone) (Well Block) (Cover) (Insulation of Cover) (Emergency Lance) (Hot Repairing Material)

PYROPLASTIC SUPER 80 / MAT 80 / MAT 80 TS IDEAL M 308 / IDEAL M 310 / IDEAL MU 60 / IDEAL B 80 IDEAL B 80 / IDEAL B 85 MAT SF 93 SP MgO-C BRICKS MAT PLUS 93 SP MAT PLUS 80 EA / MAT PLUS 80 E MAT 125 / MAT 125 G MAT PLUS 93 SP / MAT PLUS 80 E MAT 95F PF

Movable Metallic Anchors

Refractory Products

13

Steel Industry

Walking Beam Reheating Furnace

(Roof) (Discharging Zone) (Preheating Zone) (Hearth) (Burners) 14 Refractory Products

MAT RAM 50 C / MAT PLUS MC 50 / MAT RAM 80 C / MAT PLUS 60 M / MAT RAM 70 CM MAT PLUS 60 M / MAT RAM 50 C / MAT RAM 80 C / MAT 50 / MAT PLUS 42 / MAT RAM 70 CM MAT RAM 50 C / MAT PLUS MC 50 / MAT 50 GS MAT RAM 50 C / PYROPLASTIC SUPER / MAT PLUS 60 M / MAT RAM 80 C MAT PLUS 60 M / MAT RAM 80 C / MAT CAST 90 ULC C / MAT PLUS 80 EA

Steel Industry

Pusher Type Reheating Furnace

(Preheating Zone) (Roof / Burner Zone) (Charging Zone) (Soaking Zone) (Hearth) (Insulating Lining) (Outlet Zone)

MAT PLUS MC 50 / MAT RAM 50 C / MAT 50 / MAT PLUS 50 MAT PLUS 60 E / MAT RAM 80 C / MAT RAM 70 CM MAT PLUS MC 50 / MAT PLUS 60 M MAT PLUS MC 50 / MAT RAM 60 C / MAT 50 MAT PLUS 50 / MAT PLUS 60 M / MAT RAM 50 C / MAT RAM 80 C MAT 125 / MAT 125 G / MAT MW / MAT MW G MAT PLUS 60 M / MAT PLUS 80 E

Refractory Products

15

Aluminium Industry

Aluminium Industry

16

Refractory Products

Aluminium Industry

Primary - Secondary Aluminium Production

Melting Furnace

Transportation Ladle

Transportation Ladle

Melting & Holding Furnace

Refractory Products

17

Aluminium Industry

Rotary Kiln Calcination of Alumina

(Cooling Zone) (Inlet Zone) (Burner) (Calcination Zone)

MAT PLUS 80 / MAT PLUS 82 UHS / MAT PLUS 55M SiC 7 MAT PLUS 80 / MAT PLUS 82 UHS / MAT PLUS 55M SiC 7 MAT PLUS 80 / MAT PLUS 60 M / MAT PLUS 55M SiC 7 MAT PLUS 80 / MAT PLUS 82 UHS

Movable Metallic Anchors 18 Refractory Products

Aluminium Industry

Static Furnace Calcination of Alumina

(Refractory Lining) (Insulating Lining)

MAT PLUS 80 / MAT PLUS 82 UHS MAT 125 / MAT 125 G / INSULATING MATERIALS

Refractory Products

19

Aluminium Industry

Anode Baking Furnace

(Roof) (Bottom Lining) (Side Walls) (Insulation) (Insulating Lining) 20 Refractory Products

MAT 42 C IDEAL MU 44 / IDEAL M 310 IDEAL MU 48 / IDEAL A 63 INSULATING BRICKS MAT MW

Aluminium Industry

Electrolytic Cell

(Insulating Lining) (Bottom Refractory Lining)

INSULATING BRICKS / MAT MW MAT PLUS MC 45 / IDEAL M 334 AL / MAT PLUS 50

Refractory Products

21

Aluminium Industry

Melting & Holding Furnace

(Insulating Lining) (Bath Zone) (Roof & Door Side Walls) (Roof & Door Insulation) (Ceramic Anchor Bricks)

MAT MW / MAT MW AL MAT PLUS 80 AL / IDEAL B 83 AC MAT PLUS 80 / MAT PLUS 60 M / MAT 80 GS MAT MW G / MAT MW / MAT MW AL IDEAL A 63 / IDEAL MU 60

Movable Metallic Anchors

22

Refractory Products

Aluminium Industry

Ladle for Molten Aluminium Transportation

(Cover) (Refractory Lining) (Insulating Lining) (Insulation)

MAT PLUS MC 50 / MAT 50 MAT PLUS 80 H / IDEAL M 310 / IDEAL B 80 / MAT PLUS 82 UHS MAT MW AL / MAT MW G INSULATING MATERIALS - CERAMIC FIBERS

Refractory Products

23

Cement Industry

Cement Industry

24

Refractory Products

Cement Industry

Cyclone

(Insulating Lining)

MAT 125 / MAT 125 G MAT PLUS MC 35 / MAT PLUS MC 50 / MAT 32 GS / MAT 50 GS / IDEAL M 334 / MAT PLUS 50 ML E / MAT PLUS 25 ZR MAT PLUS 25 ZR / MAT PLUS 30 ZR G / MAT PLUS 82 UHS

(Cyclone Lining) (Raw Mill Duct)

Refractory Products

25

Cement Industry

Calcinator

(Insulating Lining)

MAT 125 / MAT 125 G IDEAL MU 48 / IDEAL M 334 / MAT PLUS 82 UHS / MAT PLUS 60 M / MAT 80 GS / MAT PLUS 10 SiC M

(Refractory Lining) 26 Refractory Products

Cement Industry

Riser Duct / Inlet Zone

(Insulating Lining)

MAT 125 / MAT 125 G MAT PLUS 60 M / MAT PLUS 22 ZR / MAT PLUS 10 SiC M / MAT 30 ZR G / MAT 57 M SiC 5 GS / MAT PLUS 22 ZR SiC 5 MAT PLUS 22 ZR / MAT 30 ZR G / MAT PLUS 60 M / MAT PLUS 10 SIC M / MAT PLUS 82 UHS

(Riser Duct) (Inlet Chamber)

Refractory Products

27

Cement Industry

Rotaty Kiln

(Safety Zone) (Calcination Zone) (Preheating Zone) 28 Refractory Products

IDEAL A 63 / IDEAL MU 60 / IDEAL MU 80 S / IDEAL B 80 / iDEAL A 45 SiC 25 / iDEAL A 52 SiC 15 IDEAL MU 60 / IDEAL B 50 Z IDEAL M 310 / IDEAL M 334 / IDEAL 282

Cement Industry

Grate Cooler / Bull Nose / Tertiary Air / Burner

(Nose Ring) (Bull Nose) (Kiln Hood) (Cooler-Hot Section) (Cooler-Cool Section) (Horseshoe) (Tertiary Air Duct) (Burner) (Insulating Lining)

MAT PLUS 60 A / MAT PLUS 60 M / MAT PLUS 65 M MAT PLUS 60 M / MAT PLUS 10 SiC M / MAT PLUS 82 UHS MAT PLUS 60 M / MAT 58 M GS / MAT 80 GS / MAT 57 HG MAT PLUS 80 / MAT PLUS 60 M MAT PLUS MC 50 / MAT 50 GS / IDEAL M 310 MAT PLUS 30 SiC / MAT PLUS 60 SiC / MAT PLUS 30 SiC A MAT PLUS MC 50 / MAT 50 GS / MAT 60 GS / IDEAL M 334 / IDEAL B 50 Z MAT PLUS 60 M / MAT PLUS 10 SiC M MAT 125 / MAT 125 G

Refractory Products

29

Power Generation

Power Generation

30

Refractory Products

Power Generation

Flue Gas Resuction

(Refractory Lining) (High Abrasion Refractory Lining) (Insulating Lining)

MAT 50 SMG / IDEAL M 334 / MAT 50 GS / MAT 80 GS / MAT 80 SPDG MAT PLUS MC 50 / MAT PLUS 50 ML E / IDEAL M 334 / MAT PLUS 80 MAT 125 G / GR 23 / ISO 450

