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[PEE/ Easy]
Q.13 In an NPNtransistor circuit the collector current is 10 mA. If only90%of emitted electron reach the
collector, then
(A) I
B
= 2mA (B) I
C
=1mA (C) I
E
= 11mA (D) I
E
= 9mA
[Semiconductor / Easy]
Q.14 Half lives of two isotopes X and Yof a material are known to be 2 10
9
years and 4 10
9
years
respectively. If a planet was formedwithequal number of these isotopes, estimate the current age of the
planet, giventhat currentlythe material has 20%of Xand 80%of Ybynumber.
(A) 2 10
9
years (B) 4 10
9
years (C) 6 10
9
years (D) 8 10
9
years
[Radio / Tough]
XII Part Test-8 Page # 4
Q.15 For what value of the quantumnumber n will the de broglie wavelength of an electronin the hydrogen
atombe 4ta
0
? {a
0
=radius of electron in ground state}
(A) 1 (B) 2 (C) 3 (D) 4
[Bhor / Moderate]
Q.16 Acertain radio nuclide starts getting produced at a constant rate = 10
4
s
1
by some mechanismat a
certain moment t = 0. At this moment, there are already10
5
number of radio-nuclides present in the
sample. The mean life of the radionuclide is 20 seconds. At t =40 sec, what will be dN/dt, rounded to
the nearest whole number? [Given that e
2
=7.4]
(A) 375 /s (B) +676 /s (C) 676 /s (D) + 762 /s
[Radio / Tough]
Q.17 The K, Land Menergylevels of platinumlie roughlyat 78, 12, and 3 KeVrespectively. The ratio of
wavelength of K
o
line tothat of K
|
line inX-rayspectrumis
(A)
3
22
(B)
22
3
(C)
25
22
(D)
22
25
[X-Rasy / Moderate]
Q.18 Abeamof 5 keVo-particles and a beamof 5 keVelectrons are absorbed by a target. The two beams
deliver equal amounts of energyto the target per second.
If
electron of mass
particle of mass o
= 7.2710
3
, what is the value of
electron to due target on pressure
particle - to due target on pressure o
?
(A) 1.38 10
4
(B) 1.17 10
2
(C) 1.45 (D) 85.3
[Bhor / Tough]
Q.19 If the potential difference applied across a Coolidge tube is increased :
(A) the wavelengthof the K
o
linewill increase
(B) the wavelength of the K
|
line will decrease
(C) the difference inwavelength between the K
o
and K
|
will decrease
(D) none of these
[X-Rasy / Easy]
Q.20 In a reverse biased p-n junction, almost nocurrent flows because
(A) Electrons and holes recombine before theycan cross the junction
(B) Onlyminoritycarriers, whose densities are verysmall, contributeto the current, whentheycross the
junction
(C) The electric fieldinthe neutral regions is verysmall
(D)All the applied voltage appears across the ohmic contacts
[Semiconductor / Easy]
XII Part Test-8 Page # 5
Q.21 AnLEDis made fromsemiconductingmaterial havinga bandgapof 1.1eV. What typeof radiationdoes
theLEDemit?
(A) Ultraviolet (B) Bluelight (C) Red light (D) Infrared
[PEE/ Easy]
Q.22 The Davisson-Germer experiment that first demonstrated the wave nature of matter used electrons
accelerated to 54V. Determine the wavelengthof the electrons inthe Davisson-Germer experiment.
(A) 1.67 (B) 1.21 (C) 3.45 (D) 5.21
[Bhor / Easy]
Q.23 Thehalf life Po-218is 3minutes. What fractionof a 10gramsampleof Po-218will remainafter 15min?
(A) 1/32 (B) 1/64 (C) 1/25 (D) 1/15
[Radio / Moderate]
Q.24 A1KWsignal is transmitted usinga communicationchannel whichprovides attenuationat therate of
2dBper km. If the communicationchannel has a total lengthof 5km, the power of thesignal receivedis
(A) 900 W. (B) 100 W. (C) 990 W. (D) 1010 W.
[Communication / Moderate]
Q.25 In Fig. assuming the diodes to be ideal,
(A) D
1
is forward biased and D
2
is reverse biased and hence current flows fromAto B
(B) D
2
is forward biased and D
1
is reverse biased and hence no current flows from B toAand vice
versa.
(C) D
1
and D
2
are both forward biased and hence current flows fromAto B.
(D) D
1
and D
2
are both reverse biased and hence no current flows fromAto Band vice versa.
[PNJuncation / Easy]
Q.26 Acertain metal has a workfunction |. If light of wavelength shines on this metal, the photoelectrons
have a maximumkineticenergyK. What will be their maximumkinetic energyif light of wavelength2
shines onthe metal ?
(A) (K + |) / 2 (B) (K |) / 2 (C) 2K (D) K / 2
[PEE/ Moderate]
XII Part Test-8 Page # 6
Q.27 Fig.shows Zener diode witha breakdownvoltage of 40Vconnectedto100V D.C. source witha series
resistance R
S
and a loadresistor (R
L
). Find the output voltage across R
L
.
(A) 40V (B) 20V (C) 50V (D) 60V
[Semiconductor / Easy]
Q.28 The figure shows energy levels of a certain atom. When the ystem moves from level 2E to E, a
photon of wavelength is emitted. The wavelength of photon produced during its transition from
level 4/3E to E level is
(A) 3 (B)
3
4
(C)
4
(D) 2
[Bhor / Moderate]
Q.29 90%of the active nuclei present ina radioactive sample are found to remain undecayedafter 1day. The
percentage of the undecayed nuclei left after two days will be :
(A) 85% (B) 81% (C) 80% (D) 79%
[Radio / Moderate]
Q.30 In a photoelectric effect measurement the stopping potential for a given metal is found to be V
0
Volts
whenradiationof wavelength
0
is used. If radiationof wavelength2
0
is usedwithsame metal, thenthe
stoppingpotential will be observedtobe (Where symbols have their usual meaning)
(A) V
0
/2 (B) V
0
+
e 2
hc
(C) 2V
0
(D) V
0
e 2
hc
[PEE/ Tough]
XII Part Test-8 Page # 7
Q.31 The work done in adiabatic compression of 2 moles of ideal monoatomic gas against 2 atm
external pressure if initially temperature and pressure is 300 K and 1 atm.
