Sri Chaitanya IIT- JEE Academy

RAMAN BHAVAN - VIJAYAWADA CHEMISTRY ASSIGNMENT [ALKANES] Sec : JE1 to JGE Date : 02-12-09 ************************************************************************************ 1. Which of the gi en hydrocar!on "ith form#$a C%&1% gi e' one monoch$oro deri ati e 1( ) - methy$ he*tane +( n - octane )( +, +, ), ) - tetramethy$ !#tane -( +, +, - - trimethy$ *entane +. Which of the fo$$o"ing com*o#nd' ha' highe't ../0 1( + - methy$ !#tane +( n - he1ane )( +, + - dimethy$ *ro*ane -( n - *entane ). In the gi en reaction Na *rod#ct. /rod#ct "i$$ !e C&) 2 C&+ 2 .r dry ether 1( /#re n 2 !#tane +( 3i1t#re of !#tane and hydrogen )( 3i1t#re of C-&14, C+&5 and C+&-( 3i1t#re of C+&5 and C+&-. 6C&)()C3gC$ on reaction "ith 7+8 67e#tero$y'i'( *rod#ce' 1( 6C&)()C7 +( 6C&)()C87 )( 6C7)()C7 -( 6C7)()C87 9. Which of the fo$$o"ing com*o#nd ha' $o"e't !oi$ing *oint0 1( n - he1ane +( n - *entane )( I'o*entane -( :eo*entane 5. A;#eo#' 'o$#tion of *ota''i#m acetate i' e$ectro$y'ed. The *o''i!$e organic *rod#ct' I( C5&5 II( C-&% III( C&)C88C+&9 I<( C+&5 <( C+&1( I on$y +( I, II on$y )( I, III, I<, < on$y -( A$$ =. Which of the fo$$o"ing a$>ane i' 'ynthe'i?ed from 'ing$e a$>y$ ha$ide 1( +(

)(

-(

%. C9&11Cl !y W#rt? reaction form' +, +, 9, 9 - tetra methy$ he1ane a' main *rod#ct. &ence C9&11Cl i' 1( +, + - 7imethy$ - 1- ch$oro *ro*ane +( + - 3ethy$ -1- eh$oro!#tane )( + - Ch$oro*entane -( + - Ch$oro - + - methy$ !#tane 6CH) (+ CHCH + Br 1. Li A B @. 6C&)(+ C& .r +. CuI In the a!o e 'e;#ence AAB i' ca$$ed Gi$manB' reagent. What i' .0 1( 6C&)(+C& C&+C&6C&)(+ +( 6C&)(+ C& C&+C&+C&) )( 6C&)(+ C& C&+C&+ C&+C&) -( 6C&)(+ C& 2 C& 6C&)(+ CH) C KMnO- A. &ere A i' 14. CH ) CH CH ) CH) CH) C C 1( +( CH ) CH COOH CH ) CH = CH+ CH) )( CH ) CH CH) OH
C C

-( C&)C8C&)

11.

A mi1t#re of ethy$ iodide and n 2 *ro*y$ iodide i' '#!Dected to W#rt? reaction. The hydrocar!on "hich "i$$ not !e formed i' 1( .#tane +( /ro*ane )( /entane -( &e1ane ++. The reagent #'ed for the con er'ion C&)C&+C88& C&)C&+C&) i' 1( EiA$&+( Soda 2 $ime )( &IFGed / -( Hn 2 &gF&C$ What i' AIB in the fo$$o"ing Na NaOH F CaO I 1F+ H + J CH 1( 3ethanoic acid +( Ethanoic acid )( /ro*ane -( 3ethana$ Which of the fo$$o"ing "i$$ form a hydrocar!on on reaction "ith Grignard reagent0 1( C&)C&+8& +( C&)C&8 )( C&)C8C&) -( C&)C8+C&) Cl + C&)C&+C&+C&) A K . 6monoch$orination *rod#ct'( the a**ro1imate ratio of *ercentage hv yie$d of A and . formed in a!o e reaction i' 1( 94 : 94 +( =+ : +% )( -9 : 99 -( 54 : -4 &o" many 'tr#ct#ra$ i'omer' are *o''i!$e "hen one of the hydrogen of di*heny$ methane i.e i' re*$aced !y ch$orine atom 1( 5 +( )( % -( = When cyc$ohe1ane i' *o#red on "ater, it f$oat', !eca#'e 1( It i' in !oat form +( It i' in chair form )( It i' in cro"n form -( It i' $e'' den'er than "ater Among't the fo$$o"ing com*o#nd', the o*tica$$y acti e a$>ane ha ing the $o"e't mo$ec#$ar ma'' i' CH) C 1( C&) 2 C&+ 2 C&+ 2 C&) +( CH ) CH + CH CH) CH ) CH CH CH)
C C

1+.