Refractory Products

31

Power Generation

Coal Mill Door

(Refractory Lining) (Impact Zone) (Insulating Lining) 32 Refractory Products

MAT PLUS 50 ML E / MAT PLUS MC 50 / MAT PLUS 42 MAT PLUS 80 H / MAT PLUS 82 UHS INSULATING BRICKS / ISO 450

Power Generation

Boiler Furnace Hopper

(Refractory Lining)

MAT RAM 85 SiC P / MAT PLUS 70 SiC / MAT GUN 70 SiC

Special Metallic Anchors MVP Refractory Products 33

Power Generation

Refractory Lining of Main Coal Burners

(Refractory Lining) (Insulating Lining) (Insulating Lining)

MAT PLUS 50 ML E / MAT 80 GS / MAT PLUS MC 50 INSULATION BRICKS / MAT MW / MAT MW G / GR 23 MAT 125 / MAT 125 G / ISO 450

Movable Metallic Anchors 34 Refractory Products

Power Generation

Construction

Refractory Products

35

Refineries

Refineries

36

Refractory Products

Refineries

Crude & Vacuum Distillation Unit

(Inslulating Lining) (Insulating Lining) (Floor) (Burners)

MAT 106 L P / MAT 106 L GP MAT 125 P / MAT 125 GP IDEAL M 310 / IDEAL MU 48 / IDEAL MU 60 MAT PLUS 60 M

Refractory Products

37

Refineries

Sulfur Recovery Unit (Bottom / Heads)

(Insulating Lining) (Refractory Lining) 38 Refractory Products

MAT 124 MAT 42 C

Refineries

Sulfur Recovery Unit (Main Burner Main Combustion Chamber

(Insulating Lining Low Temperature) (Insulating Lining High Temperature) (Burning Zone)

CALCIUM SILICATE P/HT GR 23 / GR 26 / GR 28 / ISO 450 IDEAL KA 90 / MAT RAM 90 C / MAT PLUS 98 ULC T

Refractory Products

39

Lime Industry

Lime Industry

40

Refractory Products

Lime Industry

Lime Shaft Kiln

(Burning Zone Safety Lining) (Inlet, Transition, Cooling Zone) (Insulating Lining) (Refractory Lining)

MAT PLUS 60 M / MAT PLUS 60 A / MAT PLUS 52 A / IDEAL MU 60 / IDEAL B 60 / IDEAL B 75 MAT PLUS 42 / IDEAL M 310 / IDEAL MU 48 / IDEAL B 60 / MAT PLUS MC 45 MAT MW / MAT 125 / MAT 106 / CALCIUM SILICATE / INSULATING BRICKS / CERAMIC FIBERS MAT 60 M / MAT 80 S

Refractory Products

41

Lime Industry

Lime Rotary Kiln

(Sintering Zone) (Transition Zone) (Calcining Zone) (Preheating Zone) (Cooler) 42 Refractory Products

MAT PLUS 60 A / IDEAL A 63 / MAT PLUS 60 M MAT PLUS 60 A / IDEAL A 63 MAT PLUS 52 A / IDEAL MU 60 MAT PLUS 80 EA / IDEAL B 50 Z MAT PLUS MC 50 / IDEAL M 310 / IDEAL MU 48

Lime Industry

Construction

Refractory Products

43

Foundry

Foundry

44

Refractory Products

Foundry

Runner Receiver

(Metal Bath) (Cover) (Insulation)

MAT PLUS 93 SP / MAT SF 93 SP MAT RAM 50 C / MAT 96 S INSULATING MATERIAL

Refractory Products

45

Glass Industry

Glass Industry

46

Refractory Products

Glass Industry

Regenerator / Melting Furnace

(Insulating Bricks) (Refractory Bricks) (Refractory Safety Lining) (Refractory Castables)

ISO 450 / GR 26 / GR 28 / GR 30 IDEAL FC 77 / IDEAL FM 72 / IDEAL FM 76 IDEAL B 60 / IDEAL MU 60 MAT PLUS 80 EA / MAT 125

Refractory Products

47

Ceramic Industry

Ceramic Industry

48

Refractory Products

Ceramic Industry

Tunnel Kiln Car

(Refractory Lining) (Prefabricated Shapes) (Insulating Lining) (Insulating Lining) (Outside Walls) (Refractory Lining)

MAT GR / MAT PLUS MC 35 / MAT PLUS 80 MAT GR / MAT 42 / MAT PLUS 80 MAT 125 / MAT MW MAT 125 / MAT MW MAT 106 / MAT 125 MAT PLUS 42 / MAT PLUS MC 50 / IDEAL M 310 / IDEAL MU 48 / IDEAL B 60

Refractory Products

49

Alumina Silicate - Fireclay Bricks - High Alumina - Andalusite - Mullite - Silimanite - SiC Based Acid Resistant

Monolithic Refractory
Castables - Hydraulically Bonded Regular Castables (R.C.) Deflocculated Castables
Medium Cement Castables (M.C.C.) Low Cement Castables (L.C.C.) Ultra low Cement Castables (U.L.C.C.)

- Chemically Bonded Insulating Castables


50 Refractory Products

Refractory Products

Refractory Bricks

Refractory Products

Gunning Materials
Isulating Gunning Refractory Gunning
- Regular Cement Gunning (R.C.G.) - Medium Cement Gunning (M.C.G.) - Low Cement Gunning (L.C.G.) - Chemically Bonded

Plastic / Ramming Materials


Chemically Bonded Ceramically Bonded

Mortar / Jointing Materials


Heat Setting Air Setting

Refractory Products

51

Technical Data

Fireclay & High Alumina Refractory Bricks


PRODUCT NAME Classification Refractoriness (S.C.) Refractoriness Under Load o C (t0,5) Raw Material Basis Bulk Density (gr/cm3) Apparent Porosity (% b.v.) C.C.S. (N/mm2)

IDEAL 282 IDEAL M 382 IDEAL M 334 IDEAL M 334 AL IDEAL M 334 H IDEAL M 308 IDEAL M 310 IDEAL B 50 IDEAL B 50 Z IDEAL B 60 IDEAL B 65 IDEAL B 70 IDEAL B 75 IDEAL B 80 IDEAL B 80 C IDEAL B 85 IDEAL BK 85 IDEAL B 85 S IDEAL B 85 C IDEAL W 90

FC 30 FC 30 FC 30 FC 30 FC 35 FC 40 FC 40 HA 45 HA 45 HA 55 HA 65 HA 65 HA 75 HA 75 HA 75 HA 75 HA 75 HA 75 HA 75 HA 85

20/23 20/23 30 26 31 32 33 35 35 36 36 36 37 38 37 38 38 38 37/38 40

1230 1250 1280 1260 1310 1315 1340 1370 1385 1390 1410 1420 1430 1470 1420 1500 1520 1540 1460 1570

Fireclay Fireclay Fireclay Fireclay Fireclay Fireclay Fireclay Bauxite / Fireclay Fireclay Bauxite / Fireclay Bauxite / Fireclay Bauxite / Fireclay Bauxite Bauxite Bauxite / Corundum Bauxite / Corundum Bauxite / Corundum Bauxite / Alumina Bauxite / Corundum Corundum

2.14 2.16 2.18 2.16 2.20 2.22 2.25 2.35 2.35 2.52 2.56 2.65 2.73 2.77 2.76 2.85 2.80 2.92 3.05 3.15

13 13 14 14 16 18 17 18 17 17 18 19 19 19 17 17 18 17 17 17

55 65 65 55 60 50 50 55 50 65 65 70 80 85 90 85 85 100 120 80

Silicon Carbide Based Refractory Bricks


PRODUCT NAME Classification Refractoriness (S.C.) Refractoriness Under Load oC (t0,5) Raw Material Basis Bulk Density (gr/cm3) Apparent Porosity (% b.v.) C.C.S. (N/mm2)

IDEAL A 45 SiC 25 IDEAL A 52 SiC 15

HA 45 HA 45

39 39

1550 1550

Andalusite / SiC Andalusite / SiC

2.60 2.65

14 13

60 75

52

Refractory Products

Technical Data

Fireclay & High Alumina Refractory Bricks


Chemical Analysis (%) Thermal Linear Expansion (% at 1000 oC) Thermal Shock Resistance (950 oC/Water)

