MEDICAL TITANIUM ALLOY Ti-6AI-4V DU Qiaolian* CHEN Xuhui t ZHANG Kehua* * ZhejiangNormal University, Jinhua Zhejiang 321004 China t Zhejiang Biomet Medical Products co., Ltd. Jinhua Zhejiang 321016 China Keywords: Medical titanium alloy, Ti-6AI-4V, high-speed cutting, cutting machinability. Abstract On the basis of analyzing the material property and microstructure feature of the Titanium alloy Ti-6AI-4v, the paper clarified the cutting deformation mechanism of the titanium alloy and stated that centralized shearing slipping is the major characteristic of the titanium alloy Ti-6AI-4V at high cutting speed. Through the milling machinability experiment, the paper investigated the milling machinability of titanium alloy Ti-6AI-4V material at high speed milling condition and normal speed milling condition, which indicated that high speed milling technology is effective for improving machining efficiency of titanium alloy and machining surface quality which is beneficial to apply widely to daily production. o Preface Due to its prominent corrosion resistance property and outstanding dynamic performance, Titanium alloy has been widely used in aerospace and chemical industry. In recent years, due to its outstanding biological compatibility, it also used widely in medical engineering industry. Ti-6AI-4V titanium alloy is the first practicable titanium alloy which is successfully developed by U.s. in 1954, it occupies 85% of market demands of various titanium alloys and become the top one alloy in titanium alloy industry. However, titanium alloys are extremely "difficult-to-machine" material due to the poor machinability and high chemical reactivity upon the temperature of 600C and tend to react with oxygen, nitrogen and hydrogen and form hardening layer with high hardness which causes the successive cutting machining more difficult [1]. Meanwhile titanium alloy material has low elasticity modulus and large elasticity recovery. It is easily deformed under the cutting force and the recovery power will decrease the actual clearance angle of the tool and increase the abrasion of the rear face with the machined surface. More often than not, the titanium alloy work piece will be damaged and the fatigue life of the implant will decrease as well. When used as orthopedic implant, medical titanium alloy Ti- 6AI-4v reveals high quality requirement to the machining surface, mostly it requires finish production. In practical finish machining production, the machined surface quality is a crucial guideline of weighing the cutting machinability [2]. Therefore, it has been an urgent problem in titanium alloy machining to get an optimum machining surface quality in finish machining production and improve the cutting machinability. It is also necessary to make further exploratory investigation to the workability of the difficult to machine titanium alloy Ti-6AI-4v material. On the basis of analyzing the material property of the titanium alloy Ti-6AI-4v and its microstructure feature, the paper aimed at investigating the high speed cutting machinability of medical Ti-6AI-4v titanium alloy from theoretically clarifying the deformation mechanism to the cutting machinability at the parameters of high speed milling and normal speed milling through out the milling machining experiment. It was proved that the main chip deformation characteristic of titanium alloy Ti-6AI-4v at high speed cutting is centralized shearing slip; while high speed milling is beneficial to improve the manufacturing efficiency and worth to apply in production. 1 Material property analysis of medical titanium alloy Ti-6AI-4v Titanium alloy Ti-6AI-4v consists of 90% of titanium, 60/0 of aluminium and 4% of vanadium. It has been considered as a high safety implant material internationally due to the good fatigue resistance, lightweight, corrosion resistance, fine biocompatibility and it doesn't affect the nuclear magnetic resonance and CT illness examination. Titanium belongs to allotropism while its fusion point is 1720C. It forms as solid hexagonal crystal pattern at the temperature lower than 882C and named a titanium; Above the temperature of 882C, it forms as space centred cubic lattice pattern and named titanium; Making use of the above two features and adding proper alloy elements will gradually transfer the phase transformation temperature and phase content so to get different organized titanium alloys. At room temperature, titanium alloy has three basic structures. According to the used state, it can be divided as ex type titanium, type titanium and type titanium. ex