(A) 360 cal (B) 720 cal (C) 800 cal (D) 1000 cal
[Thermodynamics\Easy]
Q.32 What will be the maximum amount of heat released, when 321gm of a mixture of Fe
2
O
3
and
Al is subjected to sparking in absence of air?
AH
f
Fe
2
O
3
= 199kJ/mole AH
f
Al
2
O
3
= 399kJ/mole
(A) 200 kJ (B) 300 kJ (C) 400 kJ (D) 100 kJ
[Thermochemistry\Easy]
Q.33 What will be the value of resonance energy of N
2
O if
AH
BDE
N = N = 400 kJ/mol ;
o
f
H A
N
2
O = 100 kJ mol
1
AH
BDE
N N = 950 kJ/mol ; AH
BDE
N = O = 600 kJ mol
1
AH
BDE
O = O = 500 kJ/mol
(A) 200 kJ / mol (B) 150 kJ / mol (C) 100 kJ / mol (D) 50 kJ / mol
[Thermochemistry\Easy]
Q.34 ' ' for NH
3
including contribution from vibrational degree's of freedom is
(A)
3
4
(B)
9
10
(C)
6
7
(D)
12
13
[Thermodynamics\Easy]
Q.35 Total work done in givencyclic process is
(A) Greater than zero (B) Less than zero
P
1/V
(C) Equal to zero (D) Can't determine
[Thermodynamics\Easy]
Q.36 For the real gas reaction,
2SO
2
(g) + O
2
(g) 2SO
3
(g) AH = 440 kJ/mol
If the reaction is carried out in 10 litre rigid vessel the initial pressure is 50 bar which decreases
to 20 bar in the course of reaction. The change in internal energy for the reaction is
(A) 437 kJ (B) 410 kJ (C) 443 kJ (D) 470 kJ
[Thermodynamics\Easy]
XII Part Test-8 Page # 8
Q.37 For the reaction,
2NH
3 (g)
N
2(g)
+ 3H
2(g)
Identify the statement which is not correct.
(A)
o
NH m
o
N m
o
N m
3 2 2
S 2 S 3 S > +
(B) Heat absorbed at constant pressure and temperature will be more as compared to heat
absorbed at constant volume.
(C)
reactant
energy Bond >
product
energy Bond
(D) The value of AG is expected to be negative at extremely low temperatures.
[Thermodynamics\Easy]
Q.38 Which of the following substances will have positive value of AH
formation
?
(A) Br
2
(l) (B) O
3
(g) (C) ZnO(s) (D) H
+
(aq)
[Thermochemistry\Easy]
Q.39 Which of the following option(s) will show a increase in Gibbs free energy?
(A) Combustion of propane at 1 bar and 500K.
(B) Vapourisation of any liquid at 1 atm and above its normal boiling point.
(C) Fusion of H
2
O at 1 atm and 0C if its normal melting point is 0C.
(D) Vapourisation of H
2
O at 100C and 1 bar if its normal boiling point is 100C.
[Thermodynamics\Easy]
Q.40 Which of the options contain correct set of parameters which are both amount and path
independent parameters.
(I) Internal energy
(II) Specific enthalpy
(III) Heat exchange at constant pressure condition
(IV) Molar heat exchange at constant volume condition
(V) Temperature
(VI) Work involved
(A) Only II, IV & V (B) All option except VI
(C) All options except III, IV & VI (D) Only II & V
[Thermodynamics\Easy]
XII Part Test-8 Page # 9
Q.41 Which of the following statements is incorrect?
(A)
A
vap
H H
2
O(l) > 21 373 Cal
(B)
}
= 0
T
q
for all cyclic processes.
(C) Adiabatic reversible process is isoentropic
(D) Heat exchange at constant volume condition will be independent of path.
[Thermodynamics\Easy]
Q.42 Which of the following partial derivatives are incorrect for one mole of an ideal gas?
(A)
T
C
T
S
m , v
V
=
|
.
|
c
c
(B)
P
nR
V
S
T
=
|
.
|
c
c
(C)
V
P
G
T
=
|
.
|
c
c
(D)
0
P
H
T
=
|
.
|
c
c
[Thermodynamics\Easy]
Q.43 A certain mass of a gas is expanded from [2 l, 20 atm, 300K] to [5 l, 10 atm, 320 K] against
a constant external pressure of 5 atm. If heat capacity of the gas is 100 J/C then enthalpy
change of the process will be [1 atm lit. = 100 J]
(A) 2 kJ (B) 0.5 kJ (C) 1.5 kJ (D) 1 kJ
[Thermodynamics\Easy]
Q.44 A heat engine takes up heat at 1000 K and liberates heat at 200 K. Which of the following is
an impossible amount of heat rejected by the engine if 100 J of heat is absorbed.