Al2O3 30.0 31.0 33.0 34.0 36.5 40.0 42.5 50.0 49.0 60.0 65.0 70.0 75.0 80.0 80.0 82.5 83.0 83.5 84.5 89.5

SiO2 64.0 63.5 61.5 62.0 58.0 55.0 52.5 44.5 46.5 34.5 29.0 23.0 13.8 13.0 11.0 11.5 11.5 10.2 9.8 7.5

Fe2O3 1.1 1.2 1.3 1.4 1.4 1.5 1.5 1.7 1.5 1.6 1.7 1.8 2.1 1.9 1.8 1.9 1.8 1.9 1.9 0.5

P 2O 5 -

SiC 0.48 0.48 0.51 0.50 0.53 0.55 0.57 0.62 0.62 0.65 0.67 0.67 0.68 0.70 0.72 0.73 0.73 0.74 0.74 0.78 >5 >5 10 8 15 12 20 20 20 30 30 30 30 30 30 > 30 > 30 30 30 20

1.9 1.9 -

Silicon Carbide Based Refractory Bricks


Chemical Analysis (%) Thermal Linear Expansion (% at 1000 oC) Thermal Shock Resistance (950 oC/Water)

Al2O3 45.0 51.5

SiO2 26.5 30.5

Fe2O3 0.9 0.9

P 2O 5 -

SiC 25.0 15.0 0.50 0.48 > 100 > 100

Refractory Products

53

Technical Data

Andalusite / Mullite / Silimanite Based Refractory Bricks


PRODUCT NAME Classification Refractoriness (S.C.) Refractoriness Under Load o C (t0,5) Raw Material Basis Bulk Density (gr/cm3) Apparent Porosity (% b.v.) C.C.S. (N/mm2)

IDEAL MU 44 IDEAL MU 48 IDEAL MU 60 IDEAL A 63 IDEAL MU 65 IDEAL MU 72 IDEAL FM 72 IDEAL FM 76 IDEAL FC 77 IDEAL MU 80 S

FC 40 HA 45 HA 55 HA 55 HA 65 HA 75 HA 75 HA 75 HA 75 HA 75

34 37/38 39 39 39 39 40 40 39 40

1415 1450 1540 1540 1550 1550 1650 1700 1660 1600

Fireclay / Mullite Fireclay / Mullite Mullite / High Al. Raw Mat. Andalusite Mullite / High Al. Raw Mat. Mullite / High Al. Raw Mat. Mullite Mullite / Corundum Corundum / Andalusite Mullite / High Al. Raw Mat.

2.30 2.32 2.48 2.60 2.54 2.60 2.64 2.65 2.82 2.65

14 16 14 14 17 18 15 15 15 17

65 60 70 75 70 70 90 90 80 65

Refractory Mortars
PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Form of Delivery Chemical Analysis (%) (EN ISO 12677)

Al2O3 MAC I MAC II FIRECLAY MAT MOR 38 MAT MOR 45 MAT FIRE SUPER MAT MK 4 MAC DRY MAC 50 DRY SUPER AL MAT MOR 80 DRY MAT HF 4 MAT SiC 75 1350 1500 1350 1380 1540 1400 1450 1480 1500 1500 1600 1700 1650 1500 Quartz Chamotte Chamotte Chamotte Chamotte Chamotte Chamotte Chamotte Chamotte Chamotte/Bauxite Bauxite Corundum Corundum Silicon Carbide Wet Wet Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 12.8 33.0 30,0 38.0 45.0 40.0 37.0 37.0 35.5 50.0 70.0 80.0 80.0 12.0

SiO2 81.5 59.0 61.5 57.5 52.0 45.0 58.0 58.0 57.0 41.5 23.5 13.0 13.5 4.0

Fe2O3 1.0 1.4 1.3 1.5 1.7 3.5 1.8 1.7 1.5 1.5 1.7 0.5 0.9 0.1

SiC 74.0

54

Refractory Products

Technical Data

Andalusite / Mullite / Silimanite Based Refractory Bricks


Chemical Analysis (%) Thermal Linear Expansion (% at 1000 oC) Thermal Shock Resistance (950 oC/Water)

Al2O3 44.0 48.0 60.0 62.5 65.0 71.0 72.0 76.0 77.0 79.0

SiO2 51.0 47.5 36.5 34.5 32.0 24.5 26.5 23.0 21.0 19.0

Fe2O3 1.3 0.9 0.8 0.9 0.8 1.1 0.4 0.3 0.6 0.6

P 2O 5 -

SiC 0.55 0.60 0.60 0.55 0.64 0.68 0.55 0.66 0.68 0.70 20 20 30 30 30 30 30 30 30 30

Refractory Mortars
Grain Size (mm) (EN 1402-3) Approx. water addition (EN 1402-4) (lt/100 kg dry material)

0.5 1 1 0.7 1 2 1 0.7 0.7 0.7 1 0.5 0.7 0.15

30 35 32 20 32 35 25 - 32 25 - 32 32 20 - 30 35 32

Refractory Products

55

Technical Data

Dense Castables
PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677)

Al2O3 MAT GR 35 MAT 42 C MAT 42 MAT 45 TS MAT 45 MAT 50 MAT 50 S MAT 60 TC MAT 60 MAT 60 F 75 P MAT 77 TS MAT 80 S MAT 80 MAT 80 S MAT 80 HT MAT 90 MAT 94 MAT 95 F MAT 95 F PF MAT 96 S 1300 1300 1350 1350 1450 1440 1480 1500 1500 1550 1550 1600 1550 1620 1600 1630 1650 1650 1700 1700 1700 1800 Chamotte Chamotte Chamotte Chamotte Chamotte Chamotte Chamotte High Alumina Raw Materials Bauxite/Chamotte Andalusite Andalusite Bauxite Bauxite Bauxite Bauxite Bauxite Bauxite Corundum Tabular Alumina Tabular Alumina Tabular Alumina Tabular Alumina 30.0 35.0 44.0 40.0 45.0 44.5 45.0 49.0 50.0 50.0 50.0 55.0 55.0 58.0 60.0 60.5 60.5 76.5 80.0 81.0 80.0 83.0

SiO2 54.0 50.0 41.5 45.0 46.5 47.0 45.0 43.0 41.0 38.0 41.0 34.5 36.0 34.7 29.0 30.0 30.0 13.5 8.5 8.5 6.9 6.0

Fe2O3 2.5 2.8 2.9 3.4 1.4 1.5 2.3 1.4 1.4 2.2 1.1 1.4 0.9 0.9 1.3 0.8 0.8 1.6 1.6 1.6 1.8 1.4

56

Refractory Products

Technical Data

Dense Castables
Cold Crushing Strength (N/mm2) (EN 1402-6) Grain Size (mm) (EN 1402-3) Permanent Linear Change (%) (EN 1402-6) Reversible thermal expansion at 1000 oC (%) Material required (kg/m3) Approx. water addition (EN 1402-4) (lt/100 kg dry material)

at 1100 oC 22 22 27 24 25 30 40 42 35 42 38 20 20 24 35 50 45 42 50 50 45 70

at 1500 oC 6 6 6 6 6 6 6 6 3 6 3 3 6 6 6 6 6 60 60 50 50 70 6 6 6 3 6

at 1100 oC -0.65 -0.25 -0.15 -0.45 -0.20 -0.45 -0.20 -0.10 -0.30 +0.20 +0.20 -0,30 -0,60 -0.25 -0.20 -0.20 -0.25 -0.15 -0.15 -0.15 -0.15 -0.10 0.80 0.81 0.82 0.82 0.82 0.52 0.52 0.55 0.54 0.55 0.58 0.58 0.60 0.62 0.65 0.65 0.65 0.62 0.75 0.75 0.75 2130 2150 2200 2200 2200 2200 2250 2250 2250 2550 2550 2580 2250 2600 2600 2600 2570 2850 2900 2800 2850 2930 11 - 14 11 - 13 11 - 13 10 - 13 10 - 13 10 - 13 10 - 12 10 - 12 12 - 14 9 - 12 9 - 12 14-16 11 - 14 9 - 11 9 - 12 9 - 11 9,5-11 9 - 11 7.5 - 9.0 7.5 - 9.0 7.5 - 9.0 7.5 - 9.0

