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Phase Diagrams
Need to study phase diagrams to
Understand alloying Explain heat treatments and microstructure Understand solidification
Casting and welding
Definition of a Phase
A homogeneous portion of a system that has uniform physical and chemical characteristics Examples are solid, liquid, gas For a solid, allotropes: eg FCC, BCC, HCP are considered different phases
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Isomorphous is defined as
The liquid and solid region each contain only one phase
Cu-Ni System
Liquid phase is present at all temperatures and compositions above this line
Substitutional solid solution consisting of both Cu and Ni atoms, FCC structure Cu, Ni have nearly identical atomic radii, FCC structure, etc.,..
Melting ends at 1320 C Melt temperature of pure Cu: 1085 Amount of liquid phase increases Melting starts at 1280 C
Definitions
Liquidus Line
Boundary between 100% liquid and the liquid/solid two phase region
Solidus Line
Boundary between 100% solid and the liquid/solid two phase region
DEMO
Overall composition = C0
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W + WL = 1
W C + WL CL = C0
Simultaneous solution of these two equations leads to the lever rule expression for this particular case
WL =
C Co 100 C C L
W =
Co C L 100 C C L
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Equilibrium Cooling
Very slow cooling Continuous readjustment of compositions in both phases Compositions from tieline Amount of solid and liquid at given time can be calculated from lever rule
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Non-Equilibrium Cooling
Complete Mixing in Liquid No compositional changes in solid Composition is nonuniform in solid
Coring segregated
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