(A) 60 J (B) 80 J (C) 90 J (D) 15 J
[Thermodynamics\Easy]
Q.45 For which of the following reaction |AH| < |AU| :
(A) C
2
H
6
+
2
7
O
2
2CO
2
+ 3H
2
O at 1bar and 127C
(B) C
6
H
6
(l) C
6
H
6
(g)
(C) N
2
(g) + 3H
2
2NH
3
(g)
(D) C
2
H
4
+ 3O
2
2CO
2
+ 2H
2
O at 1bar and 27C
[Thermochemistry\Easy]
XII Part Test-8 Page # 10
Q.46 Arrange in order of enolic content :
(a) (b)
(c) (d)
(A) c > d > b > a (B) d > c > a > b (C) a > c> d > b (D) b > c > a > d
[Isomerism/Easy]
Q.47 and are
(A) Chain isomers (B) Metamers (C) Positional isomers (D) Conformers
[Isomerism/Easy]
Q.48 Which of the following can not tautomerize?
(A)
O
O
(B)
Ph C C Me
O O
(C)
O
OH
(D)
O O
[Isomerism/Easy]
Q.49 Which of the fiollowing can't show geometrical isomerism?
(A) CH
3
CH=NOH (B)
(C) C = NOH (D) HO N = N OH
[Isomerism/Easy]
XII Part Test-8 Page # 11
Q.50 Molecular formula C
4
H
6
can represent different compounds , one of them can not be
...............
(A) Alkyne (B) Diene
(C) Bicyclo compound (D) Spiro compound
[Isomerism/Medium]
Q.51 + HCN A + B
A & B are
(A) Meso compounds (B) diastereoisomers
(C) enantiomers (D) both A & B
[Isomerism/Medium]
Q.52 How many stereoisomer may have this natural
occuring compound.
(A) 8 (B) 16
(C) 64 (D) 128
[Isomerism/Difficult]
Q.53 Which of the following is not the pair of diastereoisomers.
(A)
H H
H H
Cl Cl
Cl Cl
COOH COOH
COOH COOH
and
(B)
H H
H H
CH
3
CH
3
CH
3
CH
3
Me Me
Me Me
and
(C)
and
(D)
H H
H
H
OH OH
OH
OH
Me Me
Me
Me
and
[Isomerism/Medium]
XII Part Test-8 Page # 12
Q.54 Select incorrect statement :
(A) Resonance effects bond length
(B) trans-1-bromo-1,2-difluoro ethene and Z-1-bromo-1,2-difluoro ethene are geometrical isomers
(C) In CH
2
O
O
COH
COH
most acidic H is connected directly to oxygen not on carbon.
(D) Boiling point of
OH
is less than
OH
OH
[Resonance/Difficult]
Q.55 Select correct statement from the following.
(A)
O
O
is having very high resonance energy than
O
O
(B)
CH
3
COOH
is more acidic than
COOH
(C)
CH
2
.
(D)
O
N N N
(D) Order of heat of combustion cis-1,4-bis-(t-butyl) cyclohexane < Trans-1,4-bis-(t-butyl)
cyclohexane
[Hyperconjugation/Difficult]
XII Part Test-8 Page # 13
Q.57 Which of the following reaction will not form aromatic ion.
(A) + aq. AgNO
3
A
(B) + 2K
A
e
(C) + HBr (D) HBF
4
[Hyperconjugation/Difficult]
Q.58 Which of the following orders is/are incorrect?
(A) Basic strength
N
>
N
N
(B) Acidic strength
Cl
|
COOH CH CH
3
>
Cl
|
COOH CH CH
2 2
(C) Stability of carbocation
CH
2
NO
2
<
CH
2
CH
3
[Resonance/Difficult]
XII Part Test-8 Page # 15
Q.61 In how many ways can a committee be formed of 5 members from 6 men and 4 women if the
committee has at least one woman ?
(A) 186 (B) 246 (C) 252 (D) None of these
[Permutation and Combination / Easy]
Q.62 A vector whose modulus is
51
and makes the same angle with
3
k
2 j
2 i
a
+
=
,
5
k
3 i
4
b
=
and
j
c =
, will be
(A)
k
5 i
5 + +
(B)
k
5 j
5 +
(C)
k
5 j
5 + +
(D)
( ) k
5 j
5
[Vector / Difficult]
Q.63 The exponent of 3 in 100! is
(A) 12 (B) 24 (C) 48 (D) 96
[Permutations and Combinations/ Moderate]
Q.64 The edges of a parallelopiped are of unit length and are parallel to non-coplanar unit vectors
c , b , a
such that
a b a
=
c b c
=
= 1/2. Then the volume of the parallelopiped is
(A)
2
1
(B)
2 2
1
(C)
2
3
(D)
3
1
[Vector / Moderate]
Q.65 The points with position vectors
j
52 i
a , j
8 i
40 , j
3 i
60 +
are collinear if
(A) a = 40 (B) a = 40 (C) a = 20 (D) none of these
[Vector / Easy]
Q.66 All possible three digits even numbers which can be formed with the condition that if 5 is one
of the digit, then 7 is the next digit is :
(A) 5 (B) 325 (C) 345 (D) 365
[Permutations and Combinations / Moderate]
XII Part Test-8 Page # 16
Q.67 Given
k
2 i
b , k
a + + = + =
and
k
2 i
c + =
+ b
and b
+ c
is
(A)
6
k
2 + +
(B) j
(C) k
(D)
3
k
+ +
[Vector / Moderate]
Q.68 Let the value of p
= b ) 1 y x 2 ( a ) y 4 x (
+ + + + and q
= b ) 1 y 3 x 2 ( a ) 2 x 2 y (
+ + . where
a
and b
a + + =
, k
4 j
3 i
4 b + + =
and k
c | + o + =
= 3 then
(A) o = 1, | = 1 (B) o = 1, | = 1
(C) o = 1, | = 1 (D) o = 1, | = 1
[Vector / Moderate]
Q.70 Avector a
= (y, 2z,
3x) and c
+
2 2 2 2
BD AC BC AD
then the value of K is
(A) 2 (B)
3
1
(C)
2
1
(D) 1
[Vector /Easy]
Q.74 If
b a
and
d c
= 4,
c b
= 9 then is equal to
(A) 2 (B) 3 (C) 6 (D) 36
[Vector / Easy]
Q.75 A 5 digit number divisible by 3 is to be formed using the numerals 0, 1, 2, 3, 4 & 5 without
repetition. The total number of ways this can be done is :
(A) 3125 (B) 600 (C) 240 (D) 216
[Permutations and Combinations / Difficult]
Q.76 Given a parallelogram ABCD. If | AB |
= a , | AD |
= b & | AC |
= c , then DB AB
. has the
value
(A)
3
2
2 2 2
a b c +
(B)
a b c
2 2 2
3
2
+
(C)
a b c
2 2 2
3
2
+
(D) none
[Vector / Difficult]
Q.77 If ) k
( a + =
, ) k
( b + =
, and c
and
coplanar with a
and b
perpendicular to both a
and
c
is
(A)
) k
2 (
6
1
+
(B)
) k
(
2
1
+
(C)
) k
2 i
(
6
1
+
(D)
) k
(
2
1
+
=
2
3 y
=
1
2 z +
and the point (0, 7, 7)
is
(A) x + y + z = 1 (B) x + y + z = 2 (C) x + y + z = 0 (D) none of these
[ 3-D/ Moderate]
Q.81 Let P(3, 2, 6) be a point in space and Q be a point on the line
) k
5 j
3 ( ) k
2 j
( r + + + + =
.