Refractory Products

57

Technical Data

Medium Cement Castables


PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677)

Al2O3 MAT PLUS MC 35 MAT PLUS MC 40 MAT PLUS MC 45 MAT PLUS MC 50 MAT PLUS MC 50 R MAT PLUS MC 58 MAT PLUS MC 78 MAT PLUS MC 88 1320 1380 1440 1500 1500 1550 1500 1600 Chamotte Chamotte Chamotte Chamotte Chamotte Andalusite Bauxite Corundum 35.0 40.0 45.0 50.0 50.0 57.0 77.5 87.5

SiO2 58.0 53.5 50.0 44.0 44.0 39.0 13.8 7.0

Fe2O3 1.4 1.4 1.4 1.2 0.8 0.9 1.8 0.8

58

Refractory Products

Technical Data

Medium Cement Castables


Cold Crushing Strength (N/mm2) (EN 1402-6) Grain Size (mm) (EN 1402-3) Permanent Linear Change (%) (EN 1402-6) Material required (kg/m3) Approx. water addition (EN 1402-4) (lt/100 kg dry material)

at 1100 oC 75 75 75 80 95 80 80 80 6 6 6 6 6 6 6 6

at 1100 oC -0.45 -0.4 -0.4 -0.35 -0.3 -0.1 -0.35 -0.15 2250 2250 2300 2350 2350 2650 2800 3070 5.5 - 7.0 5.5 - 7.0 5.5 - 7.0 5.5 - 7.0 5.5 - 7.0 5.0 - 6.0 5.0 - 7.0 5.5 - 7.0

Mathios Refractories S.A. fail-safe packing system Mathios Refractories S.A. implements an integrated packing system to make certain its products are easily distinguished by end users and installers to minimize losses, energy consumption and ensure 100% correct installation.
MAT 42 MAT PLUS 85

Packaging of products is differentiated as follows:


MAT MW SUPER

Green bags: Maroon bags: Yellow bags: Red bags:

dense castables & gunning materials medium, low & ultra low cement castables insulating and insulating gunning materials mortars & ramming materials Refractory Products 59

Technical Data

Low Cement Castables


PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677)

Al2O3 MAT PLUS GR MAT PLUS 35 MAT PLUS 42 MAT PLUS 50 ML MAT PLUS 50 ML E MAT PLUS 52 A MAT PLUS 58 A MAT PLUS 60 A MAT PLUS 60 M MAT PLUS 62 MAT PLUS 65 M MAT PLUS 70 MAT PLUS 75 MAT PLUS 80 MAT PLUS 80 PF MAT PLUS 80 H MAT PLUS 80 E MAT PLUS 80 EA MAT PLUS 82 UHS MAT PLUS 83 HS MAT PLUS 85 MAT PLUS 90 MAT PLUS 95 W MAT PLUS 95 T MAT PLUS 98 T MAT PLUS 20 ZR MAT PLUS 25 ZR MAT PLUS 22 ZR SiC 5 1200 1350 1420 1500 1550 1530 1580 1670 1650 1650 1670 1600 1550 1600 1600 1620 1650 1650 1600 1600 1650 1680 1700 1750 1800 1500 1600 1520 Chamotte Chamotte Chamotte Chamotte Chamotte / Mullite Andalusite Andalusite Andalusite Sintered Mullite Sintered Mullite Sintered Mullite Bauxite - Chamotte Bauxite - Chamotte Bauxite Bauxite Bauxite Bauxite Bauxite - Andalusite Bauxite Bauxite Bauxite - Corundum Corundum Corundum Sintered Alumina Sintered Alumina Synthetic Raw Materials Synthetic Raw Materials Synthetic Raw Materials 29.0 35.0 42.0 50.0 50.0 52.0 58.0 60.0 60.0 62.0 65.0 70.0 74.0 80.0 80.5 84.0 79.5 75.0 82.0 82.5 83.0 90.0 94.5 94.5 97.5 49.5 50.0 47.0

SiO2 63.5 58.0 53.0 46.0 46.0 42.5 38.0 37.0 35.5 35.0 30.0 25.0 17.5 11.7 11.7 9.8 13.5 18.5 10.7 10.5 10.5 4.8 3.0 3.0 0.1 25.0 20.5 21.5

Fe2O3 1.0 1.4 1.5 1.4 1.0 0.7 0.8 0.7 1.0 0.8 1.0 1.4 2.0 1.5 1.4 1.3 1.5 1.3 1.6 1.6 1.3 0.5 0.15 0.1 0.1 0.8 0,5 0,5

ZrO2/SiC

20.0 25.0 22.0/4.5

60

Refractory Products

Technical Data

Low Cement Castables


Cold Crushing Strength (N/mm2) (EN 1402-6) Grain Size (mm) (EN 1402-3) Permanent Linear Change (%) (EN 1402-6) Reversible thermal expansion at 1000 oC (%) Material required (kg/m3) Approx. water addition (EN 1402-4) (lt/100 kg dry material)

at 1100 oC 80 80 95 80 90 90 100 95 95 80 95 80 100 120 120 120 100 100 160 145 100 110 85 95 55 80 110 90

at 1500 oC 6 6 6 90 100 100 100 95 100 90 100 95 110 110 120 120 100 100 160 145 100 110 100 100 80 100 110 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6

at 1100 oC -0.60 -0.50 -0.35 -0.25 -0.20 -0.20 +0.05 +0.05 -0.10 -0.10 -0.10 -0.20 -0.10 -0.10 -0.10 -0.10 -0.30 0.05 -0.40 -0.30 -0.30 -0.20 -0.10 -0.10 -0.10 -0.05 -0.20 -0.10 0.55 0.55 0.57 0.57 0.6 0.63 0.65 0.65 0.65 0.65 0.65 0.65 0.67 0.70 0.70 0.70 0.65 0.65 0.66 0.67 0.70 0.80 0.80 0.80 0.80 0.68 0.70 0.68 2050 2100 2300 2350 2350 2400 2600 2650 2530 2600 2550 2520 2750 2750 2750 2950 2800 2800 2850 2900 2900 3150 3100 3100 3180 2900 3000 2900 5.5 - 7.0 5.5 - 7.0 5.5 - 7.0 5.0 - 6.5 5.0 - 6.5 5.0 - 6.5 5.0 - 6.5 5.0 - 6.5 4,5 - 6,0 4,5 - 6,0 4,5 - 6,0 5.5 - 7.0 4.5 - 6.0 4.5 - 6.0 4.5 - 6.0 4.5 - 5.5 4.5 - 6.0 4.5 - 5.5 4,0 - 5,0 4,0 - 5,0 4.5 - 5.5 4.0 - 5.5 4.0 - 5.5 4.0 - 5.5 4.0 - 5.5 4.5 - 6.0 4.5 - 6.0 4.5 - 6.0

Refractory Products

61

Technical Data

Ultra Low Cement Castables


PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677)

Al2O3 MAT CAST 85 ULC E MAT CAST 95 ULC CR1 MAT CAST 97 ULC T 1700 1800 1800 Bauxite - Corundum Sintered Alumina Sintered Alumina 84.5 95.0 97.0

SiO2 9.0 2.2 2.6

Fe2O3 1.4 0.1 0.1

Cr2O3

1.0

Self Flowing Low & Ultra Low Cement Castables


PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677)

Al2O3 MAT SF 50 MAT SF 56 MAT SF 61 SiC MAT SF 93 MAT SF 93 SP MAT SF 97 T HA 1500 1500 1500 1700 1700 1760 Chamotte Chamotte Silicon Carbide Sintered Alumina Sintered Alumina / Spinell Sintered Alumina 50.0 56.0 27.0 93.0 93.0 97.0