titanium has good machining character, while titanium takes the second place and titanium the third. ex titanium and titanium are for common use. Medical Ti-6AI-4V titanium alloy belongs to ( type titanium alloy which contains favourable synthesized mechanical property. Its Predominant characteristic is as follows: - 263- Authorized licensed use limited to: PSG College of Technology. Downloaded on July 7, 2009 at 03:48 from IEEE Xplore. Restrictions apply. International Technology and Innovation Conference 2006 speed, some scholars considered it was caused by the local temperature rise generated by the plastic property of the material which lead the thermal softening effect exceed the deformation strengthening effect. Generation of concentrated shearing slip has much to do with the thermophysical property, deformation property and deformation speed of material. It has been proved by many experiments that material with concentrated shearing slip get low thermophysical property, low thermal diffusivity and is easily to generate concentrated shearing slip; For same sort of material, the chip may transfer from strip to serration along with the increasing of the cutting speed. When machining medical Ti-6AI-4V titanium alloy, cutting layer is influenced by the squash of the tool and generate elastoplastic deformation. It slips along the shearing face at the first deformation zone and separate at the nose of the cutting edge while most of them form into chips with the squash and friction of the tool at the second deformation zone along with the rake face. The other small parts squash and rub with the rear face and form into the machined face. The deformation of the material centralized at first deformation zone, therefore it is also called main deformation zone. Provided it is a single shearing face at high cutting speed, the right angle cutting model showed on Fig.2. is cutting rake I rjJ. h I a. . h Yo kn a h ang e , IS S ear ang e, C IS cutting t IC ess, C is chip thickness, therefore the deformation coefficient is: Deformation coefficient , comparatively slip & and shear angle rjJ are the guidelines to scale the cutting deformation degree. The relationship of the three can be seen from geometrical relationship of shear plane OA and shear angle rjJ on Fig. 1-1 [5]: = a ch ac (1) ;; = cos( - Yo) sinrjJ (1) Large Tenacity. 6b=900MPa of intensity, y=4.45 xl 03kg/m 3 density. (2) Low thermal conductivity. Thermal conductivity of titanium is A=7.955W/mK which is 1/5 times of iron and 1/10 times of aluminium. The low thermal conductivity coefficient of titanium makes the material poor in radiate the heat during the cutting process. Therefore, it will cause the temperature increase fast at the cutting angle and the tooI wears off rapidly as well as suffering a short tool life. (3) Low elasticity modulus. Elasticity modulus of Ti-6AI-4V titanium alloy is E=11OGPa which is 112 times of steel, therefore it is easily deformed during machining. The machining property of material can be scaled by durability of tools, quality of the machining surface, chips formation and the complex degree of chips removal etc. It was proved that the titanium alloy material belongs to difficult to machine material [3]. 2 Microstructure test analysis Taking a piece of testing sample (10xl0xlO) from the Ti- 6AI-4V titanium alloy experiment material and adopted different specification of emery cloth to obtain a high quality grinding specimen; and then polished the specimen and used solution of 1: 1: 20 proportion of hydrofluoric acid, nitric acid and distilled water for metallographic corrosion treatment for several seconds. Getting the titanium alloy metallographic micrograph through the SS550 SEM, magnification of700 which shows on Fig. 1: Fig. 1 shows the structure of the Ti-6AI-4V titanium alloy belonged to typical phase. The metallographic structure of phase caused the titanium alloy hard to cut. a phase increased the tenacity of the alloy, improving the crystalline temperature, raising the cohesion of atom in the solution and increasing the heat strength of the alloy while the Bphase makes further strengthening for the alloy. Meanwhile, the small deformation module of Ti-6AI-4V titanium alloy also showed that titanium alloy is difficult-to-cut material. There were three reasons: first of all, titanium had small plasticity (especially during process) and small shrinkage of chips; Second, due to its poor thermal conductivity at the high cutting temperature, titanium a phase transfers to Bphase, and enlargement of Bphase volume make the chip increase; Thirdly, titanium chips react with many ambient media at high temperature, such as oxygen, hydrogen, nitrogen and become friable and lose plasticity. The chips stop to shrink and the deformation coefficient decreased as well. 3 Investigation of titanium alloy deformation mechanism at high cutting speed d. cos Yo tg'f'=----.;;....- -sinYo &=ctgrjJ+tg(rjJ-yo}=. cos Yo slntlos(rjJ - Yo} +1