Then the value of for which the vector
PQ
is parallel to the plane x 4y + 3z = 1 is
(A)
4
1
(B)
4
1
(C)
8
1
(D)
8
1
[3-D/ Moderate]
Q.82 Equation of a plane which passes through the point of intersection of lines
3
1 x
=
1
2 y
=
2
3 z
and
1
3 x
=
2
1 y
=
3
2 z
and at greatest distance from the origin is
(A) 7x + 2y + 4z = 54 (B) 4x + 3y + 5z = 50
(C) 3x + 4y + 5z = 49 (D) x + y + z = 12.
[ 3-D / Difficult]
Q.83 If the points (2 x, 2, 2), (2, 2 y, 2) (2, 2, 2 z) and (1, 1, 1) are coplanar, then
(A)
1
z
1
y
1
x
1
= + +
(B) x + y + z = 1
(C)
1
1 z
1
1 y
1
1 x
1
=
and c
become same.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for
statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation
for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
[Vector / Easy]
Q.85 If ) b a ( c ) a c ( b ) c b ( a d
+ + = , then
(A)
d
+ + =
(C) 0 d =
(D) c , b , a
and d
are coplanar..
[Vector Algebra / Easy]
Q.86 If
a b c + +
= 0 ,
a = 3 ,
b = 5 ,
c = 7 , then the angle between
a b & is :
(A) 6 t (B) 3 2t (C) 3 5t (D) 3 t
[Vector / Moderate]
Q.87 The number of ways in which we can get a score of 11 by throwing three dice is
(A) 18 (B) 27 (C) 45 (D) 56
[Permutations and Combinations /Moderate]
Q.88 Vector equation of the line 6x 2 = 3y + 1 = 2z 2 is
(A) r =
) k
( k
+ + +
(B) r =
|
.
|
\
|
+ + + + k
3
1
i
3
1
k
3 j
2 i
(C) r = ( ) k
3 j
2 i
3
1
i
3
1
+ + + + (D) r = ( ) k
2 j
3 i
6 k
2 j
2 + + + +
where is a parameter
[3-D / Moderate]
XII Part Test-8 Page # 20
Q.89 Statement-1 : Astudent is allowed to select at most n books from a collection of (2n + 1)
books. If the total number of ways in which he can select at least one book is
255, then n = 3.
Because
Statement-2 : |
.
|
\
| +
0
1 n 2
+ |
.
|
\
| +
1
1 n 2
+ + |
.
|
\
| +
n
1 n 2
= 4
n
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
[Permutations and Combinations / Difficult]
Q.90 Consider the planes
P
1
: x y + z = 1
P
2
: x + y z = 1
P
3
: x 3y + 3z = 2
Let L
1
, L
2
, L
3
be the lines of intersection of the planes P
2
and P
3
, P
3
and P
1
, and P
1
and P
2
respectively.
Statement-1 : At least two of the lines L
1
, L
2
and L
3
are non-parallel.
Statement-2 : The three planes do not have a common point.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for
statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation
for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
[3-D / Moderate]
XII Part Test-8 Page # 21
ANSWERKEY
PHYSICS
Q.1 D
Q.2 A
Q.3 A
Q.4 B
Q.5 C
Q.6 B
Q.7 A
Q.8 B
Q.9 B
Q.10 A
Q.11 B
Q.12 C
Q.13 C
Q.14 D
Q.15 B
Q.16 B
Q.17 D
Q.18 D
Q.19 D
Q.20 B
Q.21 D
Q.22 A
Q.23 A
Q.24 B
Q.25 B
Q.26 B
Q.27 A
Q.28 A
Q.29 B
Q.30 D
MATHEMATICS
Q.61 B
Q.62 D
Q.63 C
Q.64 A
Q.65 A
Q.66 D
Q.67 C
Q.68 B
Q. 69 D
Q. 70 C
Q.71 C
Q.72 C
Q.73 C
Q.74 C
Q.75 D
Q.76 A
Q.77 B
Q.78 A
Q.79 B
Q.80 C
Q.81 A
Q.82 B
Q.83 A
Q.84 A
Q.85 C
Q.86 D
Q.87 B
Q.88 C
Q. 89 D
Q.90 D
CHEMISTRY
Q.31 B
Q.32 B
Q.33 C
Q.34 B
Q.35 B
Q.36 B
Q.37 D
Q.38 B
Q.39 C
Q.40 A
Q.41 B
Q.42 B
Q.43 C
Q.44 D
Q.45 A
Q.46 A
Q.47 B
Q.48 A
Q.49 C
Q.50 D
Q.51 B
Q.52 C
Q.53 B
Q.54 B
Q.55 B
Q.56 B
Q.57 C
Q.58 D
Q.59 A
Q.60 C
XII Part Test-8 Page # 22
SOLUTION
SOLUTION
Q.1
B
A
B A+
B
C B B A = +
0 T
0
C =
) 1 . 1 1 ( +
= 0
T
0
2T
0
C =
) 1 . 1 1 ( +
= 0
2T
0
C =
) 0 . 0 1 ( +
= 0
Q.2
meV 2
h
c
=
photon
hc
eV
=
Q.3
hc
= | + c . (3v
0
) in case I
2
hc
= | + c. v
0
in case II
where
0
hc
= | (
0
threshold wavelength)
Q.4 Toovercome coulomb repulsion .