SiO2 47.0 42.5 6.0 2.5 0.5 1.0

Fe2O3 1.0 1.0 0.2 0.5 0.1 0.05

SiC

MgO

59.0

4.0

62

Refractory Products

Technical Data

Ultra Low Cement Castables


Cold Crushing Strength (N/mm2) (EN 1402-6) Thermal Conductivity (W/mK) (EN 993-14) Grain Size (mm) (EN 1402-3) Permanent Linear Change (%) (EN 1402-6) Reversible thermal expansion at 1000 oC (%) Material required (kg/m3) Approx. water addition (EN 1402-4) (lt/100 kg dry material)

at 1100 oC 60 55 55

at 1500 oC 110 80 80

at 800 oC 2.25 2.92 2.92 10 6 6

at 1100 oC -0.35 0 -0.10 0.7 0.8 0.80 2950 3120 3130 4.5 - 5.5 4.0 - 5.5 4.0 - 5.5

Self Flowing Low & Ultra Low Cement Castables


Cold Crushing Strength (N/mm2) (EN 1402-6) Grain Size (mm) (EN 1402-3) Permanent Linear Change (%) (EN 1402-6) Reversible thermal expansion at 1000 oC (%) Material required (kg/m3) Approx. water addition (EN 1402-4) (lt/100 kg dry material)

at 1100oC 60 60 95 70 70 80

at 1400 oC 100 100 95 100 (1500 oC) 100 120

at 1600 oC 3 3 3 10 120 130 6 6

at 1100 oC -0.40 -0.35 -0.10 -0.10 -0.10 -0.10 0.55 0.55 0.55 0.8 0.80 0.81 2230 2250 2550 3100 2980 3150 6.5 - 7.5 6.5 - 7.5 5.0 - 6.5 4.5 - 5.5 4.5 - 5.5 4.5 - 5.5

Refractory Products

63

Technical Data

Silicon Carbide Low Cement Castables


PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677) Bulk Density (EN 1402-6) at 110 oC (g/cm3)

Al2O3 MAT PLUS 9 SiC MAT PLUS 10 SiC MAT PLUS 10 SiC M MAT PLUS 30 SiC MAT PLUS 30 SiC A MAT PLUS 32 SiC MAT PLUS 40 SiC MAT PLUS 50 SiC MAT PLUS 60 SiC MAT PLUS 70 SiC MAT PLUS 83 SiC MAT PLUS 57 SiC 5 MAT PLUS 55 M SiC 7 1500 1550 1600 (red) 1500 1530 (red) 1500 1500 1500 1500 1500 1550 1580 1550 (red) Chamotte / SiC SiC / Corundum Sintered Mullite / SiC SiC / Chamotte SiC / Andalusite SiC / Corundum SiC / Chamotte SiC / Chamotte SiC / Chamotte SiC / Chamotte Silicon Carbide Andalusite / SiC Sintered Mullite / SiC 43.0 53.0 53.0 34.0 41.5 57.0 29.0 25.0 20.5 16.0 12.0 56.5 55.5

SiO2 43.0 33.0 32.0 33.0 26.5 7.0 27.0 22.0 18.0 12.0 4.0 36.0 33.0

Fe2O3 0.4 0.4 1.0 0.3 0.65 0.3 0.2 0.2 0.6 0.2 0.2 0.8 1.0

SiC 9.0 9.0 10.0 29.0 29.0 31.0 39.0 48.0 58.0 68.0 79.0 5.0 7.0 2.25 2.45 2.45 2.28 2.65 2.55 2.33 2.38 2.42 2.44 2.50 2.55 2.52

Reinforcement Stainless Steel Fibers


PRODUCT NAME Melting Temperature at oC Critical Oxidation Temperature (%) Cycling Heating 304 310 330 430 446 METAL-X 1400-1455 1400-1455 1345-1425 1480-1530 1425-1510 1480-1530 870 1040 1050 850 1205 1250 Continuous Service 980 1150 1165 815 1200 1300 Chemical Composition (%) Coefficient of Thermal Expansion (870 oC ) at 10 -6/ oC

Cr 18-20 24-25 17-19 14-18 23-27 23

Ni 8-12 19-22 34-36 0.5 20.2 18.5 17.6 13.7 13.1 15.0

64

Refractory Products

Technical Data

Silicon Carbide Low Cement Castables


Cold Crushing Strength (N/mm2) (EN 1402-6) Grain Size (mm) (EN 1402-3) Permanent Linear Change (%) (EN 1402-6) Reversible thermal expansion at 1000 oC (%) Material required (kg/m3) Approx. water addition (EN 1402-4) (lt/100 kg dry material)

at 1100 oC 90 95 120 100 100 100 100 100 100 100 95 90 110

at 1400 oC 95 95 120 95 100 95 100 100 100 100 95 100 120 6 6 6 3 8 6 3 3 3 3 3 8 6

at 1100 oC -0.20 -0.15 0.7 -0.20 0.20 -0.20 -0.20 -0.20 -0.20 -0.25 -0.10 -0.15 -0.25 0.50 0.60 0.60 0.55 0.56 0.60 0.55 0.55 0.56 0.56 0.78 0.60 0.60 2300 2500 2500 2330 2700 2600 2380 2420 2460 2490 2550 2600 2570 5.5 - 6.5 5.0 - 6.5 4.8 - 6.0 5.5 - 6.5 4.2 - 5.0 5.5 - 6.5 5.5 - 6.5 5.5 - 6.5 5.5 - 6.5 5.5 - 6.5 5.0 - 6.5 4,5 - 6,0 4,5 - 5,5

Refractory Products

65

Technical Data

Chromium Oxide Low Cement Castables


PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677)

Al2O3 MAT PLUS 85 CR 8 MAT PLUS 88 CR 8 S MAT PLUS 88 CR 8 MAT PLUS 90 CR 4 MAT PLUS 90 CR 4 S MAT PLUS 94 CR 2 MAT PLUS 95 QC 1700 1700 1700 1700 1700 1700 1750 Corundum / Chrome Oxide Synthetic Raw Materials / Chrome Oxide Sintered Alumina / Chrome Oxide Sintered Alumina / Chrome Oxide Synthetic Raw Materials / Chrome Oxide Sintered Alumina / Chrome Oxide Sintered Alumina 85.0 87.5 88.0 91.0 90.0 93.5 95

SiO2 0.9 2.4 2.1 2.2 2.8 2.2 3.0

Fe2O3 0.5 0.6 0.1 0.1 0.7 0.1 0.1

Cr2O3 8.0 8.0 8.0 4.0 4.0 2.0 2.0

Anti-Wetting Low Cement Castables


PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677)

Al2O3 MAT PLUS 60 M AL MAT PLUS 65 M AL MAT PLUS 80 EA AL MAT PLUS 80 AL 1250 1250 1250 1200 Sintered Mullite Sintered Mullite Bauxite - Andalusite Bauxite 57.0 62.0 73.0 76.0

SiO2 33.5 28.0 16.0 10.7

Fe2O3 1.0 1.0 1.3 1.4

BaO 3.0 3.0 3.0 5.0

66

Refractory Products

Technical Data

Chromium Oxide Low Cement Castables


Cold Crushing Strength (N/mm2) (EN 1402-6) Grain Size (mm) (EN 1402-3) Permanent Linear Change (%) (EN 1402-6) Reversible thermal expansion at 1000 oC (%) Material required (kg/m3) Approx. water addition (EN 1402-4) (lt/100 kg dry material)

at 1100 oC 80 75 80 80 85 90 95

at 1500 oC 100 100 110 110 90 85 95 8 10 6 6 6 6 6

at 1100 oC -0.15 -0.15 -0.15 -0.15 -0.15 -0.15 -0.10 0.80 0.82 0.82 0.82 0.83 0.83 0.80 3250 3130 3130 3070 3050 3040 3000 4.5 - 6.0 4.5 - 6.0 4.5 - 6.0 4.5 - 6.0 4.5 - 6.0 4.5 - 6.0 4.5 - 6.0

Anti-Wetting Low Cement Castables


Cold Crushing Strength (N/mm2) (EN 1402-6) Grain Size (mm) (EN 1402-3) Reversible thermal expansion at 1000 oC (%) Material required (kg/m3) Approx. water addition (EN 1402-4) (lt/100 kg dry material)

at 1100 oC 80 80 85 90 6 6 6 6 0.63 0.65 0.65 0.67 2500 2530 2800 2950 4,5 - 6,0 4,5 - 6,0 4,5 - 6,0 4,0 - 5,5

Refractory Products

67

Technical Data

Conventional Gunning Materials


PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677)

