CHE204 AB Acid-Base Chemistry

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1: What was the accurate concentration of the approximatel 2!"# HCl$ as %etermine% from &a'H titrations( )how our calculations$ with *rief explanator text of wh ou are manipulatin+ the num*ers as ou are!

HCl + NaOH NaCL + H2O Titration done with one colour indicator Phenolphthalein : VNaOH, avg = (25.25m !25.2"m !25.#$m !2%."%m &'( = 25.(2 m )H)l = (VNaOH&()NaOH&(Vvolumetric&'(Vpipette&(VH)l& = (25.(2&(".#""*&(25"m &'(#"m &(25m & CHCl = 2.54 M 0.04 Titration done with two colour indicator +romocre,col green(+)-&: VNaOH, avg = (25."2m !25.$(m !25.22m !2(.$5m &'( = 25.2. m )H)l = (VNaOH&()NaOH&(Vvolumetric&'(Vpipette&(VH)l& = (25.2.&(".#""*&(25"m &'(#"m &(25m & CHCl = 2.52 M 0.01
,,: What was the accurate concentration of the approximatel 2!"# HCl$ as %etermine% * titration with &a2C'- ( )how our calculations$ with *rief explanator text of wh ou are manipulatin+ the num*ers as ou are!

*/ o0 Na2)O. = (22.11"g'mol&(2&!(#2."##g'mol&!(#5.111g'mol&(.& = #"5.1$$ g'mol *ole, o0 Na2)O. u,ed in titration: n# = ".#"%%g2#"5.1$$g'mol = #.""5 3 #"45. mol n2 = ".#"65g2#"5.1$$g'mol = #."#( 3#"45. mol n. = ".#"66g2#"5.1$$g'mol = #."#% 3#"45. mol average mole, o0 Na2)O. = #."## 3 #"45. mol

CHE204 AB Acid-Base Chemistry

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Na2)O. ! 2H)l H2O ! 2Na)l ! )O2 Thu,, 7#Na2)O. : 2H)l8 nH)l = (#."##3#"45.&(2& = 2."2.3#"45. mol 9verage Volume o0 H)l :e0ore heating: VH)l = (#1.("m !#$.$%m !#1."2m &'. = #$.(2 m )H)l = n'v = (2."2.3#"45. mol&'(#$.(2m & 2 (#"""m '# & 2 (".25 '"."# & CHCl = 2.74 M
,,,: Are these two concentrations .the same/( Comment on an %iscrepancies$ how the ma ha0e come a*out$ an% what ou mean * .the same/!

The two concentrations for HCl should be the same because both are the result of the same diluting process. However, the calculated HCl concentration has a difference of 0.22M. This discrepancy may have been caused by both instrumental and human error. Instrumental uncertainties are related to the use of measuring devices. For example, a 50 mL burette has an uncertainty of 0.02 mL. This means the value read from the instrument can be 0.02 mL off from the true value. Another source of error is human error, for example, a tiny spill that could have occurred from liquid transfer. So, despite the errors, the calculated concentrations can be considered the same since the difference is small compared to the result and therefore can be neglected.

CHE204 AB Acid-Base Chemistry

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,1: 2ou were +i0en un3nown aci% num*er: AC 4 05- 6 HA 2!2+ What is the molecular wei+ht of this aci%(

22$.". g'mol
)how our calculations! 7a3e more space on a further pa+e if ou nee% to!

2NaOH ! H2; 2Na; !2H2O VNaOH, avg= (#5."2*l!#5..%m !#5.1$m &'. = #5.(5 ml nNaOH = (".#"" mol' &(#5.(5m &(# '#"""m & = #.5(5 3 #"45. mol <ince molar ratio 2 NaOH : # H2;, nH29 = 6.625 3 #"45( mol Total mole, u,ing #25 m volumetric 0la,= and #" m pipette: (6.625 3#"45(&(".#25 &'("."# & = 1.%5% 3 #"45. mol */ o0 H29 = 2.2"2"g'(1.%5%3#"45.& = 228.03 g/mol