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Introduction Introductionto toBasic BasicThermodynamic ThermodynamicConcepts Concepts(3 (3h) h) Learning Objectives: Learning Objectives: (1) (1)Relevance Relevanceto toChemical ChemicalEngineering Engineering (2) (2)Thermodynamic ThermodynamicProperties Properties (3) (3)Zeroth ZerothLaw Lawof ofThermodynamics Thermodynamics (4) (4)First FirstLaw Lawof ofThermodynamics Thermodynamics Learning LearningGuides: Guides: (1) (1)Lecture Lecturehandouts handouts (2) (2)Chapters Chapters11and and22of ofIntroduction Introductionto toChemical ChemicalEngineering Engineering Thermodynamics Thermodynamics5th 5thed. ed.(Smith, (Smith,Van VanNess, Ness,Abbott) Abbott) (3) (3)Please Pleasereview reviewyour yourPhysical PhysicalChemistry ChemistryNotes Notes
Thermodynamics
(1) Thermodynamics was developed by engineers to describe the conversion of chemical energy stored in fossil fuel into heat and useful work.
Chemical Energy
Heat
Work
With this in mind, it is not surprising to see many terms used to described Thermodynamics have practical or engineering origin. Most equations are developed for ease in their use rather than for their elegance.
orm
ati o
distillation
Crude Oil
Ph y si
Refinery
cal
tra
n sf
Smelting
Chemical transformation
Distillation
Conductivity
Protein folding
Self-assembly structures
1 torr = 1 mm Hg 1 atm = pressure exerted by the air at see level 1 atm = 760 mm Hg 1 atm = 14.7 psia 1 psia = 1 poundal per square inch absolute
http://www.chemie.fu-berlin.de/chemistry/general/units_en.html
Conversions T (K) = t(C) + 273 = T(R)/1.8 T (R) = t(F) + 460 t(F) = 1.8 t(C) + 32
Conversions 1 J = 1 kg m-2 s-2 = 1 N m = 10 cm3 bar = 107 dyne cm = 107 erg = 0.239 cal = 0.7376 ft-lbf = 9.478 x 10-4 BTU Types of Energies: Stored Energies: Internal energy (energy stored in molecules) Potential energy (configurational energy) Kinetic energy (motion) macroscopic
Mechanical Energies
(1) Kinetic Energy energy stored in moving objects Ek = 1/2 mu2
Mechanical Energies
(2) Potential Energy energy stored in objects due to their relative position or configuration. Gravitational potential energy: Ep = mgz
Example 1. Calculate the kinetic and potential energies of 1 kg of water located 50 m at the top of the Hoover dam, and when it reaches the bottom. How much mechanical work could be extracted from this kilogram of water if the turbine is 100 % efficient?
Example 2. A toy designer wanted to produce a new spring loaded toy gun that shoots colored bubbles along with a 1 gram pellet to a height of 100 ft. If the maximum deflection allowed in the gun design is 3 cm, please calculate the spring constant needed for its operation.
100 ft
50 m
spring
Internal Energy
energy stored within the molecule as translational, rotational and vibrational energies. Change in the internal energy is usually manifested by a change in the temperature. U = f(T)
Example 3. A liter thermos of water at 50C was dropped by a construction worker from a height 150 m. Calculate the initial and final potential, kinetic and internal energies of the water.
translational
rotational
vibrational
Example 4. A car weighing 4000 kg decelerates from 200 kph to a full stop at around 15 s. About 60 percent of the initial kinetic energy is dissipated as heat at the brake pad and the rest absorbed by the tire.
Infrared picture of the braking car Heat (Q) refers to energy transferred from a hot to a cold object. Tire volume 10 liters Initial tire pressure 30 psia heat capacity of air 1 J/Kg Tire bursting pressure 80 psia
Important Definitions
Reversibility reversible: if the process happens slow enough to be reversed. irreversible: if the process cannot be reversed (like most processes)
Energy transfer to and from the system from and to the surrounding
Work
U + Ek + Ep SYSTEM
Heat
Reversible system allows more efficient conversion to useful work Rapid processes are usually irreversible and most energy are dissipated by viscous mixing into internal energy. Generally less amount of useful work can be gained from a irreversible system.
SURROUNDING isolated systems: no exchange of matter or energy closed systems: no exchange of matter but some exchange of energy open systems: exchange of both matter and energy
http://www.cchem.berkeley.edu/~chem130a/sauer/outline/firstlaw.html
www.planemath.com/.../propulsion/ propulsion3.html
Reversibility
Reversibility
(PV)in
min Uin
mout Uout
Q U + Ek + Ep = WT + Q
W - PV
U >> Ek + Ep U + PV = W + Q H =W+Q
Homework 1
February 11, 2002 Problem 1. A gas is contained in two cylinders A and B connected by a piston of two different diameters, as shown in the figure below. The mass of the piston is 10 kg and the gas pressure inside cylinder A is 200 kPa. Calculate the pressure in cylinder B in kPa, bar, psi and inches of water.
d = 100 mm
d = 25 mm
Problem 2. Nitrogen flows at steady-state through a horizontal, insulated pipe with inside diameter of 1.5 inch. A pressure drop results from flow through a partially opened valve. Just upstream from the valve the pressure is 100 psia, the temperature is 120F, and the velocity is 20 ft/s. If the pressure just downstream from the valve is 20 psia, what is the temperature? Assume for nitrogen that PV/T is constant, Cv = 2.5R and Cp = 7.5R. If a thermometer is use for measuring the temperature, what is the temperature reading.