Al2O3 MAT GR G MAT 35 G MAT 40 G MAT 44 G MAT 48 G MAT 50 G MAT 50 SMG MAT 57 HG MAT 60 G MAT 60 SMG MAT 70 G MAT 80 G MAT 80 SPDG MAT 90 G MAT 95 G 1270 1280 1320 1350 1460 1480 1500 1470 1560 1500 1500 1580 1600 1650 1700 Chamotte Chamotte Chamotte Chamotte Chamotte Chamotte Fireclay Hight Alumina Raw Materials Andalusite Bauxite Bauxite Bauxite Bauxite Corundum Tabular Alumina 30.0 34,5 41.5 44.0 48.0 48.5 50.0 56,0 59.5 62.0 70.0 79.0 80.0 87.7 95.0

SiO2 52.5 50 45.0 46.5 41.5 42.0 40.0 34.5 32.0 28.5 14.5 8.5 8.2 2.8 0.15

Fe2O3 3.6 2.8 2.1 1.4 1.4 1.4 1.2 1.2 1.1 1.5 1.8 1.4 1.3 0.5 0.15

Calcium Aluminates Cements


PRODUCT NAME Pyrometric cone equivalent at oC Al2O3 FONDU SECAR 51 SECAR 71 SECAR 80 ALAG 1270 - 1290 1430 - 1450 1590 - 1620 1770 - 1810 1270 - 1290 37.0 50.0 68.5 79 > 36.0 Chemical Analysis (%) (EN ISO 12677) SiO2 6.0 6.0 0.8 0.4 6.0 Fe2O3 18.5 2.8 0.4 0.3 18.5 Bulk Density (EN 1402-6) at 110 oC (g/cm3) 1.10 0.90 - 1.00 0.90 0.70 - 0.80 1.60 - 1.70

68

Refractory Products

Technical Data

Conventional Gunning Materials


Cold Crushing Strength (N/mm2) (EN 1402-6) Grain Size (mm) (EN 1402-3) Permanent Linear Change (%) (EN 1402-6) Reversible thermal expansion at 1000 oC (%) Material required (kg/m3) Approx. water addition (EN 1402-4) (lt/100 kg dry material)

at 1100 oC 20 18 28 25 45 23 41 48 24 18 40 40 42 24 40 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6

at 1100 oC -0.7 -0.45 -0.40 -0.30 -0.35 -0.30 -0.15 -0.3 +0.20 -0.20 -0.4 -0.20 -0.20 -0.15 -0.15 0.50 0.52 0.55 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.70 0.75 0.75 0.80 0.81 2100 2130 2200 2200 2250 2200 2300 2300 2300 2300 2600 2600 2600 2900 2800 At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle

Refractory Products

69

Technical Data

Medium Cement Gunning Materials


PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677)

Al2O3 MAT 32 GS MAT 40 GS MAT 48 GS MAT 50 GS MAT MC 55 G MAT 57 GS MAT 57 A GS MAT 58 M GS MAT 60 GS MAT 74 GS MAT 78 GS MAT 80 GS MAT SiC 68 GS MAT SiC 72 GS MAT 56 ZR 10 GS MAT 57M SiC 5 GS 1320 1350 1470 1500 1550 1500 1520 1500 1550 1450 1500 1500 1500 1500 1600 1500 (red) Chamotte - Synthetic Raw Materials Chamotte Chamotte Chamotte High Alumina Raw Materials Chamotte - Sintered Mullite Andalusite Sintered Mullite Sintered Mullite Bauxite - Mullite Bauxite Bauxite Silicon Carbide Silicon Carbide Andalusite Sintered Mullite/SiC 32.0 40.0 48.0 50.0 55.5 57.0 57.0 58.0 58.5 73.5 78.0 79.5 18.0 16.0 56.0 57.0

SiO2 58.5 53.0 44.5 43.0 39.0 37.5 36.5 33.5 33.5 15.5 11.5 11.8 8.0 7.4 28.0 30.0

Fe2O3 1.0 1.5 1.3 1.5 0.8 1.1 0.8 1.0 1.1 2.1 2.2 2.1 0.9 0.9 0.6 0.9

Special Gunning Materials


PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677)

Al2O3 MAT 20 ZR G MAT 30 ZR G MAT GUN 10 SiC MAT GUN 30 SiC MAT GUN 50 SiC MAT GUN 70 SiC 1450 1380 1500 1500 1550 1550 ZAC/Chamotte Zircon Based Raw Materials SiC / Chamotte SiC / Chamotte SiC / Chamotte SiC / Chamotte 50.0 39.0 42.0 35.0 26.0 17.0

SiO2 19.5 20.0 39.2 28.0 17.0 7.0

Fe2O3 0.65 1.0 0.5 0.2 0.2 0.2

SiC

ZrO2 22.0 30.0

9.5 29.0 48.0 68.0

70

Refractory Products

Technical Data

Medium Cement Gunning Materials


Cold Crushing Strength (N/mm2) (EN 1402-6) Grain Size (mm) (EN 1402-3) Permanent Linear Change (%) (EN 1402-6) Reversible thermal expansion at 1000 oC (%) Material required (kg/m3) Approx. water addition (EN 1402-4) (lt/100 kg dry material)

at 1100 oC 40 40 50 40 1200 (14) 50 65 40 55 40 50 60 60 60 65 60

at 1400 oC 1300 (60) 1300 (50) 60 55 18 65 1500 (70) 6 6 6 6 6 6 6 6 6 6 6 60 6 3 3 6 90 6

at 1100 oC -0.65 - 0.65 -0.55 - 0.55 -0.40 -0.50 -0.25 -0.40 -0.50 -0.40 -0.30 -0.55 -0.20 -0.20 -0.30 -0.25 0.52 0.54 0.6 0.60 0.6 0.58 0.58 0.58 0.6 0.65 0.74 0.74 0.55 0.55 0.58 0.58 2100 2150 2230 2250 2230 2350 2450 2450 2250 2570 2560 2580 2500 2500 2600 2430 At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle

Special Gunning Materials


Cold Crushing Strength (N/mm2) (EN 1402-6) Grain Size (mm) (EN 1402-3) Permanent Linear Change (%) (EN 1402-6) Reversible thermal expansion at 1000 oC (%) Material required (kg/m3) Approx. water addition (EN 1402-4) (lt/100 kg dry material)

at 1100 oC 60 45 50 47 48 45 6 6 6 6 6 6

at 1100 oC -0,35 -0,60 -0.05 -0.05 -0.05 -0.0.5 0.7 0.73 0.48 0.5 0.53 0.55 2670 2830 2250 2300 2400 2500 At nozzle At nozzle At nozzle At nozzle At nozzle At nozzle

Refractory Products

71

Technical Data

Insulating Castables
PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677)

Al2O3 MAT 106 LP MAT 106 L MAT 106 P MAT 106 MAT 125 P MAT 125 MAT 124 P MAT 124 MAT 135 LI P MAT MW L MAT MW 1000 1000 1020 1030 1080 1100 1120 1150 1340 1250 1300 Perlite Vermiculite Perlite Vermiculite Perlite/Expanded Clay Vermiculite / Expanded clay Perlite / Double Process Porcelain Vermiculite / Double Process Porcelain Light Weight Chamotte Lightweight Chamotte Lightweight Chamotte 36.0 34.0 37.5 35.0 36.0 27.0 31.0 27.0 37.0 38.0 38.0

SiO2 31.0 26.5 27.0 22.0 35.0 33.5 45.5 42.5 43.5 43.5 42.5

Fe2O3 4.2 6.0 4.5 8.1 4.4 12.0 3.5 7.8 6.0 6.1 6.2

Insulating Gunning Materials


PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677)

Al2O3 MAT 106 L GP MAT 106 GP MAT 106 G MAT 125 GP MAT 125 G MAT 124 GP MAT 124 G MAT MW G 1000 1020 1030 1080 1120 1100 1120 1300 Perlite Perlite Vermiculite Perlite / Expanded clay Vermiculite / Expanded clay Perlite / Double Process Porcelain Vermiculite / Double Process Porcelain Lightweight Chamotte 36.5 38.5 30.0 34.5 28.0 31.0 27.0 38.0