Q.5 e =
LC
1
=
2 6 6
10 10 10
1
= 10
7
f =
t 2
10
7
=
7
8
10
10 3
2t = 60t
Q.6 The basic equationof diode-circuit is
RI + V
0
= V
B
R =
I
V V
0 B
V =
B
1.5V
V =RI
R
V
0
R
Here V
B
= 1.5V, V
0
= 0.3V, I = 5mA= 6 10
3
A
R =
6
10 2 . 1
10 6
3 . 0 5 . 1
3
3
=
\
| t
v
r 2
e
magnetic moment =Itr
2
angular momentum=mvr
ratio =
m 2
e
Q.9 InformationBased.
Q.10 =
u
c
cv
c
Q.11 Number of nucleus decreases as deviation angle increases.
Q.12
hc
>
0
hc
s
0
Q.13 10% of I
E
= I
B
I
B
= 1mA
I
E
= I
C
+ I
B
= 10 + 1 = 11 mA
Q.14 Let total sumof number of isotopes at the formation of the planet was No and currentlyis N
N
x
=
|
|
.
|
\
|
2
N
0
t
1
e
= 0.2 N ....(i)
N
y
=
|
|
.
|
\
|
2
N
0
t
2
e
= 0.1 N ....(ii)
Dividingequation(ii) by(i)
t )
( 2 1
e
= 4
(
1
2
) t = ln 4
t
4
1
2
1
10
2 ln
9 (
= 2 ln2
t = 8 10
9
years
Q.15 2tR = n
2tn
2
a
0
= n n = 2
Q.16
N r
dt
dN
=
} }
=
t
0
N
N
dt
N r
dN
0
ln
0
N r
N r
= t
(r N) = (r N
0
)e
t
dt
dN
= r N = (r N
0
) e
t
=
20 / t
5
4
e
20
10
10
|
|
.
|
\
|
= 5000e
2
= 5000/7.4 = + 676 per second Ans.
XII Part Test-8 Page # 24
Q.17
1
hc
= 78 12
3 78
hc
2
=
2
1
=
22
25
Q.18 If nparticles each with mass mand speed vcollide inelasticallywith the target per sec.
then rate of energytransfer =n
.) E . K ( n mv
2
1
2
=
and Rate of momentumtransfer =n mv =n ) KE ( m 2
Since both beamtransfer equal energy, n
1
(KE)
1
= n
2
(KE)
2
, but KE
1
= KE
2
n
1
= n
2
ratio of momentumtransferred =
2 2 2
1 1 1
) KE ( m 2 n
) KE ( m 2 n
=
2
1
m
m
=
7270
Q.19 K
o
or K
|
characteristics
Q.20 InformationBased
Q.21 =
E
hc
=
1 . 1
1240
nm~ 1100 nminfra red.
Q.22 l =
mv
h
=
km 2
h
=
31 19
34
10 1 . 9 10 6 . 1 54 2
10 63 . 6
2
1
mv
2
= k
Q.23 15 min is 5times of 3 min 5 half lite 1 fraction left =
32
L
2
1
5
=
|
.
|
\
|
Q.24 gain in dB=10 log
|
|
.
|
\
|
t
0
P
P
Q.26
hc
|, K' =
|
2
hc
=
|
| +
2
K
=
2
K |
Q.28 2E E =
hc
3
E 4
E =
hc
' = 3
Q.29 Decay in 1 day is 10%1 decay in second day =
9 90
100
10
=
1 nuclei left = 100 10 9 = 81.
Q.30 eV
0
=
|
0
hc
|
=
0
2
hc
' eV ( )
0
0
2
hc
' V V e
=
V' = V
0
=
e 2
hc
XII Part Test-8 Page # 25
SOLUTION
Q.31 For adiabatic irreversible process
nC
v,m
(T
2
T
1
) = P
ext
(V
2
V
1
)
= P
ext
|
|
.
|
\
|
1
1
2
2
P
nRT
P
nRT
2
2
3
R (T
2
300) = 2
|
.
|
\
|
1
300 R 2
2
RT 2
2
T
2
= 420K
W = AU = nC
v,m
(T
2
T
1
)
= 2
2
3
R (420 300)
= 720 cal
Q.32 Fe
2
O
3
+ 2Al Al
2
O
3
+ 2Fe (s)
AH = 399 + 199 = 200 kJ
AH = 200 1.5 = 300 kJ
Q.33 N (g) + O (g)
2 2
N O(g)
2
2
1
2
1
AH (N O,g)
f 2
atoms
BDE
N N
BDE
O=O
+
(RE + BE + BE )
N=N N=O
N O
2
AH
f
(N
2
O,g) = BDE
NN
+
2
1
BDE
O=O
[
O N
2
RE + BE
N=N
+ BE
N=O
]
100 kJ = 950 +
2
1
500 [
O N
2
RE + 400 + 600]
100 kJ = 1200 kJ
O N
2
RE 1000
O N
2
RE = 100 kJ / mole
Q.34 C
v
=
R n R
2
n
R
2
n
vib
rot tr
+ +
=
R 9 R 6 R
2
3
R
2
3
= + +
C
p
= 9R + R = 10R
=
9
10
C
C
V
P
=
XII Part Test-8 Page # 26
Q.35 TCyclic process will be clockwise whenPplotted against V.