1). 1-.

19.

15. 1=.

)( 1%. 1( )( 1@.

-(

CH) CH)

AlCl ) HCl A, A i' +94 C +( -(

G3gI K 6C&)(+ C&8& A. If A occ#*ie' 1.- E *er gm at :.T./, the G3gI i' 1( C&)3gI +( )( -(

+4. +1.

4.)= gm of a$coho$ "hen treated "ith C&)3gI $i!erate' 11+ m$ of C&- at ST/. The mo$ec#$ar form#$a of a$coho$ "i$$ !e 1( C-&@8& +( C9&118& )( C)&=8& -( C+&98& &o" many *o''i!$e *rod#ct' are o!tained "hen ethy$ !romide and i'o*ro*y$ !romide react #nder W#rt? reaction condition' 1( +( = )( 9 -( )

++.

The fo$$o"ing *ci?' re*re'ent'

1( Same com*o#nd +). +-.

+( Str#ct#ra$ cromer' )( Enantiomer'

-( 7ia'tereomer'

Which of the fo$$o"ing ha' the highe't *otentia$ energy for *entane 1( Anti conformation +( Ec$i*'ed conformation )( Ga#che conformation -( A$$ ha e 'ame *otentia$ energy Which of the fo$$o"ing i' the maDor *rod#ct of the fo$$o"ing reaction

1( ) - !romo - + - methy$ *entane +9. +5. .romo - + - methy$ *entane )( 1 - !romo - + - methy$ *entane -( - - .romo - + - methy$ *entane Which of the fo$$o"ing *rod#ce fo#r monoch$oro deri ati e' on free radica$ ch$orination 1( +, + - 7imethy$ !#tane +( /entane )( +, + - 7imethy$ *ro*ane -( + - methy$ !#tane Which of the fo$$o"ing ha' the highe't !oi$ing *oint 1( +, + - 7imethy$ !#tane +( +, ) - 7imethy$ !#tane )( +, methy$ *entane -( /entane Which gi e' a racemic mi1t#re on monoch$orination 1( :eo*entane +( + - methy$ !#tane )( +, ) - 7imethy$ !#tane -( +, +, ), ) - tetramethy$a$ane Con'ider the fo$$o"ing reaction CH ) C H CH CH ) + B r X + HBr D CH) Identify the 'tr#ct#re of maDor *rod#ct AIB 1( CH ) C H CH C H+ D CH) CH ) CHCH CH )
C C g C C

+(

+=. +%.

+(

CH ) C H CHCH ) D CH) CH ) C CH CH )
C C

)( +@.

C C C -( CH) D CH) .r C&+ 2 C&+ 2 C&+ .r react' "ith :a in the *re'ence of ether at 1444C to *rod#ce 1( .r C&+ 2 C& L C&+ +( C&+ L C L C&+

)(

-( A$$ of the'e

)4.

Which one of the fo$$o"ing a$>ene' "i$$ react fa'te't "ith & + #nder cata$ytic hydrogenation condition'

1(

+(

)(

-(

)1. )+. )). )-. )9.

Which of the fo$$o"ing "i$$ ha e $ea't hindred rotation a!o#t car!on 2 car!on !ond0 1( Ethane +( Ethy$ene )( Aceta$ene -( &e1ach$oroethane :#m!er of mo$e' of 8+ re;#ired for com*$ete com!#'tion of one mo$e of *ro*ane 1( = +( 9 )( 15 -( 14 &o" m#ch o$#me of air needed for com*$ete com!#'tion of 14 $it of ethane 1( 1)9 $it +( )9 $it )( 1=9 $it -( +49 $it Mormation of a$>ane !y action of ?inc and a$>y$ ha$ide i' ca$$ed 1( W#rt? reaction +( Mran>$and reaction )( Corey 2 &o#'e reaction -( C$emmen'on reaction Ei't 2 I Ei't - II A( Sa!atier - 'endren reaction 1( Ei .( W#rt? reaction +( :a C( Mran>$and reaction )( :i 7( Corey 2 &o#'e 'ynthe'i' -( Hn Correct match A . C 7 A . C 7 1( 1 + ) +( ) + 1 )( + ) 1 -( 1 + )