SiO2 30.0 26.0 20.5 37.0 37.0 46.0 43.0 43.0

Fe2O3 4.2 4.5 13.5 4.7 9.5 3.7 7.8 6.2

72

Refractory Products

Technical Data

Insulating Castables
Cold Crushing Strength (N/mm2) (EN 1402-6) Thermal Conductivity (W/mK) (EN 993-14) Grain Size (mm) (EN 1402-3) Permanent Linear Change (%) (EN 1402-6) Material required (kg/m3) Approx. water addition (EN 1402-4) (lt/100 kg dry material)

at 1000 oC 0.8 0.7 0.9 1.3 2.3

at 1100 oC

at 800 oC 0.18 0.17 0.20 0.19 0.25 6 6 6 6 6 6 6 6 6 6 6

at 800 oC -0.8 -0.75 -0.55 -0.75 -0.35 -0.4 -0.45 -0.45 -0.3 -0.3 -0.25

at 1000 oC

at 1100 oC 650 650 800 800 80-95 80-95 70-80 70-80 38-48 40-50 35-45 35-45 35-40 22-27 22-27

-0.75 -0.75 -0.80 -0.85

1000 1100 1200 1200 1420 -0.70 -0.50 1580 1650

2.8 2.5 3.5 6.5 3.5 6.0

0.28 0.38 0.37 0.42 0.47 0.54

Insulating Gunning Materials


Cold Crushing Strength (N/mm2) (EN 1402-6) Thermal Conductivity (W/mK) (EN 993-14) Grain Size (mm) (EN 1402-3) Material required (kg/m3) Approx. water addition (EN 1402-4) (lt/100 kg dry material)

at 1000 oC 0.9 1.1 1.3

at 1100 oC

at 800 oC 0.18 0.19 0.21 2.9 2.7 2.7 3.6 5.5 0.28 0.27 0.40 0.39 0.56 6 6 6 6 6 6 6 6 850 850 800 1030 1100 1250 1250 1680 75-90 / At nozzle 70-85 / At nozzle 70-85 / At nozzle 37-50 / At nozzle 40-55 / At nozzle 35-45 / At nozzle 35-45 / At nozzle 22-28 / At nozzle

Refractory Products

73

Technical Data

Ramming Materials
PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677)

Al2O3 PYROPLASTIC SUPER PYROPLASTIC SUPER 80 MAT RAM 50 M MAT RAM 50 C MAT RAM 60 C MAT RAM 70 C MAT RAM 70 CM MAT RAM 80 MAT RAM 80 C MAT RAM 90 C 1450 1620 1600 1550 1600 1600 1650 1650 1650 1750 Chamotte Bauxite Chamotte / Mullite Chamotte Chamotte / Bauxite Bauxite / Corundum Mullite / Corundum Bauxite Bauxite / Sintered Alumina Corundum 37.0 72.5 53.0 50.0 60.0 69.0 70.0 77.0 80.0 89.5

SiO2 58.0 20.5 42.0 43.0 32.5 19.0 23.0 16.0 13.5 5.5

Fe2O3 1.8 1.7 0.8 1.2 1.4 1.4 1.0 1.6 1.3 0.5

Special Ramming Materials


PRODUCT NAME Classification Temperature (EN 1402-1) at oC Main Raw Material Base (EN 1402-1) Chemical Analysis (%) (EN ISO 12677)

Al2O3 MAT RAM 85 SiC P MAT RAM 90 SiC P 1550 1550 Silicon Carbide Silicon Carbide 6.0 1.5

SiO2 5.0 5.5

Fe2O3 0.2 0.1

SiC 83.0 89.0

74

Refractory Products

Technical Data

Ramming Materials
Cold Crushing Strength (N/mm2) (EN 1402-6) Grain Size (mm) (EN 1402-3) Permanent Linear Change (%) (EN 1402-6) Reversible thermal expansion at 1000 oC (%) Material required (kg/m3)

at 1100 oC 16.0 18.0 18 65 65 65 65 40 70 70 6 6 6 6 6 6 6 6 6 6

at 1100 oC -1.4 -1.4 -0.15 -0.25 -0.35 -0.25 -0.2 -0.25 -0.15 -0.15 0.55 0.72 0.55 0.55 0.57 0.58 0.58 0.72 0.72 0.75 2300 2650 2250 2350 2450 2560 2600 2750 2750 2950

Special Ramming Materials


Cold Crushing Strength (N/mm2) (EN 1402-6) Grain Size (mm) (EN 1402-3) Permanent Linear Change (%) (EN 1402-6) Reversible thermal expansion at 1000 oC (%) Material required (kg/m3)

at 1100 oC 80 70 3 3

at 1100 oC 0.10 0.15 0.68 0.72 2650 2550

Refractory Products

75

Technical Data

Insulating Firebricks
PRODUCT NAME Classification Group (ISO 2245) Classification Temperature at oC Density (ASTM C-134) kg/m3 Cold Crushing (ASTM C-93-84) MPa Modulus of Rapture (ASTM C-93-84) MPa Specific Heat (KJ/kgK) at 1000 oC

GR 23 GR 25 GR 25 A GR 25 B GR 25 CA GR 25 HS GR 26 GR 26 HS GR 28 GR 30 GR 32

125-0.5-L 135-0.8-L 135-0.8-L 135-0.9 135-1.1 135-1.1 140-0.8-L 140-0.9-L 150-0.9-L 160-1.0-L 170-1.2-L

1260 1350 1350 1350 1350 1350 1430 1430 1540 1650 1760

480 800 820 900 1100 1100 800 870 890 1020 1250

1.2 2.5 2.5 4.0 5.4 6.0 1.6 4.0 2.1 2.2 3.5

1.0 3.1 1.5 1.8 2.1 2.1

1.05 1.10 1.10 1.10 1.10

Insulating Firebricks - Calcium Silicate Insulating Boards


PRODUCT NAME Max Service Temperature oC Density (ASTM C-134) kg/m3 Cold Crushing (ASTM C-133-93) MPa

Total Porosity (ISO 5017)%

Specific Heat (KJ/kgK) at 1000 oC

ISO 450 ISO 550 ISO 750 S CALCIUM SILICATE N CALCIUM SILICATE P CALCIUM SILICATE HT

900 900 900 950 950 1050

425 500 750 245 290 290

1.3 2.5 7.0 0.9 1.15 1.9

82 81 68 1.5

0.80 0.75 0.75 0.80

76

Refractory Products

Technical Data

Insulating Firebricks
Thermal Conductivity (ASTM C-182) W/mK Chemical Analysis (%)

at 400 oC 0.12 0.24 0.24 0.27 0.32 0.32 0.25 0.29 0.30 0.38 0.49

at 600 oC 0.14 0.28 0.28 0.30 0.36 0.36 0.27 0.32 0.32 0.39 0.50

at 800 oC 0.17 0.32 0.32 0.35 0.40 0.40 0.30 0.35 0.34 0.40 0.51

at 1000 oC 0.19 0.37 0.37 0.40 0.45 0.45 0.33 0.38 0.36 0.41 0.53

at 1200 oC 0.35 0.41 0.38 0.42 0.56

at 1400 oC 0.60

Al2O3 37.0 50.0 34.0 34.0 34.0 50.0 58.0 54.0 67.1 73.4 77.0

SiO2 44.4 57.0 57.0 57.0 39.1 31.0 25.1 21.5

Fe2O3 0.7 0.9 1.2 1.2 1.2 0.9 0.7 0.8 0.6 0.5 0.3

TiO2 1.2 0.1 0.1 0.1 tr

CaO 1.2 0.1 0.1 0.1 tr

MgO 0.3 0.2 0.2 0.2 0.2 0.1 tr 0.1

Na 2O+K 2O 1.1 1.7 0.9 0.9 0.9

Insulating Firebricks - Calcium Silicate Insulating


Thermal Conductivity (ASTM C-182) W/mK Chemical Analysis (%)

at 200 oC 0.10 0.12 0.15 0.07 0.08 0.07

at 400 oC 0.12 0.14 0.17 0.10 0.10 0.10

at 600 oC 0.14 0.16 0.19 0.14 0.14 0.14

at 1000 oC 0.19 0.37 0.37 0.40 0.45 0.45

Al2O3 14.8 14.8 9.0 0.49 0.49 0.40

SiO2 66.5 66.5 77.0 44.1 44.1 46.9

Fe2O3 4.1 4.1 7.0 0.09 0.09 0.09

TiO2 0.5 0.5 0.7 -

CaO 5.0 5.0 0.8 42.7 42.7 43.2

MgO 2.1 2.1 1.3 0.3 0.3 -

Na2O+K 2O 6.5 6.5 2.0 0.12 0.12 0.01

Refractory Products

77

Technical Data

Exfoliated Vermiculite
PRODUCT NAME Grain Size(mm) Fusion Point at oC Density at kg/m3 Thermal Conductivity (under ambient conditions) Water Absorption Capacity (% b.v.) pH