Hence work done is negative.
P
V
Q.36 For constant volume process
AH = AU + VAP
AU = AH VAP
= 440 kJ 10 10
3
(20 50) 10
5
10
3
kJ
= 410 kJ
Q.37 2NH
3 (g)
N
2(g)
+ 3H
2(g)
(1) AS
rxn
> 0
AS
rxn
=
0 ] S 2 [ ] 3 S S [
3
NH
2
H
2
N
M M M
> +
3
NH
2
H
2
N
M M M
S 2 2 S S > +
(2) Process is endothermic
AH = +ve
An
g
= 2
AH = AU + An
g
RT
(3) AH
rxn
> 0
AH =
product of E B t tan ac Re of E B > 0
=
> product of E B t tan ac Re of E B
(4) AG = AH TAS
AH, AS = +ve
AG < 0 at high temperature.
Q.38 AH
formation
of element in nature state is zero.
AH
f
of O
3
is endothermic
AH
f
of ZnOis exothermic &AH
f
of AH
+
(aq)
is zero.
Q.39 AG = AH TAS
(i) Combustion is spontaneous reaction so AHis ve as AH> TAS
(ii) AGis ve for vaporisation above boiling point as TAS>AH
(iii) AGis +ve for fusion at 0Cas AH= +ve and AS = ve
(iv) AG is ve as AS = +ve & AH = +ve but TAS > AH
Q.40 II, IV&Vare intensive and path independent properties. Internal energy, AHdepends on amount and
wdepends on amount as well as path dependent.
Q.41 (B) is incorrect
}
= 0
T
q
rev
for all cyclic process.
XII Part Test-8 Page # 27
Q.42 dS =
T
PdV dT nC
m , v
+
P
nR
T
P
V
S
T
= =
|
.
|
c
c
Q.43 q = CAT = 10 20 = 2000 J
AU = q + w
AU = 2000 5 3 100 = 500 J
AH = AU + A(PV)
= 500 + 10 100 = 1500 J
Q.44 q = 80% = (
2
1 2
T
T T
in [D] q=85%which is more than q
reversible process
it is not possible.
Q.45 (1) AH = AU + An
g
RT
ve ve + 0.5 RT
(2) AH AU + An
g
RT
+ve = +1 +1 RT
(3) N
2
+ 3H
2
2NH
3
Ax = AU + An
g
RT
ve = ve ve
(4) C
2
H
4
+ 3O
2
2CO
2
+ 2H
2
O(l)
Ax = AU + An
g
RT
ve = ve ) (3)
Q.46 With increase inacidityof oHandstabilityof enol formed its %content increases.
Q.47 Structures of given compound are MeOCH
2
Et and EtOCH
2
Me so metamers.
Q.49 Not required
Q.50 Molecular formula C
4
H
6
D. B. E. 2
Possibility2tbond
or 1t bond &1 ring
or 2ring
XII Part Test-8 Page # 28
Q.51
HCN
+
ThusA&Bare diastereoisomers.
Ans: B
Q.52
Q.53 (A)
H
H
H
H
Cl
Cl
Cl
Cl
COOH
COOH
COOH
COOH
Cl
Cl
Cl
Cl
H
H
H
H
COOH
COOH
COOH
COOH
Diastereoisomers
(B) Chiral carbonis not present
(C)
and
Geometrical isomers are diastereoisomers.
(D)
H
H
H
H
H
H
H
HO
HO H
OH
OH
OH
OH
OH
OH
Me
Me
Me
Me
Me
Me
Me
Me
H
H
H
H HO
OH
OH
OH
Me
Me
Me
Me
Diastereoisomers]
XII Part Test-8 Page # 29
Q.54 (A) Resonance effect bondlength
(B)
C = C
F
Br
H
F
cis-1-bromo-1,2
difluoro ethene
C = C
F
Br F
H
Z-1-bromo-1, 2
difluoro ethene
Identical
(C)
CH
2
COOH
COOH
most acidic (eq. R.S.)
(D)
OH
B.P.
OH
OH
Q.55 (A) Ester group resonancewi th i tsel f i n abetter way not to other so both have~same resonance
energy.
(B) Due to Ortho effect.
(C) Negative onmore electronegative element is more stable.
(D) Equivalent R.S. are more stable thanunequivalent R.S.
Q.56
is less stable than so having higher heat of hydrogenation
Hence 'A' is incorrect.
Heat of combustion of cyclo alkanes increases fromcyclohexane (Higher No. of Catom) to cyclo
propane hence Bis correct.
Stabilityof Carbocation.
N N
N
Resonance
Stabilise
Less
I effect
Higher
I effect
>
>
+
+
+
Hence Cis incorrect.
Stabilityorder of disubstituted cyclohexane are is givenas
H
H
H H
tBu
>
tBu
tBu tBu
So Dis incorrect.
XII Part Test-8 Page # 30
Q.57 (A) + aq. AgNO
3
A
Ph
Ph
Ph
Ph
Aromatic
(B) + 2K
A
Aromatic
(C) + HBr
OH
Antiaromatic
(D) HBF
4
OH
OH
Aromatic
Q.58 (A)
N
+ I,
N
N
I of N
(B)
Cl
|
COOH CH CH
3
more (I),
Cl
|
COOH CH CH
2 2
Less (I)
(C)
CH
2
NO
2
more (I),
CH
2
CH
3
more (+I),
(D)
COOH
|
) CH (
|
COOH
3 2
COOH
|
COOH
more I.