(4) Titanium alloy would bring concentrated shearing slip at high cutting speed condition [4]. Concentrated shearing slip belongs to one of the metal material deformation form, and the essential condition for its occurrence depends on large and high strain ratio with temperature rise in the slip band. It also depends on the thermodynamic behavior of the material itself. For the concentrated shearing slip deformation at high cutting The deformation coefficient decreases with the increasing of the cutting rake angle. The main reason is while rake angle increasing, the shear angle rjJ increases too and cause the deformation decreases. Under the condition of guaranteeing the cutting edge strength, increasing the cutting rake angle is beneficial to improve the cutting property of the titanium alloy. In the meantime, the investigation also indicated [5] -264 - Authorized licensed use limited to: PSG College of Technology. Downloaded on July 7, 2009 at 03:48 from IEEE Xplore. Restrictions apply. Section 1 Advanced Manufacturing Technology that under the normal cutting level condition, deformation decreases within the increasing of the cutting speed; the increasing of the feed level increases the cutting thickness and the deformation grade decreases too; the deformation grade also decreases within the increasing of the strength and hardness of the work piece material. 4 Investigation of high speed milling machinability 4.1 Test conditions (I)Test piece dimension: 420mm x 200mm x 24mm; (2)Milling machine: X5040 vertical milling machine; (3)Tool: YM30 carbide end mill, 4 tooth. (4)Milling methods: Climb milling, peripheral milling. (5)Cutting data: Normal milling: n= 500rl min, vf= IOOml min, ap=IOmm, ae=O.2mm 0 High speed milling: n= 2500r/min, vf= 500mlmin, ap=10mm, ae=O.2mmo 4.2 Investigation of high speed milling machinability experiment (1 )Investigation of surface quality at high speed milling When machining with normal milling parameter at dry cutting conditions, the relationship between the distributing depth of the milling surface hardening layer and micro hardness are shown in Tab.I. But when adopting high-speed milling parameter, the relationship between the distributing depth of the milling surface hardening layer and micro hardness is shown in Tab.2. It was acknowledged that the surface micro hardness of the titanium alloy material at high speed milling is much lower than at low speed milling. It was proved that the grain size on high speed milling surface has small deformation and small degree of cold work hardening and the depth of the cold working hardening is quite shallow. Testing the machining surface at different cutting speed with surface roughometer, when using normal milling parameter, the roughness is Ra6.4Jlm, while using high speed milling parameter, the roughness is RaO.8Jlm. Surely, the roughness at high speed is much lower than at low speed. It is obviously that in order to improve the utility of the numerical control machine and improve the surface quality of titanium alloy, high speed milling technology has the superiority that other machining method can not compare with. (2)Investigation of residual stress distribution on milling surface Titanium alloy material is extremely sensitive to stress state, especially whether the residual stress on surface and distributing condition could reasonably use or not is very important. The residual stress on machined surface can be classified as residual tensile stress and residual compressive stress. The residual tensile stress can decrease the fatigue intensity and life extension of the part while the residual compressive stress sometimes can improve the fatigue intensity and life extension of the parts. The unevenness of the residual stress on various parts of the machining surface will also make the parts deformed and also affect the shape and dimension precision of the work piece. Therefore, we need to understand and investigate the residual stress and its distribution of titanium alloy Ti-6AI-4V at high speed milling. The residual stress of the titanium alloy can be obtained through X ray Residual stress distribution on surface layer after low speed milling, see