SUPER FINE FINE MEDIUM LARGE

0-2 1-3 1-4 5-8

1200-1320 1200-1320 1200-1320 1200-1320

95-120 85-110 80-100 70-90

0.063-0.069 0.063-0.069 0.063-0.069 0.063-0.069

20-50 20-50 20-50 20-50

6-9 6-9 6-9 6-9

Acid - Proof Cements & Concretes


PRODUCT NAME Density (g/cm3) Compressive Strength (N/mm2) (After 28 days) Flexural Strength (N/mm2) Tensile Strength (N/mm2) Adhesion to. (N/mm2) Flexibility 10 (N/mm2)

Ceramic ASPLIT ET ASPLIT CN 916 MAC ACID MAT ACID GS 2.05 1.45 2 2.15 100 60 35 50 30 6 40 40 -

Steel Concrete 10 1.2 1.4 1.0 -

Acid - Resistant Tiles - Bricks


PRODUCT NAME Density (g/cm3) Compressive Strength (N/mm2) Water Absorption (w.t%) Acid Solubility (% b.w) Chemical Analysis (%)

Al2O3 IDEAL ACID 20 IDEAL ACID SUPER IDEAL ACID SUPER DT 2.1 2.12 2.14 75 65 70 6.8 5.5 5.5 2.5 1.2 0.85 20 19.5 21.5

SiO2 73.5 74 72

78

Refractory Products

Technical Data

Exfoliated Vermiculite
Chemical Analysis (%)

Al2O3 10-16 10-16 10-16 10-16

SiO2 38-46 38-46 38-46 38-46

Fe2O3 6-13 6-13 6-13 6-13

CaO+K 2O 2-11 2-11 2-11 2-11

MgO 16-35 16-35 16-35 16-35

Acid - Proof Cements & Concretes


Thermal Conductivity (W/mK) Thermal Linear Expansion (106 1/K) Thermal Resistance up to (oC)

1.7 1.6 1.2 -

45 12 -

120 180 900 1100

Acid - Resistant Tiles - Bricks


Type of Bonding Thermal Shock Resistance (Cycles as per EN 993-11) Open Porosity (% b.v)

Ceramic Ceramic Ceramic

12 7 7

12 11 11

Refractory Products

79

Technical Data

Ceramic & High Temperature Soluble Insulation Fibers


PRODUCT NAME Type of Product Max Service Temperature at oC Density (Kg/cm3) Tensile Strength (KPa) Compressive Strength (MPa) Specific Heat (KJ / kgK) Thickness (mm)

at 1090 oC CERAMIC BLANKET 1260 96 128 96 128 96 128 96 128 310 310 210 200-220 70 90 70 90 65 90 70 95 750 650 0.35 0,30 1.13 13-25-38-50

CERAMIC BLANKET HT Blanket SW 607

1425

1.13

13-25-38-50

1100

1.05(at 540 oC)

13-25-38-50

SW 607 MAX CERAMIC BOARD 100 CERAMIC BOARD 115 CERAMIC PAPER SW 607 MAX PAPER CERAMIC FIBER SW 607 HT PAPER

1200 1260 1400 1260 1200 1260 1300

1.13 1.13 1.13

14-25-38-50 6-10-13-25-50 6-10-13-25-50 1-2-3-4-5-6 1-2-3-4-5-6 -

Panels

Papers

Bulk Fbers

Mineral Fibers
PRODUCT NAME Type of Product Max Service Temperature at oC Density (Kg/cm3) Thermal Conductivity (W/mK) Thickness (mm)

at 100 oC Blanket supported with wire mesh 60 700 90 120 40 FIBER BOARDS Panel 700 50 75 100 BULK FIBERS Bulk Fibers 800 150 0.045 0.042 0.042 0.050 0.049 0.048 0.045 0.045 0.043

at 200 oC 0.066 0.059 0.057 0.086 0.080 -

at 350 oC 0.113 0.097 0.092 30 up to 100 30 up to 100

BLANKET

80

Refractory Products

Technical Data

Ceramic & High Temperature Soluble Insulation Fibers


Thermal Conductivity (ASTM C-182) W/mK Chemical Analysis (%)

at 200 oC 0.06 0.06 0.06 0.06 0.06 0.06 0.09 0.08 0.06

at 400 oC 0.11 0.10 0.11 0.10 0.11 0.10 0.13 0.12 0.08 0.08 0.09 0.09

at 600 oC 0.16 0.15 0.16 0.15 0.17 0.16 0.19 0.16 0.11 0.11 0.13 0.14 -

at 800 oC 0.23 0.20 0.23 0.20 0.28 0.24 0.15 0.15 0.20 0.23 -

at 1000 oC 0.32 0.27 0.32 0.27 0.39 0.34 0.20 0.20 0.35 -

Al2O3

SiO2

Fe2O3 + TiO2

ZrO2

CaO + MgO

Na 2O+K 2O

44.0

56.0

0.15

0.05

0.10

35.0

50.0

15

0.15

0.09

0.10

0.3

60.0-70.0

25.0-40.0

0.3 44.0 44.0 47.0 0.3 44.0 -

60.0-70.0 54.0 54.0 52.0 60.0-70.0 56.0 70.0-80.0

10 -

1.0 1.0 0.15 -

25.0-40.0 1.0 1.0 25.0-40.0 0.05 18.0-25.0

1.0 1.0 0.10 -

Refractory Products

81

High Quality Solutions

High Quality Solutions

82

Refractory Products

High Quality Solutions

Chemical Industry - Glass Industry - Ceramic Industry Lime Industry - Foundry - Refineries - Waste Incinerators

Refractory Products

83

High Quality Solutions

Aluminium Industry - Steel Industry - Power Plants Cement Industry - Non Ferrous Industry

84

Refractory Products

High Quality Solutions

Aluminium Industry - Steel Industry - Power Plants Cement Industry - Non Ferrous Industry

Refractory Products

85

Research & Development

Research & Development

86

Refractory Products

Research & Development

Mathios Refractories S.A.


is developing and expanding the portfolio and the typical applications of the refractory materials through the latest technology equipment in the production line along with the highly experienced personnel of the R&D Department. The main activities of the R&D Department include the optimization of the existing formulations and products, the line tuning of formulations in order to meet the customers requirements, the research and development of new - advanced refractory materials, pilot plant trials in different industrial sectors, the technical support of Sales Department, as well as the collaboration with Institutes and Universities.

Refractory Products

87

Certification

88

Refractory Products

Certification

Refractory Products

89

Refractory Industry

5 Epidavrou Str., 182 33 Athens, Greece el: +30 210 4913502, Fax: +30 210 4903949 e-mail: mathios@mathios.gr www.mathios.gr International Sales: Tel: +30 210 42 57 377, Fax: +30 210 42 57 377 e-mail: export@mathios.gr www.mathios.com

Harpener Feld 11, 44805 Bochum, Deutschland, el: +49 234 61 03 925-926, Fax: +49 234 61 03 927 e-mail: info@mathios-gmbh.de www.mathios.de

Nikola Malasevski 9 2600 Dupnica, Bulgaria el: +359 878186555, Sofia showroom: 36 Okuluversten Pat Perl Park Mall Sofia, Bulgaria tel :+359 701 40094 Fax:+359 701 40094 e-mail: mathiosad@mathios.gr www.mathios.com

1 rue de la Haye Le Dome - BP 12910 95731 ROISSY CDG el: +33 1 49 19 26 50, Fax: +33 1 49 19 21 00 e-mail: export@mathios.gr www.mathios.com