Q.59 Stabilityof carbocation:
C H CH
6 5 2
CH = CH CH
2 2
Dancing
Resonance
More
delocalisation
XII Part Test-8 Page # 31
Basic strength:
NH
2
N
H
5 RS
6 RS
Less available
for donation
Q.60 (A) Stabilityof free radical :
CH
2
CH
3
CH CH
2 2
>
More delocalisation
(B) Stabilityof carbanion :
2 3 2
H C CH H C CH C HC
> = >
ve on more EN
More stable
(D) Stabilityof resonantingstructures :
< CH C H
2
CH = C H
2
O O
ve on more EN
More stable
XII Part Test-8 Page # 32
SOLUTION
Q.61 The number of ways can be deduce as follows :
1 women and 4 men =
4
C
1
6
C
4
= 60
2 women and 3 men =
4
C
2
6
C
3
= 120
3 women and 2 men =
4
C
3
6
C
2
= 60
4 women and 1 men =
4
C
4
6
C
1
= 6
Required number of ways = 60 + 120 + 60 + 6 = 246 Ans.
Q.62 Let, the required vector be o = k
d j
d i
d
3 2 1
+ + , where
51 d d d
2
3
2
2
2
1
= + + , (given) .........(i)
Now, each of the given vectors
c , b , a
is a unit vector
cos u =
| a | | d |
a d
=
| b | | d |
b d
=
| c | | d |
c d
or
a d
=
b d
=
c d
| d |
= 51 cancels out and | c | | b | | a |
= = = 1
Hence,
3
1
(d
1
2d
2
+ 2d
3
) =
4
1
( 4d
1
+ od
2
3d
3
) = d
d
1
5d
2
+ 2d
3
= 0
and 4d
1
+ 5d
2
+ 3d
3
= 0
On solving,
5
d
1
d
5
d
3 2 1
=
= (say)
Putting d
1
, d
2
and d
3
in (i), we get = 1
Hence, the required vectors are
( ) k
5 j
5
. Ans.
Q.63
(
+
(
+
(
+
(
4 3 2
3
100
3
100
3
100
3
100
= 33 + 11 + 3 + 1 = 48. Ans.
Q.64 (Volume)
2
=
| | c b a
| | c b a
=
c c c b c a
b c b b b a
c c a b a a
=
1 2 / 1 2 / 1
2 / 1 1 2 / 1
2 / 1 2 / 1 1
=
2
1
. Ans. Ans.
XII Part Test-8 Page # 33
Q.65 Denoting a
, b
, c
= K( b
)
a 60 = 20K and 55 = 11 K
a = 100 + 60 = 40
Q.66 5 + 8.9.5 = 365; 1
st
place is five + where 1
st
place is not five 7 5
|
5
+
5
|
9
|
8
|
Q.67 ( a
+ b
) ( b
+ c
) = 3 j
(2 i
+4 j
) = 6 k
.
Q.68 Here, b ) 3 y 3 x 6 ( a ) y 12 x 3 ( p 3
+ + + + =
b ) 2 y 6 x 4 ( a ) 4 x 4 y 2 ( q 2
+ + =
On comparing, we get
3x + 12y = 2y 4x + 4 & 6x + 3y + 3 = 4x 6y 2
7x + 10y = 4 .........(i)
and 2x + 9y = 5 .........(ii)
On solving equations, we get x = 2, 1. Ans.
Q.69 | | c b a
= 0
| o 1
4 3 4
1 1 1
= 0 or 1 | = 0 | =1
Also | c |
= 3 1 + o
2
+ |
2
= 3 Ans.
Q.70 Since a
is perpendicular to d
, so x y + 2z = 0 (i)
Moreover , | b
| = | c
| so a
= a
as a
and c
.
Thus xy 2yz + 3xz = 2xz + 3xy yz
xz 2xy yz = 0 (ii)
Also x
2
+ y
2
+ z
2
= 12 (iii)
and y < 0, Substituting the value of y from (i) in (ii) we get x
2
+ 2xz + z
2
= 0 so x = z
and y = z. Again substituting these value (iii) we get z
2
= 4 i.e. z = 2 but y < 0 and y
= iz.
So z = 2 = y and x = 2
XII Part Test-8 Page # 34
Q.71 Subtracting the first two equations we get y z = 4. From the third we get x + z = 3 which
are satisfied by (2, 5, 1).
Q.72 The total number of possible outcomes is 6
4
.
The number of possible outcomes in which 2 does not appear on any die is 5
4
.
Therefore, the number of possible outcomes in which atleast one die shows a 2 is
6
4
5
4
= 1296 625 = 671.
Q.73 Let A be the origin of reference and the position vector of B, C, D be d , c , b
, w.r.t. A. So
AB= b
, CD = c d
, AD= d
, BC = b c
, c AC
= and
b d BD
=
. The L.H.S. is equal
to ) c d ( b
. The R.H.S. is
| |
2 2 2
| b d | | c | | b c | | d | K
+ = | | b d 2 b b d d c c b c 2 b b c c d d K
+ + +
= 2K| | ) c d ( b
.
Hence K =
2
1
Q.74 We know that
) b a (
) d c (
=
d b c b
d a c a
9
4
=
2
36.
since
b a
and
d c
a b a . i.e.
a
2
a b .
(1)
now
a b c + =
a b
2
2
+ + 2
a b . =
c
2
(2)
substitute the value of
a b .
from (2) in (1) ]
XII Part Test-8 Page # 35
Q.77 Let
k
z j
y i
x c + + =
. Since
c , b , a
are coplanar,,
so
1 1 1
1 1 1
z y x
= 0 0 x 2y 2z = 0
Also
c
is perpendicular to
a
, so x + y z = 0.