Fig. 3. Residual stress distribution on surface layer after high speed milling, see Fig. 4. It can be seen from the Fig. that at low speed milling, the residual compressive stress is high and the tensile stress distribution along the inner surface layer is high too, therefore the material will deform severely after machining and with the attenuation of the stress during use, the parts would deform even severely and finally cause the parts out of use. For high speed milling surface, both the surface residual stress and the stress distribution along the inner surface layer are small, therefore the stress transfer slowly during use and the deformation on the parts will be much smaller too. 5 Conclusions Quality of biological medical metal material products directly relate to the life and healthy of human being. Investigation of cutting process machinability for medical Ti-6AI-4V has great social benefit and profound scientific sense. The investigation in this paper will establish a theoretical basis for titanium alloy machining. Following conclusions was obtained through the investigation of the high speed milling workability: (1) a + ~ phase structure makes it a difficult cutting material, the chip deformation coefficient ~ decreased with the increasing of the cutting rake angle r 0 . On the premise of guaranteeing the strength of cutting edge, enlarge the rake angle of tool could improve the cutting property of the Titanium alloy. (2)High speed milling technology is very effective for increasing the titanium alloy machining efficiency and improving the surface machining quality. (3)when applying high speed milling methods to machine titanium alloy material, the residual compressive stress formed on the surface is lower than normal milling speed, smaller gradient of residual stress formed at the surface and the stress distribute much reasonable. Especially the maximum tensile stress is much smaller and the stress transfers slightly at the tensile stress zone. Therefore, the stress attenuation will become gently while the parts at stress and the deformation generated by the parts decrease, which is beneficial to both the load and use ofthe parts. (4)Adopting high speed milling machining titanium alloy Ti- 6AI-4V, the surface metal has little plastic property and high micro hardness when forming the machining surface. The harden degree will reduce considerably. It can been seen that apply for high speed milling methods to machine the titanium alloy can directly obtain the surface quality by grinding, which has low stress, low surface roughness and low depth of cold work hardening. - 265- Authorized licensed use limited to: PSG College of Technology. Downloaded on July 7, 2009 at 03:48 from IEEE Xplore. Restrictions apply. International Technology and Innovation Conference 2006 Fig. I: Ti-6AI-4V Titanium alloy metallographic micrograph. Residual stresslMPa Fig. 2: right angle cutting model. A 300 200 100 -100 -200 -300 -400 References [I] Liu Lili, "Super High Speed Cutting of Titanium Alloy", Machinery Manufacture, 40(1): 11-15,2004. [2] Davies M A, DurrererB, Pratt J R, "On the Dynamics of High-speed Milling With Long Slender Endmills. CIRP", Annals-Manufacturing Technology, 47(1): 55-60, 1998. [3] Zheng Wenhu, Zhang Yulin, Zhan Mingrong, "Dialogue of Difficult to Machine Material Process", Beijing Publishing House, 2001. [4] Ren Kaiqiang, " High Speed Milling of High Strength Titanium Alloy", Thesisfor Master's Degree. Nanjing University ofAeronautics and Astronautics, 2003. [5] Tan Meitian, "Microscopic Study of Metal Cutting", Shanghai Science and Technology Press, 1988. [6] Perez-Bilbatua J I, "Conventional and High-speed Machining of Titanium Alloys", Information Technology, 8(2): 43-49, 1997. o 25 50 75 100 125 150 175 200 225250 Fig.3: residual stress distribution on surface layer after low speed milling. 300 200 100 o -100 -200 Residual stresslMPa -300 Depth of residual stress on surface/flm -400 25 50 75 100 125 150 175 200 225 Fig.4: residual stress distribution on surface layer after high-speed milling. -266 - Authorized licensed use limited to: PSG College of Technology. Downloaded on July 7, 2009 at 03:48 from IEEE Xplore. Restrictions apply.
Oxy-Acetylene Welding and Cutting: Electric, Forge and Thermit Welding together with related methods and materials used in metal working and the oxygen process for removal of carbon
Oxy-Acetylene Welding and Cutting
Electric, Forge and Thermit Welding together with related methods and materials used in metal working and the oxygen process for removal of carbon