Therefore
1
z
1
y
2
x
= =
and x
2
+ y
2
+ z
2
= 1
(
c
2 (
6
1
c + =
and
1 1 2
1 1 1
k
| c a | 6
1
c a
c a
1
d
=
) k
(
2
1
) k
3 j
3 i
0 (
| c a | 6
1
+ = + +
Q.78 No. of ways in which 6 men can be arranged at a round table = (6 1)! = 5! ways
Now women can be arranged in 6! ways
Total number of ways = 6! 5! Ans.
Q.79 u = cos
1
(
+
9 50
10 4 6
= cos
1
(0) =
2
t
. Ans.
Q.80 The equation of plane containing the line
3
1 x
+
=
2
3 y
=
1
2 z +
is a(x + 1) + b(y 3) + c(z + 2) = 0 .........(1)
where 3a + 2b + c = 0 ..........(2)
This passes through (0, 7, 7)
a + 4b 5c = 0 ........(3)
XII Part Test-8 Page # 36
From equation (2) and (3),
14
a
=
14
b
=
14
c
or
1
c
1
b
1
a
= =
Thus, the required plane is
x + y + z = 0. Ans.
Q.81 Let O be the origin, as Q lies on the given line,
OQ
=
) k
5 j
3 ( k
2 j
+ + + +
.
Also OP =
k
6 j
2 i
3 + +
. As PQ is parallel to the plane x 4y + 3z = 1.
PQ
) k
3 j
4 i
( +
= 0
( ) OP OQ ) k
3 j
4 i
( + = 0
(1 + 4 + 6) + ( 3 4 + 15) (3 8 + 18) = 0
11 + 8 13 = 0 =
4
1
. Ans.
Q.82 Any point on the first line is P(3 + 1, + 2, 2 + 3) and on the second line is
Q( + 3, 2 + 1, 3 + 2) P and Q represent the same point if = = 1 and the point of
intesection of the given lines is P(4, 3, 5) . The planes given is (a), (b), (c) and (d) all pass
through P. The plane at greatest distance is one which is at a distance equal to OP from the
origin. So the distance of the plane from the origin is
2 2 2
5 3 4 + +
=
50
which is satisfied
by the plane in(b). Ans.
Q.83 Given points are coplanar,
1 z 2 2 2
1 2 y 2 2
1 2 2 x 2
1 1 1 1
= 0
(Volume of the tetrahedron with given vertices is zero)
0 z 1 1 1
0 1 y 1 1
0 1 1 x 1
1 1 1 1
= 0
z 1 1 1
1 y 1 1
1 1 x 1
= 0
XII Part Test-8 Page # 37
z 0 x
0 y x
1 1 x 1
= 0
(
1 3 3
1 2 2
R R R
R R R
x(0 + y) z (y + xy x) = 0
xy + yz + zx = xyz
1
z
1
y
1
x
1
= + +
Q.84 If the lines have a common point then there exists and such that
6 = 1 + and 1 + 2 = 1 + 3
= 3, = 2
Q.85
) c b ( a
=
c ) b a ( b ) c a (
) a c ( b
=
a ) b c ( c ) a b (
) b a ( c
=
b ) a c ( a ) b c (
Q.86
a b c + = Square
a b a b
2
2
2 + + . =
c
2
cos u =
c a b
a b
2 2
2
2
Q.87 Coefficient of x
11
in (x + x
2
+ ... + x
6
)
3
= coefficient of x
8
in (1 x
6
)
3
(1 x)
3
= coefficient of x
8
in (1 3x
6
) (1 +
3
C
1
x +
4
C
2
x
2
+ ...)
=
10
C
8
3(
4
C
2
) = 27
Q.88 The line can be written as
1
3 / 1 x
=
2
3 / 1 y +
=
3
1 z
which passes through the point whose
position vector is k
3
1
i
3
1
+
|
.
|
\
|
|
.
|
\
|
and is parallel to the vector k
3 j
2 i
3
1
i
3
1
+ + ( ) k
3 j
2 i
+ + .
XII Part Test-8 Page # 38
Q.89 Let
S = |
.
|
\
| +
0
1 n 2
+ |
.
|
\
| +
1
1 n 2
+ + |
.
|
\
| +
n
1 n 2
(i)
Using
|
.
|
\
|
r
n
=
|
.
|
\
|
r n
n
, we can write (i) as
S =
|
.
|
\
|
+
+
. . +
|
.
|
\
| +
+
|
.
|
\
|
+
+
1 n
1 n 2
n 2
1 n 2
1 n 2
1 n 2
(ii)
Adding (i) and (ii), we get
2S = |
.
|
\
|
+
+
. . +
|
.
|
\
|
+
1 n 2
1 n 2
0
1 n 2
= 2
2n+1
S = 2
2n
= 4
n
The number of ways of choosing r books out of 2n + 1 is
|
.
|
\
| +
r
1 n 2
. We are given
255
n
1 n 2
2
1 n 2
1
1 n 2
=
|
.
|
\
| +
. . +
|
.
|
\
| +
+
|
.
|
\
| +
4
n
1 = 255 4
n
= 256 = 4
4
n = 4 .
Q.90 If l, m, n denote the direction ratios of L
1
then l + m n = 0 and l 3m + 3n = 0
l = 0, m = n direction ratios of L
1
are 0, 1, 1 similarly for L
2
and L
3
, we find that the
direction ratios of both are 0, 1, 1 showing that L
1
, L
2
, L
3
are parallel, thus statement-1 is
false.
Statement-2 is true, because solving the given equations we get x = 0, y z = 1 and
y z = 2/3 which is not possible.